CN111965842A - Hydrophobic contact lens - Google Patents

Hydrophobic contact lens Download PDF

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Publication number
CN111965842A
CN111965842A CN202010808134.1A CN202010808134A CN111965842A CN 111965842 A CN111965842 A CN 111965842A CN 202010808134 A CN202010808134 A CN 202010808134A CN 111965842 A CN111965842 A CN 111965842A
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CN
China
Prior art keywords
contact lens
lens body
hydrophobic
reverse
mold
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Pending
Application number
CN202010808134.1A
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Chinese (zh)
Inventor
张玉林
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Anhui Institute of Information Engineering
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Anhui Institute of Information Engineering
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Publication date
Application filed by Anhui Institute of Information Engineering filed Critical Anhui Institute of Information Engineering
Priority to CN202010808134.1A priority Critical patent/CN111965842A/en
Publication of CN111965842A publication Critical patent/CN111965842A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G02OPTICS
    • G02CSPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00Optical parts
    • G02C7/02Lenses; Lens systems ; Methods of designing lenses
    • G02C7/04Contact lenses for the eyes
    • G02C7/049Contact lenses having special fitting or structural features achieved by special materials or material structures
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/12Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes

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  • Health & Medical Sciences (AREA)
  • Ophthalmology & Optometry (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Eyeglasses (AREA)

Abstract

The invention discloses a hydrophobic contact lens, which is provided with: the contact lens body, the contact lens body is the hemisphere, and the surface of institute's lens body is equipped with the hydrophobic layer, and the hydrophobic layer has rose petal surface microstructure, uses the hydrophobic waterproof layer, does hydrophobic treatment to contact lens body surface, reduces contact lens surface and is infected with water stain or foreign matter, and the contact lens body adopts the hydrophilicity material preparation simultaneously, and the moisture content is high, reduces the injury to eyes.

Description

Hydrophobic contact lens
Technical Field
The invention belongs to the technical field of articles for daily use, and particularly relates to a hydrophobic contact lens.
Background
In the process of implementing the invention, the inventor finds that the prior art has at least the following problems:
contact lenses are worn on the eye and cause some change to the eye. Ophthalmology has only learned that the cornea needs to take up nutrients from the air for normal metabolism, and that once a contact lens is placed in front of the cornea, the cornea is slightly hypoxic because it cannot get enough oxygen from the air. This can lead to a series of pathological changes in the eye, such as mild edema of the corneal epithelium. Contact lenses are prone to water or foreign body contamination that can further damage the wearer's eyes.
Disclosure of Invention
The invention aims to solve the technical problem of providing a hydrophobic contact lens which uses a hydrophobic waterproof layer to perform hydrophobic treatment on the surface of a contact lens body so as to reduce water stains or foreign matters on the surface of the contact lens.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows: a hydrophobic contact lens, having:
the contact lens comprises a contact lens body, wherein the contact lens body is hemispherical, a hydrophobic layer is arranged on the surface of the contact lens body, and the hydrophobic layer is provided with a rose petal surface microstructure.
The rose petal surface microstructure comprises a mastoid structure of 1-5um, and nano-dots which are arranged in disorder are dotted on the surface of the mastoid structure.
The preparation method of the hydrophobic layer comprises the following steps:
1) cleaning a contact lens mold by taking the contact lens mold as a substrate;
2) preparing sol-gel;
3) preparing a reverse template, wherein the reverse template has a structure opposite to the surface microstructure of the rose petals, and is hemispherical and matched with the contact lens body;
4) pouring the sol-gel onto a reverse mold plate by taking the reverse mold as the mold plate, and covering the contact lens mold;
5) and after the sol-gel is solidified, dissolving the counter template to obtain the light trapping contact lens body with the mastoid structure on the surface of the rose petal.
In the step 2), the sol-gel composition comprises:
the polysiloxane monomer accounts for 40-60% of the mass;
hydrophilic monomer, the mass ratio is 20% -30%;
the polysiloxane monomer is trihydroxymethyl aminomethane or polydimethylsiloxane;
the hydrophilic monomer is selected from one or more of 2-hydroxyethyl methacrylate, methacrylic acid, N-vinyl pyrrolidone, polyethylene glycol methacrylate and sulfobetaine methyl methacrylate;
mixing the raw materials to obtain a mixture; and carrying out polymerization reaction on the mixture under the conditions of ultraviolet light or heating to obtain the silicon hydrogel.
In the step 3), water glass is used as a material of the reverse membrane plate, rose petals are fixed at the bottom of the reverse membrane plate mould, and the water glass is poured until the water glass is hardened; then drying the whole soluble mould; and demolding the reverse mold to obtain the reverse mold plate.
After the contact lens body is manufactured, detecting the contact lens body, and detecting the surface appearance structural characteristics of the contact lens body by adopting a scanning electron microscope, wherein when the surface appearance of the contact lens body has a structure similar to a mastoid on the surface of a rose petal and the surface of the mastoid is dotted with nano points, the surface structure of the contact lens body meets the requirements; and detecting the light transmittance of the contact lens body through a light transmittance haze meter.
One of the technical schemes has the advantages that the hydrophobic waterproof layer is used for performing hydrophobic treatment on the surface of the contact lens body, so that water stains or foreign matters on the surface of the contact lens are reduced, and meanwhile, the contact lens body is made of hydrophilic materials, so that the water content is high, and the damage to eyes is reduced.
Drawings
FIG. 1 is a schematic structural view of a hydrophobic contact lens provided in an embodiment of the present invention;
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, embodiments of the present invention will be described in detail with reference to the accompanying drawings.
Referring to fig. 1, a hydrophobic contact lens has:
the contact lens body, the contact lens body is the hemisphere, and the surface of institute's glasses body is equipped with the hydrophobic layer, and the hydrophobic layer has rose petal surface microstructure.
The rose petal surface microstructure comprises a mastoid structure of 1-5um, and the surface of the mastoid structure is decorated with nano-dots which are arranged in disorder.
The preparation method of the hydrophobic layer comprises the following steps:
1) cleaning a contact lens mold by taking the contact lens mold as a substrate;
2) preparing sol-gel;
3) preparing a reverse template, wherein the reverse template has a structure opposite to the surface microstructure of the rose petals, and is in a hemispherical shape matched with the contact lens body;
4) pouring the sol-gel onto a reverse mold plate by taking the reverse mold as the mold plate, and covering the contact lens mold;
5) and after the sol-gel is solidified, dissolving the counter template to obtain the light trapping contact lens body with the mastoid structure on the surface of the rose petal.
In the step 2), the sol-gel composition comprises:
the polysiloxane monomer accounts for 40-60% of the mass;
hydrophilic monomer, the mass ratio is 20% -30%;
the polysiloxane monomer is trihydroxymethyl aminomethane or polydimethylsiloxane;
the hydrophilic monomer is selected from one or more of 2-hydroxyethyl methacrylate, methacrylic acid, N-vinyl pyrrolidone, polyethylene glycol methacrylate and sulfobetaine methyl methacrylate;
mixing the raw materials to obtain a mixture; and carrying out polymerization reaction on the mixture under the conditions of ultraviolet light or heating to obtain the silica hydrogel.
In the step 3), water glass is used as a material of the reverse membrane plate, rose petals are fixed at the bottom of the reverse membrane plate mould, and the water glass is poured until the water glass is hardened; then drying the whole soluble mould; and demolding the reverse mold to obtain the reverse mold plate.
After the contact lens body is manufactured, detecting the contact lens body, and detecting the surface appearance structural characteristics of the contact lens body by adopting a scanning electron microscope, wherein when the surface appearance of the contact lens body has a structure similar to a mastoid on the surface of a rose petal and the surface of the mastoid is dotted with nano points, the surface structure of the contact lens body meets the requirements; and detecting the light transmittance of the contact lens body through a light transmittance haze meter.
After the structure is adopted, the hydrophobic waterproof layer is used for carrying out hydrophobic treatment on the surface of the contact lens body, so that water stains or foreign matters on the surface of the contact lens are reduced, and meanwhile, the contact lens body is made of hydrophilic materials, so that the water content is high, and the damage to eyes is reduced.
The invention has been described above with reference to the accompanying drawings, it is obvious that the invention is not limited to the specific implementation in the above-described manner, and it is within the scope of the invention to apply the inventive concept and solution to other applications without substantial modification.

Claims (6)

1. A hydrophobic contact lens, comprising:
the contact lens comprises a contact lens body, wherein the contact lens body is hemispherical, a hydrophobic layer is arranged on the surface of the contact lens body, and the hydrophobic layer is provided with a rose petal surface microstructure.
2. The hydrophobic contact lens of claim 1, wherein the rose petal surface microstructure comprises 1-5um "papilla" structures interspersed with non-ordered arrangements of nanodots.
3. The hydrophobic contact lens of claim 2, wherein the hydrophobic layer is prepared by a method comprising the steps of:
1) cleaning a contact lens mold by taking the contact lens mold as a substrate;
2) preparing sol-gel;
3) preparing a reverse template, wherein the reverse template has a structure opposite to the surface microstructure of the rose petals, and is hemispherical and matched with the contact lens body;
4) pouring the sol-gel onto a reverse mold plate by taking the reverse mold as the mold plate, and covering the contact lens mold;
5) and after the sol-gel is solidified, dissolving the counter template to obtain the light trapping contact lens body with the mastoid structure on the surface of the rose petal.
4. The hydrophobic contact lens of claim 3 wherein in step 2), the sol-gel composition comprises:
the polysiloxane monomer accounts for 40-60% of the mass;
hydrophilic monomer, the mass ratio is 20% -30%;
the polysiloxane monomer is trihydroxymethyl aminomethane or polydimethylsiloxane;
the hydrophilic monomer is selected from one or more of 2-hydroxyethyl methacrylate, methacrylic acid, N-vinyl pyrrolidone, polyethylene glycol methacrylate and sulfobetaine methyl methacrylate;
mixing the raw materials to obtain a mixture; and carrying out polymerization reaction on the mixture under the conditions of ultraviolet light or heating to obtain the silicon hydrogel.
5. The hydrophobic contact lens as claimed in claim 4, wherein in the step 3), the water glass is used as the material of the reverse membrane plate, the rose petals are fixed at the bottom of the reverse membrane plate mould, the water glass is poured, and the water glass is hardened; then drying the whole soluble mould; and demolding the reverse mold to obtain the reverse mold plate.
6. The hydrophobic contact lens of claim 5, wherein after the contact lens body is manufactured, the contact lens body is inspected and the surface topography and structure characteristics are inspected by scanning electron microscopy, and when the surface topography has a structure similar to "mastoids" on the surface of roseleaves and the surface of the "mastoids" is interspersed with nanodots, the surface structure of the contact lens body meets the requirements; and detecting the light transmittance of the contact lens body through a light transmittance haze meter.
CN202010808134.1A 2020-08-12 2020-08-12 Hydrophobic contact lens Pending CN111965842A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010808134.1A CN111965842A (en) 2020-08-12 2020-08-12 Hydrophobic contact lens

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010808134.1A CN111965842A (en) 2020-08-12 2020-08-12 Hydrophobic contact lens

Publications (1)

Publication Number Publication Date
CN111965842A true CN111965842A (en) 2020-11-20

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA956070A (en) * 1969-12-15 1974-10-15 Drahoslav Lim Method of hydrophilization of transparent objects made of hydrophobic organic polymers
CN102289086A (en) * 2011-08-25 2011-12-21 东南大学 Color contact lens with micro-structure surface and preparation method thereof
CN106610535A (en) * 2015-10-26 2017-05-03 鸿富锦精密工业(深圳)有限公司 Ophthalmic lens and preparation method thereof
CN106773120A (en) * 2015-11-25 2017-05-31 鸿富锦精密工业(深圳)有限公司 Contact lens material and contact lens
TW201742894A (en) * 2016-06-15 2017-12-16 鴻海精密工業股份有限公司 Formula of silicone hydrogel, silicone hydrogel and method for manufacturing silicone hydrogel
JP2020056994A (en) * 2018-10-03 2020-04-09 ベンキュー マテリアルズ コーポレーション Colorant composition for colored silicone hydrogel contact lenses, colored silicone hydrogel contact lens comprising the same, and method of modifying colorant for colored silicone hydrogel contact lenses

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA956070A (en) * 1969-12-15 1974-10-15 Drahoslav Lim Method of hydrophilization of transparent objects made of hydrophobic organic polymers
CN102289086A (en) * 2011-08-25 2011-12-21 东南大学 Color contact lens with micro-structure surface and preparation method thereof
CN106610535A (en) * 2015-10-26 2017-05-03 鸿富锦精密工业(深圳)有限公司 Ophthalmic lens and preparation method thereof
CN106773120A (en) * 2015-11-25 2017-05-31 鸿富锦精密工业(深圳)有限公司 Contact lens material and contact lens
TW201742894A (en) * 2016-06-15 2017-12-16 鴻海精密工業股份有限公司 Formula of silicone hydrogel, silicone hydrogel and method for manufacturing silicone hydrogel
US20170362364A1 (en) * 2016-06-15 2017-12-21 Hon Hai Precision Industry Co., Ltd. Formulation for silicone hydrogel,silicone hydrogel and method for forming silicone hydrogel
JP2020056994A (en) * 2018-10-03 2020-04-09 ベンキュー マテリアルズ コーポレーション Colorant composition for colored silicone hydrogel contact lenses, colored silicone hydrogel contact lens comprising the same, and method of modifying colorant for colored silicone hydrogel contact lenses

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Application publication date: 20201120

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