CN111944440A - Bactericidal explosion-proof heat-insulation film for automobile, building glass and high-speed rail - Google Patents

Bactericidal explosion-proof heat-insulation film for automobile, building glass and high-speed rail Download PDF

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Publication number
CN111944440A
CN111944440A CN202010602581.1A CN202010602581A CN111944440A CN 111944440 A CN111944440 A CN 111944440A CN 202010602581 A CN202010602581 A CN 202010602581A CN 111944440 A CN111944440 A CN 111944440A
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China
Prior art keywords
layer
substrate
explosion
composite
film
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Pending
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CN202010602581.1A
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Chinese (zh)
Inventor
金国华
朱霆
胡善华
李林锐
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Zhejiang Xinlin New Material Technology Co ltd
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Zhejiang Xinlin New Material Technology Co ltd
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Priority to CN202010602581.1A priority Critical patent/CN111944440A/en
Publication of CN111944440A publication Critical patent/CN111944440A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29Laminated material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00Presence of (meth)acrylic polymer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00Presence of polyester
    • C09J2467/006Presence of polyester in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2475/00Presence of polyurethane
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2475/00Presence of polyurethane
    • C09J2475/006Presence of polyurethane in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2483/00Presence of polysiloxane

Abstract

The invention discloses an explosion-proof heat insulation film for sterilization type automobiles, building glass and high-speed rails, which belongs to the technical field of protective films and comprises a substrate composite layer and a bottom film layer arranged on the lower surface of the substrate composite layer; the substrate composite layer is sequentially provided with a hardening layer, a substrate layer and an installation adhesive layer from top to bottom; the substrate layer comprises a plurality of substrate layers, the substrate layers are bonded through the composite adhesive layers, the antibacterial material is added in the hardening layer, the escherichia coli resistance rate after film forming can reach more than 95%, the heat insulation and ultraviolet insulation nano material can be added in the composite adhesive layer and the mounting adhesive layer, the heat insulation effect can reach more than 90% under the condition of high temperature in summer, the ultraviolet insulation effect can reach more than 99%, the transmittance is ensured to be more than 70%, and then the hardening layer, the substrate layer and the antibacterial material are stacked to finally form the sterilization type automobile, building glass and high-speed rail explosion-proof heat insulation film with the sterilization effect, so that the market demands are met in an all-round mode.

Description

Bactericidal explosion-proof heat-insulation film for automobile, building glass and high-speed rail
Technical Field
The invention relates to the technical field of protective films, in particular to an explosion-proof heat-insulation film for sterilization type automobiles, building glass and high-speed rails.
Background
The PET film is widely applied to various fields of production and life as a protective film, wherein the protective film for the building external window and the automobile not only has a certain scratch-resistant and wear-resistant effect on a material needing to be protected, but also has higher requirements on the high-temperature resistance of the protective film because the building external window film is exposed outdoors to resist high-temperature and variable environments for a long time, and the protective film for the automobile is used in high-temperature environments such as summer and the like, and the protective film has stronger ductility and flexibility when being used for protecting structures with different shapes, and in addition, the building external window also has higher requirements on the light transmittance of the material.
The existing PET film is poor in flexibility and can only be used as a plane protective film generally, the heat-resistant temperature of the PET film is 120 ℃, the heat-insulating property of the protective film is limited, and the surface of the existing heat-insulating protective film is frequently used and is easy to generate more bacteria, so that the existing heat-insulating protective film is short in service life, needs to be replaced frequently, is high in cost and is not easy to operate.
Disclosure of Invention
The present invention is directed to solving, at least to some extent, one of the technical problems in the related art. Therefore, one purpose of the invention is to provide an anti-explosion heat insulation film for sterilization type automobiles, building glass and high-speed rails, the invention has the advantages that the antibacterial material is added in the hardened layer, the escherichia coli resistance rate after film forming can reach more than 95%, the heat insulation and ultraviolet insulation nano material can be added in the composite adhesive layer and the mounting adhesive layer, the heat insulation effect is achieved under the condition of high temperature in summer, the unnecessary infrared rays are cut off as far as possible under the premise of ensuring lighting, the heat insulation effect reaches more than 90%, the ultraviolet insulation effect reaches more than 99%, the transmittance is ensured to be more than 70%, then the sterilization type automobiles, the building glass and the anti-explosion heat insulation film for the high-speed rails with the sterilization effect are finally formed through the superposition of the hardened layer, the base material layer and the antibacterial material, and the market requirements are met in an all-round mode.
The anti-explosion heat-insulation film for the sterilization type automobile, the building glass and the high-speed rail comprises a substrate composite layer and a bottom film layer arranged on the lower surface of the substrate composite layer;
the substrate composite layer is sequentially provided with a hardening layer, a substrate layer and an installation adhesive layer from top to bottom;
the substrate layer comprises a plurality of layers of substrate layers, and the plurality of layers of substrate layers are bonded through a composite glue layer.
Preferably, the hardening layer is made of hardening resin;
the thickness of the hardened layer is 1-10 μm.
Preferably, an antibacterial material is added in the hardened layer, and the antibacterial material is KBAF1909-2 antibacterial material
Preferably, the substrate layer comprises a first substrate layer and a second substrate layer, and the first substrate layer and the second substrate layer are bonded through a composite glue layer;
the thickness of the substrate layer is 12-250 μm.
Preferably, the composite adhesive layer is made of any one of OCA pressure-sensitive adhesive, acrylic acid pressure-sensitive adhesive, polyurethane adhesive and polyester adhesive;
the thickness of the composite glue layer is 5-25 μm.
Preferably, the material of the mounting glue layer is any one of silica gel, acrylic glue and polyurethane glue;
the thickness of the mounting glue layer is 10-100 μm.
Preferably, the heat-insulating and ultraviolet-insulating nano material is added in both the composite glue layer and the mounting glue layer.
Preferably, the material of the substrate layer is any one of a PET material and a TPU material.
Preferably, the bottom film layer is any one of a fluorine release film and a silicone oil release film;
the thickness of the bottom film layer is 36-125 μm.
Compared with the prior art, the invention has the beneficial effects that:
according to the invention, the hardening layer is made of hardening resin and internally added with antibacterial material which is KBAF1909-2 antibacterial material, the escherichia coli resistance rate after film forming can reach more than 95%, the composite adhesive layer and the mounting adhesive layer can be added with heat-insulating and ultraviolet-insulating nano material, the heat-insulating effect is achieved under the condition of high temperature in summer, unnecessary infrared rays are cut off as far as possible under the premise of ensuring lighting, so that the heat-insulating effect reaches more than 90%, the ultraviolet-insulating effect reaches more than 99%, the transmittance is ensured to be more than 70%, and then the hard layer, the base material layer and the antibacterial material are superposed to finally form the bactericidal type explosion-proof heat-insulating film with the bactericidal effect for automobiles, building glass and high-speed rails, so that the market demands are met in an all-round manner.
Drawings
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the principles of the invention and not to limit the invention. In the drawings:
fig. 1 is a schematic view of the internal structure of the bactericidal type explosion-proof heat-insulating film for automobiles, building glass and high-speed rails, which is provided by the invention.
In the figure: 1-a hardening layer, 2-a first base material layer, 3-a composite glue layer, 4-a second base material layer, 5-an installation glue layer and 6-a bottom film layer.
Detailed Description
The present invention will now be described in further detail with reference to the accompanying drawings. These drawings are simplified schematic views illustrating only the basic structure of the present invention in a schematic manner, and thus show only the constitution related to the present invention.
Examples of which are illustrated in the accompanying drawings, wherein like reference numerals refer to the same or similar elements or elements having the same or similar function throughout. The embodiments described below with reference to the drawings are illustrative and intended to be illustrative of the invention and are not to be construed as limiting the invention.
Furthermore, the terms "first", "second" and "first" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of that feature. In the description of the present invention, "a plurality" means two or more unless specifically defined otherwise.
Referring to fig. 1, the anti-explosion heat insulation film for the sterilization type automobile, building glass and high-speed rail comprises a substrate composite layer and a bottom film layer 6 arranged on the lower surface of the substrate composite layer, wherein the substrate composite layer is sequentially provided with a hardening layer 1, a substrate layer and a mounting glue layer 5 from top to bottom, the hardening layer 1 is made of hardening resin, an antibacterial material is added in the hardening layer 1, the antibacterial material is an additive and is added in the hardening resin of the hardening layer 1, and the antibacterial material is KBAF1909-2 antibacterial material, the thickness of the hardened layer 1 is 1-10 mu m, the hardness of the hardened layer 1 is 2-9H, preferably 3H, the water drop angle of the hardened layer 1 is 110-120 degrees, preferably 120 degrees, the friction coefficient of the surface is less than 0.5, preferably less than 0.05, the base material layers comprise multilayer base material layers, and the multilayer base material layers are bonded through the composite glue layer 3.
To better illustrate the invention and to facilitate the understanding of the technical solutions thereof, typical but non-limiting examples of the invention are as follows:
an explosion-proof heat insulation film for sterilization type automobiles, building glass and high-speed rails comprises a substrate composite layer and a bottom film layer 6 arranged on the lower surface of the substrate composite layer; the substrate composite layer is sequentially provided with a hardening layer 1, a substrate layer and a mounting adhesive layer 5 from top to bottom; the substrate layer comprises a plurality of layers of substrate layers, the layers of substrate layers are bonded through a composite glue layer 3, the substrate layers are made of any one of PET materials and TPU materials, and the thickness of the substrate layers is 12-250 micrometers. The stiffened layer 1 is made of stiffened resin, the thickness of the stiffened layer 1 is 1-10 μm, the material of the composite adhesive layer 3 is any one of OCA pressure-sensitive adhesive, acrylic acid pressure-sensitive adhesive, polyurethane adhesive and polyester adhesive, the thickness of the composite adhesive layer 3 is 5-25 μm, the material of the mounting adhesive layer 5 is any one of silica gel, acrylic acid adhesive and polyurethane adhesive, the thickness of the mounting adhesive layer 5 is 10-100 μm, and heat-insulating and ultraviolet-insulating nano materials are added in the composite adhesive layer 3 and the mounting adhesive layer 5. The bottom film layer 6 is any one of a fluorine release film and a silicone oil release film, and the thickness of the bottom film layer 6 is 36-125 μm.
Example 1:
the hard layer 1 is made of hard resin and is internally added with an antibacterial material, the antibacterial material is KBAF1909-2 antibacterial material, the thickness is 10 micrometers, the number of layers of base materials in the base material layer is 1, the base material layer is made of PET material, the thickness is 150 micrometers, the mounting glue layer 5 is made of silica gel, the thickness is 100 micrometers, the bottom film layer 6 is a fluorine release film, and the thickness is 125 micrometers.
Example 2:
wherein, the thickness of the stiffened layer 1 is 5 μm, the number of layers of the substrate in the substrate layer is 2, the stiffened layer is divided into a first substrate layer 2 and a second substrate layer 4, the first substrate layer 2 and the second substrate layer 4 are connected through a composite adhesive layer 3, the composite adhesive layer 3 is made of OCA pressure sensitive adhesive, the thickness is 25 μm, the substrate layer is made of PET material, the thickness is 125 μm, the material of the mounting adhesive layer 5 is silica gel, the thickness is 80 μm, the bottom film layer 6 is fluorine release film, the thickness is 100 μm, and other conditions are the same as those in embodiment 1.
Example 3:
wherein the thickness of the hardened layer 1 is 1 μm, the number of layers of the base material in the base material layer is 3, the base material layer is made of TPU material, the thickness is 100 μm, the material of the composite adhesive layer 3 is acrylic pressure sensitive adhesive, the thickness is 15 μm, the material of the installation adhesive layer 5 is acrylic adhesive, the thickness is 50 μm, the bottom film layer 6 is a silicone oil release film, the thickness is 80 μm, and other conditions are the same as those in the embodiment 2.
Example 4:
the number of layers of the base material in the base material layer is 4, the thickness is 70 μm, the material of the composite glue layer 3 is polyurethane glue, the thickness is 5 μm, the material of the installation glue layer 5 is acrylic glue, the thickness is 50 μm, the bottom film layer 6 is a silicone oil release film, the thickness is 36 μm, and other conditions are the same as those in embodiment 3.
Example 5:
wherein, the number of layers of the base material in the base material layer is 5, the thickness is 12 μm, the material of the composite glue layer 3 is polyurethane glue, the thickness is 5 μm, the material of the installation glue layer 5 is polyurethane glue, the thickness is 10 μm, and other conditions are the same as those in the embodiment 4.
When the heat-insulating protective film is used, the bottom film layer 6 is torn, the mounting glue layer 5 at the bottom of the base material composite layer is adhered to an automobile, building glass or high-speed rail window glass to be protected, the invention adopts the hard layer 1 made of hard resin and internally added with antibacterial material KBAF1909-2 antibacterial material, the escherichia coli resistance rate after film forming can reach more than 95%, the composite glue layer 3 and the mounting glue layer 5 can be added with heat-insulating and ultraviolet-insulating nano materials, the heat-insulating effect is achieved under the condition of high temperature in summer, the unnecessary infrared rays are blocked as far as possible on the premise of ensuring lighting, so that the heat-insulating effect reaches more than 90%, the ultraviolet-insulating effect reaches more than 99%, the transmittance is ensured to be more than 70%, and then the hard layer 1, the base material layer and the antibacterial material are overlapped to finally form a sterilization type automobile sterilization type sterilization protective film with a sterilization effect, The explosion-proof heat insulation film for the building glass and the high-speed rail meets the market demand in all directions.
The standard parts used in the invention can be purchased from the market, the special-shaped parts can be customized according to the description of the specification and the accompanying drawings, the specific connection mode of each part adopts conventional means such as bolts, rivets, welding and the like mature in the prior art, the machinery, parts and equipment adopt conventional models in the prior art, and the circuit connection adopts the conventional connection mode in the prior art, and the details are not described, and the content not described in detail in the specification belongs to the prior art known by persons skilled in the art.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (9)

1. The utility model provides a sterilization type car, building glass and blast proof heat insulating film for high-speed railway which characterized in that: the film comprises a substrate composite layer and a bottom film layer arranged on the lower surface of the substrate composite layer;
the substrate composite layer is sequentially provided with a hardening layer, a substrate layer and an installation adhesive layer from top to bottom;
the substrate layer comprises a plurality of layers of substrate layers, and the plurality of layers of substrate layers are bonded through a composite glue layer.
2. The bactericidal explosion-proof heat-insulating film for automobiles, architectural glass and high-speed rails according to claim 1, characterized in that: the hardening layer is made of hardening resin;
the thickness of the hardened layer is 1-10 μm.
3. The bactericidal explosion-proof heat-insulating film for automobiles, architectural glass and high-speed rails according to claim 2, characterized in that: an antibacterial material is added in the hardening layer, and the antibacterial material is KBAF1909-2 antibacterial material.
4. The bactericidal explosion-proof heat-insulating film for automobiles, architectural glass and high-speed rails according to claim 1, characterized in that: the substrate layer comprises a first substrate layer and a second substrate layer, and the first substrate layer and the second substrate layer are bonded through a composite glue layer;
the thickness of the substrate layer is 12-250 μm.
5. The bactericidal explosion-proof heat-insulating film for automobiles, architectural glass and high-speed rails according to claim 4, characterized in that: the composite adhesive layer is made of any one of OCA pressure-sensitive adhesive, acrylic acid pressure-sensitive adhesive, polyurethane adhesive and polyester adhesive;
the thickness of the composite glue layer is 5-25 μm.
6. The bactericidal explosion-proof heat-insulating film for automobiles, architectural glass and high-speed rails according to claim 1, characterized in that: the mounting adhesive layer is made of any one of silica gel, acrylic adhesive and polyurethane adhesive;
the thickness of the mounting glue layer is 10-100 μm.
7. The bactericidal explosion-proof heat-insulating film for automobiles, architectural glass and high-speed rails according to claim 6, characterized in that: and the composite glue layer and the mounting glue layer are both added with heat-insulating and ultraviolet-insulating nano materials.
8. The bactericidal explosion-proof heat-insulating film for automobiles, architectural glass and high-speed rails according to claim 1, characterized in that: the material of the substrate layer is any one of PET material and TPU material.
9. The bactericidal explosion-proof heat-insulating film for automobiles, architectural glass and high-speed rails according to claim 1, characterized in that: the bottom film layer is any one of a fluorine release film and a silicone oil release film;
the thickness of the bottom film layer is 36-125 μm.
CN202010602581.1A 2020-06-29 2020-06-29 Bactericidal explosion-proof heat-insulation film for automobile, building glass and high-speed rail Pending CN111944440A (en)

Priority Applications (1)

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CN202010602581.1A CN111944440A (en) 2020-06-29 2020-06-29 Bactericidal explosion-proof heat-insulation film for automobile, building glass and high-speed rail

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CN202010602581.1A CN111944440A (en) 2020-06-29 2020-06-29 Bactericidal explosion-proof heat-insulation film for automobile, building glass and high-speed rail

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112521880A (en) * 2020-11-27 2021-03-19 湖北航天化学技术研究所 Antibacterial explosion-proof membrane and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103507351A (en) * 2012-06-20 2014-01-15 苏州金海薄膜科技发展有限公司 Fully anti-ultraviolet solar energy heat insulation film and making method thereof
CN203625289U (en) * 2013-09-12 2014-06-04 苏州金海薄膜科技发展有限公司 Automobile film capable of emitting light under excitation of ultraviolet light and reflecting blue light
WO2016088852A1 (en) * 2014-12-05 2016-06-09 コニカミノルタ株式会社 Heat-shielding film, production method therefor, and heat shield using said film
CN207044856U (en) * 2017-07-11 2018-02-27 崔照富 A kind of high insulation protection film of unioresistant
CN207044852U (en) * 2017-03-13 2018-02-27 康得新光学膜材料(上海)有限公司 A kind of multi-functional fenestrated membrane
CN109096940A (en) * 2018-06-07 2018-12-28 苏州袭麟光电科技产业有限公司 One kind exempting from the anti-scratch optics rupture pressure disc of hot pressing antibacterial

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103507351A (en) * 2012-06-20 2014-01-15 苏州金海薄膜科技发展有限公司 Fully anti-ultraviolet solar energy heat insulation film and making method thereof
CN203625289U (en) * 2013-09-12 2014-06-04 苏州金海薄膜科技发展有限公司 Automobile film capable of emitting light under excitation of ultraviolet light and reflecting blue light
WO2016088852A1 (en) * 2014-12-05 2016-06-09 コニカミノルタ株式会社 Heat-shielding film, production method therefor, and heat shield using said film
CN207044852U (en) * 2017-03-13 2018-02-27 康得新光学膜材料(上海)有限公司 A kind of multi-functional fenestrated membrane
CN207044856U (en) * 2017-07-11 2018-02-27 崔照富 A kind of high insulation protection film of unioresistant
CN109096940A (en) * 2018-06-07 2018-12-28 苏州袭麟光电科技产业有限公司 One kind exempting from the anti-scratch optics rupture pressure disc of hot pressing antibacterial

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112521880A (en) * 2020-11-27 2021-03-19 湖北航天化学技术研究所 Antibacterial explosion-proof membrane and preparation method thereof
CN112521880B (en) * 2020-11-27 2021-08-03 湖北航天化学技术研究所 Antibacterial explosion-proof membrane and preparation method thereof

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Application publication date: 20201117