CN109096940A - One kind exempting from the anti-scratch optics rupture pressure disc of hot pressing antibacterial - Google Patents
One kind exempting from the anti-scratch optics rupture pressure disc of hot pressing antibacterial Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J125/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
- C09J125/02—Homopolymers or copolymers of hydrocarbons
- C09J125/04—Homopolymers or copolymers of styrene
- C09J125/08—Copolymers of styrene
- C09J125/14—Copolymers of styrene with unsaturated esters
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/10—Homopolymers or copolymers of methacrylic acid esters
- C09J133/12—Homopolymers or copolymers of methyl methacrylate
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/24—Homopolymers or copolymers of amides or imides
- C09J133/26—Homopolymers or copolymers of acrylamide or methacrylamide
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/318—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of liquid crystal displays
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/16—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
Abstract
The present invention relates to one kind to exempt from the anti-scratch optics rupture pressure disc of hot pressing antibacterial.It is nanocrystalline and by chitin modified that konjaku glucomannan is added in protective layer, substantially increases intermolecular interfacial interaction power in formula system, improves the dispersion performance and compatibility performance between component, so that the mechanical property of protective layer structure is improved；Inorganic and organic composite synergistic antimicrobial agent is added, greatly strengthens the antibacterial effect of protective layer, avoids the cross transmission of human body bacterium after surface touch；Exempt from hot-press solidifying molding, shortens manufacturing procedure and production and processing cost；TPU processability and flexibility are good, protecting against shock, and optical grade PET base material optical transparence is good, it is ensured that the optical performance requirements of rupture pressure disc and the light transmittance for improving rupture pressure disc；Rupture pressure disc of the invention has stronger light transmission, antistatic property, Wear-resistant scratch-resistant performance, anti-microbial property, and the setting of blast resistance construction layer guarantees safety and stability when using, while reaching optical grade appearance requirement.
Description
Technical field
The invention belongs to explosion-proof technical field of membrane, are related to one kind and exempt from the anti-scratch optics rupture pressure disc of hot pressing antibacterial.
Background technique
Rupture pressure disc is mounted in digital electronic goods display screen, automobile industry control display screen, shield glass, industrial work
One layer on display screen is controlled for protecting the protective film of display screen or glass.With the hair of electronic product touch screen technology and market
, there are the various rupture pressure discs in touch screen outer surface in the market in exhibition, touch screen can be prevented because outer by rupture pressure disc
Portion, which hits to be crushed, leads to separation of fragments, can satisfy consumer demand.But rupture pressure disc currently on the market is usually in the presence of anti-
Bacterium performance is poor or does not have anti-microbial property, and scratch resistance wear-resisting property is inadequate, and service life is low etc.；And the processing of rupture pressure disc is logical
Frequently with heat pressing process, will cause product rupture during heat pressing process reduces yield rate, waste of resource；And heat pressing process
Cost can be greatly increased.
Summary of the invention
The purpose of invention: the present invention provides one kind to exempt from the anti-scratch optics rupture pressure disc of hot pressing antibacterial.
Technical solution: in order to achieve the goal above, the invention discloses one kind to exempt from the anti-scratch optics rupture pressure disc of hot pressing antibacterial, packet
The PET base material of optical grade is included, with a thickness of 60-150 μm, sided corona treatment, electricity are passed through in light transmittance >=90%, the PET base material surface
The lower surface of the PET base material of dizzy processing has been coated with UV solidification glue-line, and the UV solidification glue-line lower end of PET base material lower surface is compounded with
Release film layer, PET base material upper surface are successively compounded with TPU membrane layer, blast resistance construction layer and the protection of antibacterial anti-scratching wearproof from lower to upper
Layer, is fixedly connected between the TPU membrane layer, blast resistance construction layer and antibacterial anti-scratching wearproof protective layer by OCA glue-line.
Preferably, the UV solidification glue-line comprises the following components in parts by weight: 5-25 parts of ethoxyquin phenoxy group acrylate,
3-14 parts of polyethyleneglycol diacrylate (TEGDA), 5-30 parts of polypropyleneglycol diacrylate (TPGDA), pentaerythrite three or four
10-40 parts of acrylate (PETA), 10-55 parts of trimethylolpropane trimethacrylate (TMPTA), dipentaerythritol five six the third
10-55 parts of olefin(e) acid ester (DPHA), 5-18 parts of pentaerythritol tetraacrylate (PETTA), pentaerythritol triacrylate 10-80
Part, 10-75 parts of multiple functional radical polyester acrylate, 184 0.1-10 parts of photoinitiator, 1173 0.1-10 parts of photoinitiator, light
0.1-10 parts of initiator TPO, 0.1-5 parts of organosilicon levelling agent, 0.1-6 parts of fluorine richness auxiliary agent, 0.1-5 parts of antistatic agent, isopropyl
2-30 parts of alcohol, 5-50 parts of ethyl acetate, 10-40 parts of toluene, 10-30 parts of propylene glycol monomethyl ether.
Preferably, the OCA glue-line comprises the following components in parts by weight: 5-45 parts of ethyl acrylate, butyl acrylate
10-55 parts, 5-40 parts of Isooctyl acrylate monomer, 4-35 parts of vinylacetate, 10-25 parts of acrylic ester, 10-35 parts of acrylamide, benzene
10-45 parts of ethylene, 10-45 parts of methyl methacrylate, 10-66 parts of methyl acrylate, 8-36 parts of methacrylic acid, acrylic acid 8-
45 parts, 2-18 parts of hydroxyethyl methacrylate, 2-15 parts of hydroxy propyl methacrylate, diamino ethyl methacrylate 15-
50 parts, 0.2-35 parts of isocyanates, 0.5-40 parts of diisocyanate, 184 0.1-10 parts of photoinitiator, photoinitiator TPO
0.1-10 parts, 0.1-5 parts of organosilicon levelling agent, 0.01-3 parts of blue-light absorbers, 0.1-5 parts of antistatic agent.
Preferably, the organosilicon levelling agent is the organic modified polyorganosiloxane propylene of the response type of Mo Neng chemical company
Acid type levelling agent 1073 and 1074 is combined according to weight ratio 1:1, the former compatibility is good, and slipping is poor.The latter's phase tolerance, it is sliding
It is may just as well good, improve compatibility and slipping by being used in combination.
Preferably, the blue-light absorbers are azo, azo metal complexing class, nitrodiphenylamine class, aminoketones, nitre
Base class, Anthraquinones, quinolines, azines, benzothiazoles, benzimidazole, benzanthrones, lactone type, Coumarins dye
The mixture of one or more of material.
Preferably, the blast resistance construction layer comprises the following components in parts by weight: fluorine-carbon modified polyacrylic resin 30-50
Part, 10-20 parts of acryl-modified silicone resin resin, 2-4 parts of polypropylene terephthalate, polyflon 8-12
Part, is gathered 6-12 parts of explosion-proof fiber, 2-4 parts of nano aluminium oxide, 4-8 parts of alkyl benzene sulphonate antifoggant, 1-3 parts of titanate coupling agent
2-4 parts of urethane curing agent, 10-20 parts of deionized water.
Preferably, the antibacterial anti-scratching wearproof protective layer comprises the following components in parts by weight: 15-25 parts of polyurethane resin,
30-60 parts of fluorinated acrylic resin, konjaku glucomannan be 15-20 parts nanocrystalline, 8-12 parts of chitosan, nano silica 1-3
Part, 6-10 parts of polyetheretherketonefiber fiber, 8-12 parts of nano organic montmorillonite, 2-4 parts of 1,2- benzisothiazole-3-ketone (BIT),
1-3 parts of nano silver antimicrobials, 1-2 parts of linoleic acid sodium dispersing agent, 10-20 parts of deionized water.Fluorinated acrylic resin hot property,
Mechanical performance, surface property and optical property are all relatively strong；Konjaku glucomannan it is nanocrystalline by with chitosan is compound is modified,
Improve the stability, mechanical property and mechanical performance of protective layer, wear-resisting scratch-resisting performance；Increased using the collaboration of inorganic and organic composite
Antibacterial agent is imitated, the antibacterial effect of protective layer is enhanced.
Above-mentioned technical proposal can be seen that the invention has the following beneficial effects:
(1) it is nanocrystalline that konjaku glucomannan is added in protective layer, while it is composite modified to be added chitosan, substantially increases and matches
Intermolecular interfacial interaction power in cube system, improves the dispersion performance and compatibility performance between component, so that protection
The mechanical property of layer structure is improved；
(2) antibacterial anti-scratching wearproof protective layer substantially increases the anti-scratching wearproof effect of protective layer, while being added inorganic and having
Machine composite synergistic antibacterial agent, greatly strengthens the antibacterial effect of protective layer, and the intersection of human body bacterium after surface touch is avoided to pass
It broadcasts；
(3) substrate lower surface is coated with UV solidification glue-line as parting agent layer, by addition composite photoinitiator, exempts from hot pressing
Curing molding shortens manufacturing procedure and production and processing cost；
(4) TPU material has good processability and flexibility, effective protecting against shock, and optical grade PET base material has good
Optical transparence, composite coating optics OCA glue, it is ensured that the optical performance requirements of rupture pressure disc and the light transmittance for improving rupture pressure disc,
Ensure the hardness requirement of product with TPU membrane layer；
(5) rupture pressure disc of the invention has stronger light transmission, antistatic property, Wear-resistant scratch-resistant performance, anti-microbial property,
The setting of blast resistance construction layer guarantees safety and stability when using, while reaching optical grade appearance requirement.
Detailed description of the invention
Fig. 1 is protection membrane structure diagram of the invention.
Wherein, 1-PET substrate, 2- release film layer, 3-UV solidify glue-line, 4-TPU film layer, 5- blast resistance construction layer, 6- antibacterial
Anti-scratching wearproof protective layer, 7-OCA glue-line.
Specific embodiment
The embodiment of the present invention is described in detail with reference to the accompanying drawing.
As shown in Figure 1, the invention discloses one kind to exempt from the anti-scratch optics rupture pressure disc of hot pressing antibacterial, the PET base including optical grade
Material 1, with a thickness of 60-150 μm, it is advantageously ensured that corona is passed through on hardness requirement, light transmittance >=90%, 1 surface of PET base material
Processing, the lower surface of the PET substrate 1 of sided corona treatment have been coated with UV solidification glue-line 3, and the UV of PET base material lower surface solidifies glue-line
3 lower ends are compounded with release film layer 2, and 1 upper surface of PET base material is successively compounded with TPU membrane layer 4, blast resistance construction layer 5 from lower to upper and resists
Bacterium anti-scratching wearproof protective layer 6 passes through OCA glue between the TPU membrane layer 4, blast resistance construction layer 5 and antibacterial anti-scratching wearproof protective layer 6
Layer 7 is fixedly connected.
Table 1 is that UV of the present invention solidifies glue-line constituent table (unit: part)；Table 2 is OCA of the present invention
Glue-line constituent table (unit: part)；Table 3 is blast resistance construction layer constituent table (unit: part) of the present invention；Table 4 is
Antibacterial anti-scratching wearproof protective layer constituent table (unit: part) of the present invention；In comparative example 1-4 UV solidification glue layer component and
Embodiment 3 is identical, and specific formula is shown in Table 1, and OCA glue-line constituent leads to embodiment 3 in comparative example 1-4；The explosion-proof knot of comparative example 1-4
Structure layer constituent is specifically shown in Table 3 with embodiment 3；It is received in antibacterial anti-scratching wearproof layer without konjaku glucomannan in comparative example 1
Meter Jing passes through and chitosan, remaining component is free of 1,2- benzisothia with embodiment 3 in antibacterial anti-scratching wearproof layer in comparative example 2
Oxazoline -3- ketone (BIT) remaining component with embodiment 3, in comparative example 3 in antibacterial anti-scratching wearproof layer without nano silver antimicrobials its
Remaining component is free of 1,2-benzisothiazolin-3-one (BIT) and nanometer with embodiment 3 in antibacterial anti-scratching wearproof layer in comparative example 4
Remaining component of silver antibacterial agent is the same as embodiment 3；Table 5 is the basic performance of the protective film of embodiment 1-3 and documents 1-4.
The UV of the present invention of table 1 solidifies glue-line constituent table (unit: part)
The OCA glue-line constituent table (unit: part) of the present invention of table 2
The blast resistance construction layer constituent table (unit: part) of the present invention of table 3
The antibacterial anti-scratching wearproof protective layer constituent table (unit: part) of the present invention of table 4
Table 5 is the basic performance of the protective film of embodiment 1-3 and documents 1-4
From above table it can be seen that the protective film of 1-3 of embodiment of the present invention preparation is had excellent performance, optical property is up to standard, thoroughly
Light rate is high, the nanocrystalline mechanical property by that can greatly increase protective layer after composite modified with chitosan of konjaku glucomannan；1,
2- benzisothiazole-3-ketone (BIT) and nano silver antimicrobials Organic-inorganic composite antibacterial agent can greatly improve protective layer
Anti-microbial property, effectively avoid bacterium cross transmission.
The above is only a preferred embodiment of the present invention, it should be noted that for those skilled in the art
For, without departing from the principle of the present invention, several improvement can also be made, these improvement also should be regarded as guarantor of the invention
Protect range.
Claims (7)
1. one kind exempts from the anti-scratch optics rupture pressure disc of hot pressing antibacterial, it is characterised in that: the PET base material including optical grade, with a thickness of 60-
150 μm, sided corona treatment is passed through on light transmittance >=90%, the PET base material surface, and the lower surface of the PET base material of sided corona treatment is coated with
There is UV to solidify glue-line, the UV solidification glue-line lower end of PET base material lower surface is compounded with release film layer, PET base material upper surface from it is lower toward
On be successively compounded with TPU membrane layer, blast resistance construction layer and antibacterial anti-scratching wearproof protective layer, the TPU membrane layer, blast resistance construction layer and anti-
It is fixedly connected between bacterium anti-scratching wearproof protective layer by OCA glue-line.
2. one kind according to claim 1 exempts from the anti-scratch optics rupture pressure disc of hot pressing antibacterial, it is characterised in that: the UV solidification
Glue-line comprises the following components in parts by weight: 5-25 parts of ethoxyquin phenoxy group acrylate, polyethyleneglycol diacrylate (TEGDA)
3-14 parts, 5-30 parts of polypropyleneglycol diacrylate (TPGDA), 10-40 parts of three tetraacrylate of pentaerythrite (PETA), three hydroxyls
10-55 parts of propane tri (TMPTA), 10-55 parts of five or six acrylate of dipentaerythritol (DPHA), pentaerythrite
5-18 parts of tetraacrylate (PETTA), 10-80 parts of pentaerythritol triacrylate, multiple functional radical polyester acrylate 10-75
Part, 184 0.1-10 parts of photoinitiator, 1173 0.1-10 parts of photoinitiator, 0.1-10 parts of photoinitiator TPO, organosilicon levelling
0.1-5 parts of agent, 0.1-6 parts of fluorine richness auxiliary agent, 0.1-5 parts of antistatic agent, 2-30 parts of isopropanol, 5-50 parts of ethyl acetate, toluene
10-40 parts, 10-30 parts of propylene glycol monomethyl ether.
3. one kind according to claim 1 exempts from the anti-scratch optics rupture pressure disc of hot pressing antibacterial, it is characterised in that: the OCA glue-line
It comprises the following components in parts by weight: 5-45 parts of ethyl acrylate, 10-55 parts of butyl acrylate, 5-40 parts of Isooctyl acrylate monomer, vinegar
4-35 parts of vinyl acetate, 10-25 parts of acrylic ester, 10-35 parts of acrylamide, 10-45 parts of styrene, methyl methacrylate 10-
45 parts, 10-66 parts of methyl acrylate, 8-36 parts of methacrylic acid, 8-45 parts of acrylic acid, 2-18 parts of hydroxyethyl methacrylate,
2-15 parts of hydroxy propyl methacrylate, 15-50 parts of diamino ethyl methacrylate, 0.2-35 parts of isocyanates, two isocyanides
0.5-40 parts of acid esters, 184 0.1-10 parts of photoinitiator, 0.1-10 parts of photoinitiator TPO, 0.1-5 parts of organosilicon levelling agent, indigo plant
0.01-3 parts of light absorber, 0.1-5 parts of antistatic agent.
4. one kind according to claim 2 or 3 exempts from the anti-scratch optics rupture pressure disc of hot pressing antibacterial, it is characterised in that: described has
Machine silicon levelling agent is that the organic modified polyorganosiloxane acrylic type levelling agent 1073 and 1074 of the response type of Mo Neng chemical company is pressed
It is combined according to weight ratio 1:1.
5. one kind according to claim 3 exempts from the anti-scratch optics rupture pressure disc of hot pressing antibacterial, it is characterised in that: the blue light absorption
Agent be azo, azo metal be complexed class, nitrodiphenylamine class, aminoketones, nitro class, Anthraquinones, quinolines, azines,
The mixture of one or more of benzothiazoles, benzimidazole, benzanthrones, lactone type, Coumarins dyestuff.
6. one kind according to claim 1 exempts from the anti-scratch optics rupture pressure disc of hot pressing antibacterial, it is characterised in that: the blast resistance construction
Layer comprises the following components in parts by weight: fluorine-carbon modified polyacrylic resin 30-50 parts, acryl-modified silicone resin resin 10-20
Part, 2-4 parts of polypropylene terephthalate, 8-12 parts of polyflon, 6-12 parts of explosion-proof fiber, nano aluminium oxide 2-
4 parts, 4-8 parts of alkyl benzene sulphonate antifoggant, 1-3 parts of titanate coupling agent, 2-4 parts of polyurethane curing agent, deionized water 10-20
Part.
7. one kind according to claim 1 exempts from the anti-scratch optics rupture pressure disc of hot pressing antibacterial, it is characterised in that: the antibacterial is anti-
It scrapes wear-resistant protective layer to comprise the following components in parts by weight: 15-25 parts of polyurethane resin, 30-60 parts of fluorinated acrylic resin, evil spirit
Taro Glucomannan is 15-20 parts nanocrystalline, 8-12 parts of chitosan, 1-3 parts of nano silica, 6-10 parts of polyetheretherketonefiber fiber, receives
Rice 8-12 parts of organo montmorillonite, 2-4 parts of 1,2- benzisothiazole-3-ketone (BIT), 1-3 parts of nano silver antimicrobials, linoleic acid sodium
1-2 parts of dispersing agent, 10-20 parts of deionized water.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810582920.7A CN109096940A (en) | 2018-06-07 | 2018-06-07 | One kind exempting from the anti-scratch optics rupture pressure disc of hot pressing antibacterial |
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| CN201810582920.7A CN109096940A (en) | 2018-06-07 | 2018-06-07 | One kind exempting from the anti-scratch optics rupture pressure disc of hot pressing antibacterial |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110358464A (en) * | 2019-06-20 | 2019-10-22 | 深圳昌茂粘胶新材料有限公司 | A kind of scratch resistant ageing-resistant super soft high TPU protective film and preparation method thereof thoroughly |
| CN111434722A (en) * | 2019-01-15 | 2020-07-21 | 湖南国柔科技有限公司 | High-strength explosion-proof polyimide film and preparation method thereof |
| CN111732906A (en) * | 2020-05-19 | 2020-10-02 | 太湖金张科技股份有限公司 | Antiviral and antibacterial functional film and preparation method thereof |
| CN111944440A (en) * | 2020-06-29 | 2020-11-17 | 浙江欣麟新材料技术有限公司 | Bactericidal explosion-proof heat-insulation film for automobile, building glass and high-speed rail |
| CN112280487A (en) * | 2020-10-28 | 2021-01-29 | 南京汇鑫光电材料有限公司 | High-performance acrylate explosion-proof membrane |
| CN113930172A (en) * | 2020-07-13 | 2022-01-14 | 株式会社Skcs | Antibacterial film |
| CN113993323A (en) * | 2021-11-09 | 2022-01-28 | Oppo广东移动通信有限公司 | Electronic equipment shell, preparation method thereof and electronic equipment |
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| CN111434722A (en) * | 2019-01-15 | 2020-07-21 | 湖南国柔科技有限公司 | High-strength explosion-proof polyimide film and preparation method thereof |
| CN110358464A (en) * | 2019-06-20 | 2019-10-22 | 深圳昌茂粘胶新材料有限公司 | A kind of scratch resistant ageing-resistant super soft high TPU protective film and preparation method thereof thoroughly |
| CN111732906A (en) * | 2020-05-19 | 2020-10-02 | 太湖金张科技股份有限公司 | Antiviral and antibacterial functional film and preparation method thereof |
| CN111944440A (en) * | 2020-06-29 | 2020-11-17 | 浙江欣麟新材料技术有限公司 | Bactericidal explosion-proof heat-insulation film for automobile, building glass and high-speed rail |
| CN113930172A (en) * | 2020-07-13 | 2022-01-14 | 株式会社Skcs | Antibacterial film |
| CN112280487A (en) * | 2020-10-28 | 2021-01-29 | 南京汇鑫光电材料有限公司 | High-performance acrylate explosion-proof membrane |
| CN113993323A (en) * | 2021-11-09 | 2022-01-28 | Oppo广东移动通信有限公司 | Electronic equipment shell, preparation method thereof and electronic equipment |
| CN113993323B (en) * | 2021-11-09 | 2023-08-15 | Oppo广东移动通信有限公司 | Electronic equipment shell, preparation method thereof and electronic equipment |
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Application publication date: 20181228 |