CN111863754A - A through-silicon via interconnect structure with an inner confinement ring and a method for forming the same - Google Patents

A through-silicon via interconnect structure with an inner confinement ring and a method for forming the same Download PDF

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CN111863754A
CN111863754A CN202010882298.9A CN202010882298A CN111863754A CN 111863754 A CN111863754 A CN 111863754A CN 202010882298 A CN202010882298 A CN 202010882298A CN 111863754 A CN111863754 A CN 111863754A
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hole
substrate
etching
insulating layer
layer
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王俊强
李孟委
李明浩
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North University of China
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76898Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics formed through a semiconductor substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/48Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor
    • H01L23/481Internal lead connections, e.g. via connections, feedthrough structures

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Abstract

A through silicon via interconnect structure with an internal retaining ring and a method of forming the same, the through silicon via interconnect structure comprising: the device comprises a substrate, a first insulating layer and a second insulating layer, wherein at least one through hole is formed in the substrate; a first insulating layer disposed on an upper end face and a lower end face of the substrate; a second insulating layer disposed on an inner wall of the through-hole; the seed layer is arranged on the surface of the second insulating layer in the through hole; the metal layer is filled and arranged on the inner side of the seed layer; and the limiting part is arranged on the through hole, the second insulating layer, the seed layer and the metal layer. The invention has simple process, lower cost and high reliability, and the manufactured silicon through hole structure has higher thermomechanical reliability and higher practical value due to the existence of the internal limiting ring.

Description

一种具有内部限位环的硅通孔互连结构及其形成方法A through-silicon via interconnect structure with an inner confinement ring and a method for forming the same

技术领域technical field

本发明涉及微电子封装领域,具体涉及一种具有内部限位环的硅通孔互连结构及其形成方法。The invention relates to the field of microelectronic packaging, in particular to a through-silicon via interconnection structure with an inner confinement ring and a method for forming the same.

背景技术Background technique

随着微机电系统不断向小型化、高密度和三维堆叠技术的发展,利用硅通孔制作的互连技术已成为半导体行业先进的技术之一。硅通孔互连技术是一项高密度封装技术,正在逐渐取代目前工艺比较成熟的引线键合技术,被认为是第四代封装技术。所谓硅通孔互连技术是通过硅晶片的通孔建立了从硅晶片的正面到背面的垂直电连接,从而实现了芯片与芯片、晶圆与晶圆多层堆叠之间的垂直导通,极大提高了封装密度和自由度,为三维堆叠技术提供了一种方法。这种技术不仅可以用在微电子领域,而且还可以用在机械、声学、流体、光电子、生物医学等领域。由于压力传感器、加速度计和陀螺仪、投射式微镜、喷墨打印头等快速增长的市场需求,这种新技术通常开发在单独的芯片上。With the continuous development of MEMS to miniaturization, high density and three-dimensional stacking technology, interconnection technology using through silicon vias has become one of the advanced technologies in the semiconductor industry. Through silicon via interconnection technology is a high-density packaging technology, which is gradually replacing the current wire bonding technology with relatively mature technology, and is considered to be the fourth-generation packaging technology. The so-called through-silicon via interconnection technology establishes a vertical electrical connection from the front to the back of the silicon wafer through the through holes of the silicon wafer, thereby realizing the vertical conduction between the multi-layer stack of chips and chips, wafers and wafers. The packaging density and degrees of freedom are greatly improved, providing a method for three-dimensional stacking technology. This technology can be used not only in the field of microelectronics, but also in the fields of mechanics, acoustics, fluids, optoelectronics, biomedicine, etc. This new technology is often developed on a separate chip due to rapidly growing market demands for pressure sensors, accelerometers and gyroscopes, projected micromirrors, inkjet printheads, etc.

硅通孔直径通常为数十微米,深宽比最高可达50,通常以铜作为填充料。由于当前种子层的制作技术还不够完善,无法实现深孔的种子层沉积,导致当前的金属填充方式制作的硅通孔结构还无法满足MEMS封装的需要。同时由于硅通孔填充的铜金属层与孔外硅材料之间存在热膨胀系数(CTE)失配的问题,当器件中硅通孔互连结构区域热量增加时(热量可来自服役中作为信号通道的硅通孔互连结构自发热,也可来自环境热源),由于硅通孔互连结构区域中材料热膨胀系数失配导致的热机械应力进一步加剧,通常表现为铜金属层胀出,增加芯片局部出现分层的风险,最终可能会导致器件失效。因此,深孔金属填充的实现以及减小硅通孔热应力带来的损害是亟待解决的问题。TSVs are usually tens of microns in diameter, with aspect ratios up to 50, and are usually filled with copper. Since the current fabrication technology of the seed layer is not perfect enough to realize the deposition of the deep hole seed layer, the current through-silicon via structure fabricated by the metal filling method cannot meet the needs of MEMS packaging. At the same time, due to the mismatch of the coefficient of thermal expansion (CTE) between the copper metal layer filled with the TSV and the silicon material outside the hole, when the heat in the TSV interconnect structure area in the device increases (the heat can come from the service as a signal channel) The through-silicon via interconnect structure is self-heating, and it can also come from an environmental heat source), and the thermomechanical stress caused by the mismatch of the thermal expansion coefficient of the material in the through-silicon via interconnect structure area is further aggravated, usually manifested as the copper metal layer bulging out, increasing the chip There is a risk of localized delamination that could eventually lead to device failure. Therefore, the realization of deep hole metal filling and the reduction of damage caused by thermal stress of TSVs are urgent problems to be solved.

为了解决上述问题,目前都是考虑以外部散热的方式来降低硅通孔互连结构周围的温度,从而降低热膨胀系数失配的程度。然而,外部散热的方法成本较高,并且散热效果不理想。因此,开发一种散热效果更好,通孔填充更深,成本更低的硅通孔互连结构制作工艺是十分有必要的,避免硅通孔填充的铜金属层受热后向外膨胀破坏芯片之间的连接点。In order to solve the above problems, it is currently considered to reduce the temperature around the TSV interconnect structure by means of external heat dissipation, thereby reducing the degree of thermal expansion coefficient mismatch. However, the method of external heat dissipation is expensive, and the heat dissipation effect is not ideal. Therefore, it is very necessary to develop a TSV interconnect structure fabrication process with better heat dissipation effect, deeper via filling and lower cost, so as to prevent the copper metal layer filled with TSV from expanding outward after being heated and destroying the internal structure of the chip. connection point between.

发明内容SUMMARY OF THE INVENTION

为了有效解决上述背景技术问题的不足,通过分步深硅刻蚀的工艺在通孔内部形成内部限位环结构来代替传统的刻蚀工艺,通过双面盲孔电镀工艺将通孔金属完全填充,设计了一种具有内部限位环的硅通孔结构制作工艺。内部限位环结构可以在高温环境下有效地固定填充金属,具体是温度导致金属膨胀,内部限位环结构将金属固定,避免金属脱离硅通孔,从而延长高温环境下芯片的寿命。In order to effectively solve the above-mentioned deficiencies of the background technology, an internal limit ring structure is formed inside the through hole by a step-by-step deep silicon etching process to replace the traditional etching process, and the through hole metal is completely filled by a double-sided blind hole electroplating process. , a fabrication process of a TSV structure with an internal limiting ring is designed. The internal limit ring structure can effectively fix the filler metal in a high temperature environment. Specifically, the temperature causes the metal to expand, and the internal limit ring structure fixes the metal to prevent the metal from detaching from the TSV, thereby prolonging the life of the chip in a high temperature environment.

一种具有内部限位环的硅通孔互连结构,可长期稳定工作在300℃的高温环境中,所述硅通孔互连结构包括:A through-silicon via interconnection structure with an inner confinement ring can work stably in a high temperature environment of 300° C. for a long time, and the through-silicon via interconnection structure includes:

衬底,所述衬底上开设有至少一个通孔;a substrate, at least one through hole is formed on the substrate;

第一绝缘层,所述第一绝缘层设置在所述衬底的上端面和下端面上;a first insulating layer, the first insulating layer is disposed on the upper end face and the lower end face of the substrate;

第二绝缘层,所述第二绝缘层设置在所述通孔的内壁上;a second insulating layer, the second insulating layer is disposed on the inner wall of the through hole;

种子层,所述种子层设置在所述通孔内第二绝缘层的表面;a seed layer, the seed layer is arranged on the surface of the second insulating layer in the through hole;

金属层,所述金属层填充设置在种子层内侧;a metal layer, the metal layer is filled and arranged inside the seed layer;

以及设置在所述通孔,第二绝缘层,种子层和金属层上的限位部。and a limiting portion disposed on the through hole, the second insulating layer, the seed layer and the metal layer.

可选地,所述限位部包括:设置在所述通孔内壁上的第一凹陷部,所述通孔内壁设置有至少一个环形的第一凹陷部,设置在所述第二绝缘层上的第二凹陷部,设置在所述种子层上的第三凹陷部以及设置在所述第金属层上的限位环。Optionally, the limiting portion includes: a first concave portion disposed on the inner wall of the through hole, and the inner wall of the through hole is provided with at least one annular first concave portion disposed on the second insulating layer The second concave part, the third concave part arranged on the seed layer and the limiting ring arranged on the first metal layer.

可选地,所述第二凹陷部对应所述通孔的第一凹陷部位置设置并且形状适配第一凹陷部,所述第三凹陷部对应所述第二绝缘层的的第二凹陷部位置设置并且形状适配第二凹陷部,所述限位环对应所述种子层的第三凹陷部的位置设置并且形状适配第三凹陷部。Optionally, the second concave portion is positioned corresponding to the first concave portion of the through hole and the shape is adapted to the first concave portion, and the third concave portion corresponds to the second concave portion of the second insulating layer. The position is set and the shape is adapted to the second recess, and the limit ring is positioned corresponding to the position of the third recess of the seed layer and the shape is adapted to the third recess.

可选地,所述通孔呈阵列式分布,所述通孔的阵列式分布排布包括:圆形、环形、扇形、矩形、平行四边形或梯形排布。Optionally, the through holes are distributed in an array, and the array distribution of the through holes includes: circle, ring, sector, rectangle, parallelogram or trapezoid.

可选地,所述第一凹陷部均匀的排布在通孔内壁的上部、中部和/或下部。Optionally, the first concave parts are evenly arranged on the upper part, the middle part and/or the lower part of the inner wall of the through hole.

可选地,所述第一凹陷部非均匀的排布在通孔内壁,所述第一凹陷部为对称或非对称结构。Optionally, the first concave parts are non-uniformly arranged on the inner wall of the through hole, and the first concave parts have a symmetric or asymmetric structure.

可选地,所述限位环一体成形在所述金属层表面,所述限位环数量至少为一个,所述限位环为对称或非对称结构。Optionally, the limiting ring is integrally formed on the surface of the metal layer, the number of the limiting ring is at least one, and the limiting ring is a symmetrical or asymmetrical structure.

一种具有内部限位环的硅通孔互连结构形成方法,所述方法包括以下步骤:A method for forming a through-silicon via interconnect structure with an inner confinement ring, the method comprising the steps of:

S1、提供半导体衬底,使用深硅刻蚀工艺在衬底表面进行刻蚀制作盲孔,在刻蚀过程中采用分步深硅刻蚀工艺形成第一凹陷部;S1. Provide a semiconductor substrate, use a deep silicon etching process to etch blind holes on the surface of the substrate, and use a step-by-step deep silicon etching process to form a first recess during the etching process;

S2、使用干湿干氧化工艺在所述衬底表面及通孔分别制作第一绝缘层和第二绝缘层;S2, using a dry-wet dry-oxidation process to make a first insulating layer and a second insulating layer on the surface of the substrate and the through holes, respectively;

S3、使用磁控溅射工艺在通孔内的第二绝缘层表面沉积种子层;S3, using a magnetron sputtering process to deposit a seed layer on the surface of the second insulating layer in the through hole;

S4、使用双面盲孔电镀工艺对通孔内种子层内部的空间进行填充形成金属层;S4, using a double-sided blind hole electroplating process to fill the space inside the seed layer in the through hole to form a metal layer;

S5、使用化学机械抛光工艺将衬底两个端面的金属层去除,使端面平整。S5, using a chemical mechanical polishing process to remove the metal layers on the two end faces of the substrate to make the end faces flat.

可选地,所述步骤S1中分步深硅刻蚀工艺具体为:使用Bosch工艺对完成光刻工艺的衬底进行深硅刻蚀,根据刻蚀的目标深度与刻蚀设备的刻蚀速率设定刻蚀时间,通过多次、分段地刻蚀使刻蚀深度达到设定值,每次在深硅刻蚀完成后将刻蚀腔室内残留的气体完全排出,并进行短暂等待后再进行下一次刻蚀,重复上述步骤直至达到目标深度后停止。Optionally, the step-by-step deep silicon etching process in the step S1 is specifically: using the Bosch process to perform deep silicon etching on the substrate on which the photolithography process has been completed, according to the target depth of the etching and the etching rate of the etching equipment. Set the etching time, and make the etching depth reach the set value through multiple and segmented etching. After each deep silicon etching is completed, the gas remaining in the etching chamber is completely discharged, and after a short wait For the next etch, repeat the above steps until the target depth is reached and then stop.

可选地,所述步骤S4双面盲孔电镀工艺包括以下步骤:Optionally, the step S4 double-sided blind hole electroplating process includes the following steps:

S4.1、使用电镀工艺将金属材料从衬底的一端面对盲孔进行填充;S4.1. Use the electroplating process to fill the blind hole with metal material from one end of the substrate;

S4.2、使用减薄抛光工艺使衬底另一端面的盲孔漏出;S4.2. Use the thinning and polishing process to leak out the blind hole on the other end face of the substrate;

S4.3、使用电镀工艺将金属材料从衬底的另一端面对盲孔进行填充,使两个端面填充的金属柱形成一个整体。S4.3. Use an electroplating process to fill the blind hole with metal material from the other end of the substrate, so that the metal pillars filled on the two end faces form a whole.

本发明的有益效果在于,本发明通过多次深硅刻蚀在通孔内形成独特的限位环结构,使得该通孔互连结构对金属柱有较高的附着能力,极大地减小热应力影响,可长期稳定工作在300℃的高温环境中,适用于各种工作于高温环境的芯片的电学互连,利用双面盲孔电镀实现深孔的安全填充使得制作的通孔互连结构达到200μm以上的深度,可以广泛地应用于MEMS封装、集成电路器件的三维封装等。The beneficial effect of the present invention is that the present invention forms a unique confinement ring structure in the through hole through multiple deep silicon etchings, so that the through hole interconnection structure has a higher adhesion ability to the metal column and greatly reduces heat Under the influence of stress, it can work stably in a high temperature environment of 300 ° C for a long time, and is suitable for the electrical interconnection of various chips working in high temperature environments. The use of double-sided blind hole electroplating to realize safe filling of deep holes makes the through-hole interconnection structure fabricated. With a depth of more than 200 μm, it can be widely used in MEMS packaging, three-dimensional packaging of integrated circuit devices, etc.

本发明工艺简单,成本较低,可靠性高,制作的硅通孔结构由于内部限位环的存在,有较高的热机械可靠性,具有很高的实用价值。The process of the invention is simple, the cost is low, and the reliability is high, and the fabricated through-silicon via structure has high thermo-mechanical reliability and high practical value due to the existence of the inner limit ring.

附图说明Description of drawings

图1为本发明硅通孔互连结构外部示意图;1 is an external schematic diagram of the through-silicon via interconnection structure of the present invention;

图2为本发明硅通孔互连结构内部示意图;FIG. 2 is an internal schematic diagram of the through-silicon via interconnection structure of the present invention;

图3为本发明硅通孔内多个限位环结构示意图;FIG. 3 is a schematic structural diagram of a plurality of limiting rings in the TSV of the present invention;

图4为本发明硅通孔互连结构仰视示意图;4 is a schematic bottom view of the through-silicon via interconnection structure of the present invention;

图5为本发明硅通孔互连结构局部放大结构示意图;FIG. 5 is a schematic diagram of a partially enlarged structure of the through-silicon via interconnection structure of the present invention;

图中所示,附图标记清单如下:As shown in the figure, the list of reference numerals is as follows:

1-衬底;2、3-第一绝缘层;8、9-第二绝缘层;4、6、7-种子层;5-金属层;10、11、12-限位环;13-通孔;14-第一凹陷部;15-第二凹陷部;16-第三凹陷部。1-substrate; 2,3-first insulating layer; 8,9-second insulating layer; 4,6,7-seed layer; 5-metal layer; 10,11,12-limiting ring; 13-pass hole; 14-first recess; 15-second recess; 16-third recess.

具体实施方式Detailed ways

下面详细描述本发明的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,仅用于解释本发明,而不能理解为对本发明的限制。The following describes in detail the embodiments of the present invention, examples of which are illustrated in the accompanying drawings, wherein the same or similar reference numerals refer to the same or similar elements or elements having the same or similar functions throughout. The embodiments described below with reference to the accompanying drawings are exemplary, only used to explain the present invention, and should not be construed as a limitation of the present invention.

在本发明的描述中,需要理解的是,术语“中心”、“上”、“下”、“前”、“后”、“左”、“右”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的组合或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。另外,本发明实施例的描述过程中,所有图中的“上”、“下”、“前”、“后”、“左”、“右”等器件位置关系,均以图1为标准。In the description of the present invention, it should be understood that the orientation or positional relationship indicated by the terms "center", "upper", "lower", "front", "rear", "left", "right", etc. is based on the attached The orientation or positional relationship shown in the figures is only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the indicated combination or element must have a specific orientation, be constructed and operated in a specific orientation, and therefore should not be construed as a reference to the present invention. Invention limitations. In addition, during the description of the embodiments of the present invention, the positional relationships of components such as "up", "down", "front", "rear", "left", and "right" in all figures are based on FIG. 1 .

在本发明的描述中,需要说明的是,除非另有明确的规定和限定,术语“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本发明中的具体含义。In the description of the present invention, it should be noted that, unless otherwise expressly specified and limited, the terms "connected" and "connected" should be understood in a broad sense, for example, it may be a fixed connection, a detachable connection, or an integral connection. It can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediate medium, and it can be the internal communication between the two components. For those of ordinary skill in the art, the specific meanings of the above terms in the present invention can be understood in specific situations.

以下结合附图对本发明做进一步说明:The present invention will be further described below in conjunction with the accompanying drawings:

如图1-2所示,为本发明第一实施例的外观立体图,提供一种具有内部限位环的硅通孔互连结构,可长期稳定工作在300℃的高温环境中,所述硅通孔互连结构包括:As shown in FIG. 1-2, which is a perspective view of the appearance of the first embodiment of the present invention, a through-silicon via interconnection structure with an inner limit ring is provided, which can work stably in a high temperature environment of 300°C for a long time. Via interconnect structures include:

衬底1,所述衬底1上开设有至少一个通孔13;Substrate 1, at least one through hole 13 is formed on the substrate 1;

第一绝缘层2、3,所述第一绝缘层2、3设置在所述衬底1的上端面和下端面上;first insulating layers 2, 3, the first insulating layers 2, 3 are arranged on the upper end face and the lower end face of the substrate 1;

第二绝缘层8、9,所述第二绝缘层8、9设置在所述通孔13的内壁上;second insulating layers 8, 9, the second insulating layers 8, 9 are disposed on the inner walls of the through holes 13;

种子层4、6、7,所述种子层4、6、7设置在所述通孔13内第二绝缘层8、9的表面;Seed layers 4, 6, 7, the seed layers 4, 6, 7 are arranged on the surfaces of the second insulating layers 8, 9 in the through hole 13;

金属层5,所述金属层5填充设置在种子层4、6、7内侧;Metal layer 5, the metal layer 5 is filled and arranged inside the seed layers 4, 6, 7;

以及设置在所述通孔13,第二绝缘层8、9,种子层4、6、7和金属层5上的限位部。And the limiting parts provided on the through holes 13 , the second insulating layers 8 , 9 , the seed layers 4 , 6 , 7 and the metal layer 5 .

如图2、3、5所示,所述限位部包括:设置在所述通孔13内壁上的第一凹陷部14,所述通孔13内壁设置有至少一个环形的第一凹陷部14,设置在所述第二绝缘层8、9上的第二凹陷部15,设置在所述种子层4、6、7上的第三凹陷部16以及设置在所述第金属层5上的限位环10、11、12。As shown in FIGS. 2 , 3 and 5 , the limiting portion includes: a first concave portion 14 disposed on the inner wall of the through hole 13 , and at least one annular first concave portion 14 is disposed on the inner wall of the through hole 13 , the second recesses 15 arranged on the second insulating layers 8 and 9 , the third recesses 16 arranged on the seed layers 4 , 6 and 7 , and the limiter arranged on the first metal layer 5 Bit rings 10, 11, 12.

如图2、3、5所示,所述第二凹陷部15对应所述通孔13的第一凹陷部14位置设置并且形状适配第一凹陷部14,所述第三凹陷部16对应所述第二绝缘层8、9的的第二凹陷部15位置设置并且形状适配第二凹陷部15,所述限位环10、11、12对应所述种子层4、6、7的第三凹陷部16的位置设置并且形状适配第三凹陷部16。As shown in FIGS. 2 , 3 and 5 , the second concave portion 15 is positioned corresponding to the first concave portion 14 of the through hole 13 and the shape is adapted to the first concave portion 14 , and the third concave portion 16 corresponds to the first concave portion 14 . The second concave portions 15 of the second insulating layers 8 and 9 are positioned and adapted in shape to the second concave portions 15 , and the limiting rings 10 , 11 and 12 correspond to the third The position of the recessed portion 16 is set and the shape is adapted to the third recessed portion 16 .

如图1所示,所述衬底1整体可以为任意立体几何形状,包括:圆柱体、立方体、长方体等形状,并不做具体限定,本发明附图中,仅示出了长方体结构。As shown in FIG. 1 , the substrate 1 as a whole can be in any three-dimensional geometric shape, including: cylinder, cube, cuboid and other shapes, which are not specifically limited. In the accompanying drawings of the present invention, only the cuboid structure is shown.

如图1所示,所述衬底1上设置的通孔13,用于制作硅通孔互连结构,所述通孔13形状包括但不限于:圆形、矩形或平行四边形。所述通孔13也可呈阵列式分布,所述通孔13的阵列式分布排布为圆形、环形、扇形、矩形、平行四边形或梯形排布。所述衬底1材料可采用Si材料,优选的,所述衬底1采用高阻硅作为制作材料。所述通孔13内部由外向内依次由第二绝缘层8、9,种子层4、6、7,金属层5填充。As shown in FIG. 1 , the through hole 13 provided on the substrate 1 is used to fabricate a through silicon via interconnection structure, and the shape of the through hole 13 includes but is not limited to: circle, rectangle or parallelogram. The through holes 13 may also be distributed in an array, and the array distribution of the through holes 13 may be circular, annular, fan-shaped, rectangular, parallelogram or trapezoidal. The material of the substrate 1 can be made of Si material. Preferably, the substrate 1 is made of high-resistance silicon. The inside of the through hole 13 is filled with the second insulating layers 8 , 9 , the seed layers 4 , 6 , 7 , and the metal layer 5 sequentially from the outside to the inside.

如图2、3、5所示,所述第一凹陷部14通过分布刻蚀工艺形成在所述通孔13内壁上。所述第一凹陷部14可以均匀的排布在通孔13内壁的上部、中部和/或下部。所述第一凹陷部14也可以非均匀的排布在通孔13内壁。所述第一凹陷部14可以为一个、两个或多个。所述第一凹陷部14形状包括但不限于为适配通孔13截面形状的圆形、矩形或平行四边形。所述第一凹陷部14在通孔13内的分布可以是对称的,也可以是非对称的。As shown in FIGS. 2 , 3 and 5 , the first concave portion 14 is formed on the inner wall of the through hole 13 through a distributed etching process. The first concave parts 14 may be uniformly arranged on the upper part, the middle part and/or the lower part of the inner wall of the through hole 13 . The first concave parts 14 may also be non-uniformly arranged on the inner wall of the through hole 13 . The first concave portion 14 may be one, two or more. The shape of the first concave portion 14 includes, but is not limited to, a circle, a rectangle or a parallelogram adapted to the cross-sectional shape of the through hole 13 . The distribution of the first recesses 14 in the through holes 13 may be symmetrical or asymmetrical.

如图2、3、5所示,所述第一绝缘层2、3和第二绝缘层8、9通过高热氧化工艺附着在所述衬底1上,高温热氧化工艺形成的第一绝缘层2、3和第二绝缘层8、9可以紧密附着在衬底1表面,不易脱落,同时可以完全覆盖通孔13内部。优选的,所述第一绝缘层2、3通过干湿干氧化工艺形成在衬底1的上端面及下端面上,所述第二绝缘层8、9通过干湿干氧化工艺形成在通孔13的内壁上。所述第一绝缘层2、3和第二绝缘层8、9可采用SiO2、SiN、SiON或其他低K材料。所述第一绝缘层2、3和第二绝缘层8、9的覆盖使得衬底1绝缘,同时对衬底1提供一定的保护。As shown in FIGS. 2 , 3 and 5 , the first insulating layers 2 and 3 and the second insulating layers 8 and 9 are attached to the substrate 1 through a high-temperature thermal oxidation process, and the first insulating layer formed by the high-temperature thermal oxidation process 2, 3 and the second insulating layers 8, 9 can be closely attached to the surface of the substrate 1, not easy to fall off, and can completely cover the interior of the through hole 13. Preferably, the first insulating layers 2 and 3 are formed on the upper end surface and the lower end surface of the substrate 1 by a dry-wet dry oxidation process, and the second insulating layers 8 and 9 are formed on the through holes by a dry-wet dry oxidation process. 13 on the inner wall. The first insulating layers 2 and 3 and the second insulating layers 8 and 9 can be made of SiO 2 , SiN, SiON or other low-K materials. The covering of the first insulating layers 2 and 3 and the second insulating layers 8 and 9 insulates the substrate 1 and provides certain protection to the substrate 1 at the same time.

由于所述衬底1的通孔13内具有第一凹陷部14,所述第二绝缘层8、9形成在通孔13内壁时,会附着在所述第一凹陷部14内壁,形成适配第一凹陷部14形状的第二凹陷部15。Since the through hole 13 of the substrate 1 has the first concave portion 14 , when the second insulating layers 8 and 9 are formed on the inner wall of the through hole 13 , they will be attached to the inner wall of the first concave portion 14 to form a fitting The second recess 15 in the shape of the first recess 14 .

如图2、3、5所示,所述种子层4、6、7可通过磁控溅射工艺附着在所述第二绝缘层8、9表面,所述种子层4、6、7可采用包括TaN、Ta、TiN、Ti材料中的一种或多种。由于所述第二绝缘层8、9上具有第二凹陷部15,所述种子层4、6、7形成在第二绝缘层8、9上时,会附着在所述第二凹陷部15内壁,形成适配第二凹陷部15形状的第三凹陷部16。As shown in FIGS. 2 , 3 and 5 , the seed layers 4 , 6 and 7 can be attached to the surfaces of the second insulating layers 8 and 9 by a magnetron sputtering process, and the seed layers 4 , 6 and 7 can be Including one or more of TaN, Ta, TiN, and Ti materials. Since the second insulating layers 8 and 9 have the second recesses 15 , when the seed layers 4 , 6 and 7 are formed on the second insulating layers 8 and 9 , they will be attached to the inner walls of the second recesses 15 . , forming a third recessed portion 16 adapted to the shape of the second recessed portion 15 .

如图2-5所示,所述金属层5完全填充在所述第二绝缘层8、9与种子层4、6、7共同界定的圆环形环形空间内,所述金属层5可通过双面盲孔电镀工艺形成,所述金属层5沉积填充在所述种子层4、6、7内侧。所述金属层5可采用Cu、Al或W材料。过双面盲孔电镀工艺,可以实现深孔的金属填充,增大可填充金属的厚度,同样增加完成硅通孔结构后硅片衬底1的厚度,使其可以满足MEMS封装对硅片衬底1的可靠性要求;As shown in FIGS. 2-5 , the metal layer 5 is completely filled in the annular space defined by the second insulating layers 8 , 9 and the seed layers 4 , 6 , 7 , and the metal layer 5 can pass through The double-sided blind hole electroplating process is formed, and the metal layer 5 is deposited and filled inside the seed layers 4 , 6 , and 7 . The metal layer 5 can be made of Cu, Al or W material. Through the double-sided blind hole electroplating process, the metal filling of deep holes can be realized, the thickness of the metal that can be filled can be increased, and the thickness of the silicon wafer substrate 1 after the through silicon via structure is also increased, so that it can meet the requirements of MEMS packaging for silicon wafer lining. The reliability requirements of bottom 1;

如图2、3、5所示,所述限位环10、11、12一体成形在所述金属层5表面,由于所述种子层4、6、7上具有第三凹陷部16,所述金属层5在种子层4、6、7内部的形成过程中,金属层5会将所述第三凹陷部16完全填充,使金属层5表面形成适配第三凹陷部16形状的环状限位凸起。所述限位环10、11、12适配所述第三凹陷部16,可以为一个或多个,所述限位环10、11、12可以为对称分布,也可以为不对称分布。所述限位环10、11、12能够提高金属层5在通孔13内的固定性,实现更优的效果。As shown in FIGS. 2 , 3 and 5 , the limiting rings 10 , 11 and 12 are integrally formed on the surface of the metal layer 5 . Since the seed layers 4 , 6 and 7 have third recesses 16 , the During the formation process of the metal layer 5 inside the seed layers 4 , 6 , and 7 , the metal layer 5 will completely fill the third recess 16 , so that the surface of the metal layer 5 forms an annular limit adapted to the shape of the third recess 16 . Bit raised. The limiting rings 10 , 11 , 12 are adapted to fit the third concave portion 16 , which may be one or more, and the limiting rings 10 , 11 , 12 may be distributed symmetrically or asymmetrically. The limiting rings 10 , 11 , and 12 can improve the fixation of the metal layer 5 in the through hole 13 and achieve better effects.

当芯片处于高温环境中,由于各部分组成材料的性能不同,会导致热失配产生,硅通孔互连结构内金属层5膨胀,由于内部具有第一凹陷部14、第二凹陷部15、第三凹陷部16和限位环10、11、12的存在,使得金属层5被固定在硅通孔互连结构中无法脱离,提高了芯片在高温环境下的工作时间和工作温度上限,确保了芯片各部分的电学互连,从而使芯片长期稳定工作于高温环境中。When the chip is in a high temperature environment, due to the different properties of the constituent materials of each part, thermal mismatch will occur, and the metal layer 5 in the TSV interconnect structure expands. The existence of the third recessed portion 16 and the limiting rings 10 , 11 , and 12 makes the metal layer 5 fixed in the through silicon via interconnection structure and cannot be detached, which improves the working time and upper limit of the working temperature of the chip in a high temperature environment, and ensures that the The electrical interconnection of each part of the chip is realized, so that the chip can work stably in a high temperature environment for a long time.

一种具有内部限位环的硅通孔互连结构形成方法,所述方法包括以下步骤:A method for forming a through-silicon via interconnect structure with an inner confinement ring, the method comprising the steps of:

S1、提供半导体衬底,使用深硅刻蚀工艺在衬底表面进行刻蚀制作盲孔,在刻蚀过程中采用分步深硅刻蚀工艺形成第一凹陷部;S1. Provide a semiconductor substrate, use a deep silicon etching process to etch blind holes on the surface of the substrate, and use a step-by-step deep silicon etching process to form a first recess during the etching process;

S2、使用干湿干氧化工艺在所述衬底表面及盲孔内分别制作第一绝缘层和第二绝缘层;S2, using a dry-wet dry-oxidation process to form a first insulating layer and a second insulating layer on the surface of the substrate and in the blind holes, respectively;

S3、使用磁控溅射工艺在盲孔内的第二绝缘层表面沉积种子层;S3, using a magnetron sputtering process to deposit a seed layer on the surface of the second insulating layer in the blind hole;

S4、使用双面盲孔电镀工艺对盲孔内种子层内部的空间进行填充形成金属层;S4, using a double-sided blind hole electroplating process to fill the space inside the seed layer in the blind hole to form a metal layer;

S5、使用化学机械抛光工艺将衬底两个端面的金属层去除,使端面平整。S5, using a chemical mechanical polishing process to remove the metal layers on the two end faces of the substrate to make the end faces flat.

所述步骤S1中深硅刻蚀工艺具体为:使用Bosch工艺对完成光刻工艺的衬底进行常规的深硅刻蚀。The deep silicon etching process in the step S1 is specifically: using the Bosch process to perform conventional deep silicon etching on the substrate on which the photolithography process has been completed.

所述步骤S1中分步深硅刻蚀工艺具体为:使用Bosch工艺对完成光刻工艺的衬底进行深硅刻蚀,根据刻蚀的目标深度与刻蚀设备的刻蚀速率设定刻蚀时间,通过多次、分段地刻蚀使刻蚀深度达到设定值,每次在深硅刻蚀完成后将刻蚀腔室内残留的气体完全排出,并进行短暂等待后再进行下一次刻蚀,重复上述步骤直至达到目标深度后停止。The step-by-step deep silicon etching process in the step S1 is specifically as follows: using the Bosch process to perform deep silicon etching on the substrate on which the photolithography process is completed, and setting the etching according to the target depth of the etching and the etching rate of the etching equipment The etching depth reaches the set value through multiple and segmented etchings. After each deep silicon etching is completed, the residual gas in the etching chamber is completely discharged, and the next etching is performed after a short wait. etch, repeat the above steps until the target depth is reached and stop.

所述分步深硅刻蚀工艺可以分为两步、三步或多步深硅刻蚀对衬底1进行刻蚀。The step-by-step deep silicon etching process may be divided into two-step, three-step or multi-step deep silicon etching to etch the substrate 1 .

所述步骤S4双面盲孔电镀工艺包括以下步骤:The step S4 double-sided blind hole electroplating process includes the following steps:

S4.1、使用电镀工艺将金属材料从衬底的一端面对盲孔进行填充;S4.1. Use the electroplating process to fill the blind hole with metal material from one end of the substrate;

S4.2、使用减薄抛光工艺使衬底另一端面的盲孔漏出;S4.2. Use the thinning and polishing process to leak out the blind hole on the other end face of the substrate;

S4.3、使用电镀工艺将金属材料从衬底的另一端面对盲孔进行填充,使两个端面填充的金属柱形成一个整体。S4.3. Use an electroplating process to fill the blind hole with metal material from the other end of the substrate, so that the metal pillars filled on the two end faces form a whole.

所述金属材料包括:Cu、Al或W材料。The metal material includes: Cu, Al or W material.

所述硅通孔互连结构使用双面盲孔电镀的方法进行填充时,两次电镀时通孔13底部都处于密闭状态,整体呈一端开口状。When the through-silicon via interconnection structure is filled by the double-sided blind-hole electroplating method, the bottom of the through-hole 13 is in a closed state during the two electroplating times, and the whole is open at one end.

本发明原理是:The principle of the present invention is:

利用Bosch工艺每次刻蚀都会扩大刻蚀窗口的特点,将一次深硅刻蚀达到目标深度替换为多次深硅刻蚀达到目标深度,相邻两次深硅刻蚀之间便会形成向内凹陷的环形结构,在完成金属填充后形成的金属层便会嵌入通孔内。硅通孔结构通过分步深硅刻蚀方法形成内部限位环结构,提高了对填充金属的固定能力,极大地减少了热应力对结构的损伤,延长了硅通孔结构在高温环境下的工作时间,可应用于极其恶劣的高温工作环境,提高了芯片的高温可靠性,从而提高了芯片的工作寿命,是十分理想的耐高温硅通孔结构。Taking advantage of the feature that each etching of the Bosch process will expand the etching window, a deep silicon etching to reach the target depth is replaced with multiple deep silicon etchings to reach the target depth, and a direction will be formed between two adjacent deep silicon etchings. In the inner recessed annular structure, the metal layer formed after the metal filling is completed will be embedded in the through hole. Through the step-by-step deep silicon etching method, the TSV structure forms an internal confinement ring structure, which improves the fixing ability of the filler metal, greatly reduces the damage to the structure due to thermal stress, and prolongs the TSV structure in high temperature environments. The working time can be applied to extremely harsh high temperature working environment, which improves the high temperature reliability of the chip, thereby improving the working life of the chip. It is a very ideal high temperature resistant TSV structure.

本发明有益效果在于:The beneficial effects of the present invention are:

本发明通过多次深硅刻蚀在通孔内形成独特的限位环结构,使得该通孔互连结构对金属柱有较高的附着能力,极大地减小热应力影响,可长期稳定工作在300℃的高温环境中,适用于各种工作于高温环境的芯片的电学互连,利用双面盲孔电镀实现深孔的安全填充使得制作的通孔互连结构达到200μm以上的深度,可以广泛地应用于MEMS封装、集成电路器件的三维封装等。The invention forms a unique limiting ring structure in the through hole through multiple deep silicon etching, so that the through hole interconnection structure has a high adhesion ability to the metal column, greatly reduces the influence of thermal stress, and can work stably for a long time In the high temperature environment of 300 ℃, it is suitable for the electrical interconnection of various chips working in high temperature environment. The double-sided blind hole electroplating is used to realize the safe filling of deep holes, so that the through-hole interconnection structure can reach a depth of more than 200 μm. Widely used in MEMS packaging, three-dimensional packaging of integrated circuit devices, etc.

本发明工艺简单,成本较低,可靠性高,制作的硅通孔结构由于内部限位环的存在,有较高的热机械可靠性,具有很高的实用价值。The process of the invention is simple, the cost is low, and the reliability is high, and the fabricated through-silicon via structure has high thermo-mechanical reliability and high practical value due to the existence of the inner limit ring.

在本说明书的描述中,参考术语“一个实施例”、“一些实施例”、“示意性实施例”、“示例”、“具体示例”、或“一些示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不一定指的是相同的实施例或示例。而且,描述的具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。In the description of this specification, reference to the terms "one embodiment," "some embodiments," "exemplary embodiment," "example," "specific example," or "some examples," or the like, is meant to incorporate the embodiment. A particular feature, structure, material, or characteristic described by an example or example is included in at least one embodiment or example of the present invention. In this specification, schematic representations of the above terms do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.

尽管已经示出和描述了本发明的实施例,本领域的普通技术人员可以理解,在不脱离本发明的原理和宗旨的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由权利要求及其等同物限定。Although embodiments of the present invention have been shown and described, it will be understood by those of ordinary skill in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, The scope of the invention is defined by the claims and their equivalents.

Claims (10)

1. A through-silicon via interconnect structure with an internal limiting ring, capable of long-term stable operation in a high temperature environment of 300 ℃, the through-silicon via comprising:
the device comprises a substrate (1), wherein at least one through hole (13) is formed in the substrate (1);
first insulating layers (2, 3), the first insulating layers (2, 3) being provided on upper and lower end faces of the substrate (1);
a second insulating layer (8, 9), the second insulating layer (8, 9) being disposed on an inner wall of the through-hole (13);
a seed layer (4, 6, 7), the seed layer (4, 6, 7) being disposed on a surface of the second insulating layer (8, 9) within the via hole (13);
the metal layer (5) is filled in the seed layers (4, 6, 7);
and a limiting part arranged on the through hole (13), the second insulating layers (8, 9), the seed layers (4, 6, 7) and the metal layer (5).
2. The tsv interconnect structure with an internal stopper ring according to claim 1, wherein the stopper portion comprises: the seed layer structure comprises a first sunken part (14) arranged on the inner wall of the through hole (13), at least one annular first sunken part (14) arranged on the inner wall of the through hole (13), a second sunken part (15) arranged on the second insulating layer (8, 9), a third sunken part (16) arranged on the seed layer (4, 6, 7) and a limiting ring (10, 11, 12) arranged on the second metal layer (5).
3. The TSV interconnect structure with an internal retaining ring according to claim 2, wherein the second recess (15) is located and form-fitted to the first recess (14) of the via (13), the third recess (16) is located and form-fitted to the second recess (15) of the second insulating layer (8, 9), and the retaining ring (10, 11, 12) is located and form-fitted to the third recess (16) of the seed layer (4, 6, 7).
4. The through-silicon-via interconnect structure with internal retaining ring according to claim 1, wherein the through-holes (13) are distributed in an array, and the array distribution of the through-holes (13) comprises: circular, annular, fan-shaped, rectangular, parallelogram or trapezoidal arrangement.
5. The TSV interconnect structure having an internal limiting ring according to claim 2, wherein the first recesses (14) are uniformly arranged at upper, middle and/or lower portions of the inner wall of the through hole (13).
6. The TSV interconnect structure with an internal retaining ring according to claim 2, wherein the first recesses (14) are non-uniformly arranged on the inner wall of the through hole (13), and the first recesses (14) are symmetrical or asymmetrical.
7. The TSV interconnect structure with an internal retaining ring according to claim 2, wherein the retaining rings (10, 11, 12) are integrally formed on the surface of the metal layer (5), the number of the retaining rings (10, 11, 12) is at least one, and the retaining rings (10, 11, 12) are symmetrical or asymmetrical.
8. A method for forming a through silicon via interconnection structure with an internal limiting ring is characterized by comprising the following steps:
s1, providing a semiconductor substrate, etching the surface of the substrate by using a deep silicon etching process to manufacture a blind hole, and forming a first concave part by adopting a step-by-step deep silicon etching process in the etching process;
s2, manufacturing a first insulating layer and a second insulating layer on the surface of the substrate and the through hole respectively by using a dry-wet dry oxidation process;
s3, depositing a seed layer on the surface of the second insulating layer in the through hole by using a magnetron sputtering process;
s4, filling the space inside the seed layer in the through hole by using a double-sided blind hole electroplating process to form a metal layer;
and S5, removing the metal layers on the two end faces of the substrate by using a chemical mechanical polishing process to make the end faces flat.
9. The method for forming the through-silicon-via interconnection structure with the internal limiting ring according to claim 8, wherein the step-by-step deep silicon etching process in the step S1 specifically comprises: and carrying out deep silicon etching on the substrate which is subjected to the photoetching process by using a Bosch process, setting etching time according to the etching target depth and the etching rate of etching equipment, enabling the etching depth to reach a set value by carrying out multiple times of segmented etching, completely discharging gas remained in an etching chamber after the deep silicon etching is finished each time, carrying out next etching after short waiting, and repeating the steps until the target depth is reached.
10. The method for forming a through silicon via interconnection structure with an internal limiting ring according to claim 8, wherein the step S4 double-sided blind hole electroplating process comprises the following steps:
s4.1, filling the blind hole with a metal material from one end face of the substrate by using an electroplating process;
s4.2, leaking the blind hole on the other end face of the substrate by using a thinning and polishing process;
and S4.3, filling the blind hole with a metal material from the other end face of the substrate by using an electroplating process, so that the metal columns filled on the two end faces form a whole.
CN202010882298.9A 2020-08-28 2020-08-28 A through-silicon via interconnect structure with an inner confinement ring and a method for forming the same Pending CN111863754A (en)

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