CN111805986A - 一种超薄防水复合石材及其制备方法 - Google Patents

一种超薄防水复合石材及其制备方法 Download PDF

Info

Publication number
CN111805986A
CN111805986A CN202010632286.0A CN202010632286A CN111805986A CN 111805986 A CN111805986 A CN 111805986A CN 202010632286 A CN202010632286 A CN 202010632286A CN 111805986 A CN111805986 A CN 111805986A
Authority
CN
China
Prior art keywords
layer
stone
waterproof
ultrathin
ultra
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN202010632286.0A
Other languages
English (en)
Inventor
肖启洪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Chengyi Stone Technology Co ltd
Original Assignee
Wuxi Chengyi Stone Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Chengyi Stone Technology Co ltd filed Critical Wuxi Chengyi Stone Technology Co ltd
Priority to CN202010632286.0A priority Critical patent/CN111805986A/zh
Publication of CN111805986A publication Critical patent/CN111805986A/zh
Withdrawn legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/002—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising natural stone or artificial stone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/0007—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality
    • B32B37/003—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality to avoid air inclusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B32B37/1018—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure using only vacuum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/0012—Mechanical treatment, e.g. roughening, deforming, stretching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/0036—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
    • B32B2037/243—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/28—Multiple coating on one surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Quality & Reliability (AREA)
  • Thermal Sciences (AREA)
  • Fluid Mechanics (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明公开了一种超薄防水复合石材及其制备方法，所述超薄防水复合石材包括超薄防水复合石材、夹胶层和基板层，所述基板层通过夹胶层设置在超薄防水复合石材的一侧或者两侧，所述超薄防水复合石材包括超薄石材层和复合层，所述复合层设置在超薄石材层的一面或者两面，所述复合层包括依次设置的第一密封层、防水层、第二密封层、夹胶层、增强层和第三密封层，所述第一密封层与超薄石材层粘结。本发明的复合石材柔韧性、防水密封性及强度均比较高，在兼顾装饰美化的同时可提高复合石材使用的安全性。

Description

一种超薄防水复合石材及其制备方法
技术领域：
本发明涉及装饰性复合板材技术领域,具体的涉及一种超薄防水复合石材及其制备方法。
背景技术：
近年来，随着人们生活水平的提高，对装饰材料的质量、质感和独特性，要求越来越严格。天然石材与玻璃形成的复合石材由于颜色和纹路的天然性、独特性、透光纹理色彩丰富、超薄半透晶莹剔透，越来越受到人们的欢迎，然而现有的复合石材其密封性及防水性均有一定的缺陷，在使用过程中易出现脱胶等问题，从而容易导致安全事故。
公开于该背景技术部分的信息仅仅旨在增加对本发明的总体背景的理解，而不应当被视为承认或以任何形式暗示该信息构成已为本领域一般技术人员所公知的现有技术。
发明内容：
本发明的目的在于提供一种超薄防水复合石材及其制备方法，从而克服上述现有技术中的缺陷。
为实现上述目的，本发明提供了一种超薄防水复合石材，包括超薄防水复合石材、夹胶层和基板层，所述基板层通过夹胶层设置在超薄防水复合石材的一侧或者两侧，所述超薄防水复合石材包括超薄石材层和复合层，所述复合层设置在超薄石材层的一面或者两面，所述复合层包括依次设置的第一密封层、防水层、第二密封层、夹胶层、增强层和第三密封层，所述第一密封层与超薄石材层粘结。
所述超薄防水复合板的外边缘处还设置有AS防水耐候密封带。
所述超薄石材层的厚度为1-5mm，所述超薄石材层的规格为3000*2000mm。
所述第一密封层、第二密封层、第三密封层的厚度均为20-100μm，所述防水层的厚度为20-100μm，所述夹胶层的厚度为0.38-3.14mm。
所述增强层为玻璃纤维布或透明PET，所述增强层的厚度为0.2-1mm。
所述基板层为玻璃基板层或者塑料基板层，所述基板层的厚度为2-22mm，所述玻璃基板层选用浮法玻璃、超白玻璃、高硼硅玻璃、热弯玻璃、钢化浮法玻璃、钢化超白玻璃、钢化高鹏硅玻璃或钢化弯玻璃。
一种超薄防水复合石材的制备方法，包括以下步骤：
1)在容器中装上双组份环氧液态树脂，将超薄石材层浸没在液态树脂中，将装有超薄石材层和液态树脂的容器密封后放置到真空高温高压设备中，先对容器抽真空处理，其中真空压力为-0.092Pa以下，再继续正压处理，其中处理功率为80KW-100KW，正压力为15Mpa，总计处理2-10小时；
2)对经过步骤1)处理的超薄石材层的两面进行定厚及抛光处理，其中定厚设备总功率为260KW-450KW，抛光机的总功率为180KW-220KW；
3)将定厚抛光处理后的超薄石材层放入真空微波烘烤设备中脱去石材中的水汽3-6小时，其中真空微波烘烤设备的总功率为100KW-260KW，极限真空压力为-0.092Mpa；
4)将经过步骤3)处理的超薄石材层放置在无尘间，保持无尘间恒温恒湿环境，在超薄石材层的一面或两面喷涂一层第一密封层；
5)待第一密封层完全固化后在第一密封层表面喷涂一层防水层；
6)在防水层完全固化后在防水层表面喷涂一层第二密封层；
7)将经过步骤6)处理的石材、夹胶层和增强层叠放到一起，其中夹胶层紧贴石材的第二密封层，增强层紧贴夹胶层并在四周贴上AS防水耐候胶带固定后放入到高压釜或夹胶炉中抽真空10-30分钟后将温度升到150-180℃，恒温恒压60-120分钟，将温度降至40℃以下，打开高温釜或夹胶炉，取出超薄防水复合石材；
8)在步骤7)制成的超薄防水复合石材的增强层上喷涂一层第三密封层；
9)将步骤8)获得的带第三密封层的超薄防水复合石材、夹胶层和基板层叠放到一起并按照步骤7)的制备工艺条件制备成薄防水复合板成品。
所述步骤4)第一密封层、步骤6)第二密封层、步骤8)第三密封层均采用以下重量百分比的原料：硅氧烷改性水性聚氨酯50-60％、聚氨酯10-20％、固化剂1-10％，其余为溶剂，所述第一密封层、第二密封层、第三密封层喷涂后均放入70-100℃的红外烘箱中烘烤5-10分钟，其中红外烘箱的总功率为75KW。
所述步骤5)防水层采用以下重量百分比的原料：硅氧烷改性水性聚氨酯50-60％、石墨烯分散液2-8％、纳米ZnO添加剂1-3％、纳米SiO2添加剂2-5％、固化剂1-10％，其余为溶剂，所述防水层喷涂后放入85-105℃的红外烘箱中烘烤15-35分钟。
所述夹胶层选用PVB胶片、GS胶片、POE胶片、EVA胶片、TPU胶片、AS胶片或者SGP胶片。
与现有技术相比，本发明的一个方面具有如下有益效果：
(1)本发明在制备过程之中首先将石材浸泡在树脂中，树脂渗透到石材的毛孔内并进行固化，一方面可降低石材的吸水性，另一方面可提高石材的密封性及柔韧性，可根据需要制备成弧形复合石材；
(2)浸泡树脂后两面进行定厚抛光处理后再喷涂第一密封层，更便于第一密封层的附着且表面更平整美观；
(3)定厚抛光处理后再放置到真空微波烘烤炉中处理后可脱去包裹石材的树脂中的小气泡，使得树脂的致密性更好，从而减小石材的吸水性，提高石材的整体强度；
(4)夹胶时在高压釜或夹胶炉中抽真空处理，可减少贴合过程中产生的气泡；
(5)第一密封层、第二密封层、第三密封层主体均以聚氨酯为主体，可提高密封性和防水性；
(6)防水层以硅氧烷改性水性聚氨酯为主体，并添加少量石墨烯分散液、纳米ZnO添加剂及纳米SiO2添加剂在提高防水性能的同时可提高复合石材的强度及耐腐蚀性。
附图说明：
图1为本发明的实施例1、实施例4、实施例5的截面示意图；
图2为本发明的实施例2的截面示意图；
图3为本发明的实施例2制成的复合板弯折示意图；
图4为本发明的实施例3的截面示意图；
附图标记：1-超薄防水复合石材、11-超薄石材层、12-复合层、121-第一密封层、122-防水层、123-第二密封层、124-增强层、125-第三密封层、2-夹胶层、3-基板层、4-密封带。
具体实施方式：
下面对本发明的具体实施方式进行详细描述，但应当理解本发明的保护范围并不受具体实施方式的限制。
除非另有其它明确表示，否则在整个说明书和权利要求书中，术语“包括”或其变换如“包含”或“包括有”等等将被理解为包括所陈述的元件或组成部分，而并未排除其它元件或其它组成部分。
实施例1：
如图1所示，一种超薄防水复合石材，包括超薄防水复合石材1、夹胶层2和基板层3，所述基板层3通过夹胶层2设置在超薄防水复合石材1的一侧，所述超薄防水复合石材1包括超薄石材层11和复合层12，所述复合层12设置在超薄石材层11的一面，所述复合层12包括依次设置的第一密封层121、防水层122、第二密封层123、夹胶层2、增强层124和第三密封层125，所述第一密封层121与树脂层111粘结。
所述超薄防水复合板的外边缘处还设置有AS防水耐候密封带4。
所述超薄石材层11的厚度为3mm，所述超薄石材层11的规格为3000*2000mm。
所述第一密封层121、第二密封层123、第三密封层125的厚度均为35μm，所述防水层122的厚度为35μm，所述夹胶层2的厚度为2mm。
所述增强层124为玻璃纤维布或透明PET，所述增强层124的厚度为1mm。
所述基板层3为玻璃基板层或者塑料基板层，所述基板层3的厚度为0.1-15mm。
一种超薄防水复合石材的制备方法，包括以下步骤：
1)在容器中装上双组份环氧液态树脂，将超薄石材层浸没在液态树脂中，将装有超薄石材层和液态树脂的容器密封后放置到真空高温高压设备中，先对容器抽真空处理，其中真空压力为-0.092Pa以下，再继续正压处理，其中处理功率为80KW-100KW，正压力为15Mpa，总计处理6小时；2)对经过步骤1)处理的超薄石材层的两面进行定厚及抛光处理，其中定厚设备总功率为260KW-450KW，抛光机的总功率为180KW-220KW；3)将定厚抛光处理后的超薄石材层放入真空微波烘烤设备中脱去石材中的水汽4小时，其中真空微波烘烤设备的总功率为100KW-260KW，极限真空压力为-0.092Mpa；4)将经过步骤3)处理的超薄石材层放置在无尘间，保持无尘间恒温恒湿环境，在超薄石材层的一面或两面喷涂一层第一密封层；5)待第一密封层完全固化后在第一密封层表面喷涂一层防水层；6)在防水层完全固化后在防水层表面喷涂一层第二密封层；7)将经过步骤6)处理的石材、夹胶层和增强层叠放到一起，其中夹胶层紧贴石材的第二密封层，增强层紧贴夹胶层并在四周贴上AS防水耐候胶带固定后放入到高压釜或夹胶炉中抽真空20分钟后将温度升到160℃，恒温恒压90分钟，将温度降至40℃以下，打开高温釜或夹胶炉，取出超薄防水复合石材；8)在步骤7)制成的超薄防水复合石材的增强层上喷涂一层第三密封层；9)将步骤8)获得的带第三密封层的超薄防水复合石材、夹胶层和基板层叠放到一起并按照步骤7)的制备工艺条件制备成薄防水复合板成品。
所述步骤4)第一密封层、步骤6)第二密封层、步骤8)第三密封层均采用以下重量百分比的原料：聚氨酯55％、添加剂8％、固化剂5％，其余为溶剂，所述第一密封层、第二密封层、第三密封层喷涂后均放入85℃的红外烘箱中烘烤20分钟。
所述步骤5)防水层采用以下重量百分比的原料：硅氧烷改性水性聚氨酯55％、石墨烯分散液5％、纳米ZnO添加剂2％、纳米SiO2添加剂3％、固化剂5％，其余为溶剂，所述防水层喷涂后放入90℃的红外烘箱中烘烤10分钟。
所述夹胶层选用PVB胶片、GS胶片、POE胶片、EVA胶片、TPU胶片或者SGP胶片。
实施例2：
如图2、图3所示，与实施例1不同的是复合层12设置在超薄石材层11的两面，其余制备方法均相同。
实施例3：
如图1所示，结构与实施例1相同，不同的是未经过浸泡树脂处理，其制备方法包括以下步骤：
1)将超薄石材层放置在无尘间，保持无尘间恒温恒湿环境，在超薄石材层的一面或两面喷涂一层第一密封层；2)待第一密封层完全固化后在第一密封层表面喷涂一层防水层；3)在防水层完全固化后在防水层表面喷涂一层第二密封层；4)将经过步骤3)处理的石材、夹胶层和增强层叠放到一起，其中夹胶层紧贴石材的第二密封层，增强层紧贴夹胶层并在四周贴上AS防水耐候胶带固定后放入到高压釜或夹胶炉中抽真空20分钟后将温度升到160℃，恒温恒压95分钟，将温度降至40℃以下，打开高温釜或夹胶炉，取出超薄防水复合石材；5)在步骤4)制成的超薄防水复合石材的增强层上喷涂一层第三密封层；6)将步骤5)获得的带第三密封层的超薄防水复合石材、夹胶层和基板层叠放到一起并按照步骤4)的制备工艺条件制备成薄防水复合板成品。
所述步骤1)第一密封层、步骤3)第二密封层、步骤5)第三密封层均采用以下重量百分比的原料：聚氨酯60％、添加剂10％、固化剂5％，其余为溶剂，所述第一密封层、第二密封层喷涂后均放入90℃的红外烘箱中烘烤8分钟。
所述步骤2)防水层采用以下重量百分比的原料：硅氧烷改性水性聚氨酯60％、石墨烯分散液6％、纳米ZnO添加剂3％、纳米SiO2添加剂5％、固化剂5％，其余为溶剂，所述防水层喷涂后放入95℃的红外烘箱中烘烤25分钟。
所述夹胶层选用PVB胶片、GS胶片、POE胶片、EVA胶片、TPU胶片或者SGP胶片。
实施例4：
如图1所示结构与实施例1相同，不同的是其制备方法包括以下步骤：
1)在容器中装上双组份环氧液态树脂，将超薄石材层浸没在液态树脂中，将装有超薄石材层和液态树脂的容器密封后放置到真空高温高压设备中，先对容器抽真空处理，其中真空压力为-0.092Pa以下，再继续正压处理，其中处理功率为80KW-100KW，正压力为15Mpa，总计处理6小时；2)对经过步骤1)处理的超薄石材层的两面进行定厚及抛光处理，其中定厚设备总功率为260KW-450KW，抛光机的总功率为180KW-220KW；3)将经过步骤2)处理的超薄石材层放置在无尘间，保持无尘间恒温恒湿环境，在超薄石材层的一面或两面喷涂一层第一密封层；4)待第一密封层完全固化后在第一密封层表面喷涂一层防水层；5)在防水层完全固化后在防水层表面喷涂一层第二密封层；6)将经过步骤5)处理的石材、夹胶层和增强层叠放到一起，其中夹胶层紧贴石材的第二密封层，增强层紧贴夹胶层并在四周贴上AS防水耐候胶带固定后放入到高压釜或夹胶炉中抽真空20分钟后将温度升到160℃，恒温恒压90分钟，将温度降至40℃以下，打开高温釜或夹胶炉，取出超薄防水复合石材；7)在步骤6)制成的超薄防水复合石材的增强层上喷涂一层第三密封层；8)将步骤7)获得的带第三密封层的超薄防水复合石材、夹胶层和基板层叠放到一起并按照步骤5)的制备工艺条件制备成薄防水复合板成品。
所述步骤3)第一密封层、步骤5)第二密封层、步骤7)第三密封层均采用以下重量百分比的原料：聚氨酯55％、添加剂8％、固化剂5％，其余为溶剂，所述第一密封层、第二密封层喷涂后均放入85℃的红外烘箱中烘烤20分钟。
所述步骤4)防水层采用以下重量百分比的原料：硅氧烷改性水性聚氨酯55％、石墨烯分散液5％、纳米ZnO添加剂2％、纳米SiO2添加剂3％、固化剂5％，其余为溶剂，所述防水层喷涂后放入90℃的红外烘箱中烘烤20分钟。
所述夹胶层选用PVB胶片、GS胶片、POE胶片、EVA胶片、TPU胶片或者SGP胶片。
实施例5：
如图1所示结构及制备方法与实施例1相同，不同的是防水层采用以下重量百分比的原料：硅氧烷改性水性聚氨酯60％、固化剂5％，其余为溶剂。
对实施例1、实施例2、实施例3、实施例4和实施例5制成的复合石材进行性能测试，其测试结果如下表：
Figure BDA0002566130390000101
其中浸泡测试是将制备好的复合石材浸泡在水中，观察有无脱胶现象。
从上述测试结果看，采用本发明制备而成的复合石材其吸水性、强度及柔韧性均较好，可提高复合石材使用的安全性。
前述对本发明的具体示例性实施方案的描述是为了说明和例证的目的。这些描述并非想将本发明限定为所公开的精确形式，并且很显然，根据上述教导，可以进行很多改变和变化。对示例性实施例进行选择和描述的目的在于解释本发明的特定原理及其实际应用，从而使得本领域的技术人员能够实现并利用本发明的各种不同的示例性实施方案以及各种不同的选择和改变。

Claims (10)

1.一种超薄防水复合石材，其特征在于：包括超薄防水复合石材、夹胶层和基板层，所述基板层通过夹胶层设置在超薄防水复合石材的一侧或者两侧，所述超薄防水复合石材包括超薄石材层和复合层，所述复合层设置在超薄石材层的一面或者两面，所述复合层包括依次设置的第一密封层、防水层、第二密封层、夹胶层、增强层和第三密封层，所述第一密封层与超薄石材层粘结。
2.根据权利要求1所述的一种超薄防水复合石材，其特征在于：所述超薄防水复合板的外边缘处还设置有AS防水耐候密封带。
3.根据权利要求1所述的一种超薄防水复合石材，其特征在于：所述超薄石材层的厚度为1-5mm，所述超薄石材层的规格为3000*2000mm。
4.根据权利要求1所述的一种超薄防水复合石材，其特征在于：所述第一密封层、第二密封层、第三密封层的厚度均为20-100μm，所述防水层的厚度为20-100μm，所述夹胶层的厚度为0.38-3.14mm。
5.根据权利要求1所述的一种超薄防水复合石材，其特征在于：所述增强层为玻璃纤维布或透明PET，所述增强层的厚度为0.2-1mm。
6.根据权利要求1所述的一种超薄防水复合石材，其特征在于：所述基板层为玻璃基板层或者塑料基板层，所述基板层的厚度为2-22mm，所述玻璃基板层选用浮法玻璃、超白玻璃、高硼硅玻璃、热弯玻璃、钢化浮法玻璃、钢化超白玻璃、钢化高鹏硅玻璃或钢化弯玻璃。
7.一种超薄防水复合石材的制备方法，其特征在于：包括以下步骤：
1)在容器中装上双组份环氧液态树脂，将超薄石材层浸没在液态树脂中，将装有超薄石材层和液态树脂的容器密封后放置到真空高温高压设备中，先对容器抽真空处理，其中真空压力为-0.092Pa以下，再继续正压处理，处理功率为80KW-100KW，正压力为15Mpa，总计处理2-10小时；
2)对经过步骤1)处理的超薄石材层的两面进行定厚及抛光处理，其中定厚设备总功率为260KW-450KW，抛光机的总功率为180KW-220KW；
3)将定厚抛光处理后的超薄石材层放入真空微波烘烤设备中脱去石材中的水汽3-6小时，其中真空微波烘烤设备的总功率为100KW-260KW，极限真空压力为-0.092Mpa；
4)将经过步骤3)处理的超薄石材层放置在无尘间，保持无尘间恒温恒湿环境，在超薄石材层的一面或两面喷涂一层第一密封层；
5)待第一密封层完全固化后在第一密封层表面喷涂一层防水层；
6)在防水层完全固化后在防水层表面喷涂一层第二密封层；
7)将经过步骤6)处理的石材、夹胶层和增强层叠放到一起，其中夹胶层紧贴石材的第二密封层，增强层紧贴夹胶层并在四周贴上AS防水耐候胶带固定后放入到高压釜或夹胶炉中抽真空10-30分钟后将温度升到150-180℃，恒温恒压60-120分钟，将温度降至40℃以下，打开高温釜或夹胶炉，取出超薄防水复合石材；
8)在步骤7)制成的超薄防水复合石材的增强层上喷涂一层第三密封层；
9)将步骤8)获得的带第三密封层的超薄防水复合石材、夹胶层和基板层叠放到一起并按照步骤7)的制备工艺条件制备成薄防水复合板成品。
8.根据权利要求7所述的一种超薄防水复合石材的制备方法，其特征在于：所述步骤4)第一密封层、步骤6)第二密封层、步骤8)第三密封层均采用以下重量百分比的原料：硅氧烷改性水性聚氨酯50-60％、聚氨酯10-20％、固化剂1-10％，其余为溶剂，所述第一密封层、第二密封层、第三密封层喷涂后均放入70-100℃的红外烘箱中烘烤5-10分钟，其中红外烘箱的总功率为75KW。
9.根据权利要求7所述的一种超薄防水复合石材的制备方法，其特征在于：所述步骤5)防水层采用以下重量百分比的原料：硅氧烷改性水性聚氨酯50-60％、石墨烯分散液2-8％、纳米ZnO添加剂1-3％、纳米SiO2添加剂2-5％、固化剂1-10％，其余为溶剂，所述防水层喷涂后放入85-105℃的红外烘箱中烘烤15-35分钟。
10.根据权利要求7所述的一种超薄防水复合石材的制备方法，其特征在于：所述夹胶层选用PVB胶片、GS胶片、POE胶片、EVA胶片、TPU胶片、AS胶片或者SGP胶片。
CN202010632286.0A 2020-07-02 2020-07-02 一种超薄防水复合石材及其制备方法 Withdrawn CN111805986A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010632286.0A CN111805986A (zh) 2020-07-02 2020-07-02 一种超薄防水复合石材及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010632286.0A CN111805986A (zh) 2020-07-02 2020-07-02 一种超薄防水复合石材及其制备方法

Publications (1)

Publication Number Publication Date
CN111805986A true CN111805986A (zh) 2020-10-23

Family

ID=72856152

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010632286.0A Withdrawn CN111805986A (zh) 2020-07-02 2020-07-02 一种超薄防水复合石材及其制备方法

Country Status (1)

Country Link
CN (1) CN111805986A (zh)

Similar Documents

Publication Publication Date Title
CN109750816A (zh) 一种厚芯实木复合地板及其制备方法
CN110794608B (zh) 一种pdlc调光膜及其封边工艺
CN108859323B (zh) 一种铝木复合多层功能板及其制备方法
CN114316787A (zh) 一种uv转印胶、其制备方法和应用
CN212446569U (zh) 一种超薄防水复合石材
CN111805986A (zh) 一种超薄防水复合石材及其制备方法
CN1771125A (zh) 具有聚硅氧烷－脲共聚物的层合玻璃
CN202706410U (zh) 天然石材复合板
CN111409331A (zh) 一种夹胶玻璃的制作方法
CN105818490A (zh) 一种薄木/铝箔复合装饰贴面材料及其制造方法
CN114015370B (zh) 一种超薄印刷网格胶带及其生产方法
CN211815180U (zh) 一种防硅油转移的耐低温离型纸
CN206736156U (zh) 一种仿真皮革用泡棉胶带
TW201636407A (zh) 光學膠組成物、光學膠膜以及光學積層板
CN112571910B (zh) 一种多层夹胶玻璃的制作方法
CN112277409A (zh) 一种耐龟裂浸渍胶膜纸饰面板及其制备方法
CN101054269A (zh) 一种装饰玻璃的制造方法
CN210082579U (zh) 一种含金属层塑料网布的复合板
CN115503320B (zh) 一种人造仿皮革膜及其制备方法
CN117260901A (zh) 表面改性的竹束纤维层积材及其制备方法
CN206375827U (zh) 一种家用电器用弯钢玻璃
CN107718837A (zh) 一种复合材料板粘贴装饰层的方法
CN213680529U (zh) 一种直贴型曲面屏保护贴
CN211542675U (zh) 一种frp复合板
CN114260993B (zh) 一种复合木地板生产方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20201023

WW01 Invention patent application withdrawn after publication