CN111770693A - 泡沫控制 - Google Patents
泡沫控制 Download PDFInfo
- Publication number
- CN111770693A CN111770693A CN201980014076.0A CN201980014076A CN111770693A CN 111770693 A CN111770693 A CN 111770693A CN 201980014076 A CN201980014076 A CN 201980014076A CN 111770693 A CN111770693 A CN 111770693A
- Authority
- CN
- China
- Prior art keywords
- control agent
- foam control
- food
- foam
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000006260 foam Substances 0.000 title claims abstract description 78
- 235000013305 food Nutrition 0.000 claims abstract description 51
- 239000000203 mixture Substances 0.000 claims abstract description 47
- 238000000034 method Methods 0.000 claims abstract description 23
- 238000012545 processing Methods 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 48
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 16
- -1 dodecyltridecyl Chemical group 0.000 claims description 13
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 claims description 12
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 12
- 244000061456 Solanum tuberosum Species 0.000 claims description 12
- 235000021536 Sugar beet Nutrition 0.000 claims description 12
- 229920001400 block copolymer Polymers 0.000 claims description 9
- 239000003995 emulsifying agent Substances 0.000 claims description 9
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 claims description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000002210 silicon-based material Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 239000001993 wax Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 24
- 230000000052 comparative effect Effects 0.000 description 12
- 239000007788 liquid Substances 0.000 description 10
- 150000001298 alcohols Chemical class 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- XMVBHZBLHNOQON-UHFFFAOYSA-N 2-butyl-1-octanol Chemical compound CCCCCCC(CO)CCCC XMVBHZBLHNOQON-UHFFFAOYSA-N 0.000 description 4
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- 235000016068 Berberis vulgaris Nutrition 0.000 description 3
- 241000335053 Beta vulgaris Species 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 229920001223 polyethylene glycol Chemical class 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 2
- QHZLMUACJMDIAE-UHFFFAOYSA-N 1-monopalmitoylglycerol Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(O)CO QHZLMUACJMDIAE-UHFFFAOYSA-N 0.000 description 2
- WOFPPJOZXUTRAU-UHFFFAOYSA-N 2-Ethyl-1-hexanol Natural products CCCCC(O)CCC WOFPPJOZXUTRAU-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
- 238000007869 Guerbet synthesis reaction Methods 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229930195725 Mannitol Natural products 0.000 description 2
- 241000047703 Nonion Species 0.000 description 2
- 239000002202 Polyethylene glycol Chemical class 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 239000000594 mannitol Substances 0.000 description 2
- 235000010355 mannitol Nutrition 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N pentanal Chemical compound CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 2
- 235000012015 potatoes Nutrition 0.000 description 2
- YLQLIQIAXYRMDL-UHFFFAOYSA-N propylheptyl alcohol Chemical compound CCCCCC(CO)CCC YLQLIQIAXYRMDL-UHFFFAOYSA-N 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- JNYAEWCLZODPBN-KVTDHHQDSA-N (2r,3r,4r)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@@H](O)[C@H]1O JNYAEWCLZODPBN-KVTDHHQDSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- QAQSNXHKHKONNS-UHFFFAOYSA-N 1-ethyl-2-hydroxy-4-methyl-6-oxopyridine-3-carboxamide Chemical compound CCN1C(O)=C(C(N)=O)C(C)=CC1=O QAQSNXHKHKONNS-UHFFFAOYSA-N 0.000 description 1
- LFEHSRSSAGQWNI-UHFFFAOYSA-N 2,6,8-trimethylnonan-4-ol Chemical compound CC(C)CC(C)CC(O)CC(C)C LFEHSRSSAGQWNI-UHFFFAOYSA-N 0.000 description 1
- NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical compound CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 description 1
- MLWVTLFAQAGOGZ-UHFFFAOYSA-N 2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCOCCOCCOCCO MLWVTLFAQAGOGZ-UHFFFAOYSA-N 0.000 description 1
- IDTQVQPVUYLMJJ-UHFFFAOYSA-N 2-[2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCOCCOCCOCCOCCOCCO IDTQVQPVUYLMJJ-UHFFFAOYSA-N 0.000 description 1
- XPHIURAKMYNURA-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOCCOCCOCCOCCOCCOCCOCCOCCO XPHIURAKMYNURA-UHFFFAOYSA-N 0.000 description 1
- QNJAZNNWHWYOEO-UHFFFAOYSA-N 2-ethylheptan-1-ol Chemical compound CCCCCC(CC)CO QNJAZNNWHWYOEO-UHFFFAOYSA-N 0.000 description 1
- WGKYSFRFMQHMOF-UHFFFAOYSA-N 3-bromo-5-methylpyridine-2-carbonitrile Chemical compound CC1=CN=C(C#N)C(Br)=C1 WGKYSFRFMQHMOF-UHFFFAOYSA-N 0.000 description 1
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- DPBVCQFZSNLFCE-UHFFFAOYSA-N CCCCCCCCCCCCCCCCCCCCCC(=O)OC(CCCCCCCCCCCCC)C(CCCCCCCCCCCCC)O Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OC(CCCCCCCCCCCCC)C(CCCCCCCCCCCCC)O DPBVCQFZSNLFCE-UHFFFAOYSA-N 0.000 description 1
- SQSUQPMQFUIANC-UHFFFAOYSA-N CCCCCCCCCCCCCCCCCCCCCC(=O)OC(CCCCCCCCCCCCC)C(CCCCCCCCCCCCC)OC(=O)CCCCCCCCCCCCCCCCCCCCC Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OC(CCCCCCCCCCCCC)C(CCCCCCCCCCCCC)OC(=O)CCCCCCCCCCCCCCCCCCCCC SQSUQPMQFUIANC-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- IJCWFDPJFXGQBN-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-octadecanoyloxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCCCC IJCWFDPJFXGQBN-RYNSOKOISA-N 0.000 description 1
- QQVGEJLUEOSDBB-KTKRTIGZSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(CO)(CO)CO QQVGEJLUEOSDBB-KTKRTIGZSA-N 0.000 description 1
- JYXAPDMICIHKLZ-UHFFFAOYSA-N acetic acid N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine Chemical compound C(C)(=O)O.C(C)(=O)O.NCCNCCNCCN JYXAPDMICIHKLZ-UHFFFAOYSA-N 0.000 description 1
- VQARCJVIMMGOHZ-UHFFFAOYSA-N acetic acid;1-(2-heptadec-1-enyl-4,5-dihydroimidazol-1-yl)ethanamine Chemical compound CC(O)=O.CCCCCCCCCCCCCCCC=CC1=NCCN1C(C)N VQARCJVIMMGOHZ-UHFFFAOYSA-N 0.000 description 1
- ANRCSZILOHNONR-UHFFFAOYSA-N acetic acid;hexadecan-1-amine Chemical compound CC([O-])=O.CCCCCCCCCCCCCCCC[NH3+] ANRCSZILOHNONR-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- BZSWJGHEQUOKIP-UHFFFAOYSA-M didodecyl(diethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](CC)(CC)CCCCCCCCCCCC BZSWJGHEQUOKIP-UHFFFAOYSA-M 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- JLSXKFXWPLYPTE-UHFFFAOYSA-N n-(2,4-diaminobutyl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCC(N)CCN JLSXKFXWPLYPTE-UHFFFAOYSA-N 0.000 description 1
- FYRUYUVOQKFYAR-UHFFFAOYSA-N n-dodecyldodecan-1-amine;2-hydroxypropanoic acid Chemical compound CC(O)C(O)=O.CCCCCCCCCCCCNCCCCCCCCCCCC FYRUYUVOQKFYAR-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 235000021067 refined food Nutrition 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000001589 sorbitan tristearate Substances 0.000 description 1
- 235000011078 sorbitan tristearate Nutrition 0.000 description 1
- 229960004129 sorbitan tristearate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L19/00—Products from fruits or vegetables; Preparation or treatment thereof
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
- A23L5/20—Removal of unwanted matter, e.g. deodorisation or detoxification
- A23L5/27—Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
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Abstract
一种用于控制泡沫的方法，其包含提供包含泡沫控制剂和食物的食品组合物，所述泡沫控制剂；并加工所述食品组合物。一种食品组合物，其包含食物和泡沫控制剂。
Description
背景技术
用于制造食物的过程有时会导致产生不需要的泡沫。用于泡沫管理的机械方法效果有限。换言之，将泡沫控制剂添加到制造过程中以减少泡沫的产生。对于食品和制药应用，传统的泡沫控制剂包括基于环氧乙烷、基于环氧丙烷和基于硅酮的试剂。然而，这些现有的泡沫控制剂在食品工业中变得不受欢迎。需要可生物降解的并且可再生来源的泡沫控制剂。
发明内容
一种用于控制泡沫的方法，其包含提供包含泡沫控制剂和食物的食品组合物，所述泡沫控制剂包含如式(1)中所示的组合物
其中R是甲基、乙基、丙基、丁基、戊基、己基、庚基、辛基、壬基、癸基、十一烷基、十二烷基十三烷基或十四烷基，且m是1到14；并加工所述食品组合物。
一种食品组合物，其包含食物和泡沫控制剂，所述泡沫控制剂包含如式(1)中所示的组合物
其中R是甲基、乙基、丙基、丁基、戊基、己基、庚基、辛基、壬基、癸基、十一烷基、十二烷基十三烷基或十四烷基，且m是1到14。
具体实施方式
本公开描述用于控制泡沫的方法。本文所描述的方法具体与食品加工应用相关。在食品加工期间，在生产过程中的各个阶段都可产生泡沫。当在加工期间进行通气(例如通过机械搅动、混合、洗涤、萃取、搅拌、喷射等产生)时，泡沫由表面活性物质(如蛋白质、脂肪酸和糖)的存在引起。泡沫以许多不同的方式损害食品加工过程，并且极大地扰乱加工流程。与不使用本文所描述的方法的类似食品加工相比，本文所描述的方法在限制食品加工应用中产生的泡沫量方面是有效的。在不受理论限制的情况下，预期本公开的方法具有以下特征：(1)限制食品加工中产生的泡沫量(也称为抗泡剂)和(2)使所产生的泡沫降至最低或消除(也称为消泡剂)。如本领域中已知，将食品组合物和泡沫控制剂例如通过混合来组合。
本文所描述的方法包括向食物提供泡沫控制剂。泡沫控制剂包含式(1)中所示的组合物：
其中R是甲基、乙基、丙基、丁基、戊基、己基、庚基、辛基、壬基、癸基、十一烷基、十二烷基十三烷基或十四烷基，且
m是1到14；
式(1)的组合物是醇，其是格尔伯特反应(Guerbet reaction)的反应产物，这一反应将脂肪族伯醇转化成β-烷基化醇。在实验部分中描述了这些醇的合成。式(1)的组成为C6到C32。2-乙基己醇和2-丙基庚醇是具有式(1)的定义的组合物的实例，且二者均可从西格玛奥德里奇公司(Sigma Aldrich)购买获得。泡沫控制剂任选地还包括溶剂、表面活性剂、乳化剂或其组合。泡沫控制剂含有0.5重量％到100重量％的式(1)的组合物。
或者，泡沫控制剂含有5重量％到100重量％的式(1)的组合物。或者，泡沫控制剂含有10重量％到100重量％的式(1)的组合物。或者，泡沫控制剂含有15重量％到100重量％的式(1)的组合物。或者，泡沫控制剂含有20重量％到100重量％的式(1)的组合物。或者，泡沫控制剂含有25重量％到100重量％的式(1)的组合物。或者，泡沫控制剂含有30重量％到100重量％的式(1)的组合物。
选择泡沫控制剂中所含的任选溶剂以适合于溶解或分散式(1)的组合物。此类溶剂包括烃(芳香族和脂肪族二者)和氧化溶剂(醇、酮、醛、醚、二醇醚、酯和二醇醚酯)。
选择泡沫控制剂中所含的任选表面活性剂或乳化剂以适合于改进泡沫控制剂对食物的润湿性，或形成具有式(1)的组合物的乳液。任选的表面活性剂或乳化剂的量在式(1)的组合物的0.1重量％-30重量％的范围内。
任选的表面活性剂或乳化剂可以是阴离子的、阳离子的或非离子的。合适的阴离子表面活性剂或乳化剂的实例是碱金属、铵和胺皂；此类皂的脂肪酸部分优选地含有至少16个碳原子。皂也可以“原位”形成；换句话说，可将脂肪酸添加到油相中且将碱性材料添加到水相中。
合适的阴离子表面活性剂或乳化剂的其它实例是烷基-芳基磺酸的碱金属盐、二烷基磺基琥珀酸钠、硫酸化或磺化油(例如硫酸化蓖麻油)；磺化牛脂和短链石油磺酸的碱金属盐。
合适的阳离子表面活性剂或乳化剂是长链伯、仲或叔胺的盐，如油酰胺乙酸盐、十六烷基胺乙酸盐、二-十二烷基胺乳酸盐、氨基乙基-氨基乙基硬脂酰胺的乙酸盐、二月桂酰基三亚乙基四胺二乙酸盐、1-氨基乙基-2-十七烯基咪唑啉乙酸盐；和季盐，如十六烷基溴化吡啶鎓、十六烷基乙基氯化吗啉鎓和二乙基双十二烷基氯化铵。
合适的非离子表面活性剂或乳化剂的实例是高碳数脂肪醇与环氧乙烷的缩合产物，如油醇与10个环氧乙烷单元的反应产物；烷基酚与环氧乙烷的缩合产物，如异辛基酚与12个环氧乙烷单元的反应产物；高碳数脂肪酸酰胺与5个或更多个环氧乙烷单元的缩合产物；长链脂肪酸的聚乙二醇酯，如四乙二醇单棕榈酸酯、六乙二醇单月桂酸酯、九乙二醇单硬脂酸酯、九乙二醇二油酸酯、十三乙二醇单花生酸酯、二十三乙二醇单山嵛酸酯、二十三乙二醇二山嵛酸酯、如脱水山梨醇三硬脂酸酯的多元醇偏高碳数脂肪酸酯、多元醇偏高碳数脂肪酸酯以及其内酸酐(甘露醇酐，称为Mannitan，和山梨醇酐，称为Sorbitan)的环氧乙烷缩合产物，如与10分子环氧乙烷反应的甘油单棕榈酸酯、与12分子环氧乙烷反应的季戊四醇单油酸酯、与10-15分子环氧乙烷反应的山梨醇酐单硬脂酸酯、与10-15分子环氧乙烷反应的甘露醇酐单棕榈酸酯；其中一个羟基用高碳数脂肪酸酯化并且另一个羟基用低分子醇醚化的长链聚乙二醇，如甲氧基聚乙二醇550单硬脂酸酯(550意指聚乙二醇醚的平均分子量)。可使用这些表面活性剂中的两种或更多种的组合；例如，阳离子可与非离子掺合，或阴离子可与非离子掺合。
泡沫控制剂还可包含一种或多种添加剂。添加剂的实例包括环氧乙烷/环氧丙烷嵌段共聚物、环氧丁烷/环氧丙烷嵌段共聚物、环氧乙烷/环氧丁烷嵌段共聚物、蜡或基于硅酮的材料。
本文所描述的“食品组合物”是泡沫控制剂与食物的组合。食物是马铃薯衍生物或甜菜衍生物或其组合。如本文所使用，衍生物意指加工过的食物。此类方法的实例包括洗涤、切片、发酵、磨碎、压碎、去皮和混合。甜菜衍生物优选地是糖用甜菜衍生物(sugarbeetderivative)。可以在添加泡沫控制剂之前根据一个或多个加工步骤对食物进行预加工。或者，食物可以在加工步骤之间洗涤，从而在加工步骤的一个或多个期间单独添加泡沫控制剂。
将泡沫控制剂以足够的量添加到食物中，以达到所述过程所需的泡沫控制水平。应认识到，不同的食品加工技术导致不同泡沫产生水平，并且因此，需要不同量的泡沫控制剂来达到所需的结果。添加到食物中的泡沫控制剂的量以占泡沫控制剂和食物的组合重量(食品组合物的总重量)的百分比来测量，其中泡沫控制剂的量是食品组合物总重量的0.01重量％到5重量％，优选地是食品组合物总重量的0.1重量％到1重量％。
实例
混合的C8-C10格尔伯特醇的合成：
通过真空将2wt％的氢氧化钠于水中的溶液(50mL)转移到300mL的帕尔反应器(Parr reactor)中。然后将戊醛(48.2g，0.56mol)和丁醛(40.4g，0.56mol)进行预混合，并且随后添加到反应器中。用氮气加压反应器并快速搅拌(900rpm)，同时加热到120℃，在达到温度之后，搅拌反应混合物持续两小时，从而引起C8-C10烯醛中间体的形成。在五次氮气加压-放空-真空循环的情况下将C8-C10烯醛中间体装入含有25g
镍5887-200催化剂(
Nickel 5887-200 catalyst)(购自格雷斯催化剂技术公司(Grace CatalystTechnologies))的500mL注射管中，之后添加到反应器中。在添加期间，将反应控制在约25℃和1000rpm下。当温度逐渐上升到所需的设定点时，确定氢气控制压力(500psig)和时间零点(time zero)。在150℃和500psig-750psig下进行氢化。一旦氢气消耗停止，就确定反应结束。进程结束时，排出C8-C10格尔伯特醇产物并加以过滤以去除催化剂细粒。将此格尔伯特醇混合物在未经纯化的情况下用作泡沫控制剂进行测试(实例5)。
精制混合的C8-C10格尔伯特醇以获得C9格尔伯特醇
使用旋转带蒸馏塔在真空下以约10的回流比从如上文所描述制备的混合C8-C10格尔伯特醇的样品蒸馏C9格尔伯特醇(2-乙基庚-1-醇(2-ethylheptan-1-ol)和2-丙基己-1-醇(2-propylhexan-1-ol))的混合物。将此混合物用作泡沫控制剂进行测试(实例2)
实例1.可商购自西格玛-奥德里奇公司的2-乙基-1-己醇(C8格尔伯特醇)。
实例2.如上文所描述制备的C9格尔伯特醇混合物。
实例3.可商购自赢创公司(Evonik Company)的2-丙基庚醇(C10格尔伯特醇)。
实例4.可商购自西格玛-奥德里奇公司的2-丁基-1-辛醇(C11格尔伯特醇)。
实例5.如上文所描述制备的C8-C10格尔伯特醇混合物。
实例6.2-丁基-1-辛醇(C11格尔伯特醇)和2-乙基-1-己醇(C8格尔伯特醇)在室温下以1:1的重量比混合在一起。
以下醇用作比较实例，且可商购。一些比较实例是支链醇，但不是格尔伯特醇。其在不经进一步纯化的情况下就可以使用：
比较例1：获自西格玛-奥德里奇公司的4-甲基-2-戊醇。
比较例2：获自西格玛-奥德里奇公司的苯甲醇。
比较例3：获自西格玛-奥德里奇公司的2-甲基-1-丙醇。
比较例4：获自陶氏化学公司(Dow Chemical)的TMN醇、2,6,8-三甲基-4-壬醇。
泡沫控制性能评估
马铃薯用水洗涤、去皮并切片。将780g切片的马铃薯和520g去离子(DI)水添加到厨房食品加工机中，并加工1分钟。产生马铃薯浆液，将其透过滤纸进行过滤，并将所述液体用于评估泡沫控制剂。这种液体被称为马铃薯液。
类似地，糖用甜菜用水洗涤、去皮并切片。将780g切片的糖用甜菜和520g DI水添加到食品加工机中，并加工1分钟。产生糖用甜菜浆液，将其透过滤纸进行过滤，并将所述液体用于评估泡沫控制剂。这种液体被称为糖用甜菜液。
对于实例和比较实例中所描述的醇中的每一种，制备两个样品。第一样品含有0.5g的相应实例或比较实例中所描述的醇和99.5g的马铃薯液，以得到100g的用于评估的材料。第二样品含有0.5g的相应实例或比较实例中所描述的醇和99.5g的甜菜液，以得到100g的用于评估的材料。制备两个对照样品。第一样品含有100g马铃薯液，而不含任何醇。第二样品含有100g甜菜液，而不含任何醇。
利用喷射管测试来评估格尔伯特醇作为泡沫控制剂的性能。此测试程序的描述在文献中为已知的并且以引用的方式并入本文中：N.D.Denkov，“通过基于油的消泡剂来破坏泡沫的机理(Mechanisms of Foam Destruction by Oil-Based Antifoams)”，《朗缪尔(Langmuir)》2004，20(22)，9463-9505。通过测量材料对泡沫高度的影响来评估材料的“泡沫控制效率”。将100g上文所描述的每种液体样品单独添加到直径为5cm的1000mL玻璃圆筒中。将装配有烧结玻璃料的竖直气体喷射管放置在圆筒底部，并从圆筒底部鼓入空气。气流由设置为1的Ametek Lo-Flo 0-10浮点仪控制。在施加气流后的前10分钟期间记录泡沫高度。如果泡沫高度在前10分钟内达到1000mL，那么停止实验。
表1和2分别为随时间变化的实例、比较实例和对照样品的糖用甜菜液和马铃薯液的泡沫体积。在所述表中，实例缩写为“ex.”，且比较实例缩写为“cp.”。泡沫体积的数值单位为mL。如表中所示，对于马铃薯液和糖用甜菜液两者，格尔伯特醇的存在引起比没有格尔伯特醇的比较实例低得多的泡沫含量水平，其中泡沫体积在5分钟内达到至少1000mL。
表1：糖用甜菜液随时间变化的泡沫体积(mL)的增加
| 0.5分钟 | 1分钟 | 2分钟 | 3分钟 | 4分钟 | 5分钟 | 6分钟 | 7分钟 | 8分钟 | 9分钟 | 10分钟 | |
| 对照物 | 480 | 600 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 |
| ex.1 | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 20 | 20 |
| ex.2 | 50 | 50 | 50 | 60 | 60 | 60 | 60 | 60 | 60 | 60 | 60 |
| ex.3 | 100 | 80 | 80 | 80 | 60 | 60 | 60 | 60 | 60 | 60 | 60 |
| ex.4 | 200 | 220 | 310 | 410 | 450 | 400 | 350 | 350 | 350 | 350 | 350 |
| ex.5 | 50 | 50 | 50 | 50 | 50 | 50 | 50 | 50 | 50 | 50 | 50 |
| ex.6 | 140 | 150 | 220 | 250 | 250 | 250 | 300 | 300 | 300 | 300 | 300 |
| cp.1 | 450 | 530 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 |
| cp.2 | 500 | 580 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 |
| cp.3 | 450 | 510 | 850 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 |
| cp.4 | 350 | 430 | 710 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 |
表2：马铃薯液随时间变化的泡沫体积(mL)的增加
| 0.5分钟 | 1分钟 | 2分钟 | 3分钟 | 4分钟 | 5分钟 | 6分钟 | 7分钟 | 8分钟 | 9分钟 | 10分钟 | |
| 对照物 | 320 | 600 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 |
| ex.1 | 90 | 90 | 100 | 100 | 100 | 100 | 120 | 120 | 120 | 120 | 120 |
| ex.2 | 330 | 360 | 410 | 410 | 410 | 410 | 410 | 390 | 390 | 390 | 390 |
| ex.3 | 310 | 340 | 350 | 370 | 370 | 370 | 370 | 370 | 370 | 370 | 370 |
| ex.4 | 400 | 450 | 450 | 630 | 670 | 670 | 670 | 670 | 650 | 650 | 650 |
| ex.5 | 300 | 350 | 410 | 350 | 370 | 370 | 370 | 370 | 370 | 370 | 370 |
| ex.6 | 420 | 470 | 520 | 520 | 520 | 520 | 520 | 520 | 520 | 520 | 520 |
| cp.1 | 550 | 580 | 750 | 820 | 870 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 |
| cp.2 | 570 | 630 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 |
| cp.3 | 440 | 510 | 650 | 750 | 840 | >1000 | >1000 | >1000 | >1000 | >1000 | >1000 |
| cp.4 | 430 | 470 | 740 | 840 | 700 | 830 | 830 | 830 | 830 | 830 | 830 |
Claims (15)
1.一种用于控制泡沫的方法，其包含：
提供包含泡沫控制剂和食物的食品组合物，所述泡沫控制剂包含式(1)中所示的组合物
其中R是甲基、乙基、丙基、丁基、戊基、己基、庚基、辛基、壬基、癸基、十一烷基、十二烷基十三烷基或十四烷基，且
m是1到14；
加工所述食品组合物。
2.根据权利要求1所述的方法，其中所述泡沫控制剂含有0.5重量％到100重量％的如式(1)中所示的所述组合物。
3.根据权利要求1所述的方法，其中所述泡沫控制剂含有30重量％到100重量％的如式(1)中所示的所述组合物。
4.根据权利要求1到3中任一项所述的方法，其中所述食品组合物中的所述泡沫控制剂的量为0.01重量％到5重量％。
5.根据权利要求1到3中任一项所述的方法，其中所述食品组合物中的所述泡沫控制剂的量为0.1重量％到1重量％。
6.根据权利要求1到5中任一项所述的方法，其中所述泡沫控制剂还包含溶剂。
7.根据权利要求1到6所述的方法，其中所述泡沫控制剂还包含表面活性剂或乳化剂。
8.根据权利要求1到7中任一项所述的方法，其中所述食品加工包含洗涤、切片、发酵、磨碎、压碎、去皮或混合中的一种或多种。
9.根据权利要求1到8中任一项所述的方法，其中所述泡沫控制剂还包含添加剂，所述添加剂包含环氧乙烷/环氧丙烷嵌段共聚物、环氧丁烷/环氧丙烷嵌段共聚物、环氧乙烷/环氧丁烷嵌段共聚物、蜡或基于硅酮的材料。
10.根据权利要求1到9中任一项所述的方法，其中所述食物包含马铃薯衍生物或甜菜衍生物。
11.一种食品组合物，其包含：
食物和泡沫控制剂，所述泡沫控制剂包含如式(1)中所示的组合物
其中R是甲基、乙基、丙基、丁基、戊基、己基、庚基、辛基、壬基、癸基、十一烷基、十二烷基十三烷基或十四烷基，且
m是1到14。
12.根据权利要求11所述的食品组合物，其中所述食品组合物中的所述泡沫控制剂的量为0.01重量％到5重量％。
13.根据权利要求11到12中任一项所述的食品组合物，其中所述泡沫控制剂还包含溶剂。
14.根据权利要求11到13中任一项所述的食品组合物，其中所述泡沫控制剂还包含添加剂：环氧乙烷嵌段共聚物、环氧丙烷嵌段共聚物、环氧丁烷嵌段共聚物、蜡或基于硅酮的材料。
15.根据权利要求11到14中任一项所述的食品组合物，其中所述食物包含马铃薯衍生物或甜菜衍生物。
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| US201862644015P | 2018-03-16 | 2018-03-16 | |
| US62/644015 | 2018-03-16 | ||
| PCT/US2019/017648 WO2019177726A1 (en) | 2018-03-16 | 2019-02-12 | Foam control |
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| CN111770693A true CN111770693A (zh) | 2020-10-13 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| TWI815186B (zh) * | 2020-10-26 | 2023-09-11 | 美商陶氏全球科技有限責任公司 | 泡沫控制劑 |
| TWI838643B (zh) | 2020-10-26 | 2024-04-11 | 美商陶氏全球科技有限責任公司 | 廢水泡沫控制劑 |
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| CA3119465A1 (en) | 2018-11-21 | 2020-05-28 | Dow Global Technologies Llc | Polyester foam control agents and methods of processing foodstuffs |
| EP3842110B1 (en) * | 2019-12-23 | 2023-02-08 | Oleon N.V. | Foam destabilizers |
| JP7022451B2 (ja) * | 2020-09-16 | 2022-02-18 | 大洋香料株式会社 | 飲食品の液体原料用消泡剤 |
| US20230391644A1 (en) * | 2020-10-26 | 2023-12-07 | Dow Silicones Corporation | Wastewater foam control agent |
| TWI815185B (zh) * | 2020-10-26 | 2023-09-11 | 美商陶氏全球科技有限責任公司 | 農用產品泡沫控制劑 |
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- 2019-02-12 WO PCT/US2019/017648 patent/WO2019177726A1/en active Application Filing
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| TWI838643B (zh) | 2020-10-26 | 2024-04-11 | 美商陶氏全球科技有限責任公司 | 廢水泡沫控制劑 |
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| Publication number | Publication date |
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| EP3764821A1 (en) | 2021-01-20 |
| BR112020016994A2 (pt) | 2020-12-15 |
| EP3764821B1 (en) | 2022-08-31 |
| WO2019177726A1 (en) | 2019-09-19 |
| JP7317033B2 (ja) | 2023-07-28 |
| US20210000147A1 (en) | 2021-01-07 |
| JP2021516543A (ja) | 2021-07-08 |
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