CN111749030A - Reactive yellow dye ink for digital printing - Google Patents

Reactive yellow dye ink for digital printing Download PDF

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Publication number
CN111749030A
CN111749030A CN202010765922.7A CN202010765922A CN111749030A CN 111749030 A CN111749030 A CN 111749030A CN 202010765922 A CN202010765922 A CN 202010765922A CN 111749030 A CN111749030 A CN 111749030A
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Prior art keywords
parts
acid
component
yellow dye
digital printing
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Withdrawn
Application number
CN202010765922.7A
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Chinese (zh)
Inventor
苏勇志
杨泽辉
江启明
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Jiangsu Dewang Digital Technology Co ltd
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Jiangsu Dewang Digital Technology Co ltd
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Priority to CN202010765922.7A priority Critical patent/CN111749030A/en
Publication of CN111749030A publication Critical patent/CN111749030A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D06P1/5257—(Meth)acrylic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
    • D06P1/5285—Polyurethanes; Polyurea; Polyguanides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/56—Condensation products or precondensation products prepared with aldehydes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613—Polyethers without nitrogen
    • D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
    • D06P1/6135—Addition products of hydroxyl groups-containing compounds with oxiranes from aromatic alcohols or from phenols, naphthols
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6495—Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65118—Compounds containing hydroxyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65131—Compounds containing ether or acetal groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/667—Organo-phosphorus compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58—Material containing hydroxyl groups
    • D06P3/60—Natural or regenerated cellulose
    • D06P3/66—Natural or regenerated cellulose using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30—Ink jet printing

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)

Abstract

The invention discloses reactive yellow dye ink for digital printing, which comprises the following components in parts by weight: 2-15 parts of a reactive yellow dye; 20-35 parts of a surfactant; 0.2-0.4 part of a bactericide; 10-15 parts of a moisture absorbent; 2-3 parts of a dispersing agent; 8-10 parts of a penetrating agent; 2-4 parts of a stabilizer; 0.2-0.4 parts of pH value buffering agent; 82-85 parts of deionized water; the addition of the auxiliary agent in the ink synergistically improves the hydrolytic stability of the dye, the surface tension and the viscosity of the solution, thereby ensuring the good flowing property of the dye ink, having good thermal stability and being suitable for the inkjet printing of textiles. The ink-jet printing product has bright color, soft hand feeling and good fastness, wherein the fastness to sunlight can reach more than 4.5 grade, the fastness to dry rubbing can reach more than 4.5 grade, and the fastness to washing is 5 grade.

Description

Reactive yellow dye ink for digital printing
Technical Field
The invention belongs to ink for digital printing, and particularly relates to reactive yellow dye ink for digital printing.
Background
The digital printing is that the pattern is input into the Computer by digital form, and edited and processed by Computer printing color separation and drawing system (CAD-Computer Aided Design), and then the Computer controls the micro-piezoelectric ink jet nozzle to directly spray the special dye liquor onto the textile to form the required pattern.
The production process of the printing is realized by various digital means such as: the method comprises inputting various digital patterns processed by scanning, digital photo, image or computer into computer, processing by computer color separation printing system, directly spray-printing various special dyes (active, disperse, acidic main paint) on various fabrics or other media by special software through spray-printing system, and processing to obtain various high-precision printed products on various textile fabrics.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: provides the reactive yellow dye ink with high fastness for digital printing.
In order to solve the technical problems, the technical scheme provided by the invention is as follows: the reactive yellow dye ink for digital printing comprises the following components in parts by weight:
Figure BDA0002614585190000011
Figure BDA0002614585190000021
the active yellow dye comprises the following components in parts by weight: and (2) component A: 30-40 parts of a component B: 25-28 parts of component C: 28-30 parts of component D: 10-12 parts, component E: 6-8 parts of a component F: 25-28 parts;
the component A is as follows:
Figure BDA0002614585190000022
the component B is as follows:
Figure BDA0002614585190000023
Figure BDA0002614585190000031
mixtures of (a) in any proportion;
the component C is as follows:
Figure BDA0002614585190000032
the component D is
Figure BDA0002614585190000033
The component E is
Figure BDA0002614585190000034
Figure BDA0002614585190000041
The mixture is in any ratio.
The surfactant is a surfactant X-100.
The bactericide is one or a mixture of more of 5-chloro-2-methyl-4-isothiazolin-3-one, 1, 2-benzisothiazolin-3-one, s-triazine, 1, 6-dihydroxy-2, 5-dioxan and isothiazolinone.
The moisture absorbent is one or more of glycerol, propylene glycol, diethylene glycol and ethylene glycol.
The dispersing agent is selected from sodium methylene dinaphthalene sulfonate, a copolymer of sodium acrylate and propionamide, sodium polyacrylate, a condensate of naphthalenesulfonic acid, alkylphenol polyoxyethylene ether phosphate, sodium fatty acid methyl ester sulfonate, polyaspartic acid (sodium), hydrolytic polymaleic anhydride, TH-164 phosphono polyacrylic acid, polyacrylic acid and 2-amino-2-methyl-1-propanol, one or more of dimethyl-1-amino-1-ethanol, citric acid, phosphate, fatty alcohol-polyoxyethylene ether, C6-C18 fatty alcohol-polyoxyethylene ether, C6-C18 fatty ester-polyoxyethylene ether, styrene phenol sodium sulfonate, sodium polyacrylate, maleic acid-acrylic acid copolymer, polyvinyl alcohol, vinyl acetate copolymer, methacrylate and maleic anhydride copolymer.
The penetrating agent is one or a mixture of several of isooctanol, diethylene glycol monobutyl ether, dialkyl (hexyl, butyl and octyl) sulfosuccinate, hexanediol and isopropanol.
The stabilizer is one or a mixture of more of polyurethane, acrylate, acrylamide, amino trimethylene phosphonic acid, hydroxyethylidene diphosphonic acid, sodium ethylene diamine tetra methylene phosphonic acid, diethylene triamine penta methylene phosphonic acid, 2-phosphonic butane-1, 2, 4-tricarboxylic acid, 2-hydroxyphosphonoacetic acid and hexamethylene diamine tetramethylene phosphonic acid.
Has the advantages that: the addition of the auxiliary agent in the ink synergistically improves the hydrolytic stability of the dye, the surface tension and the viscosity of the solution, thereby ensuring the good flowing property of the dye ink, having good thermal stability and being suitable for the inkjet printing of textiles. The ink-jet printing product has bright color, soft hand feeling and good fastness, wherein the fastness to sunlight can reach more than 4.5 grade, the fastness to dry rubbing can reach more than 4.5 grade, and the fastness to washing is 5 grade.
Detailed Description
The process of the present invention is further illustrated below with reference to examples, but the invention is not limited thereto.
The active yellow dye ink for digital printing comprises the following components in g.
Figure BDA0002614585190000051
Figure BDA0002614585190000061
The performance test results of the reactive dye ink products for digital printing obtained in examples 1-4 are as follows:
Figure BDA0002614585190000062
examples 1-4 reactive yellow dye inks for digital printing of pure cotton fabrics:
fabric pretreatment (solution of padding liquid containing Matexil Enhancer SJP, sodium bicarbonate and sodium alginate paste) → drying (drying before printing) → ink-jet printing (printing on a Stork Trucolor ink-jet printing machine by adopting Procion p dye paste → drying (drying after printing) → steaming (steaming at normal pressure, 120 ℃, 8min) → washing with water → drying.
Figure BDA0002614585190000071
The ink-jet printing product has bright color, soft hand feeling and good fastness, wherein the light fastness can reach more than 4.5 grade, the friction fastness can reach more than 4.5 grade, and the washing fastness can reach 5 grade.

Claims (7)

1. The reactive yellow dye ink for digital printing comprises the following components in parts by weight:
Figure FDA0002614585180000011
the active yellow dye comprises the following components in parts by weight: and (2) component A: 30-40 parts of a component B: 25-28 parts of component C: 28-30 parts of component D: 10-12 parts, component E: 6-8 parts of a component F: 25-28 parts;
the component A is as follows:
Figure FDA0002614585180000012
the component B is as follows:
Figure FDA0002614585180000021
Figure FDA0002614585180000022
mixtures of (a) in any proportion;
the component C is as follows:
Figure FDA0002614585180000023
the component D is
Figure FDA0002614585180000031
The component E is
Figure FDA0002614585180000032
The mixture is in any ratio.
2. The reactive yellow dye ink for digital printing according to claim 1, wherein: the surfactant is a surfactant X-100.
3. The reactive yellow dye ink for digital printing according to claim 1, wherein: the bactericide is one or a mixture of more of 5-chloro-2-methyl-4-isothiazolin-3-one, 1, 2-benzisothiazolin-3-one, s-triazine, 1, 6-dihydroxy-2, 5-dioxan and isothiazolinone.
4. The reactive yellow dye ink for digital printing according to claim 1, wherein: the moisture absorbent is one or more of glycerol, propylene glycol, diethylene glycol and ethylene glycol.
5. The reactive yellow dye ink for digital printing according to claim 1, wherein: the dispersing agent is selected from sodium methylene dinaphthalene sulfonate, a copolymer of sodium acrylate and propionamide, sodium polyacrylate, a condensate of naphthalenesulfonic acid, alkylphenol polyoxyethylene ether phosphate, sodium fatty acid methyl ester sulfonate, polyaspartic acid (sodium), hydrolytic polymaleic anhydride, TH-164 phosphono polyacrylic acid, polyacrylic acid and 2-amino-2-methyl-1-propanol, one or more of dimethyl-1-amino-1-ethanol, citric acid, phosphate, fatty alcohol-polyoxyethylene ether, C6-C18 fatty alcohol-polyoxyethylene ether, C6-C18 fatty ester-polyoxyethylene ether, styrene phenol sodium sulfonate, sodium polyacrylate, maleic acid-acrylic acid copolymer, polyvinyl alcohol, vinyl acetate copolymer, methacrylate and maleic anhydride copolymer.
6. The reactive yellow dye ink for digital printing according to claim 1, wherein: the penetrating agent is one or a mixture of several of isooctanol, diethylene glycol monobutyl ether, dialkyl (hexyl, butyl and octyl) sulfosuccinate, hexanediol and isopropanol.
7. The reactive yellow dye ink for digital printing according to claim 1, wherein: the stabilizer is one or a mixture of more of polyurethane, acrylate, acrylamide, amino trimethylene phosphonic acid, hydroxyethylidene diphosphonic acid, sodium ethylene diamine tetra methylene phosphonic acid, diethylene triamine penta methylene phosphonic acid, 2-phosphonic butane-1, 2, 4-tricarboxylic acid, 2-hydroxyphosphonoacetic acid and hexamethylene diamine tetramethylene phosphonic acid.
CN202010765922.7A 2020-08-03 2020-08-03 Reactive yellow dye ink for digital printing Withdrawn CN111749030A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010765922.7A CN111749030A (en) 2020-08-03 2020-08-03 Reactive yellow dye ink for digital printing

Publications (1)

Publication Number Publication Date
CN111749030A true CN111749030A (en) 2020-10-09

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Country Status (1)

Country Link
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