CN111636218A - Acid dye ink for digital printing - Google Patents

Acid dye ink for digital printing Download PDF

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Publication number
CN111636218A
CN111636218A CN202010592137.6A CN202010592137A CN111636218A CN 111636218 A CN111636218 A CN 111636218A CN 202010592137 A CN202010592137 A CN 202010592137A CN 111636218 A CN111636218 A CN 111636218A
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China
Prior art keywords
acid
dye ink
digital printing
mixture
parts
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Application number
CN202010592137.6A
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Chinese (zh)
Inventor
苏勇志
杨泽辉
江启明
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Jiangsu Dewang Digital Technology Co ltd
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Jiangsu Dewang Digital Technology Co ltd
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Priority to CN202010592137.6A priority Critical patent/CN111636218A/en
Publication of CN111636218A publication Critical patent/CN111636218A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/39—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D06P1/5257—(Meth)acrylic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
    • D06P1/5285—Polyurethanes; Polyurea; Polyguanides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613—Polyethers without nitrogen
    • D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
    • D06P1/6135—Addition products of hydroxyl groups-containing compounds with oxiranes from aromatic alcohols or from phenols, naphthols
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621—Compounds without nitrogen
    • D06P1/622—Sulfonic acids or their salts
    • D06P1/623—Aliphatic, aralophatic or cycloaliphatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621—Compounds without nitrogen
    • D06P1/622—Sulfonic acids or their salts
    • D06P1/625—Aromatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/6426—Heterocyclic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65118—Compounds containing hydroxyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65131—Compounds containing ether or acetal groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/667—Organo-phosphorus compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30—Ink jet printing

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses acid dye ink for digital printing, which comprises the following components in parts by weight: 5-10 parts of acid dye, 0.2-1 part of surfactant, 0.1-0.5 part of bactericide, 8-15 parts of diethylene glycol, 8-12 parts of glycerol, 1.5-3 parts of dispersant, 8-12 parts of penetrating agent, 1-5 parts of stabilizer, 0.8-1.2 parts of pH regulator and 50-80 parts of deionized water. The reactive dye ink has the advantages of high reaction speed on fabrics, low cost, good color intensity, color fastness and color reproducibility and good proofing effect. The requirements for digital printing are met, various indexes of the disperse dye ink reach the standard, the stability is good, and the storage time is long.

Description

Acid dye ink for digital printing
Technical Field
The invention belongs to ink for digital printing, and particularly relates to acid dye ink for digital printing.
Background
The digital printing is that the pattern is input into the Computer by digital form, and edited and processed by Computer printing color separation and drawing system (CAD-Computer Aided Design), and then the Computer controls the micro-piezoelectric ink jet nozzle to directly spray the special dye liquor onto the textile to form the required pattern.
The production process of the printing is realized by various digital means such as: the method comprises inputting various digital patterns processed by scanning, digital photo, image or computer into computer, processing by computer color separation printing system, directly spray-printing various special dyes (active, disperse, acidic main paint) on various fabrics or other media by special software through spray-printing system, and processing to obtain various high-precision printed products on various textile fabrics.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: provides an acid dye ink for digital printing.
In order to solve the technical problems, the technical scheme provided by the invention is as follows: an acid dye ink for digital printing comprises the following components in parts by weight:
Figure BDA0002556346160000011
Figure BDA0002556346160000021
the acid dye ink for code printing preferably comprises the following components in parts by weight:
Figure BDA0002556346160000022
the acid dyes are C.I. acid yellow, C.I. acid orange, C.I. acid red, C.I. acid magenta, C.I. acid blue, C.I. acid violet and C.I. acid black.
The C.I. acid yellow is selected from one or a mixture of more of C.I. acid yellow 19, 49, 79, 90, 141 and 169;
the C.I. acid orange is selected from one or a mixture of C.I. acid orange 56, 95 and 156;
the C.I. acid red is selected from one or a mixture of more of C.I. acid red 114, 127, 145, 266, 318 and 337;
the C.I. acid fuchsin is selected from one or a mixture of more of C.I. acid fuchsin 143, 143:1, 249, 254 and 274;
the C.I. acid blue is selected from one or a mixture of more of C.I. acid blue 7, 9, 62, 83, 90, 112 and 185;
the C.I. acid violet is one or a mixture of C.I. acid violet 47 and C.I. acid violet 54;
the C.I. acid black is one or a mixture of more of C.I. acid black 24, 26, 52, 110 and 172.
The C.I. acid yellow is C.I. acid yellow 90; the C.I. acid red is C.I. acid red 266; the C.I. acid black is C.I. acid black 26 and/or C.I. acid black 110.
The surfactant is a surfactant X-100.
The bactericide is one or a mixture of more of 5-chloro-2-methyl-4-isothiazolin-3-one, 1, 2-benzisothiazolin-3-one, s-triazine, 1, 6-dihydroxy-2, 5-dioxan and isothiazolinone.
The dispersing agent is selected from sodium methylene dinaphthalene sulfonate, a copolymer of sodium acrylate and propionamide, sodium polyacrylate, a condensate of naphthalenesulfonic acid, alkylphenol polyoxyethylene ether phosphate, sodium fatty acid methyl ester sulfonate, polyaspartic acid (sodium), hydrolytic polymaleic anhydride, TH-164 phosphono polyacrylic acid, polyacrylic acid and 2-amino-2-methyl-1-propanol, one or more of dimethyl-1-amino-1-ethanol, citric acid, phosphate, fatty alcohol-polyoxyethylene ether, C6-C18 fatty alcohol-polyoxyethylene ether, C6-C18 fatty ester-polyoxyethylene ether, styrene phenol sodium sulfonate, sodium polyacrylate, maleic acid-acrylic acid copolymer, polyvinyl alcohol, vinyl acetate copolymer, methacrylate and maleic anhydride copolymer.
The penetrating agent is one or a mixture of several of isooctanol, diethylene glycol monobutyl ether, dialkyl (hexyl, butyl and octyl) sulfosuccinate, hexanediol and isopropanol.
The stabilizer is one or a mixture of more of polyurethane, acrylate, acrylamide, amino trimethylene phosphonic acid, hydroxyethylidene diphosphonic acid, sodium ethylene diamine tetra methylene phosphonic acid, diethylene triamine penta methylene phosphonic acid, 2-phosphonic butane-1, 2, 4-tricarboxylic acid, 2-hydroxyphosphonoacetic acid and hexamethylene diamine tetramethylene phosphonic acid.
Has the advantages that: the reactive dye ink has the advantages of high reaction speed on fabrics, low cost, good color intensity, color fastness and color reproducibility and good proofing effect. The requirements for digital printing are met, various indexes of the disperse dye ink reach the standard, the stability is good, and the storage time is long. The ink-jet printing product has bright color, soft hand feeling and good fastness, wherein the light fastness can reach more than 4 grades, the friction fastness can reach more than 5 grades, and the washing fastness can reach more than 5 grades.
Detailed Description
The process of the present invention is further illustrated below with reference to examples, but the invention is not limited thereto.
The acid dye ink for digital printing comprises the following components in g.
Figure BDA0002556346160000041
Figure BDA0002556346160000051
The acid dye ink products for digital printing obtained in examples 1 to 4 have the following performance test results:
Figure BDA0002556346160000052
examples 1-4 acid dye inks for digital printing were used for digital printing of nylon fabrics:
fabric pretreatment (solution of padding liquid containing Matexil Enhancer SJP, sodium bicarbonate and sodium alginate paste) → drying (drying before printing) → ink-jet printing (printing on a Stork Trucolor ink-jet printing machine by adopting Procion p dye paste → drying (drying after printing) → steaming (steaming at normal pressure, 120 ℃, 20-30 min) → washing in cold water → washing in warm water at 30-50 ℃), rinsing in warm water → rinsing in cold water → drying.
Figure BDA0002556346160000053
Figure BDA0002556346160000061
The reactive dye ink has the advantages of high reaction speed on fabrics, low cost, good color intensity, color fastness and color reproducibility and good proofing effect. The ink-jet printing product has bright color, soft hand feeling and good fastness, wherein the light fastness can reach more than 4 grades, the friction fastness can reach more than 5 grades, and the washing fastness can reach more than 5 grades.

Claims (10)

1. An acid dye ink for digital printing comprises the following components in parts by weight:
Figure FDA0002556346150000011
2. the acid dye ink for digital printing according to claim 1, which comprises the following components in parts by weight:
Figure FDA0002556346150000012
Figure FDA0002556346150000021
3. an acid dye ink for digital printing according to claim 1 or 2, wherein: the acid dyes are C.I. acid yellow, C.I. acid orange, C.I. acid red, C.I. acid magenta, C.I. acid blue, C.I. acid violet and C.I. acid black.
4. The acid dye ink for digital printing according to claim 3, wherein:
the C.I. acid yellow is selected from one or a mixture of more of C.I. acid yellow 19, 49, 79, 90, 141 and 169;
the C.I. acid orange is selected from one or a mixture of C.I. acid orange 56, 95 and 156;
the C.I. acid red is selected from one or a mixture of more of C.I. acid red 114, 127, 145, 266, 318 and 337;
the C.I. acid fuchsin is selected from one or a mixture of more of C.I. acid fuchsin 143, 143:1, 249, 254 and 274;
the C.I. acid blue is selected from one or a mixture of more of C.I. acid blue 7, 9, 62, 83, 90, 112 and 185;
the C.I. acid violet is one or a mixture of C.I. acid violet 47 and C.I. acid violet 54;
the C.I. acid black is one or a mixture of more of C.I. acid black 24, 26, 52, 110 and 172.
5. The acid dye ink for digital printing according to claim 4, wherein: the C.I. acid yellow is C.I. acid yellow 90; the C.I. acid red is C.I. acid red 266; the C.I. acid black is C.I. acid black 26 and/or C.I. acid black 110.
6. The acid dye ink for digital printing according to claim 1, wherein: the surfactant is a surfactant X-100.
7. The acid dye ink for digital printing according to claim 1, wherein: the bactericide is one or a mixture of more of 5-chloro-2-methyl-4-isothiazolin-3-one, 1, 2-benzisothiazolin-3-one, s-triazine, 1, 6-dihydroxy-2, 5-dioxan and isothiazolinone.
8. The acid dye ink for digital printing according to claim 1, wherein: the dispersing agent is selected from sodium methylene dinaphthalene sulfonate, a copolymer of sodium acrylate and propionamide, sodium polyacrylate, a condensate of naphthalenesulfonic acid, alkylphenol polyoxyethylene ether phosphate, sodium fatty acid methyl ester sulfonate, polyaspartic acid (sodium), hydrolytic polymaleic anhydride, TH-164 phosphono polyacrylic acid, polyacrylic acid and 2-amino-2-methyl-1-propanol, one or more of dimethyl-1-amino-1-ethanol, citric acid, phosphate, fatty alcohol-polyoxyethylene ether, C6-C18 fatty alcohol-polyoxyethylene ether, C6-C18 fatty ester-polyoxyethylene ether, styrene phenol sodium sulfonate, sodium polyacrylate, maleic acid-acrylic acid copolymer, polyvinyl alcohol, vinyl acetate copolymer, methacrylate and maleic anhydride copolymer.
9. The acid dye ink for digital printing according to claim 1, wherein: the penetrating agent is one or a mixture of several of isooctanol, diethylene glycol monobutyl ether, dialkyl (hexyl, butyl and octyl) sulfosuccinate, hexanediol and isopropanol.
10. The acid dye ink for digital printing according to claim 1, wherein: the stabilizer is one or a mixture of more of polyurethane, acrylate, acrylamide, amino trimethylene phosphonic acid, hydroxyethylidene diphosphonic acid, sodium ethylene diamine tetra methylene phosphonic acid, diethylene triamine penta methylene phosphonic acid, 2-phosphonic butane-1, 2, 4-tricarboxylic acid, 2-hydroxyphosphonoacetic acid and hexamethylene diamine tetramethylene phosphonic acid.
CN202010592137.6A 2020-06-25 2020-06-25 Acid dye ink for digital printing Withdrawn CN111636218A (en)

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Application Number Priority Date Filing Date Title
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Publications (1)

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CN111636218A true CN111636218A (en) 2020-09-08

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Country Status (1)

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Application publication date: 20200908