CN109627848A - A kind of functional ink and its Method of printing - Google Patents
A kind of functional ink and its Method of printing Download PDFInfo
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- CN109627848A CN109627848A CN201811504977.1A CN201811504977A CN109627848A CN 109627848 A CN109627848 A CN 109627848A CN 201811504977 A CN201811504977 A CN 201811504977A CN 109627848 A CN109627848 A CN 109627848A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
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- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
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Abstract
The invention discloses a kind of functional inks, by weight percentage, it is made of the following components: moisturizer: 5%-40%, viscosity modifier: 0.1%-5%, surfactant: 0.1%-10%, pH adjusting agent: 0.1%-5%, complexing agent: 0.1%-5%, fungicide: 0.1%-2%, functional aid: 0.1%-30%, water: its surplus；Wherein, the functional aid is one of quick colour-developing agent, fastness elevator, bleeding agent, softening agent, antistatic agent, anti-cloth hard finishing agent, antibacterial finishing agent and water-proof aagent or a variety of.In addition, the invention also discloses the Method of printings of the functional ink comprising 1) carry out pre-print on the print medium first with the functional ink before ink-jet ink carries out inkjet printing；2) it is printed after being carried out on the print media after the completion of ink-jet ink inkjet printing on the print medium using the functional ink；At least one of and 3) carry out printing on the print medium simultaneously using the functional ink and ink-jet ink.
Description
Technical field
The present invention relates to a kind of functional inks for inkjet printing, and in particular to it is a kind of can be with various ink jet ink water phases
The functional ink of excellent printing effect is realized in cooperation on all kinds of print media, moreover, it relates to described in one kind
The Method of printing of functional ink belongs to inkjet printing technology field.
Background technique
Currently, inkjet printing technology is widely used to building decoration materials printing, textile printing, packaging material
The various fields such as printing.It is by ink-jet printer by different types of ink-jet ink print on corresponding print media with
Printed patterns needed for being formed.Due to the diversity of print media, it is situated between especially for certain printings for not having ink-absorbed coated layer
Matter or the print media for being not suitable for certain class ink-jet ink, especially in textile field, before ink jet printing, it usually needs
Print media is pre-processed, by spray, the modes such as roller coating, pads, scratch and apply pretreating reagent on the print medium, with
After solving in ink injection to print media the problems such as required permeability, clarity, levelability and reactivity.Inkjet printing
After the completion, as needed, it also needs to carry out final finishing to the medium after printing sometimes, by spray, roller coating, pads, scratch etc. just
The dielectric surface of formula after printing applies post-treatment agent, so that the medium after printing meets the qualities such as color fastness, glossiness and wants
It asks.
In the prior art, pretreatment, inkjet printing and post-processing generally all carry out respectively, that is, use aforesaid way
The medium before printing and the medium after printing are pre-processed and post-processed respectively, and it is then sharp for inkjet printing link
It is carried out with ink-jet printer.This not only adds many and diverse treatment process, also result in can not to print media progress essence
Quasi- pretreatment and/or post-processing, does not reach satisfying printing effect；And it wastes there is also inorganic agent and thus makes
At environmental issue.
Summary of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of functional inks, can be auxiliary as needed
Various ink-jet inks are helped to realize excellent printing effect on various print media.In addition, another object of the present invention is to mention
For a kind of Method of printing of functional ink.
To achieve the above object, the invention adopts the following technical scheme:
According to an aspect of the present invention, a kind of functional ink is provided, by weight percentage, by with the following group
At being made: moisturizer: 5%-40%, viscosity modifier: 0.1%-5%, surfactant: 0.1%-10%, pH adjusting agent:
0.1%-5%, complexing agent: 0.1%-5%, fungicide: 0.1%-2%, functional aid: 0.1%-30%, water: its surplus.
Wherein, the moisturizer is higher boiling, difficult volatilization reagent, with for keeping the wetting of spray head to avoid blocking, specifically
Ground, in the present invention, the moisturizer includes but is not limited to: polyalcohol, hydramine, alcohol ether, amides, polyalcohols, polyethers, 2-
In pyrrolidones, 2-pyrrolidone-5-carboxylic acid, lactate, amine, uric acid, aminoglucose, citrate, sodium, potassium, calcium, magnesium phosphate, chlorine,
One or more of sugar, organic acid, peptides and other moisturizer.Preferably, the moisturizer is glycerine, 1,2- the third two
Alcohol, 1,3-PD, diglycol, dipropylene glycol, 1,5-PD, butanediol, polyethylene glycol, 1,2- hexylene glycol, two
Ethylene glycol monobutyl ether, xylitol, polypropylene glycol, D-sorbite sodium lactate, urea, N-Methyl pyrrolidone, 2-Pyrrolidone, urine
One of element, polyamine, ether and polyethers, polyalcohol and shrink alcohol are a variety of.
The viscosity modifier is used to adjust the requirement of the viscosity of ink to adapt to spray head, specifically, in the present invention, institute
State viscosity modifier can be polyalcohol, alcohol ether, long-chain fatty alcohol, polymerized polyalcohol, rouge and polyester, ether and polyethers, amide and
Polyamide and its salt, polyacrylic, polyurethanes dispersion and lotion, natural thickener such as sodium alginate, etherification starch, melon
That bean gum, methylcellulose, carboxymethyl cellulose, polyvinylpyrrolidone K40, hydroxyethyl cellulose, hydroxypropyl methyl fiber
One of high molecular polymers such as plain, middle molecule alcohol ether, macromolecule alcohol ether, PVA, PVC, PE, PET, PVP are a variety of.
The surfactant can be living using cationic surfactant, nonionic surfactant, anionic surface
Property one of agent and amphoteric surfactant or a variety of, surfactant can be it is natural, such as phosphatide, choline, albumen
Matter etc. is also possible to chemically synthesized, carboxylic acid, sulfonic acid, sulfuric acid, phosphoric acid, hydroxyl, amide groups, ether as having nonpolar hydrocarbon chain
Key, amino or amido and its salt are also possible to alcohols, ethers, lipid material and organic salt and polysalt.Specifically, in the present invention
In, the surfactant includes but is not limited to dodecyl sodium sulfate, sodium n-alkylbenzenesulfonate (LAS), fatty alcohol polyoxy
Ethylene ether sodium sulfate (AES), fatty alcohol polyoxyethylene ether ammonium sulfate (AESA), sldium lauryl sulfate (K12 or SDS), lauroyl
It is base glutamic acid, nonylphenol polyoxyethylene ether (TX-10), paregal O, diglycollic amide (6501) glycerol stearate monoesters, wooden
Plain sulfonate, heavy alkylbenzene sulfonate, alkylsulfonate (petroleum sulfonate), dispersing agent NNO, dispersing agent MF, alkyl, polyether
(PO-EO copolymer), fatty alcohol polyoxyethylene ether (AEO-3), have the acetylenic diols surfactant such as S-465 of air chemical industry
One of machine silicon class surfactant and organic fluoride class surfactant are a variety of, by the surface of the functional ink
Power is adjusted to 20-60mN/m, is preferably adjusted to 24-35mN/m.
On the one hand the pH adjusting agent can provide a good pH environment for the stability of the functional ink, another
Aspect can be also pH environment needed for ink printed post-processing.In the present invention, the pH adjusting agent can be inorganic acid alkali
Salt is also possible to organic acid alkali salt, is also possible to that acid or alkalinity substance is presented in water or other solvents, can also be with
Be it is subsequent evaporate or bake decomposite under environment acid perhaps alkaline matter evaporate or bake link embody it is suitable
The acid or alkali environment of reaction.Such as, under 100 DEG C of steaming conditions, sulfuric acid ammonium material can discharge acidic materials, further decrease Jie
The pH value on matter surface can provide the environment being suitble in conjunction with the fibers such as nylon for acid dyes；And sodium bicarbonate can be 100
Slight alkali environment is provided under DEG C steaming condition, adapts to contaminate cotton fiber on reactive dye.Therefore, pH adjusting agent is not only to guarantee institute
Stability and suitable spray property before stating functional ink printing, or required for subsequent i alphakjet printing and post-processing offer
Acidity and alkalinity environment.Specifically, the pH adjusting agent can be acetic acid, sodium hydroxide, citric acid, ammonium hydroxide, ammonium citrate, more
One of first organic amine, ammonium acetate, ammonium sulfate, urea, sodium carbonate, sodium bicarbonate, sodium phosphate, fatty alcohol ether sulfonate sodium or
It is a variety of.
The complexing agent is used to that high-valency metal salt ion that may be present and other inorganic impurities in ink-jet ink to be complexed,
It can also promote the interaction between the functional ink and other ink-jet inks and print media.Specifically, at this
In invention, the complexing agent can be hydroxide, citrate, pyrophosphate, thiosulfate, sulphite, ammonium phosphate,
Phosphoric acid salt such as sodium tripolyphosphate, sodium pyrophosphate, calgon；Alcamines such as monoethanolamine, diethanol amine, triethanolamine
Deng；Aminocarboxylate, such as sodium ammonium triacetate (NTA), edetate (EDETATE SODIUM or four sodium), five second of diethyl triamine
One of sour (DTPA), hydroxycarboxylate, organic phosphate, acrylic compounds chelating agent or a variety of.
The fungicide be sodium benzoate, potassium sorbate, dehydroactic acid sodium, calcium propionate, sodium Diacetate, sodium lactate, to hydroxyl
Yl benzoic acid propyl ester, nisin, hydrogen peroxide, chlorophenols, isothiazolinone, one kind or more of quaternary ammonium salt fungicide
Kind.
The water is deionized water, and conductivity is preferably smaller than 10000us/cm, is further preferably no larger than 2000us/cm,
Still more preferably it is less than 300us/cm.
In the present invention, the functional aid can be quick colour-developing agent, fastness mentions elevator, bleeding agent, softening agent,
One of antistatic agent, anti-cloth hard finishing agent, antibacterial finishing agent and water-proof aagent are a variety of, and its weight percent group
At preferably 5%-25%, further preferably 10%-20%.
Wherein, the quick colour-developing agent can be with the ingredient of rapid curing ink, in the present invention, and the quick colour-developing agent can
To be resin, high molecular polymer, the polyphosphazene polymer of cationic, non-ionic, anionic and amphoteric ion type can be
Object and surfactant are closed, inorganic acid, inorganic base, inorganic salts or its mixture are also possible to.It can be the substance of solid
The substance that can be liquid, can be deliquescent, be also possible to that the substance among solvent can be distributed to.Specifically, this hair
It is bright preferably to use the compounds such as cationic amine salt type, quaternary, heterocyclic type, there can be the different degree of polymerization, such as chlorination ten
Six alkyl pyridines, brocide, polymeric ammonium salts substance；The condensation of amine aldehyde resin type dicyandiamide formaldehyde initial reduced body polyamines
Body；Phenol formaldehyde condensation body；It is crosslinked color fixing agent；Active dye fixing agent KS, and the phenol sulfonic acid formaldehyde condensation on nylon fabric
Object, metal salt such as magnesium sulfate etc..Polyacrylamide high-molecular compound can also be used, no matter using anionic cation
Type or non-ionic polyacrylamide may all generate different functional impacts to print result.Poly- third can also be used
Olefin(e) acid resin, polyurethane based resin, and ink fastness, glossiness are obviously increased using organic siliconresin, fluorocarbon resin etc.
Substance.According to used ink and medium difference is printed, can also use has with cation: Na+、K+、NH4 +、Mg2+、Ca2+、
Ba2+、Al3+、Fe2+、Fe3+、Zn2+、Cu2+、Ag+The organic and substance salt of plasma is as color fixing agent.
The fastness elevator with other ink-jet inks for having an effect to obtain better fastness.Specifically,
The fastness elevator can be the high molecular polymer that can be combined closely with print media, such as water-based acrylic resin, aqueous
Polyurethane resin, water-based fluorocarbon resin, polyacrylamide, ammonium salt such as dodecyl dimethyl benzyl ammonium chloride and fatty alcohol
One of ether, metal salt are a variety of.
The bleeding agent can be used for the penetrating power of the other ink-jet inks of service hoisting on the print medium.Specifically, institute
Stating bleeding agent can be non-ionic such as penetrating agent JFC, paregal O；Anion has fast penetrant T, alkali-resistant penetrant
OEP-70, alkali-resistant penetrant AEP etc..Organic solvent or inorganic salts can also be added to reduce surface tension, such as polyalcohol gathers
Alcohol, polyethers and lipid etc., it is preferable that use fatty alcohol polyethenoxy ether class bleeding agent.
The softening agent can assist the functional ink to complete ejection function and not block spray head, while also achievable beat
Medium is printed, such as the soft final finishing function of fabric.Specifically, in the present invention, the softening agent can be sulfuric acid ester, sulfonate
Class surfactant, polyol esters of fatty acids, pentaerythritol fatty ester and fatty acid monoglyceride and Sorbitan alcohol ester
Fat acid esters etc.；Softening agent further includes alkanolamide, Polyoxyethylene fatty acid amides fatty acid ester, fatty diglycollic amide, polyethers, quaternary ammonium salt
Class, chitosan class, poly- ammonium salt class and a variety of organic amines.It can also be high molecular polymer softening agent, such as polyethylene wax, organosilicon
Polymer, as waterborne organic silicon oil EASYSOFT AEE (upper marine extraction Fine Chemical Co., Ltd), amino modified polysiloxane,
Acid anhydrides analog derivative, acid anhydrides or ketenes, quaternized pyridinium salt derivative, stearmide methylene pyridine chloride, epoxy group are spread out
One of distearyl amide ethyl glycidyl ammonium chloride biological, with epoxy group is a variety of.
The antistatic agent can avoid the print media such as chemical fibre, cotton fabric, plastic film in inkjet printing and subsequent make
With middle generation electrostatic.Specifically, the antistatic agent can be cationic antistatic agent such as quaternary ammonium alkyl, Lin Huo phosphonium salt
Chlorine, bromide；The anionic such as alkaline metal salt of alkylsulfonate, phosphate or aminodithioformic acid；Irrational type is anti-
Electrostatic agent has ethoxylated fat race alkylamine, ethoxylated alkyl acid amide, such as ethyoxyl lauramide and glycerol-stearic acid
One of ester is a variety of.
The anti-cloth hard finishing agent can have elastic stiffening effect according to print media is assigned, for example, it may make
The wool-like effect of textile is stronger, more flexible, and can be non-ironing after washing.Specifically, the anti-cloth hard finishing agent can be
Cymel, Lauxite, polyacrylate, polyvinyl acetate and its copolymer, melamine resin, polyethylene
Three-in-one non-ironing stiffening resin YT-808, polyesters or the starch of alcohols, reactive adipic acid resin such as Jinan space great waves chemical industry
And its one of derivative or a variety of.
The antibacterial finishing agent has the function of sterilizing and it is inhibited to generate.Specifically, the antibacterial finishing agent can be
All kinds of complex compounds of the elements such as nitrogen, sulphur, chlorine, principal item have: quaternary ammonium salt, alcohols, phenols, aldehydes, has biguanides
Machine metal class, pyridines, thiophene-based etc..Cationic nitrogenous compound, to bacterium have it is apparent inhibit and bactericidal effect, such as sun from
The geramine " 1227 " of subtype and bromogeramine etc., inorganic nano antiseptic class, mainly Ag, Co, Ni, Al, Ti, Zn,
The salt of the metal ions such as Cu, Fe, Mn, Sn, Ba, Mg, Ca.Such as nano zine oxide, nano-titanium oxide, nano aluminium oxide and containing silver-colored
The salt of ion.Natural antibacterial agent, such as Effect of Water Soluble Quaternary Ammonium Salt of Chitosan chitosan substance can also be added.
The water-proof aagent can assign the functions such as print media waterproof, antifouling, anti-stick and moisture absorbing and sweat releasing, print
After the completion, by being crosslinked, the surface tension of the print media polar regions such as fabric is assigned, not only makes moisture outside print media
It is easy to condense drippage, while can also retains print media for the permeability of air.Specifically, the water-proof aagent include but
It is not limited to metal ion complexes, stearic acid and the amino resins such as " aluminum acetate+paraffin soap lotion ", fatty acid and chromium, titanium, aluminium
Initial reduced body reaction product, it is poly- with paraffin wax emulsions mixture, hydroxyl methyl ether cellulose or itself condensation polymer, Organosilicon Polymers such as line style
Silicone emulsion or amino silicone oils, the polyether-modified fluorocarbon resin of fluorine-containing carbon structure are copolymerized containing fluoroalkyl
The substances such as object, fluorinated acrylate emulsion class.
According to another aspect of the present invention, a kind of preparation method of functional ink as described above, step packet are provided
Include: by each component, weight percent is mixed evenly and filters up to functional ink of the present invention as described above.
In accordance with a further aspect of the present invention, a kind of Method of printing of functional ink as described above is provided comprising: 1)
Pre-print is carried out on the print medium first with the functional ink before ink-jet ink carries out inkjet printing；2) in ink jet ink
Water prints after inkjet printing is carried out on the print media using the functional ink after the completion on the print medium；And 3)
At least one of carry out printing on the print medium simultaneously using the functional ink and ink-jet ink.
Specifically, functional ink of the invention can be used for any link of inkjet printing, for example, in printing ink jet ink
Before water, among and later at least one link, also, can for printing the ink-jet printer of the functional ink
It, can also be simultaneously using the functional ink with different function with independent, the same functional ink of reuse.In addition, suitable
Can be the different type channel of same print head together in functional ink print system of the invention and install respectively has difference
The functional ink of function is realized；It is also possible to using multiple print heads, each print head difference installation function ink comes real
It is existing；Alternatively, multiple groups spray head can also be used, every group of spray head installs the functional ink with a certain function respectively to realize；Again
Alternatively, a kind of functional ink is all installed in all channels for being also possible to whole printer or impression block group, by printer and
The combination of impression block group is realized.In short, can by selection sprayer channel, spray head quantity, nozzle group, printer quantity and
The printing of functional ink of the invention is realized at least one of impression block group, preferably at least two kinds of combination.
A preferred embodiment of the invention, the plurality of printers that can connect form print system, that is, by one
Different type channels, at least one spray head in the combination of N number of spray head, at least one set in N group spray head or the printing of N platform of spray head
At least one print unit in N number of print unit of machine is together in series on the moving direction of print media, in order to this
Print media carries out continuous inkjet and processing, wherein N is preferably greater than or equal to 2, also, the printer can be wide format printer, lead
With machine, purl machine either other be capable of the printer of separate printed.
For example, Fig. 1 shows a kind of print system including 5 printers or impression block group (P01-P05), wherein each
Printer or impression block group can install functional ink or ink-jet ink with different function respectively, to complete required printing
It is required that.According to the present invention, for example, the functional ink with pretreating reagent function can be installed in P01 and pacified in P02
Fill disperse dye ink, print media, as dacron successively passes through P01 and P02 according to the direction of motion of medium in figure
The printing of the dacron of pre-treatment is exempted from completion.Alternatively, installing in P01 a kind of has the function of aqueous pigment pretreatment function
Property ink, a kind of aqueous pigment ink is then installed in P02, a plurality of types of weavings without starching pre-treatment can be completed
Product printing.Or a kind of functional ink with aqueous pigment pretreatment function can be installed in P01, pacify in P02
A kind of aqueous pigment ink is filled, while installation has the functional ink for promoting color fastness in P03, to can not only realize nothing
Printing color fastness can also be promoted by needing a plurality of types of textiles of starching pre-treatment to print.For another example, in printing coloured media, such as band
When the cloth of background color, a kind of functional ink with aqueous white pigment pretreatment liquid function can be installed in P01, in P02
Middle installation white inkjet ink, white ink can be used then in print procedure by installing aqueous pigment color inks in P03
Background color is covered, color inks are printed upon above white ink again, to complete to the ink-jet printed of colored fabric.It is logical
Often, white ink printing must be pre- previously processed, and use Method of printing of the invention eliminates before being additionally carried out chalk printing
Pretreatment process, keep whole flow process very convenient.On the basis of above-mentioned printing, can also be installed in P04, P05 for example with
The functional ink of hard finishing function, with antistatic functional ink etc., above-mentioned print media is carried out with respectively hard
Very processing, antistatic treatment etc., in order to disposably realize more printing functions.
Particularly, functional printing is carried out using digital printing spray head due to the present invention, is arranged by printer software,
Can according to need and neatly control ink ejection amount, with spray head drop on demand ink jet, need to spray or do not spray according to function, spray it is how many and
Where spray, thus it is easier, digitally control print quality.Also, digital control software is used, can also be realized
Pattern part is sprayed or is not having figuratum place injection (being mirrored into pattern setting), and completes gray level printing；This is just
Condition is provided to the mirror image for printing pattern.The mirror image of pattern is exactly the reverse phase of pattern, the softwares such as existing PS be easy to by
Pattern reverse phase.The purpose of printing reverse tone is, in some textiles printings for needing to permeate, such as carpet and long pile fabric, because
The reason of to print principle, in the more ink-jets of pattern dark parts, lack ink-jet in light-colored part, this has resulted in entire picture infiltration
The different problem of depth, and light-colored part can show money or valuables one carries unintentionally, and reduce product quality.Purpose using mirror printed is by having
The functional ink for seeping sexual function is helped, mirror image, that is, the place of multicolour pattern depth are first printed on medium, few spray, which has, helps infiltration
The functional ink of sexual function, in the place that pattern is shallow, more sprays have the functional ink for helping and seeping sexual function, beat until next group
Print machine or impression block group print color inks, just have the functional ink and coloured silk for helping infiltration sexual function for what is printed on medium
Chromatic ink overall balance is got up, and is reached uneven color and is permeated consistent printing effect.
Using Method of printing of the invention, as N=2, function may be implemented in another embodiment according to the present invention
The inkjet printing and functional ink of ink-jet ink also may be implemented in the pre-print of ink and the inkjet printing of ink-jet ink
After print；And as N > 2, then the pre-print of achievable functional ink, the inkjet printing of ink-jet ink and functional ink
Rear printing.Particularly, pre-print process can also be split into more print units, to complete friction speed, difference
Ink ejection amount, and the printing of the functional ink with different function are completed with facilitating for speed, functionality, ink ejection amount etc.
Technique requirement；The ink jet printing process for being used for ink-jet coloring can also be split into more print units, e.g., come according to color code
It separating, each subelement is only completed a kind of printing of color ink jet ink, and multiple subelements complete the printing of bigger Essential colour, with
Expand printing colour gamut and other function requirement；It can also be using the spray of single perhaps multiple monochromes or a polychrome
Head combines these print units, can be scan-type, is also possible to single PASS printing.Similarly, the rear printing of functional ink
Process can also split into several subelements, to complete different auxiliary agents, different accuracy, different ink ejection amounts and different function
Inkjet printing or inkjet printing combination.
It will be appreciated by persons skilled in the art that ink-jet ink herein refers to the ink containing colorant, specifically
Ground, in the present invention, the ink-jet ink can be aqueous dye ink, aqueous pigment ink, reactive dye ink, dispersion dye
Expect ink, textile pigment ink, acid dye ink, basic dye ink, neutral dye ink, dye of positive ion ink, go back
Former dye ink, direct dyes ink, soluble vat dye ink, dispersible cationic ink, sulfur dye ink, azoic coupling component color
Base class azoic dyes insoluble azo dyes leuco dye ink, ice dye ink, solvent-based inks, Weak solvent dye ink and Weak solvent
Paint ink and Neutral writing ink, UV ink and aqueous UV ink, solvent type inorganic ceramic ink, aqueous inorganic ceramic ink,
One of aqueous UV white ink and solvent type white ink are a variety of.
The print media for being suitable for functional ink of the invention can be fabric, plate, art paper, glass, ceramics, modeling
Material, metal etc. do not have the print media of ink-absorbed coated layer, are also possible to printing paper, blank sheet of paper, paper jam, label paper etc. and have ink-absorbed coated layer
Print media, no longer enumerate herein.
Present invention functional ink as described above may be not only suitable for the heat hair of such as CANON, HP, Lexmark company
Alveolitoid spray head is equally applicable to each serial minute-pressure electric injector of such as EPSON company, could be applicable to the pressure of such as FUJI company
The pressure of the companies such as electric printing head and XAAR company, company, Kyocera, company, Ricoh, Panasonic Corporation, Konica Minolta
Electric-type printing head.
The beneficial effects of the present invention are functional ink of the invention can match progress with various ink-jet inks
Joint printing, auxiliary ink-jet ink realize excellent permeability, fixation ability, color representation power, jail on various print media
The performances such as degree, to reach different medium to fastness, color and other functional high requests.Print procedure is simply high
Effect, the processes such as can effectively replace pre-treatment in the prior art, post-processing save cost and improve production efficiency.
Detailed description of the invention
A kind of Fig. 1 embodiment according to the present invention, shows the schematic diagram of print system；
Fig. 2 shows the printing effect comparison diagrams in the embodiment of the present invention 1；
Fig. 3 shows the printing effect comparison diagram in the embodiment of the present invention 2；
Fig. 4 shows the printing effect comparison diagram in the embodiment of the present invention 3；
Fig. 5 shows the printing effect comparison diagram in the embodiment of the present invention 4.
Specific embodiment
A specific embodiment of the invention is described further combined with specific embodiments below.Unless otherwise noted, originally
Each component employed in invention can be commercially available by market.
Embodiment 1
A kind of functional ink is made up of and is made by weight percentage: glycerine: 25%, carboxymethyl cellulose
Element: 5%, S-465:0.5%, triethanolamine: 1.2%, ammonium sulfate: 4.5%, sodium tripolyphosphate: 0.7%, potassium sorbate:
0.5%, penetrating agent JFC: 6%, deionized water: its surplus；Each component is mixed evenly by the weight percent to obtain the final product
The functional ink.
By functional ink obtained in the present embodiment with acid dyes ink-jet ink (for example, available
Ink-jet printed acid dye ink in ZL2010102562359) it matches for pattern needed for being printed on nylon carpet
Mirror image grayscale image, specific print procedure include: advanced on nylon carpet using functional ink obtained in the present embodiment
It reuses acid dyes ink-jet ink after row printing and is printed, subsequent drying, decatize (at 100 DEG C 25 minutes), washing, again
After drying and processing.Meanwhile identical comparison, result such as Fig. 2 institute are done so that the printed matter of acid dyes ink-jet ink is used only
Show, in which: Fig. 2 a is the functional ink for having used the present embodiment and the printed product of acid dyes ink-jet ink；Fig. 2 b is only
Use the printed product of acid dyes ink-jet ink.As can be seen from Figure 2, ink has used the functionality of the present embodiment in fig. 2 a
Penetration depth in the nylon carpet of ink is much larger than the printing depth that functional ink is not used in Fig. 2 b；It follows that this
Functional ink obtained can effectively promote penetrating power of the acid dye ink on nylon carpet in embodiment.
Embodiment 2
A kind of functional ink is made of the following components by weight percentage: 1,2-PD: 25%, polyethylene
Pyrrolidones K-40 (PVP-K40): 1%, S-465:1%, ammonium sulfate: 0.5%, sodium tripolyphosphate: 2.2%, chlorination dodecane
Base dimethyl benzyl amine: 7.5%, isothiazolinone: 0.03%, deionized water: its surplus；Each component is pressed into the weight percent
Than being mixed evenly up to the functional ink.
By functional ink obtained in the present embodiment and aqueous pigment ink-jet ink (for example, in ZL2006100265953
Aqueous pigment digit printing ink) match for being printed on cotton fabric, specific print procedure include: using this
Functional ink obtained first carries out pre-print on cotton fabric in embodiment, is then beaten with aqueous pigment ink-jet ink
Print, and drying, bake (at 160 DEG C 3 minutes) and get product.Meanwhile the printed matter of aqueous pigment ink-jet ink is used only
Identical comparison is done, result is as shown in Figure 3, in which: Fig. 3 a is the printed product using only aqueous pigment ink-jet ink, and Fig. 3 b is
The functional ink of the present embodiment and the printed product of aqueous pigment ink-jet ink are used.From figure 3, it can be seen that having used this reality
The printed matter for applying the functional ink of example, color depth, saturation degree and in terms of be better than in Fig. 3 a be not used
The printed matter of functional ink.The Lab value testing result of the two is as shown in table 1:
Table 1Lab value testing result
Can be seen that from the testing result of table 1, using the present embodiment functional ink carry out pre-print after obtain at
Product have in terms of colour saturation, color depth and saturation degree and are significantly promoted, and largely expand colour gamut, mention
Product quality is risen.
Embodiment 3
A kind of functional ink is made of the following components by weight percentage: diglycol: 21%, poly- second
Glycol 400:5%, PVP-K40:4.5%, S-465:0.5%, dodecyl sodium sulfate: 0.45%, triethanolamine: 1%, carbonic acid
Sodium: 1.5%, EDTA- disodium: 0.5%, penetrating agent JFC: 0.5%, deionized water: its surplus；Each component is pressed into the weight hundred
Divide than the functional ink up to the present embodiment is mixed evenly.
By functional ink obtained in the present embodiment and reactive dye ink-jet ink (for example, in ZL2011100060210
Reactive dye ink) match for being printed on people's cotton filament yarn fabric, specific print procedure includes: to utilize this reality
It applies functional ink obtained in example first to carry out pre-print on cotton fabric and dry, then be beaten with reactive dye ink
Print, and drying, decatize (at 100 DEG C 15 minutes), cold water is washed, hot water wash, soaped, washing and finished product obtained by drying.Meanwhile
It is compared with the digit printing product that padding machine commonly used in the art pads active prime cement, result is as shown in Figure 4, wherein Fig. 4 a
The digit printing product of active prime cement is padded for padding machine in the prior art, Fig. 4 b is to have used functional ink in the present embodiment
Printed product illustrate the functionality using the present embodiment figure 4, it can be seen that the color and fastness ability of the two are suitable
The digit printing product of ink has tradition and pads the process function that prime cement has.Table 2 further illustrates the two
Lab value testing result:
Table 2Lab value testing result
From the Lab value testing result of table 2 it can further be shown that using the product after functional ink printing of the invention,
It obtains the depth or suitable of color than in the prior art, this shows function of the invention in terms of representative tetra- color of CMYK
It can the expansible printing colour gamut of property ink.
Embodiment 4
A kind of functional ink is made of the following components by weight percentage: 1,5-PD: 27%, poly- second two
Alcohol 400:10%, S-465:1%, dodecyl sodium sulfate: 1%, triethanolamine: 0.5%, EDTA- disodium: 0.7%, trimerization phosphorus
Sour sodium: 1.5%, Lubrijet T900 (Lubrizol Corp., main component be polyurethane resin): 15%, magnesium sulfate:
0.7%, PVA:0.55%, potassium sorbate: 0.2%, deionized water: its surplus；Each component is mixed by the weight percent
Stir evenly the functional ink up to the present embodiment.
By functional ink obtained in the present embodiment and aqueous pigment ink-jet ink (for example, in ZL2006100265953
Aqueous pigment digit printing ink) match for being printed on cotton fabric, specific print procedure include: first with reality
It applies the functional ink in example 2 and carries out pre-print on cotton fabric, aqueous pigment ink printing is then carried out, finally with this implementation
Functional ink in example prints after the same position of cotton fabric carries out to get product.Meanwhile functional ink is not used
Printout compare, result is respectively as shown in Fig. 5 and table 3- table 4, wherein Fig. 5 a be not used functional ink
Printed sample, and Fig. 5 b is the printed sample for having used functional ink, fastness to soaping test method: AATCC-61-2003-
2A (50 steel balls)；Fabric: Quality Pure Cotton Yarn Production card.In conjunction with can be seen that in Fig. 5 and table 3 and table 4, functionality ink of the invention has been used
Printed sample after water, coloured light pool, in terms of have and be obviously improved.Also, in the function for having used the present embodiment
The fastness to wet rubbing of printed sample after energy property ink is improved than the fastness to wet rubbing of the sample of unused functional ink
0.5 grade, there is higher fastness to wet rubbing, improve the wearability of printed sample.
3 fastness to soaping testing result of table
4 fastness to rubbing testing result of table
Embodiment 5
A kind of functional ink is made of the following components by weight percentage: diethylene glycol monobutyl ether: 33%, hydroxyl
Propyl methocel: 4.5%, S-465:1.2%, triethanolamine: 2%, EDTA- disodium: 0.2%, potassium sorbate:
0.22%, waterborne organic silicon oil EASYSOFT AEE:7%, deionized water: its surplus；Each component is pressed into the weight percent
The functional ink up to the present embodiment is mixed evenly.
By functional ink obtained in the present embodiment and aqueous pigment ink-jet ink (for example, in ZL2006100265953
Aqueous pigment digit printing ink) match for being printed on cotton fabric, specific print procedure include: first with water
Property paint ink printed on cotton fabric, then in the present embodiment functional ink carry out after print, and drying,
(at 140 DEG C 1 minute) is baked to get product.Relative to the printed sample of unused functional ink, the present embodiment has been used
The sample that functional ink obtains after printing after carrying out, in fabrics feel soft degree, smooth sophistication, resilience, whiteness etc.
Aspect, which has, to be obviously improved.
Embodiment 6
A kind of functional ink is made of the following components by weight percentage: 1,2- hexylene glycol: 15%, poly- second two
Alcohol 400:25%, sodium alginate: 3.5%, dodecyl sodium sulfate: 1.2%, triethanolamine: 3%, EDTA- disodium: 0.5%,
Sodium tripolyphosphate: 0.2%, dodecyl dimethyl benzyl ammonium chloride: 5%, deionized water: its surplus；By each component by described
The functional ink that weight percent is mixed evenly up to the present embodiment.
By functional ink obtained in the present embodiment and disperse dye ink (for example, the heat in ZL2014108204007
Transfer ink) it matches for being printed on terylene, specific print procedure includes: first with disperse dye ink in terylene
On printed, printed after then being carried out with the functional ink in the present embodiment, and thermally treated (at 130 DEG C 3 minutes) are i.e.
Obtain finished product.Meanwhile progress antistatic property detection, result such as table 5 are compared so that the printout of functional ink is not used
It is shown, in which: sample A is the printed sample for having used the functional ink of the present embodiment, and sample B is that functional ink is not used
Printed sample, the specific resistance of dacron is generally higher than 1014Ω cm is the non-conductive substance of high resistance, once generate electrostatic
Then it is easy to assemble to cause to concentrate and discharges.Specific resistance is reduced to 107Ω cm becomes conductive fine hereinafter, electric conductivity greatly increases
Peacekeeping fabric.As can be seen from Table 5, under different relative humidity, using knitting after the functional ink printing of the present embodiment
Object, hence it is evident that reduce its unit resistance, improve conductivity, and then increase the electric conductivity of fabric, enhance its antistatic energy
Power.
5 antistatic property testing result of table
| Relative humidity | 30% | 45% | 65% |
| Sample A | > 1013Ω·cm | > 1013Ω·cm | > 1013Ω·cm |
| Sample B | 1011~1012Ω·cm | 1010~1011Ω·cm | 109~1010Ω·cm |
Embodiment 7
A kind of functional ink is made of the following components by weight percentage: polyethylene glycol 200: 5%, poly- second two
Alcohol 400:25%, carboxyethyl cellulose: 0.85%, dodecyl sodium sulfate: 0.77%, triethanolamine: 0.5%, EDTA- tetra-
Sodium: 0.3%, potassium sorbate: 1.2%, penetrating agent JFC: 0.2%, fluorinated acrylate emulsion (Shanghai shriek chemical industry): 15%,
Deionized water: its surplus；Each component is mixed evenly to the functional ink of the present embodiment to obtain the final product by the weight percent.
By functional ink obtained in the present embodiment and disperse dye ink (for example, the heat in ZL2014108204007
Transfer ink) it matches for being printed on terylene, specific print procedure includes: first with disperse dye ink in terylene
On printed, printed after then being carried out with the functional ink in the present embodiment, and thermally treated (at 150 DEG C 1 minute) is i.e.
Obtain finished product.Meanwhile its contact angle to pure water of detection is compared so that the printout of functional ink is not used, contact angle is big
, water is not easy to soak in design on fabric surface, illustrates waterproofness height, and contact angle is small, and water is easy to soak in design on fabric surface, illustrates anti-
Aqueous difference, table 6 show testing result, in which: sample A is the printed sample for having used the functional ink of the present embodiment, sample
Product B is the printed sample that functional ink is not used.
The detection of 6 waterproof performance of table
| Pendulous frequency | For the first time | Second | For the third time | Average value |
| Sample A (contact angle) | 130° | 135° | 135° | 133.33° |
| Sample B (contact angle) | 63° | 65° | 62° | 43.33° |
As can be seen from Table 4, the sample A for having used the functional ink of the present embodiment to print, contact of the pure water on its surface
Angle becomes larger, and is transformed into opposite water repellent by relative hydropathic, produces good water repellent finish effect.
Embodiment 8
A kind of functional ink is made of the following components by weight percentage: 1,3 propylene glycol: 10%, poly- second two
Alcohol 400:15%, PVP-K40:4.4%, S-465:0.5%, ammonium sulfate: 1%, Effect of Water Soluble Quaternary Ammonium Salt of Chitosan: 8%, pyrophosphoric acid
Sodium: 3.5%, sodium benzoate: 0.5%, deionized water: its surplus；Each component is mixed evenly by the weight percent
Up to the functional ink of the present embodiment.
By functional ink obtained in the present embodiment and disperse dye ink (for example, the heat in ZL2014108204007
Transfer ink) it matches for being printed on terylene, specific print procedure includes: first with disperse dye ink in terylene
On printed, then in the present embodiment functional ink carry out after print, through preliminary drying (80 DEG C) and heat treatment (150
3 minutes at DEG C) after dry in the air to room temperature after carry out microculture (by AATCC90-1999 haloing test method(s) progress, this method is to be used for
The antibacterial efficacy qualitative rapid techniques of antibacterial agent screening, principle is: the inoculation test bacterium on agar medium, then is close to sample.
After being cultivated for 24 hours at 37 DEG C, with the haloing size of aseptic area around amplification sem observation mushroom breeding situation and sample).Meanwhile with
The printed sample that functional ink is not used compares, and the results are shown in Table 7, wherein sample A is to have used the present embodiment
The printed sample of functional ink, sample B are the printed sample that functional ink is not used.
The comparison of 7 anti-microbial property of table
As can be seen from Table 5, relative to sample B, the sample A for having used the functional ink of the present embodiment to print, dizzy
Occur apparent antibacterial circle in circle method antibacterial tests, illustrates it with good anti-microbial property.
Embodiment 9
A kind of functional ink is made of the following components by weight percentage: dipropylene glycol: 10%, polyethylene glycol
400:12%, carboxyethyl cellulose: 2%, S-465:0.5%, ammonium sulfate: 2%, sodium tripolyphosphate: 0.2%, penetrating agent JFC:
0.5%, three-in-one non-ironing stiffening resin YT-808 (Jinan space great waves chemical industry): 11%, deionized water: its surplus；Each component is pressed
The weight percent is mixed evenly up to functional ink described in the present embodiment.
By functional ink obtained in the present embodiment and aqueous pigment ink-jet ink (for example, in ZL2006100265953
Aqueous pigment digit printing ink) match for being printed on cotton fabric, specific print procedure include: first with water
Property paint ink is printed on cotton fabric, and with the functional ink in the present embodiment after being baked (at 150 DEG C 1 minute)
It is printed after progress, then thermally treated (at 150 DEG C 1 minute) obtains finished product.Relative to the printed sample of unused functional ink,
Obtained sample after printing after having used the functional ink of the present embodiment to carry out, Fabric Style are intended to very to scrape, smoothly, bullet
Property it is good, and reduce washing shrinkage, there is preferable dimensional stability for fabric.
The present invention has carried out detailed explanation by multiple implementation forms and embodiment.However, by grinding above
It reads, the variation and increase to each embodiment are also apparent to those of ordinary skill in the art.The intention of applicant
It is that all these variations and increase have been fallen in the protection scope of the claims in the present invention.
Term used herein is only to be illustrated to specific embodiment, is not intended to and limits the present invention
System.Unless otherwise defined, all terms (including technical terms and scientific terms) used herein are led with belonging to the present invention
The understanding of the those skilled in the art in domain is identical.Must also it is clear that, it is logical in such as dictionary except there is specific definition outer herein
The term often defined should be construed to can have the consistent meaning in the context of this specification and the relevant technologies, without that should solve
The idealization or excessively formalization released.
Claims (16)
1. a kind of functional ink is made of the following components by weight percentage: moisturizer: 5%-40%, viscosity-adjusting agent
Agent: 0.1%-5%, surfactant: 0.1%-10%, pH adjusting agent: 0.1%-5%, complexing agent: 0.1%-5%, sterilization
Agent: 0.1%-2%, functional aid: 0.1%-30%, water: its surplus.
2. functional ink according to claim 1, it is characterised in that: the moisturizer be glycerine, 1,2-PD,
1,3-PD, diglycol, dipropylene glycol, 1,5-PD, butanediol, polyethylene glycol, 1,2- hexylene glycol, diethyl two
Alcohol monobutyl ether, xylitol, polypropylene glycol, D-sorbite sodium lactate, urea, N-Methyl pyrrolidone, 2-Pyrrolidone, urea,
One of polyamine, ether and polyethers, polyalcohol and shrink alcohol are a variety of；The viscosity modifier is sodium alginate, etherificate shallow lake
Powder, guar gum, methylcellulose, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose, polyvinyl pyrrole
One of alkanone K40, middle molecule alcohol ether, macromolecule alcohol ether, PVA, PVC, PE, PET, PVP or a variety of.
3. functional ink according to claim 1, it is characterised in that: the surfactant is dodecyl sodium sulfonate
Sodium, sodium n-alkylbenzenesulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol, fatty alcohol polyoxyethylene ether ammonium sulfate, laruyl alcohol sulfuric acid
Sodium, lauroyl glutamate, nonylphenol polyoxyethylene ether, paregal O, diglycollic amide (6501) glycerol stearate monoesters, wood
Mahogany sulfonate, heavy alkylbenzene sulfonate, alkylsulfonate, dispersing agent NNO, dispersing agent MF, PO-EO copolymer, poly alkyl alcohol
One of ethylene oxide ether, acetylenic diols surfactant, organosilicone surfactants and organic fluoride class surfactant or
It is a variety of；The pH adjusting agent is sodium carbonate, sodium hydroxide, acetic acid, citric acid, ammonium hydroxide, ammonium citrate, ammonium acetate, sulfuric acid
One of ammonium, multi-element organic amine, urea, sodium bicarbonate, sodium phosphate, fatty alcohol ether sulfonate sodium are a variety of.
4. functional ink according to claim 1, it is characterised in that: the complexing agent be ammonium phosphate, sodium tripolyphosphate,
Sodium pyrophosphate, calgon, monoethanolamine, diethanol amine, triethanolamine, sodium ammonium triacetate, EDETATE SODIUM, tetra- sodium of EDTA,
One of diethyl pentetic acid, hydroxycarboxylate, organic phosphate, acrylic compounds chelating agent are a variety of；The sterilization
Agent is sodium benzoate, potassium sorbate, dehydroactic acid sodium, calcium propionate, sodium Diacetate, sodium lactate, propylparaben, lactic acid
Streptostacin, hydrogen peroxide, chlorophenols, isothiazolinone, quaternary ammonium salt fungicide it is one or more.
5. functional ink according to claim 1, it is characterised in that: the functional aid is quick colour-developing agent, jail
Spend one of elevator, bleeding agent, softening agent, antistatic agent, anti-cloth hard finishing agent, antibacterial finishing agent and water-proof aagent
Or it is a variety of.
6. functional ink according to claim 5, it is characterised in that: the quick colour-developing agent is hexadecyl pyrrole
Pyridine, brocide, dicyandiamide formaldehyde initial reduced body polyamines condensation body, color fixing agent KS, phenol sulfonic acid formaldehyde condensation products, metal
One of salt is a variety of；The fastness elevator be water-based acrylic resin, waterborne polyurethane resin, water-based fluorocarbon resin,
One of polyacrylamide, ammonium salt and fatty alcohol ether, metal salt are a variety of.
7. functional ink according to claim 5, it is characterised in that: the bleeding agent be penetrating agent JFC, paregal O,
One of penetrant t, bleeding agent OEP-70, bleeding agent AEP or a variety of；The softening agent is polyol esters of fatty acids, season penta
Four alcohol fatty acid esters, fatty acid monoglyceride, sorbitan fatty acid ester, alkanolamide, Polyoxyethylene fatty acid amides fatty acid ester, fat
Sour diglycollic amide, polyethylene wax, organosilicon polymer, amino modified polysiloxane, acid anhydrides analog derivative, acid anhydrides or ketenes,
Quaternized pyridinium salt derivative, stearmide methylene pyridine chloride, epoxy radical derivative, the distearyl with epoxy group
One of amine ethyl glycidyl ammonium chloride is a variety of.
8. functional ink according to claim 5, it is characterised in that: the antistatic agent is ethoxylated fat race alkane
One of base amine, ethoxylated alkyl acid amide, ethyoxyl lauramide, glycerol-stearate are a variety of；It is described it is anti-endure with all one's will it is whole
Reason agent be cymel, Lauxite, polyacrylate, polyvinyl acetate and its copolymer, melamine resin,
Polyvinyl alcohol, polyesters or one of starch and its derivative are a variety of.
9. functional ink according to claim 5, it is characterised in that: the antibacterial finishing agent is nano zine oxide, receives
Rice titanium oxide, one of nano aluminium oxide, chitosan substance or a variety of；The water-proof aagent is amino silicone oils, is contained
The polyether-modified fluorocarbon resin of fluorine carbon structure, fluorine-containing alkyl acrylate copolymer, one in lotion containing fluoroalkyl
Kind is a variety of.
10. a kind of Method of printing of the functional ink as described in any one of claim 1-9, it is characterised in that: described
Method includes: 1) to be beaten in advance on the print medium before ink-jet ink carries out inkjet printing first with the functional ink
Print；2) it is carried out on the print media after the completion of ink-jet ink inkjet printing on the print medium using the functional ink
After print；And 3) using the functional ink and ink-jet ink printed simultaneously on the print medium at least one
Kind.
11. Method of printing according to claim 10, it is characterised in that: the pre-print includes same functional ink
Printing or the printing at least once of the functional ink with different function at least once.
12. Method of printing according to claim 10, it is characterised in that: printing includes same functional ink after described
Printing or the printing at least once of the functional ink with different function at least once.
13. the Method of printing according to any one of claim 9-12, it is characterised in that: the Method of printing can pass through
At least one of sprayer channel, spray head quantity, nozzle group, printer quantity and impression block group is selected to realize.
14. Method of printing according to claim 13, it is characterised in that: the Method of printing can be logical by selection spray head
At least two in road, spray head quantity, nozzle group, printer quantity and impression block group realize.
15. the Method of printing according to any one of claim 9-12, it is characterised in that: the pre-print may be split into
Multiple print units are to complete the printing of friction speed, different ink ejection amount and the functional ink with different function.
16. the Method of printing according to any one of claim 9-12, it is characterised in that: printing may be split into after described
Multiple print units are to complete the printing of friction speed, different ink ejection amount and the functional ink with different function.
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