CN111691184A - 一种缝编连续毡浸润剂的制备方法 - Google Patents
一种缝编连续毡浸润剂的制备方法 Download PDFInfo
- Publication number
- CN111691184A CN111691184A CN202010409432.3A CN202010409432A CN111691184A CN 111691184 A CN111691184 A CN 111691184A CN 202010409432 A CN202010409432 A CN 202010409432A CN 111691184 A CN111691184 A CN 111691184A
- Authority
- CN
- China
- Prior art keywords
- water
- stitch
- reactor
- sizing agent
- uniformly stirring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004513 sizing Methods 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- 238000003756 stirring Methods 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920000728 polyester Polymers 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- 239000000314 lubricant Substances 0.000 claims abstract description 11
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 8
- 238000005303 weighing Methods 0.000 claims abstract description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 18
- 239000002202 Polyethylene glycol Substances 0.000 claims description 9
- 229920001223 polyethylene glycol Polymers 0.000 claims description 9
- 150000001408 amides Chemical group 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 4
- 239000003093 cationic surfactant Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 239000004846 water-soluble epoxy resin Substances 0.000 claims description 3
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims description 2
- 238000002242 deionisation method Methods 0.000 claims 1
- 239000003365 glass fiber Substances 0.000 abstract description 9
- 239000000080 wetting agent Substances 0.000 abstract description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 2
- 238000009776 industrial production Methods 0.000 abstract description 2
- 239000004014 plasticizer Substances 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 201000003373 familial cold autoinflammatory syndrome 3 Diseases 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000012681 fiber drawing Methods 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 238000009787 hand lay-up Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
- D06M13/5135—Unsaturated compounds containing silicon atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/55—Epoxy resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Abstract
一种缝编连续毡浸润剂的制备方法，属于玻璃纤维缝编毡的润湿剂制备领域，包括如下步骤：步骤一：称量的水溶性成膜剂、润滑剂、硅烷偶联剂、酸碱度调节剂；步骤二：将酸碱度调节剂与去离子水加入反应器中，搅拌均匀：步骤三：向反应器中加入硅烷偶联剂，搅拌均匀；步骤四：向反应器中加入水溶性成膜剂，搅拌均匀；步骤五：向反应器中加入润滑剂，搅拌均匀；步骤六：向反应器中补加入去离子水，搅拌均匀，既得浸润剂。本发明是水溶性体系，操作简单，便于工业化生产；同时，本发明中的水溶性成膜剂中选用的水溶性聚酯为含有较的酯键和醚键，使该成膜剂具有较好的亲水性和极性，反应型增塑剂的加入使产品在未烘干状态滑爽，烘干状态集束性极佳。
Description
技术领域
本发明属于玻璃纤维缝编毡的润湿剂制备领域，具体地说是一种缝编连续毡浸润剂的制备方法。
背景技术
玻璃纤维缝编毡，是由按一定方向排列的无捻粗纱或方格布作为基层材料，经短切成一定的长度后，无定向均匀平铺,用有机纤维缝编而成。玻璃纤维缝编毡应用于增强不饱和聚酯树脂并适用于拉挤成型、注射成型 (RTM)、缠绕成型、手糊成型等玻璃钢成型工艺。如拉挤型材管道、贮罐、风力发电机叶片等制品。但是目前的现有技术不能满足产品连续抛丝作业需求。在抛丝附件上无法附着或易结皮导致抛丝作业无法进行。从而影响了产品的性能。
发明内容
本发明提供一种缝编连续毡浸润剂的制备方法，用以解决现有技术中的缺陷。
本发明通过以下技术方案予以实现：
一种缝编连续毡浸润剂的制备方法，包括如下步骤：
步骤一：称量的水溶性成膜剂、润滑剂、硅烷偶联剂、酸碱度调节剂；
步骤二：将酸碱度调节剂与去离子水加入反应器中，搅拌均匀：
步骤三：向反应器中加入硅烷偶联剂，搅拌均匀；
步骤四：向反应器中加入水溶性成膜剂，搅拌均匀；
步骤五：向反应器中加入润滑剂，搅拌均匀；
步骤六：向反应器中补加入去离子水，搅拌均匀，既得浸润剂。
如上所述的一种缝编连续毡浸润剂的制备方法，所述的物料的重量百分比为：
如上所述的一种缝编连续毡浸润剂的制备方法，所述的水溶性成膜剂为水溶性聚酯、水性环氧树脂、水性聚酯乳液的其中一种或任意两种以上以任意比例混合的混合物。
如上所述的一种缝编连续毡浸润剂的制备方法，所述的润滑剂为非离子型表面活性剂、阳离子表面活性剂的其中一种或两种以任意比例混合的混合物。
如上所述的一种缝编连续毡浸润剂的制备方法，所述的非离子型表面活性剂为聚乙二醇，所述的聚乙二醇的分子量为200-600。
如上所述的一种缝编连续毡浸润剂的制备方法，所述的阳离子表面活性剂为酰胺类表面活性剂。
如上所述的一种缝编连续毡浸润剂的制备方法，所述的酰胺类表面活性剂使用前要先用65-70℃的去离子充分稀释均匀。
如上所述的一种缝编连续毡浸润剂的制备方法，所述的硅烷偶联剂为γ-氨丙基三乙氧基硅烷、γ-缩水甘油醚氧丙基三甲氧基硅烷、γ-(甲基丙烯酰氧)丙基三甲氧基硅烷的其中一种或任意两种以上以任意比例混合的混合物。
如上所述的一种缝编连续毡浸润剂的制备方法，所述的酸碱度调节剂占总重量为乙酸或柠檬酸的其中任意一种。
本发明的优点是：本发明是水溶性体系，操作简单，便于工业化生产；同时，本发明中的水溶性成膜剂中选用的水溶性聚酯为含有较的酯键和醚键，使该成膜剂具有较好的亲水性和极性，反应型增塑剂的加入使产品在未烘干状态滑爽，烘干状态集束性极佳。水性环氧及聚酯乳液的加入给产品提供了良好的浸透效果，聚酯乳液的使用为拉丝过程提供良好的附着效果。本发明的润滑体系以聚乙二醇非离子表面活性剂为主，酰胺类阳离子润滑剂为辅。阳离子润滑剂满足玻璃纤维拉丝过程的摩擦要求，非离子润滑剂提供纱线铺层较薄的效果。此润滑体系满足成膜剂相溶性和浸润剂稳定性要求。
具体实施方式
为使本发明实施例的目的、技术方案和优点更加清楚，下面将结合本发明实施例，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1
步骤一：称量0.5Kg水溶性聚酯、0.5Kg水性环氧树脂、0.1Kg水性聚酯乳液、0.1Kg聚乙二醇(分子量为400)、0.05Kg酰胺类表面活性剂、 0.2Kgγ-(甲基丙烯酰氧)丙基三甲氧基硅烷、0.05kg乙酸；
步骤二：将乙酸与50Kg去离子水加入反应器中，搅拌均匀：
步骤三：向反应器中加入γ-(甲基丙烯酰氧)丙基三甲氧基硅烷，搅拌均匀；
步骤四：向反应器中加入的水溶性聚酯、水性环氧树脂、水性聚酯乳液，搅拌均匀；
步骤五：向反应器中加入聚乙二醇和事先用1Kg的65-70℃的去离子水充分稀释均匀的酰胺类表面活性剂，搅拌均匀；
步骤六：向反应器中补加入去离子水至总重量为100Kg，搅拌均匀，既得浸润剂。
实施例2
步骤一：称量0.3Kg水溶性聚酯、0.6Kg水性环氧树脂、0.2Kg水性聚酯乳液、0.15Kg聚乙二醇(分子量为400)、0.05Kg酰胺类表面活性剂、0.2Kgγ-氨丙基三乙氧基硅烷、0.1kg乙酸；
步骤二：将乙酸与50Kg去离子水加入反应器中，搅拌均匀：
步骤三：向反应器中加入γ-氨丙基三乙氧基硅烷，搅拌均匀；
步骤四：向反应器中加入的水溶性聚酯、水性环氧树脂、水性聚酯乳液，搅拌均匀；
步骤五：向反应器中加入聚乙二醇和事先用1Kg的65-70℃的去离子水充分稀释均匀的酰胺类表面活性剂，搅拌均匀；
步骤六：向反应器中补加入去离子水至总重量为100Kg，搅拌均匀，既得浸润剂。
将使用传统方法制备的玻璃纤维缝编毡与使用本实施例1和实施例2的浸润剂的制备的玻璃纤维缝编毡在性能上进行对比，其结果如表一所示：
表一
由表一数据可以得知，使用施例1和实施例2的浸润剂的制备的玻璃纤维缝编毡在拉伸性能与弯曲性能上均明显优于使用传统方法制备的玻璃纤维缝编毡，故而使用本发明所制备的润湿剂能够起到提升产品性能的作用。
最后应说明的是：以上实施例仅用以说明本发明的技术方案，而非对其限制；尽管参照前述实施例对本发明进行了详细的说明，本领域的普通技术人员应当理解：其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换；而这些修改或者替换，并不使相应技术方案的本质脱离本发明各实施例技术方案的精神和范围。
Claims (9)
1.一种缝编连续毡浸润剂的制备方法，其特征在于：包括如下步骤：
步骤一：称量的水溶性成膜剂、润滑剂、硅烷偶联剂、酸碱度调节剂；
步骤二：将酸碱度调节剂与去离子水加入反应器中，搅拌均匀：
步骤三：向反应器中加入硅烷偶联剂，搅拌均匀；
步骤四：向反应器中加入水溶性成膜剂，搅拌均匀；
步骤五：向反应器中加入润滑剂，搅拌均匀；
步骤六：向反应器中补加入去离子水，搅拌均匀，既得浸润剂。
2.根据权利要求1所述的一种缝编连续毡浸润剂的制备方法，其特征在于：所述的物料的重量百分比为：
3.根据权利要求1或2所述的一种缝编连续毡浸润剂的制备方法，其特征在于：所述的水溶性成膜剂为水溶性聚酯、水性环氧树脂、水性聚酯乳液的其中一种或任意两种以上以任意比例混合的混合物。
4.根据权利要求1或2所述的一种缝编连续毡浸润剂的制备方法，其特征在于：所述的润滑剂为非离子型表面活性剂、阳离子表面活性剂的其中一种或两种以任意比例混合的混合物。
5.根据权利要求4所述的一种缝编连续毡浸润剂的制备方法，其特征在于：所述的非离子型表面活性剂为聚乙二醇，所述的聚乙二醇的分子量为200-600。
6.根据权利要求4所述的一种缝编连续毡浸润剂的制备方法，其特征在于：所述的阳离子表面活性剂为酰胺类表面活性剂。
7.根据权利要求6所述的一种缝编连续毡浸润剂的制备方法，其特征在于：所述的酰胺类表面活性剂使用前要先用65-70℃的去离子充分稀释均匀。
8.根据权利要求1或2所述的一种缝编连续毡浸润剂的制备方法，其特征在于：所述的硅烷偶联剂为γ-氨丙基三乙氧基硅烷、γ-缩水甘油醚氧丙基三甲氧基硅烷、γ-(甲基丙烯酰氧)丙基三甲氧基硅烷的其中一种或任意两种以上以任意比例混合的混合物。
9.根据权利要求1或2所述的一种缝编连续毡浸润剂的制备方法，其特征在于：所述的酸碱度调节剂占总重量为乙酸或柠檬酸的其中任意一种。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010409432.3A CN111691184A (zh) | 2020-05-14 | 2020-05-14 | 一种缝编连续毡浸润剂的制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010409432.3A CN111691184A (zh) | 2020-05-14 | 2020-05-14 | 一种缝编连续毡浸润剂的制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111691184A true CN111691184A (zh) | 2020-09-22 |
Family
ID=72477766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010409432.3A Pending CN111691184A (zh) | 2020-05-14 | 2020-05-14 | 一种缝编连续毡浸润剂的制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111691184A (zh) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1923740A (zh) * | 2006-09-13 | 2007-03-07 | 中材科技股份有限公司 | 细玻璃纤维膨体纱用增强型浸润剂 |
| CN101367623A (zh) * | 2008-09-26 | 2009-02-18 | 江苏九鼎新材料股份有限公司 | 一种低延伸玻璃纤维膨体纱浸润剂 |
| CN108249784A (zh) * | 2018-03-30 | 2018-07-06 | 山东玻纤集团股份有限公司 | 一种玻璃纤维连续原丝毡浸润剂 |
| CN108558234A (zh) * | 2018-05-29 | 2018-09-21 | 山东玻纤集团股份有限公司 | 一种电子织物用玻璃纤维浸润剂 |
| CN109320100A (zh) * | 2018-10-29 | 2019-02-12 | 山东玻纤集团股份有限公司 | 一种增强型玻璃纤维浸润剂 |
-
2020
- 2020-05-14 CN CN202010409432.3A patent/CN111691184A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1923740A (zh) * | 2006-09-13 | 2007-03-07 | 中材科技股份有限公司 | 细玻璃纤维膨体纱用增强型浸润剂 |
| CN101367623A (zh) * | 2008-09-26 | 2009-02-18 | 江苏九鼎新材料股份有限公司 | 一种低延伸玻璃纤维膨体纱浸润剂 |
| CN108249784A (zh) * | 2018-03-30 | 2018-07-06 | 山东玻纤集团股份有限公司 | 一种玻璃纤维连续原丝毡浸润剂 |
| CN108558234A (zh) * | 2018-05-29 | 2018-09-21 | 山东玻纤集团股份有限公司 | 一种电子织物用玻璃纤维浸润剂 |
| CN109320100A (zh) * | 2018-10-29 | 2019-02-12 | 山东玻纤集团股份有限公司 | 一种增强型玻璃纤维浸润剂 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1229267A (en) | Glass fibers to reinforce polymeric materials | |
| EP0741676B1 (en) | Glass fiber sizing compositions, sized glass fibers and methods of reinforcing polymeric materials using the same | |
| CN110818284A (zh) | 一种玻璃纤维合股无捻粗纱浸润剂及制备方法、产品和应用 | |
| CN109485274B (zh) | 一种高速喷射成型玻璃纤维用浸润剂及其制备方法和应用 | |
| CN113548813B (zh) | 一种玻璃纤维直接纱用浸润剂及制备方法、产品和应用 | |
| CN109455953B (zh) | 一种增强聚丙烯用玻璃纤维浸润剂及其制备方法和应用 | |
| CN107555814A (zh) | 一种绝缘拉挤用无碱玻璃纤维纱浸润剂 | |
| EP0559865B1 (en) | Glass size compositions and glass fibers coated therewith | |
| CN112429978A (zh) | 一种玻纤材料改性增强成型处理方法 | |
| CN108249784A (zh) | 一种玻璃纤维连续原丝毡浸润剂 | |
| TW201546009A (zh) | 用於溼式及乾式長絲捲繞之上漿組合物 | |
| CN108892396A (zh) | 一种用于生产高表面质量smc用玻璃纤维的浸润剂 | |
| CN108483945A (zh) | 一种增强尼龙用无碱玻璃纤维直接纱的浸润剂 | |
| CN112679110A (zh) | 一种浸润剂以及浸润剂在玄武岩纤维上的处理方法 | |
| CN113979649A (zh) | 一种玄武岩纤维增强热固性树脂复合材料用纤维表面改性剂及其制备方法 | |
| CN111517671B (zh) | 一种无碱玻璃纤维浸润剂及其制备方法、产品和应用 | |
| CN111691184A (zh) | 一种缝编连续毡浸润剂的制备方法 | |
| CN113234284A (zh) | 一种玻纤增强聚丙烯复合材料及其制备方法 | |
| CN113880458B (zh) | 玻璃纤维浸润剂组合物及玻璃纤维浸润剂、玻璃纤维及环氧基复合纱材料 | |
| CN113213781A (zh) | 一种玻璃纤维直接纱浸润剂及其制备方法和应用 | |
| CN113387599B (zh) | 一种玻璃纤维浸润剂及制备方法和产品 | |
| WO2009112515A1 (en) | Fibre coated with a sizing composition | |
| CN112376279B (zh) | 一种用于生产玻璃纤维连续毡浸润剂的制备方法 | |
| US20240140862A1 (en) | Glass fiber sizing composition, preparation method, glass fiber product and use thereof | |
| ZA200404288B (en) | Sizing composition for glass yarns, the glass yarns thus obtained and composite materials comprising said yarns. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200922 |