CN111647363A - Environment-friendly elastomer modified asphalt waterproof coiled material - Google Patents
Environment-friendly elastomer modified asphalt waterproof coiled material Download PDFInfo
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- CN111647363A CN111647363A CN202010565696.8A CN202010565696A CN111647363A CN 111647363 A CN111647363 A CN 111647363A CN 202010565696 A CN202010565696 A CN 202010565696A CN 111647363 A CN111647363 A CN 111647363A
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- 239000010426 asphalt Substances 0.000 title claims abstract description 91
- 229920001971 elastomer Polymers 0.000 title claims abstract description 71
- 239000000463 material Substances 0.000 title claims abstract description 45
- 239000000806 elastomer Substances 0.000 title claims abstract description 23
- 229920000728 polyester Polymers 0.000 claims abstract description 46
- 239000010410 layer Substances 0.000 claims abstract description 41
- 230000003068 static effect Effects 0.000 claims abstract description 37
- 239000002994 raw material Substances 0.000 claims abstract description 32
- 239000011241 protective layer Substances 0.000 claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 claims abstract description 16
- 239000003921 oil Substances 0.000 claims description 60
- 239000000843 powder Substances 0.000 claims description 30
- 239000004744 fabric Substances 0.000 claims description 24
- 230000009545 invasion Effects 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 24
- 239000004698 Polyethylene Substances 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- 230000003712 anti-aging effect Effects 0.000 claims description 15
- 239000003963 antioxidant agent Substances 0.000 claims description 15
- 230000003078 antioxidant effect Effects 0.000 claims description 15
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- -1 polyethylene Polymers 0.000 claims description 15
- 229920000573 polyethylene Polymers 0.000 claims description 15
- 239000000741 silica gel Substances 0.000 claims description 15
- 229910002027 silica gel Inorganic materials 0.000 claims description 15
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 claims description 12
- 238000000576 coating method Methods 0.000 claims description 12
- 239000003365 glass fiber Substances 0.000 claims description 12
- 238000007654 immersion Methods 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 239000011253 protective coating Substances 0.000 claims description 12
- 239000004902 Softening Agent Substances 0.000 claims description 9
- 239000011280 coal tar Substances 0.000 claims description 9
- 238000005260 corrosion Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 238000003723 Smelting Methods 0.000 claims description 6
- 229910000831 Steel Inorganic materials 0.000 claims description 6
- 239000012790 adhesive layer Substances 0.000 claims description 6
- 239000011294 coal tar pitch Substances 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000002955 isolation Methods 0.000 claims description 6
- 238000004806 packaging method and process Methods 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000003825 pressing Methods 0.000 claims description 6
- 238000003892 spreading Methods 0.000 claims description 6
- 239000010959 steel Substances 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 239000010705 motor oil Substances 0.000 claims description 3
- 239000002699 waste material Substances 0.000 claims description 3
- 239000012528 membrane Substances 0.000 claims 1
- 238000004078 waterproofing Methods 0.000 claims 1
- 239000000779 smoke Substances 0.000 abstract description 7
- 230000006750 UV protection Effects 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 239000002912 waste gas Substances 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 238000012545 processing Methods 0.000 abstract description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
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- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
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- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/046—Reinforcing macromolecular compounds with loose or coherent fibrous material with synthetic macromolecular fibrous material
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/06—Polyethene
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09J7/00—Adhesives in the form of films or foils
- C09J7/50—Adhesives in the form of films or foils characterised by a primer layer between the carrier and the adhesive
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C11/00—Details of pavings
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01D—CONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
- E01D19/00—Structural or constructional details of bridges
- E01D19/08—Damp-proof or other insulating layers; Drainage arrangements or devices ; Bridge deck surfacings
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- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D31/00—Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution
- E02D31/02—Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution against ground humidity or ground water
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/66—Sealings
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D5/00—Roof covering by making use of flexible material, e.g. supplied in roll form
- E04D5/10—Roof covering by making use of flexible material, e.g. supplied in roll form by making use of compounded or laminated materials, e.g. metal foils or plastic films coated with bitumen
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2395/00—Bituminous materials, e.g. asphalt, tar or pitch
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2421/00—Characterised by the use of unspecified rubbers
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08J2453/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2453/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
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- C09J2423/00—Presence of polyolefin
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Abstract
The invention relates to the technical field of waterproof materials, in particular to an environment-friendly elastomer modified asphalt waterproof coiled material, which has the advantages that the types of raw materials required by the production of the modified asphalt coiled material are reduced, the cost investment of raw materials and the cost investment of equipment are effectively reduced, the product process is shortened, the production efficiency of products is improved, the discharge amount of waste gas generated in the processing of the raw materials is reduced, the pollution source is reduced, the ultraviolet resistance of the surface of the product is improved, the absorption amount of surface ultraviolet rays is effectively reduced, the surface is prevented from being softened and generating smoke, the smoke is prevented from damaging the environment, and the practicability and; comprises an outer static protective layer, a modified asphalt layer and a polyester base tire layer.
Description
Technical Field
The invention relates to the technical field of waterproof materials, in particular to an environment-friendly elastomer modified asphalt waterproof coiled material.
Background
As is well known, the asphalt coiled material has the advantages of good high temperature resistance, corrosion resistance, aging resistance, good plasticity and the like, is greatly applied to the fields of building construction, interior decoration, highways, bridges and the like, and can be modified to obtain the modified asphalt coiled material, and the modified asphalt coiled material has the following defects in the production process due to the fact that the types of required raw materials are more, the production process is complex and the like:
a) the cost investment in the manufacturing process is large, and the production efficiency is low;
b) the raw materials are more in variety, and the raw material treatment process is complex, so that the waste gas emission is large, and the environment is polluted;
c) when the modified asphalt coiled material is used, the surface of the modified asphalt coiled material has weak ultraviolet resistance, is easy to soften and generates smoke, and pollutes the environment.
Disclosure of Invention
In order to solve the technical problems, the invention provides the environment-friendly elastomer modified asphalt waterproof coiled material which is reduced in raw material types required by the production of the modified asphalt coiled material, effectively reduces the raw material cost investment and the equipment cost investment, shortens the product process, improves the product production efficiency, reduces the waste gas discharge amount in the raw material processing, reduces the pollution source, improves the ultraviolet resistance of the product surface, effectively reduces the surface ultraviolet absorption amount, prevents the surface from softening and generating smoke, prevents the smoke from damaging the environment, and improves the practicability and the reliability.
The invention relates to an environment-friendly elastomer modified asphalt waterproof coiled material which comprises an outer static protective layer, a modified asphalt layer and a polyester base tire layer.
The modified asphalt layer comprises, by mass, 120 parts of coal tar asphalt 100-one, 60-80 parts of styrene-butadiene-styrene rubber, 5-10 parts of a softener, 4-8 parts of an anti-aging agent and 15-25 parts of silica gel powder.
The raw materials for preparing the polyester base tire layer comprise a fine anti-corrosion soft steel wire mesh, a polyester glass fiber felt and a reinforced glass fiber felt.
The raw materials for preparing the external static protective layer comprise, by mass, 20-30 parts of argil powder, 70-90 parts of polyethylene rubber, 50-60 parts of ternary waterproof rubber and 2-3 parts of antioxidant.
The invention relates to an environment-friendly elastomer modified asphalt waterproof coiled material which comprises an outer static protective layer, a modified asphalt layer and a polyester base tire layer.
The modified asphalt layer is prepared from raw materials including, by mass, 95-125 parts of coal tar asphalt, 50-80 parts of styrene-butadiene-styrene rubber, 3-10 parts of a softener, 2-9 parts of an anti-aging agent and 12-26 parts of silica gel powder.
The raw materials for preparing the polyester base tire layer comprise a fine anti-corrosion soft steel wire mesh, a polyester glass fiber felt and a reinforced glass fiber felt.
The raw materials for preparing the external static protective layer comprise, by mass, 18-32 parts of argil powder, 66-95 parts of polyethylene rubber, 45-58 parts of ternary waterproof rubber and 1-3 parts of antioxidant.
According to the environment-friendly elastomer modified asphalt waterproof coiled material, the softening agent can be one of alkyl rubber oil, naphthenic oil or waste engine oil.
A preparation method of an environment-friendly elastomer modified asphalt waterproof coiled material comprises the following steps:
a) weighing the raw materials in parts by weight;
b) adding coal tar pitch into a smelting furnace, heating to 120 ℃, sequentially adding styrene-butadiene-styrene rubber, an anti-aging agent and silica gel powder, mixing for 45 minutes, adding a softening agent, stirring for 20 minutes under the condition of isolating air and water, and stirring at the speed of 320rad/min to obtain liquid modified asphalt oil, and introducing the modified asphalt oil into a primary invasion oil tank;
c) slowly softening, mixing and stirring the argil powder, the polyethylene rubber, the ternary waterproof rubber and the antioxidant at the temperature of 200 ℃, stirring at the speed of 100rad/min to obtain a liquid external static protective coating, and guiding the coating into a secondary invasion oil tank;
d) spreading the polyester base fabric into a primary invasion oil groove for oil immersion and coating treatment, controlling the oil immersion thickness of the modified asphalt oil on the polyester base fabric, cooling, and standing for 4 hours at normal temperature;
e) placing the polyester base fabric after standing into a secondary invasion oil tank, and adsorbing an external static protective coating on the surface of the polyester base fabric so as to form an external static protective layer, wherein the production work of the asphalt coiled material is initially finished;
f) attaching the polymer self-adhesive layer and the isolation paper layer on the surface of the asphalt coiled material, and then pre-pressing, curling, packaging and warehousing.
Compared with the prior art, the invention has the beneficial effects that: the raw material types required by the production of the modified asphalt coiled material are reduced, the raw material cost input and the equipment cost input are effectively reduced, the product process is shortened, the production efficiency of the product is improved, the waste gas discharge amount in the raw material processing is reduced, the pollution source is reduced, the ultraviolet resistance of the surface of the product is improved, the surface ultraviolet absorption amount is effectively reduced, the surface is prevented from being softened and generating smoke, the smoke is prevented from damaging the environment, and the practicability and the reliability are improved.
Drawings
FIG. 1 is a comparative graph of the test of the present invention.
Detailed Description
The following examples are given to further illustrate the embodiments of the present invention. The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention.
The invention relates to an environment-friendly elastomer modified asphalt waterproof coiled material which comprises an outer static protective layer, a modified asphalt layer and a polyester base tire layer.
The modified asphalt layer comprises, by mass, 120 parts of coal tar asphalt 100-one, 60-80 parts of styrene-butadiene-styrene rubber, 5-10 parts of a softener, 4-8 parts of an anti-aging agent and 15-25 parts of silica gel powder.
The raw materials for preparing the polyester base tire layer comprise a fine anti-corrosion soft steel wire mesh, a polyester glass fiber felt and a reinforced glass fiber felt.
The raw materials for preparing the external static protective layer comprise, by mass, 20-30 parts of argil powder, 70-90 parts of polyethylene rubber, 50-60 parts of ternary waterproof rubber and 2-3 parts of antioxidant.
The invention relates to an environment-friendly elastomer modified asphalt waterproof coiled material which comprises an outer static protective layer, a modified asphalt layer and a polyester base tire layer.
The modified asphalt layer is prepared from raw materials including, by mass, 95-125 parts of coal tar asphalt, 50-80 parts of styrene-butadiene-styrene rubber, 3-10 parts of a softener, 2-9 parts of an anti-aging agent and 12-26 parts of silica gel powder.
The raw materials for preparing the polyester base tire layer comprise a fine anti-corrosion soft steel wire mesh, a polyester glass fiber felt and a reinforced glass fiber felt.
The raw materials for preparing the external static protective layer comprise, by mass, 18-32 parts of argil powder, 66-95 parts of polyethylene rubber, 45-58 parts of ternary waterproof rubber and 1-3 parts of antioxidant.
According to the environment-friendly elastomer modified asphalt waterproof coiled material, the softening agent can be one of alkyl rubber oil, naphthenic oil or waste engine oil.
A preparation method of an environment-friendly elastomer modified asphalt waterproof coiled material comprises the following steps:
a) weighing the raw materials in parts by weight;
b) adding coal tar pitch into a smelting furnace, heating to 120 ℃, sequentially adding styrene-butadiene-styrene rubber, an anti-aging agent and silica gel powder, mixing for 45 minutes, adding a softening agent, stirring for 20 minutes under the condition of isolating air and water, and stirring at the speed of 320rad/min to obtain liquid modified asphalt oil, and introducing the modified asphalt oil into a primary invasion oil tank;
c) slowly softening, mixing and stirring the argil powder, the polyethylene rubber, the ternary waterproof rubber and the antioxidant at the temperature of 200 ℃, stirring at the speed of 100rad/min to obtain a liquid external static protective coating, and guiding the coating into a secondary invasion oil tank;
d) spreading the polyester base fabric into a primary invasion oil groove for oil immersion and coating treatment, controlling the oil immersion thickness of the modified asphalt oil on the polyester base fabric, cooling, and standing for 4 hours at normal temperature;
e) placing the polyester base fabric after standing into a secondary invasion oil tank, and adsorbing an external static protective coating on the surface of the polyester base fabric so as to form an external static protective layer, wherein the production work of the asphalt coiled material is initially finished;
f) attaching the polymer self-adhesive layer and the isolation paper layer on the surface of the asphalt coiled material, and then pre-pressing, curling, packaging and warehousing.
Example 1
The invention relates to an environment-friendly elastomer modified asphalt waterproof coiled material which comprises an outer static protective layer, a modified asphalt layer and a polyester base tire layer.
The modified asphalt layer is prepared from 110 parts by mass of coal tar asphalt, 71 parts by mass of styrene-butadiene-styrene rubber, 8 parts by mass of a softener, 6 parts by mass of an anti-aging agent and 19 parts by mass of silica gel powder.
The outer static protective layer is prepared and comprises 25 parts of argil powder, 82 parts of polyethylene rubber, 56 parts of ternary waterproof rubber and 2 parts of antioxidant by mass.
A preparation method of an environment-friendly elastomer modified asphalt waterproof coiled material comprises the following steps:
a) weighing the raw materials in parts by weight;
b) adding coal tar pitch into a smelting furnace, heating to 120 ℃, sequentially adding styrene-butadiene-styrene rubber, an anti-aging agent and silica gel powder, mixing for 45 minutes, adding a softening agent, stirring for 20 minutes under the condition of isolating air and water, and stirring at the speed of 320rad/min to obtain liquid modified asphalt oil, and introducing the modified asphalt oil into a primary invasion oil tank;
c) slowly softening, mixing and stirring the argil powder, the polyethylene rubber, the ternary waterproof rubber and the antioxidant at the temperature of 200 ℃, stirring at the speed of 100rad/min to obtain a liquid external static protective coating, and guiding the coating into a secondary invasion oil tank;
d) spreading the polyester base fabric into a primary invasion oil groove for oil immersion and coating treatment, controlling the oil immersion thickness of the modified asphalt oil on the polyester base fabric, cooling, and standing for 4 hours at normal temperature;
e) placing the polyester base fabric after standing into a secondary invasion oil tank, and adsorbing an external static protective coating on the surface of the polyester base fabric so as to form an external static protective layer, wherein the production work of the asphalt coiled material is initially finished;
f) attaching the polymer self-adhesive layer and the isolation paper layer on the surface of the asphalt coiled material, and then pre-pressing, curling, packaging and warehousing.
Example 2
The invention relates to an environment-friendly elastomer modified asphalt waterproof coiled material which comprises an outer static protective layer, a modified asphalt layer and a polyester base tire layer.
The modified asphalt layer is prepared from 103 parts by mass of coal tar asphalt, 65 parts by mass of styrene-butadiene-styrene rubber, 6 parts by mass of a softener, 5 parts by mass of an anti-aging agent and 17 parts by mass of silica gel powder.
The outer static protective layer is prepared and comprises 22 parts of argil powder, 73 parts of polyethylene rubber, 52 parts of ternary waterproof rubber and 2 parts of antioxidant by mass.
A preparation method of an environment-friendly elastomer modified asphalt waterproof coiled material comprises the following steps:
a) weighing the raw materials in parts by weight;
b) adding coal tar pitch into a smelting furnace, heating to 120 ℃, sequentially adding styrene-butadiene-styrene rubber, an anti-aging agent and silica gel powder, mixing for 45 minutes, adding a softening agent, stirring for 20 minutes under the condition of isolating air and water, and stirring at the speed of 320rad/min to obtain liquid modified asphalt oil, and introducing the modified asphalt oil into a primary invasion oil tank;
c) slowly softening, mixing and stirring the argil powder, the polyethylene rubber, the ternary waterproof rubber and the antioxidant at the temperature of 200 ℃, stirring at the speed of 100rad/min to obtain a liquid external static protective coating, and guiding the coating into a secondary invasion oil tank;
d) spreading the polyester base fabric into a primary invasion oil groove for oil immersion and coating treatment, controlling the oil immersion thickness of the modified asphalt oil on the polyester base fabric, cooling, and standing for 4 hours at normal temperature;
e) placing the polyester base fabric after standing into a secondary invasion oil tank, and adsorbing an external static protective coating on the surface of the polyester base fabric so as to form an external static protective layer, wherein the production work of the asphalt coiled material is initially finished;
f) attaching the polymer self-adhesive layer and the isolation paper layer on the surface of the asphalt coiled material, and then pre-pressing, curling, packaging and warehousing.
Example 3
The invention relates to an environment-friendly elastomer modified asphalt waterproof coiled material which comprises an outer static protective layer, a modified asphalt layer and a polyester base tire layer.
The modified asphalt layer is prepared from 116 parts of coal tar asphalt, 78 parts of styrene-butadiene-styrene rubber, 9 parts of a softener, 7 parts of an anti-aging agent and 25 parts of silica gel powder by mass.
The outer static protective layer is prepared and comprises 28 parts of argil powder, 87 parts of polyethylene rubber, 58 parts of ternary waterproof rubber and 3 parts of antioxidant by mass.
A preparation method of an environment-friendly elastomer modified asphalt waterproof coiled material comprises the following steps:
a) weighing the raw materials in parts by weight;
b) adding coal tar pitch into a smelting furnace, heating to 120 ℃, sequentially adding styrene-butadiene-styrene rubber, an anti-aging agent and silica gel powder, mixing for 45 minutes, adding a softening agent, stirring for 20 minutes under the condition of isolating air and water, and stirring at the speed of 320rad/min to obtain liquid modified asphalt oil, and introducing the modified asphalt oil into a primary invasion oil tank;
c) slowly softening, mixing and stirring the argil powder, the polyethylene rubber, the ternary waterproof rubber and the antioxidant at the temperature of 200 ℃, stirring at the speed of 100rad/min to obtain a liquid external static protective coating, and guiding the coating into a secondary invasion oil tank;
d) spreading the polyester base fabric into a primary invasion oil groove for oil immersion and coating treatment, controlling the oil immersion thickness of the modified asphalt oil on the polyester base fabric, cooling, and standing for 4 hours at normal temperature;
e) placing the polyester base fabric after standing into a secondary invasion oil tank, and adsorbing an external static protective coating on the surface of the polyester base fabric so as to form an external static protective layer, wherein the production work of the asphalt coiled material is initially finished;
f) attaching the polymer self-adhesive layer and the isolation paper layer on the surface of the asphalt coiled material, and then pre-pressing, curling, packaging and warehousing.
Test example
Cutting a 30 x 50cm strip sample from a traditional asphalt coiled material and the environment-friendly elastomer modified asphalt waterproof coiled materials of the embodiments 1 to 3, placing four groups of samples under an ultraviolet searchlight for 10 hours to perform a softening test, taking four groups of samples with the same specification again, soaking the four groups of samples into water for 6 hours, and measuring the performance of the samples, wherein the measurement result is shown in the attached drawing 1
The above description is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, several modifications and variations can be made without departing from the technical principle of the present invention, and these modifications and variations should also be regarded as the protection scope of the present invention.
Claims (4)
1. An environment-friendly elastomer modified asphalt waterproof coiled material is characterized by comprising an outer static protective layer, a modified asphalt layer and a polyester base tire layer.
The modified asphalt layer comprises, by mass, 120 parts of coal tar asphalt 100-one, 60-80 parts of styrene-butadiene-styrene rubber, 5-10 parts of a softener, 4-8 parts of an anti-aging agent and 15-25 parts of silica gel powder.
The raw materials for preparing the polyester base tire layer comprise a fine anti-corrosion soft steel wire mesh, a polyester glass fiber felt and a reinforced glass fiber felt.
The raw materials for preparing the external static protective layer comprise, by mass, 20-30 parts of argil powder, 70-90 parts of polyethylene rubber, 50-60 parts of ternary waterproof rubber and 2-3 parts of antioxidant.
2. The environment-friendly elastomer modified asphalt waterproofing membrane as claimed in claim 1, which comprises an outer static protective layer, a modified asphalt layer and a polyester-based base layer.
The modified asphalt layer is prepared from raw materials including, by mass, 95-125 parts of coal tar asphalt, 50-80 parts of styrene-butadiene-styrene rubber, 3-10 parts of a softener, 2-9 parts of an anti-aging agent and 12-26 parts of silica gel powder.
The raw materials for preparing the polyester base tire layer comprise a fine anti-corrosion soft steel wire mesh, a polyester glass fiber felt and a reinforced glass fiber felt.
The raw materials for preparing the external static protective layer comprise, by mass, 18-32 parts of argil powder, 66-95 parts of polyethylene rubber, 45-58 parts of ternary waterproof rubber and 1-3 parts of antioxidant.
3. The roll of environmentally friendly elastomer-modified asphalt as claimed in claims 1-2, wherein the softening agent is one of alkyl rubber oil, naphthenic oil or waste engine oil.
4. A preparation method of an environment-friendly elastomer modified asphalt waterproof coiled material is characterized by comprising the following steps:
a) weighing the components according to the parts by weight of claim 1 or 2;
b) adding coal tar pitch into a smelting furnace, heating to 120 ℃, sequentially adding styrene-butadiene-styrene rubber, an anti-aging agent and silica gel powder, mixing for 45 minutes, adding a softening agent, stirring for 20 minutes under the condition of isolating air and water, and stirring at the speed of 320rad/min to obtain liquid modified asphalt oil, and introducing the modified asphalt oil into a primary invasion oil tank;
c) slowly softening, mixing and stirring the argil powder, the polyethylene rubber, the ternary waterproof rubber and the antioxidant at the temperature of 200 ℃, stirring at the speed of 100rad/min to obtain a liquid external static protective coating, and guiding the coating into a secondary invasion oil tank;
d) spreading the polyester base fabric into a primary invasion oil groove for oil immersion and coating treatment, controlling the oil immersion thickness of the modified asphalt oil on the polyester base fabric, cooling, and standing for 4 hours at normal temperature;
e) placing the polyester base fabric after standing into a secondary invasion oil tank, and adsorbing an external static protective coating on the surface of the polyester base fabric so as to form an external static protective layer, wherein the production work of the asphalt coiled material is initially finished;
f) attaching the polymer self-adhesive layer and the isolation paper layer on the surface of the asphalt coiled material, and then pre-pressing, curling, packaging and warehousing.
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