CN106893536A - A kind of waterproof roll PUR and preparation method thereof - Google Patents
A kind of waterproof roll PUR and preparation method thereof Download PDFInfo
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- CN106893536A CN106893536A CN201710140523.XA CN201710140523A CN106893536A CN 106893536 A CN106893536 A CN 106893536A CN 201710140523 A CN201710140523 A CN 201710140523A CN 106893536 A CN106893536 A CN 106893536A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
- C09J153/025—Vinyl aromatic monomers and conjugated dienes modified
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09J157/02—Copolymers of mineral oil hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J191/00—Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to chemical modification technical field of polymer materials, and in particular to a kind of waterproof roll PUR and preparation method thereof.PUR is made up of following parts by weight component：Butadiene-styrene rubber 50~200,200~300 parts of benzene thermoplastic olefinic elastomer rubber, 200~300 parts of tackifying resin, 5~20 parts of antioxidant, 5~20 parts of UV absorbers, 0~200 part of naphthenic oil, 0~200 part of base oil；100~200 parts of polyisobutene, tackifying resin are the one kind or any combination in Petropols, hydrogenated petroleum resin and monomer resin.Compounded as rubber matrix using butadiene-styrene rubber and styrenic thermoplastic elastomer's rubber, with compatibility high, Petropols, hydrogenated petroleum resin or monomer resin are added again as tackifying resin, lift initial bonding strength, cold resistance, heat endurance, the adhesion strength of PUR, reduce the volatility of PUR, especially lift the cohesive force of the PUR architectural environment moist to cement, concrete, great Sha etc..
Description
Technical field
The present invention relates to chemical modification technical field of polymer materials, and in particular to a kind of waterproof roll PUR and its
Preparation method.
Background technology
Buildings waterproof be in order to ensure some positions of building or structures by rainwater, underground water, domestic water and
The etch of moisture in air and special measures taking, occupy an important position in whole building engineering.Buildings waterproof
The quality of quality of materials, directly influences normal use and the life-span of building and structures.Early in the twentieth century, Foreign Architecture is prevented
Water material is main based on malthoid, and asphalt paper is gradually replaced by glass malthoid.With chemical industry particularly rubber work
Industry has great development, and development and production have gone out many resins and rubber suitable for architectural waterproof material so that buildings waterproof
The investigative technique of material is developed rapidly, and the use of modified bituminous pitch coiled material and polymer membranes is increasingly extensive.It is modified
Easily be hardened when asphalt felt is due to low temperature embrittlement, high temperature when can trickle, intolerant to sunlight irradiation, and volatile quantity is big, not environmentally cause high
The defects such as cancer, are gradually replaced by polymer membranes.The polymer membranes adhesive of market is mostly at present
With resin as matrix, assign modifying agent and lift its combination property.
As Chinese patent CN106281151A discloses a kind of polymer membranes PUR and preparation method thereof, should
PUR using polyisobutene, SBS, SIS, butadiene-styrene rubber, butyl rubber as rubber base-material, add tackifying resin, mineral oil,
Age resistor and light stabilizer are prepared from as auxiliary agent, although the PUR is compounded by by various rubber base-materials, improve heat
The performances such as heat resistance, adhesion strength, the uvioresistant irradiation of melten gel, but its raw material prescription is complicated, and the cold resistance of the PUR,
The performances such as water proofing property, adhesion strength, volatility still can not meet use requirement higher.
Therefore, research and develop that a kind of raw material prescription is simple, excellent combination property disclosure satisfy that the anti-of use requirement high
Water coiled material PUR, becomes current problem demanding prompt solution.
The content of the invention
In order to overcome the defect of prior art, it is an object of the invention to provide a kind of waterproof roll PUR, the hot melt
Glue tack is good, peel strength is high, have strong bonding to particular surroundings (cement, concrete, great Sha etc. moist architectural environment)
Power, cold resistance and heat endurance are good, and volatility is low.
Meanwhile, the present invention is also resided in and provides a kind of preparation method of waterproof roll PUR.
In order to realize the above object the technical solution adopted in the present invention is：
A kind of waterproof roll PUR, is prepared from by the component of following parts by weight：50~150 parts of butadiene-styrene rubber,
200~300 parts of styrenic thermoplastic elastomer's rubber, 200~300 parts of tackifying resin, 5~20 parts of antioxidant, UV Absorption
5~20 parts of agent, 0~200 part of naphthenic oil, 0~200 part of base oil, 100~200 parts of polyisobutene；The tackifying resin is oil
One kind or any combination in resin, hydrogenated petroleum resin and monomer resin.
Optionally, styrenic thermoplastic elastomer's rubber is SIS rubber or SEPS rubber.
Optionally, the tackifying resin is monomer resin.
Optionally, the monomer resin is Kristalex3085 or Kristalex5140.
Optionally, the softening point of the monomer resin is 85 DEG C.
Optionally, the polyisobutene is the PB1300 or PB1400 of South Korea great Lin.
Optionally, the naphthenic oil is Kelamayi 4010；The base oil is the double dragon 250N of South Korea.The base oil
When kinematic viscosity is 100 DEG C, 10mm2/s。
Optionally, the antioxidant be four [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters and β-
The mixture of the positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid.
Optionally, the UV absorbers are 2- (- 5 '-aminomethyl phenyl of 2- hydroxyls) BTAs and/or 2- (2- hydroxyls
Base -3- tertiary butyl -5- aminomethyl phenyls) -5- chlorobenzotriazoles.
The preparation method of above-mentioned waterproof roll PUR, including following operating procedure：
1) butadiene-styrene rubber, continuous heating to butadiene-styrene rubber is added to melt completely after taking PART EPOXY oil and base oil heating
Afterwards, remaining Epoxy oil and base oil, whole styrenic thermoplastic elastomer's rubber and part resin are added, continuous heating is extremely
Solid material is melted completely；
2) after adding remaining resin, antioxidant, UV absorbers, polyisobutene well mixed, cooling and solidifying is that is, complete
Into.
Optionally, step 1) in the mass ratio of part resin and styrenic thermoplastic elastomer's rubber that adds be 8：10.
Optionally, step 1) in add PART EPOXY oil and base oil heating-up temperature be 150 DEG C；The temperature of continuous heating
It is 150~165 DEG C.
Optionally, occur the phenomenon of thermal oxide decomposition, step 1 under the high temperature conditions in order to avoid butadiene-styrene rubber) middle addition
It is 0.08 atmospheric pressure vacuum plant to be opened after butadiene-styrene rubber and keeps vacuum.
The beneficial effect of waterproof roll PUR of the present invention：
1st, the present invention is compounded as rubber matrix using butadiene-styrene rubber and styrenic thermoplastic elastomer's rubber, with high
Compatibility, then Petropols, hydrogenated petroleum resin or monomer resin are added as tackifying resin, mutually act synergistically, lifting heat
The initial bonding strength of melten gel, cold resistance, heat endurance, adhesion strength, reduce the volatility of PUR, especially lift PUR to water
The cohesive force of mud, concrete, great Sha etc. moist architectural environment；
2nd, further, it was four [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] seasons that antioxidant is selected in the present invention
The mixture of Doutrate and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid；UV absorbers are
2- (- 5 '-aminomethyl phenyl of 2- hydroxyls) BTAs and/or 2- (2- hydroxyl -3- tertiary butyl -5- aminomethyl phenyls) -5- chlorobenzenes and three
Azoles, further the ageing resistance of lifting PUR, lifts the service life of waterproof roll, complies fully with the application of waterproof roll
It is required that；
The preparation method of waterproof roll PUR of the present invention, is firstly added butadiene-styrene rubber after butadiene-styrene rubber is melted completely
Add styrenic thermoplastic elastomer's rubber, it is to avoid can there is butadiene-styrene rubber two kinds of rubber matrixs are melted simultaneously during
The defect that can not melt completely；Secondly, resin is added at twice, it is ensured that resin is sufficiently mixed with rubber matrix, is further carried
Rise the initial bonding strength and holding power of PUR.
Specific embodiment
Technical scheme is described in detail below by specific embodiment.
Embodiment 1
A kind of waterproof roll PUR, is prepared from by the component of following parts by weight：100 parts of butadiene-styrene rubber, SIS rubbers
250 parts of glue, 250 parts of Kristalex5140, four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] 5 parts of pentaerythritol esters,
β-positive 5 parts of the octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid, 2- (- 5 '-aminomethyl phenyl of 2- hydroxyls) BTA
10 parts, 4,010 100 parts of Kelamayi, double 100 parts of the dragon 250N of South Korea, 100 parts of polyisobutene PB1300.
The preparation method of above-mentioned waterproof roll PUR, including following operating procedure：
1) take in the double dragon 250N additions reactors in part Kelamayi 4010 and South Korea, be heated to 150 DEG C of addition butylbenzene rubbers
Glue, opens vacuum extractor, the vacuum in reactor is reached 0.08 atmospheric pressure, continuous heating to 150~165 DEG C, fourth
After benzene rubber is melted completely, add remaining Kelamayi 4010 and the double dragon 250N of South Korea, the SIS rubber of whole and
200 parts of Kristalex5140, continuous heating to solid material is melted completely；
2) remaining 50 parts of Kristalex5140, four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] seasons are added
Doutrate, β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid, 2- (- 5 '-aminomethyl phenyl of 2- hydroxyls) benzene
And triazole, polyisobutene, after being well mixed, cooling and solidifying completes.
Embodiment 2
A kind of waterproof roll PUR, is prepared from by the component of following parts by weight：50 parts of butadiene-styrene rubber, SEPS rubbers
200 parts of glue, 200 parts of Kristalex3085, four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] 2 parts of pentaerythritol esters,
β-positive 3 parts of the octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid, 2- (- 5 '-aminomethyl phenyl of 2- hydroxyls) BTA
5 parts, 4,010 200 parts of Kelamayi, 100 parts of polyisobutene PB1300
The preparation method of above-mentioned waterproof roll PUR, including following operating procedure：
1) take in the addition of part Kelamayi 4010 reactor, be heated to 150 DEG C of addition butadiene-styrene rubber, open vacuum means
Put, the vacuum in reactor is reached 0.08 atmospheric pressure, to 150~165 DEG C, butadiene-styrene rubber is melted continuous heating completely
Afterwards, remaining Kelamayi 4010, whole 160 parts of SEPS rubber and Kristalex3085, continuous heating to solid are added
Raw material is melted completely；
2) remaining 40 parts of Kristalex3085, four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] seasons are added
Doutrate, β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid, 2- (- 5 '-aminomethyl phenyl of 2- hydroxyls) benzene
And triazole, polyisobutene PB1300, after being well mixed, cooling and solidifying completes.
Embodiment 3
A kind of waterproof roll PUR, is prepared from by the component of following parts by weight：50 parts of butadiene-styrene rubber, SIS rubbers
300 parts of glue, 300 parts of C9 Petropols, four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] 10 parts of pentaerythritol esters, β-
Positive 10 parts of the octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid, 2- (- 5 '-aminomethyl phenyl of 2- hydroxyls) BTA
10 parts, 2- (2- hydroxyl -3- tertiary butyl -5- aminomethyl phenyls) 10 parts of -5- chlorobenzotriazoles, double 200 parts of the dragon 250N of South Korea, gather different
Butylene PB1300
The preparation method of above-mentioned waterproof roll PUR, including following operating procedure：
1) take in the double dragon 250N additions reactors of part South Korea, be heated to 150 DEG C of addition butadiene-styrene rubber, open vacuum means
Put, the vacuum in reactor is reached 0.08 atmospheric pressure, to 150~165 DEG C, butadiene-styrene rubber is melted continuous heating completely
Afterwards, the double dragon 250N of remaining South Korea, whole 240 parts of SIS rubber and C9 Petropols are added, continuous heating is complete to solid material
Full-fusing；
2) remaining 60 parts of C9 Petropols, four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] Ji Wusi are added
Alcohol ester, β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid, 2- (- 5 '-aminomethyl phenyl of 2- hydroxyls) benzo three
Azoles, 2- (2- hydroxyl -3- tertiary butyl -5- aminomethyl phenyls) -5- chlorobenzotriazoles, polyisobutene PB1300, after being well mixed, cooling
Solidification, that is, complete.
Comparative example 1
This comparative example additionally with the addition of SBS rubber during this comparative example prepares the component of PUR as different from Example 1,
Adjustment SBS rubber, butadiene-styrene rubber, the consumption of SIS rubber are respectively 130 parts of SBS rubber, 150 parts of butadiene-styrene rubber, SIS rubber 170
Part；Other are with embodiment 1.
Comparative example 2
This comparative example component that this comparative example prepares PUR as different from Example 1 is acrylic block copolymers
300 parts, 80 parts of ethylene ethyl acrylate, 70 parts of ethylene methacrylic acid, Kristalex5140250 parts, the four [β-(uncles of 3,5- bis-
Butyl -4- hydroxy phenyls) propionic acid] 5 parts of pentaerythritol ester, β-(3,5- di-tert-butyl-hydroxy phenyls) positive octadecanol of propionic acid
5 parts of ester, 2- (- 5 '-aminomethyl phenyl of 2- hydroxyls) 10 parts of BTA, 4,010 100 parts of Kelamayi, the double dragon 250N 100 of South Korea
Part；Other are with embodiment 1.
Comparative example 3
From unlike comparative example 2, this comparative example is prepared in the component of PUR using DCPD resin replacements this comparative example
Kristalex5140；Other are with comparative example 2.
Comparative example 4
As different from Example 1, this comparative example is prepared in the component of PUR using DCPD resin replacements this comparative example
Kristalex5140；Other are with embodiment 1.
Comparative example 5
This comparative example as different from Example 1, in preparation method, step 1) in add the double dragon 250N of remaining South Korea,
Whole SIS rubber and the Kristalex5140 of whole, other are with embodiment 1.
Test example
The combination property that PUR prepared by embodiment 1, comparative example 1~5 is applied to waterproof roll is detected respectively,
Testing result is as shown in table 1 below：
Table 1
Data shown in above-mentioned table 1, the properties of PUR prepared by the embodiment of the present invention 1 are superior to contrast
Example 1 is substantially equivalent with comparative example 1, it can be seen that simplify rubber matrix formula in the present invention, while adjust tackifying resin being
Monomer resin or Petropols or hydrogenated petroleum resin, in the case where formula is simplified, remain in that PUR has low waving
Hair property, and the combination properties such as the cold resistance of PUR, holding power are lifted, PUR is especially improved to cement, concrete, great Sha
Deng the cohesive force of moist architectural environment；In addition, the properties of the PUR of the preparation of embodiment 1 are better than comparative example 5, thus may be used
See the combination property that PUR can be lifted using addition tackifying resin in batches；In addition, PUR prepared by embodiment 1 is waved
Hair property is less than comparative example 4, and the volatility of the PUR of comparative example 2 is equal to comparative example 3, it can be seen that monomer resin is used as thickening
Resin is relevant to the improvement result of PUR volatile performance and the species of rubber matrix, and the rubber matrix that the present invention is limited adds single
The volatile performance of PUR can be significantly reduced when body resin is as tackifying resin.
The properties of PUR prepared by the embodiment of the present invention 2 and embodiment 3 are basic with PUR prepared by embodiment 1
It is equivalent.
Claims (10)
1. a kind of waterproof roll PUR, it is characterised in that be prepared from by the component of following parts by weight：Butadiene-styrene rubber 50
~200 parts, it is 200~300 parts of styrenic thermoplastic elastomer's rubber, 200~300 parts of tackifying resin, 5~20 parts of antioxidant, purple
5~20 parts of outer light absorber, 0~200 part of naphthenic oil, 0~200 part of base oil；100~200 parts of polyisobutene；The thickening tree
Fat is the one kind or any combination in Petropols, hydrogenated petroleum resin and monomer resin.
2. waterproof roll PUR as claimed in claim 1, it is characterised in that styrenic thermoplastic elastomer's rubber
It is SIS rubber or SEPS rubber.
3. waterproof roll PUR as claimed in claim 1 or 2, it is characterised in that the tackifying resin is monomer resin.
4. waterproof roll PUR as claimed in claim 3, it is characterised in that the monomer resin is
Kristalex3085 or Kristalex5140.
5. waterproof roll PUR as claimed in claim 3, it is characterised in that the softening point of the monomer resin is 85
℃。
6. waterproof roll PUR as claimed in claim 1, it is characterised in that the naphthenic oil is Kelamayi 4010；
Base oil is the double dragon 250N of South Korea.
7. waterproof roll PUR as claimed in claim 3, it is characterised in that the molecular weight of the polyisobutene is
1000-2000。
8. waterproof roll PUR as claimed in claim 1, it is characterised in that the antioxidant is four [β-(3,5- bis- uncles
Butyl -4- hydroxy phenyls) propionic acid] pentaerythritol ester and β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid
Mixture；The UV absorbers are 2- (- 5 '-aminomethyl phenyl of 2- hydroxyls) BTAs and/or 2- (2- hydroxyls -3- spies
Butyl -5- aminomethyl phenyls) -5- chlorobenzotriazoles.
9. a kind of preparation method of waterproof roll PUR as claimed in claim 1, it is characterised in that including following operation step
Suddenly：
1) take after adding butadiene-styrene rubber, continuous heating to be melted completely to butadiene-styrene rubber after PART EPOXY oil is heated with base oil, plus
Enter remaining Epoxy oil and base oil, whole styrenic thermoplastic elastomer's rubber and part resin, continuous heating to solid
Raw material is melted completely；
2) remaining resin, antioxidant, polyisobutene, UV absorbers are added, after being well mixed, cooling and solidifying completes.
10. the preparation method of the waterproof roll PUR described in claim 9, it is characterised in that step 1) in the part that adds
Resin is 8 with the mass ratio of styrenic thermoplastic elastomer's rubber：10.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108587509A (en) * | 2018-04-26 | 2018-09-28 | 昆山科顺防水材料有限公司 | Novel non-bituminous base adhesive waterproof coil of one kind and preparation method thereof |
| CN108641628A (en) * | 2018-04-26 | 2018-10-12 | 昆山科顺防水材料有限公司 | A kind of waterproof roll non-bituminous self-adhesion sizing material and preparation method thereof |
| CN108715749A (en) * | 2018-06-05 | 2018-10-30 | 嘉好(太仓)新材料股份有限公司 | A kind of high uvioresistant marine glue and preparation method thereof |
| CN110079256A (en) * | 2019-05-10 | 2019-08-02 | 无锡市万力粘合材料股份有限公司 | Hot-fusible pressure-sensitive adhesive of UV resistant and preparation method thereof |
| CN111320763A (en) * | 2018-12-14 | 2020-06-23 | 科建高分子材料（上海）股份有限公司 | Production process for preventing hot melt adhesive from generating particles |
| CN111548758A (en) * | 2020-05-19 | 2020-08-18 | 上海嘉好胶粘制品有限公司 | Special hot-melt pressure-sensitive adhesive for low-temperature waterproof coiled material butt-joint adhesive tape and preparation method thereof |
| CN111592843A (en) * | 2020-05-19 | 2020-08-28 | 上海嘉好胶粘制品有限公司 | Hot-melt pressure-sensitive adhesive for normal-temperature waterproof coiled material butt-joint adhesive tape and preparation method thereof |
| CN111647377A (en) * | 2020-06-11 | 2020-09-11 | 广东荣嘉新材料科技有限公司 | Anti-wrinkle type environment-friendly hot melt adhesive for film back adhesive bags and preparation method and application thereof |
| CN114854344A (en) * | 2022-05-11 | 2022-08-05 | 浙江本源纸塑科技有限公司 | Glue for price paper |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| CN108587509A (en) * | 2018-04-26 | 2018-09-28 | 昆山科顺防水材料有限公司 | Novel non-bituminous base adhesive waterproof coil of one kind and preparation method thereof |
| CN108641628A (en) * | 2018-04-26 | 2018-10-12 | 昆山科顺防水材料有限公司 | A kind of waterproof roll non-bituminous self-adhesion sizing material and preparation method thereof |
| CN108715749A (en) * | 2018-06-05 | 2018-10-30 | 嘉好(太仓)新材料股份有限公司 | A kind of high uvioresistant marine glue and preparation method thereof |
| CN108715749B (en) * | 2018-06-05 | 2020-07-14 | 嘉好(太仓)新材料股份有限公司 | High-ultraviolet-resistance waterproof adhesive and preparation method thereof |
| CN111320763A (en) * | 2018-12-14 | 2020-06-23 | 科建高分子材料（上海）股份有限公司 | Production process for preventing hot melt adhesive from generating particles |
| CN111320763B (en) * | 2018-12-14 | 2022-12-02 | 科建高分子材料（上海）股份有限公司 | Production process for preventing hot melt adhesive from generating particles |
| CN110079256A (en) * | 2019-05-10 | 2019-08-02 | 无锡市万力粘合材料股份有限公司 | Hot-fusible pressure-sensitive adhesive of UV resistant and preparation method thereof |
| CN111548758A (en) * | 2020-05-19 | 2020-08-18 | 上海嘉好胶粘制品有限公司 | Special hot-melt pressure-sensitive adhesive for low-temperature waterproof coiled material butt-joint adhesive tape and preparation method thereof |
| CN111592843A (en) * | 2020-05-19 | 2020-08-28 | 上海嘉好胶粘制品有限公司 | Hot-melt pressure-sensitive adhesive for normal-temperature waterproof coiled material butt-joint adhesive tape and preparation method thereof |
| CN111647377A (en) * | 2020-06-11 | 2020-09-11 | 广东荣嘉新材料科技有限公司 | Anti-wrinkle type environment-friendly hot melt adhesive for film back adhesive bags and preparation method and application thereof |
| CN111647377B (en) * | 2020-06-11 | 2021-06-29 | 广东荣嘉新材料科技有限公司 | Anti-wrinkle type environment-friendly hot melt adhesive for film back adhesive bags and preparation method and application thereof |
| CN114854344A (en) * | 2022-05-11 | 2022-08-05 | 浙江本源纸塑科技有限公司 | Glue for price paper |
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