CN106893536B - A kind of waterproof roll hot melt adhesive and preparation method thereof - Google Patents
A kind of waterproof roll hot melt adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN106893536B CN106893536B CN201710140523.XA CN201710140523A CN106893536B CN 106893536 B CN106893536 B CN 106893536B CN 201710140523 A CN201710140523 A CN 201710140523A CN 106893536 B CN106893536 B CN 106893536B
- Authority
- CN
- China
- Prior art keywords
- parts
- hot melt
- melt adhesive
- rubber
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
- C09J153/025—Vinyl aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09J157/02—Copolymers of mineral oil hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J191/00—Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to chemical modification technical field of polymer materials, and in particular to a kind of waterproof roll hot melt adhesive and preparation method thereof.Hot melt adhesive is made of following parts by weight component：Butadiene-styrene rubber 50~200,200~300 parts of benzene thermoplastic olefinic elastomer rubber, 200~300 parts of tackifying resin, 5~20 parts of antioxidant, 5~20 parts of UV absorbers, 0~200 part of naphthenic oil, 0~200 part of base oil；100~200 parts of polyisobutene, tackifying resin are one kind or arbitrary combination in Petropols, hydrogenated petroleum resin and monomer resin.Rubber matrix is used as using butadiene-styrene rubber and styrenic thermoplastic elastomer's rubber compounding, with high compatibility, Petropols, hydrogenated petroleum resin or monomer resin are added again as tackifying resin, the initial bonding strength of promotion hot melt adhesive, cold resistance, thermal stability, adhesion strength, reduce the volatility of hot melt adhesive, especially promotes cohesive force of the hot melt adhesive to the architectural environment of the humidity such as cement, concrete, great Sha.
Description
Technical field
The present invention relates to chemical modification technical field of polymer materials, and in particular to a kind of waterproof roll hot melt adhesive and its
Preparation method.
Background technology
Buildings waterproof be in order to ensure certain positions of building or structures not by rainwater, underground water, domestic water and
The etch of moisture in air and the special measures taken, occupy an important position in whole building engineering.Buildings waterproof
The quality of quality of materials directly influences normal use and the service life of building and structures.Early in the twentieth century, Foreign Architecture is anti-
Water material is mainly based on malthoid, and asphalt paper is gradually replaced by glass malthoid.With chemical industry especially rubber work
Industry has great development, development and production to go out many resins and rubber for being suitable for architectural waterproof material so that buildings waterproof
The investigative technique of material is rapidly developed, and the use of modified bituminous pitch coiled material and polymer membranes is increasingly extensive.It is modified
Easily be hardened when asphalt felt is due to low temperature embrittlement, high temperature when can trickle, intolerant to sunlight, and volatile quantity is big, not environmentally high cause
The defects of cancer, is gradually replaced by polymer membranes.The polymer membranes adhesive of market is mostly at present
Using resin as matrix, assigns modifying agent and promote its comprehensive performance.
It, should if Chinese patent CN106281151A discloses a kind of polymer membranes hot melt adhesive and preparation method thereof
Hot melt adhesive using polyisobutene, SBS, SIS, butadiene-styrene rubber, butyl rubber as rubber base-material, add tackifying resin, mineral oil,
Anti-aging agent and light stabilizer are prepared as auxiliary agent, although the hot melt adhesive improves heat by compounding a variety of rubber base-materials
The performances such as heat resistance, adhesion strength, the uvioresistant irradiation of melten gel, but its raw material prescription is complicated, and the cold resistance of the hot melt adhesive,
The performances such as water proofing property, adhesion strength, volatility still cannot meet higher requirement.
Therefore, research and develop that a kind of raw material prescription is simple, excellent combination property disclosure satisfy that the anti-of high requirement
Water coiled material hot melt adhesive, becomes current urgent problem to be solved.
Invention content
In order to overcome the deficiencies of existing technologies, the object of the present invention is to provide a kind of waterproof roll hot melt adhesive, the hot melts
Glue tack is good, peel strength is high, has strong bonding to particular surroundings (architectural environment of the humidity such as cement, concrete, great Sha)
Power, cold resistance and thermal stability are good, and volatility is low.
Meanwhile the present invention also resides in and provides a kind of preparation method of waterproof roll hot melt adhesive.
In order to achieve the goal above, the technical solution adopted in the present invention is：
A kind of waterproof roll hot melt adhesive, is prepared by the component of following parts by weight：50~150 parts of butadiene-styrene rubber,
200~300 parts of styrenic thermoplastic elastomer's rubber, 200~300 parts of tackifying resin, 5~20 parts of antioxidant, UV Absorption
5~20 parts of agent, 0~200 part of naphthenic oil, 0~200 part of base oil, 100~200 parts of polyisobutene；The tackifying resin is oil
One kind in resin, hydrogenated petroleum resin and monomer resin or arbitrary combination.
Optionally, styrenic thermoplastic elastomer's rubber is SIS rubber or SEPS rubber.
Optionally, the tackifying resin is monomer resin.
Optionally, the monomer resin is Kristalex3085 or Kristalex5140.
Optionally, the softening point of the monomer resin is 85 DEG C.
Optionally, the polyisobutene is the PB1300 or PB1400 of South Korea great Lin.
Optionally, the naphthenic oil is Kelamayi 4010；The base oil is the double dragon 250N of South Korea.The base oil
When kinematic viscosity is 100 DEG C, 10mm2/s。
Optionally, the antioxidant is four [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters and β-
The mixture of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid n-octadecyl alcohol ester.
Optionally, the UV absorbers are 2- (2- hydroxyls -5 '-aminomethyl phenyl) benzotriazole and/or 2- (2- hydroxyls
Base -3- tertiary butyl -5- aminomethyl phenyls) -5- chlorobenzotriazoles.
The preparation method of above-mentioned waterproof roll hot melt adhesive, including following operating procedure：
1) butadiene-styrene rubber is added after taking PART EPOXY oil and base oil to heat, continuous heating to butadiene-styrene rubber melts completely
Afterwards, remaining Epoxy oil and base oil, styrenic thermoplastic elastomer's rubber of whole and part resin is added, continuous heating is extremely
Solid material melts completely；
2) remaining resin, antioxidant, UV absorbers, polyisobutene is added after mixing, cooling and solidifying is that is, complete
At.
Optionally, the mass ratio of the part resin being added in step 1) and styrenic thermoplastic elastomer's rubber is 8：10.
Optionally, the heating temperature that PART EPOXY oil and base oil are added in step 1) is 150 DEG C；The temperature of continuous heating
It is 150~165 DEG C.
Optionally, in order to avoid butadiene-styrene rubber occurs the phenomenon that thermal oxide decomposition, being added in step 1) under the high temperature conditions
It is 0.08 atmospheric pressure to open vacuum plant after butadiene-styrene rubber and keep vacuum degree.
The advantageous effect of waterproof roll hot melt adhesive of the present invention：
1, the present invention is used as rubber matrix using butadiene-styrene rubber and styrenic thermoplastic elastomer's rubber compounding, has high
Compatibility, then Petropols, hydrogenated petroleum resin or monomer resin are added as tackifying resin, it mutually acts synergistically, promotes heat
The initial bonding strength of melten gel, cold resistance, thermal stability, adhesion strength reduce the volatility of hot melt adhesive, especially promote hot melt adhesive to water
The cohesive force of the architectural environment of the humidity such as mud, concrete, great Sha；
2, further, select antioxidant for four [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] seasons in the present invention
The mixture of Doutrate and β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid n-octadecyl alcohol ester；UV absorbers are
2- (2- hydroxyls -5 '-aminomethyl phenyl) benzotriazole and/or 2- (2- hydroxyl -3- tertiary butyl -5- aminomethyl phenyls) -5- chlorobenzenes and three
Azoles further promotes the ageing resistance of hot melt adhesive, promotes the service life of waterproof roll, comply fully with the application of waterproof roll
It is required that；
The preparation method of waterproof roll hot melt adhesive of the present invention is firstly added butadiene-styrene rubber after butadiene-styrene rubber melts completely
Styrenic thermoplastic elastomer's rubber is added, avoids having butadiene-styrene rubber by two kinds of rubber matrixs while during melting
The defect that cannot melt completely；Secondly, resin is added in two portions, it is ensured that resin is sufficiently mixed with rubber matrix, is further carried
Rise the initial bonding strength and holding power of hot melt adhesive.
Specific implementation mode
The technical scheme of the invention is described in detail through specific implementation examples.
Embodiment 1
A kind of waterproof roll hot melt adhesive, is prepared by the component of following parts by weight：100 parts of butadiene-styrene rubber, SIS rubbers
250 parts of glue, 250 parts of Kristalex5140, four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] 5 parts of pentaerythritol esters,
5 parts of β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid n-octadecyl alcohol ester, 2- (2- hydroxyls -5 '-aminomethyl phenyl) benzotriazole
10 parts, 4,010 100 parts of Kelamayi, double 100 parts of the dragon 250N of South Korea, 100 parts of polyisobutene PB1300.
The preparation method of above-mentioned waterproof roll hot melt adhesive, including following operating procedure：
1) it takes part Kelamayi 4010 and the double dragon 250N of South Korea to be added in reaction kettle, is heated to 150 DEG C of addition butylbenzene rubbers
Glue opens vacuum extractor, and the vacuum degree in reaction kettle is made to reach 0.08 atmospheric pressure, and continuous heating is to 150~165 DEG C, fourth
After the melting completely of benzene rubber, be added the double dragon 250N of remaining Kelamayi 4010 and South Korea, whole SIS rubber and
200 parts of Kristalex5140, continuous heating to solid material melts completely；
2) remaining 50 parts of Kristalex5140, four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] seasons are added
Doutrate, β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid n-octadecyl alcohol ester, 2- (2- hydroxyls -5 '-aminomethyl phenyl) benzene
And triazole, polyisobutene, after mixing, cooling and solidifying is completed.
Embodiment 2
A kind of waterproof roll hot melt adhesive, is prepared by the component of following parts by weight：50 parts of butadiene-styrene rubber, SEPS rubbers
200 parts of glue, 200 parts of Kristalex3085, four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] 2 parts of pentaerythritol esters,
3 parts of β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid n-octadecyl alcohol ester, 2- (2- hydroxyls -5 '-aminomethyl phenyl) benzotriazole
5 parts, 4,010 200 parts of Kelamayi, 100 parts of polyisobutene PB1300
The preparation method of above-mentioned waterproof roll hot melt adhesive, including following operating procedure：
1) it takes part Kelamayi 4010 to be added in reaction kettle, is heated to 150 DEG C of addition butadiene-styrene rubber, opens vacuum means
It sets, so that the vacuum degree in reaction kettle is reached 0.08 atmospheric pressure, to 150~165 DEG C, butadiene-styrene rubber melts continuous heating completely
Afterwards, 160 parts of remaining Kelamayi 4010, whole SEPS rubber and Kristalex3085, continuous heating to solid is added
Raw material melts completely；
2) remaining 40 parts of Kristalex3085, four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] seasons are added
Doutrate, β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid n-octadecyl alcohol ester, 2- (2- hydroxyls -5 '-aminomethyl phenyl) benzene
And triazole, polyisobutene PB1300, after mixing, cooling and solidifying is completed.
Embodiment 3
A kind of waterproof roll hot melt adhesive, is prepared by the component of following parts by weight：50 parts of butadiene-styrene rubber, SIS rubbers
300 parts of glue, 300 parts of C9 Petropols, four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] 10 parts of pentaerythritol esters, β-
10 parts of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid n-octadecyl alcohol ester, 2- (2- hydroxyls -5 '-aminomethyl phenyl) benzotriazole
10 parts, 2- (2- hydroxyl -3- tertiary butyl -5- aminomethyl phenyls) 10 parts of -5- chlorobenzotriazoles, double 200 parts of the dragon 250N of South Korea, gather it is different
Butylene PB1300
The preparation method of above-mentioned waterproof roll hot melt adhesive, including following operating procedure：
1) it takes the double dragon 250N of part South Korea to be added in reaction kettle, is heated to 150 DEG C of addition butadiene-styrene rubber, opens vacuum means
It sets, so that the vacuum degree in reaction kettle is reached 0.08 atmospheric pressure, to 150~165 DEG C, butadiene-styrene rubber melts continuous heating completely
Afterwards, 240 parts of the double dragon 250N of remaining South Korea, whole SIS rubber and C9 Petropols are added, continuous heating is complete to solid material
Full-fusing；
2) remaining 60 parts of C9 Petropols, four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] Ji Wusi are added
Alcohol ester, β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid n-octadecyl alcohol ester, 2- (2- hydroxyls -5 '-aminomethyl phenyl) benzo three
Azoles, 2- (2- hydroxyl -3- tertiary butyl -5- aminomethyl phenyls) -5- chlorobenzotriazoles, polyisobutene PB1300, it is after mixing, cooling
Solidification, that is, complete.
Comparative example 1
This comparative example as different from Example 1 this comparative example prepare hot melt adhesive component in be additionally added to SBS rubber,
Adjust SBS rubber, butadiene-styrene rubber, SIS rubber dosage be respectively 130 parts of SBS rubber, 150 parts of butadiene-styrene rubber, SIS rubber 170
Part；Other are the same as embodiment 1.
Comparative example 2
This comparative example as different from Example 1 this comparative example prepare hot melt adhesive group be divided into acrylic block copolymers
300 parts, 80 parts of ethylene ethyl acrylate, 70 parts of ethylene methacrylic acid, Kristalex5140250 parts, four [β-(bis- uncles of 3,5-
Butyl -4- hydroxy phenyls) propionic acid] 5 parts of pentaerythritol ester, the positive octadecanol of β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid
5 parts of ester, 10 parts of 2- (2- hydroxyls -5 '-aminomethyl phenyl) benzotriazole, 4,010 100 parts of Kelamayi, the double dragon 250N 100 of South Korea
Part；Other are the same as embodiment 1.
Comparative example 3
This comparative example uses DCPD resin replacements unlike comparative example 2 in the component of this comparative example preparation hot melt adhesive
Kristalex5140；Other are the same as comparative example 2.
Comparative example 4
This comparative example as different from Example 1, DCPD resin replacements is used in the component of this comparative example preparation hot melt adhesive
Kristalex5140；Other are the same as embodiment 1.
Comparative example 5
This comparative example as different from Example 1, be added in preparation method, in step 1) the double dragon 250N of remaining South Korea,
Whole SIS rubber and whole Kristalex5140, other are the same as embodiment 1.
Test example
The comprehensive performance that the hot melt adhesive prepared respectively to embodiment 1, comparative example 1~5 is applied to waterproof roll is detected,
Testing result is as shown in table 1 below：
Table 1
The data shown in above-mentioned table 1 are it is found that the properties of hot melt adhesive prepared by the embodiment of the present invention 1 are superior to compare
Example 1 is substantially equivalent with comparative example 1, it can be seen that simplifies rubber matrix formula in the present invention, while adjusting tackifying resin and being
Monomer resin or Petropols or hydrogenated petroleum resin, in the case where simplifying formula, still maintaining hot melt adhesive has low wave
Hair property, and the comprehensive performances such as the cold resistance of hot melt adhesive, holding power are promoted, hot melt adhesive is especially improved to cement, concrete, great Sha
Deng the cohesive force of moist architectural environment；In addition, the properties of hot melt adhesive prepared by embodiment 1 are better than comparative example 5, thus may be used
The comprehensive performance of hot melt adhesive can be promoted using addition tackifying resin in batches by seeing；In addition, hot melt adhesive prepared by embodiment 1 is waved
Hair property is less than comparative example 4, and the volatility of the hot melt adhesive of comparative example 2 is equal with comparative example 3, it can be seen that monomer resin is as thickening
Resin is related to the improvement result of hot melt adhesive volatile performance and the type of rubber matrix, and the rubber matrix that the present invention limits is added single
The volatile performance of hot melt adhesive can be significantly reduced when body resin is as tackifying resin.
The properties of hot melt adhesive prepared by the embodiment of the present invention 2 and embodiment 3 and hot melt adhesive prepared by embodiment 1 are basic
It is equivalent.
Claims (5)
1. a kind of waterproof roll hot melt adhesive, which is characterized in that be prepared by the component of following parts by weight：Butadiene-styrene rubber 50
~200 parts, it is 200~300 parts of styrenic thermoplastic elastomer's rubber, 200~300 parts of tackifying resin, 5~20 parts of antioxidant, purple
5~20 parts of outer light absorber, 0~200 part of naphthenic oil, 0~200 part of base oil；100~200 parts of polyisobutene；
Styrenic thermoplastic elastomer's rubber is SIS rubber；The tackifying resin Kristalex5140；
Preparation method is：Including following operating procedure：
1) butadiene-styrene rubber is added after taking part naphthenic oil and base oil to heat after continuous heating to butadiene-styrene rubber melts completely to add
Enter remaining naphthenic oil and base oil, styrenic thermoplastic elastomer's rubber of whole and part resin, continuous heating to solid
Raw material melts completely；
2) remaining resin, antioxidant, polyisobutene, UV absorbers are added, after mixing, cooling and solidifying is completed.
2. waterproof roll hot melt adhesive as described in claim 1, which is characterized in that the naphthenic oil is Kelamayi 4010；
Base oil is the double dragon 250N of South Korea.
3. waterproof roll hot melt adhesive as claimed in claim 2, which is characterized in that the molecular weight of the polyisobutene is
1000-2000。
4. waterproof roll hot melt adhesive as described in claim 1, which is characterized in that the antioxidant is four [β-(3,5- bis- uncles
Butyl -4- hydroxy phenyls) propionic acid] pentaerythritol ester and β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid n-octadecyl alcohol ester
Mixture；The UV absorbers are 2- (2- hydroxyls -5 '-aminomethyl phenyl) benzotriazole and/or 2- (2- hydroxyls -3- spies
Butyl -5- aminomethyl phenyls) -5- chlorobenzotriazoles.
5. waterproof roll hot melt adhesive described in claim 1, which is characterized in that the part resin and benzene being added in step 1)
The mass ratio of ethylene thermoplastic's elastomer rubber is 8：10.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710140523.XA CN106893536B (en) | 2017-03-10 | 2017-03-10 | A kind of waterproof roll hot melt adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710140523.XA CN106893536B (en) | 2017-03-10 | 2017-03-10 | A kind of waterproof roll hot melt adhesive and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106893536A CN106893536A (en) | 2017-06-27 |
| CN106893536B true CN106893536B (en) | 2018-10-30 |
Family
ID=59192570
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710140523.XA Active CN106893536B (en) | 2017-03-10 | 2017-03-10 | A kind of waterproof roll hot melt adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106893536B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108587509A (en) * | 2018-04-26 | 2018-09-28 | 昆山科顺防水材料有限公司 | Novel non-bituminous base adhesive waterproof coil of one kind and preparation method thereof |
| CN108641628A (en) * | 2018-04-26 | 2018-10-12 | 昆山科顺防水材料有限公司 | A kind of waterproof roll non-bituminous self-adhesion sizing material and preparation method thereof |
| CN108715749B (en) * | 2018-06-05 | 2020-07-14 | 嘉好(太仓)新材料股份有限公司 | High-ultraviolet-resistance waterproof adhesive and preparation method thereof |
| CN111320763B (en) * | 2018-12-14 | 2022-12-02 | 科建高分子材料（上海）股份有限公司 | Production process for preventing hot melt adhesive from generating particles |
| CN110079256A (en) * | 2019-05-10 | 2019-08-02 | 无锡市万力粘合材料股份有限公司 | Hot-fusible pressure-sensitive adhesive of UV resistant and preparation method thereof |
| CN111592843A (en) * | 2020-05-19 | 2020-08-28 | 上海嘉好胶粘制品有限公司 | Hot-melt pressure-sensitive adhesive for normal-temperature waterproof coiled material butt-joint adhesive tape and preparation method thereof |
| CN111548758A (en) * | 2020-05-19 | 2020-08-18 | 上海嘉好胶粘制品有限公司 | Special hot-melt pressure-sensitive adhesive for low-temperature waterproof coiled material butt-joint adhesive tape and preparation method thereof |
| CN111647377B (en) * | 2020-06-11 | 2021-06-29 | 广东荣嘉新材料科技有限公司 | Anti-wrinkle type environment-friendly hot melt adhesive for film back adhesive bags and preparation method and application thereof |
| CN114854344A (en) * | 2022-05-11 | 2022-08-05 | 浙江本源纸塑科技有限公司 | Glue for price paper |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104099039A (en) * | 2014-06-26 | 2014-10-15 | 青岛博洋生物技术有限公司 | Sticky water-proof material and preparation method thereof |
| CN106281151A (en) * | 2016-08-06 | 2017-01-04 | 石春意 | Polymer membranes PUR and preparation method thereof |
| CN106398642A (en) * | 2016-08-26 | 2017-02-15 | 广西青龙化学建材有限公司 | High viscosity non-asphalt base self-adhesive glue for waterproof coiled materials and preparation method thereof |
-
2017
- 2017-03-10 CN CN201710140523.XA patent/CN106893536B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104099039A (en) * | 2014-06-26 | 2014-10-15 | 青岛博洋生物技术有限公司 | Sticky water-proof material and preparation method thereof |
| CN106281151A (en) * | 2016-08-06 | 2017-01-04 | 石春意 | Polymer membranes PUR and preparation method thereof |
| CN106398642A (en) * | 2016-08-26 | 2017-02-15 | 广西青龙化学建材有限公司 | High viscosity non-asphalt base self-adhesive glue for waterproof coiled materials and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106893536A (en) | 2017-06-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106893536B (en) | A kind of waterproof roll hot melt adhesive and preparation method thereof | |
| CN106349723B (en) | Modified asphalt sizing material, preparation method thereof and asphalt waterproof coiled material | |
| KR101672823B1 (en) | Modified nonvolatile cold asphalt binder and recycled asphalt mixture using thereof | |
| CN101921545B (en) | Asphalt waterproof paint for building and preparation method thereof | |
| CN105885693A (en) | Non-curable rubber asphalt waterproof coating and preparation method and composite waterproof roll material thereof | |
| CN101864259A (en) | SIS (Styrene-Isoprene-Styrene) hot melt adhesive for car light adhesion and preparation method thereof | |
| CN104946178A (en) | Novel hot-melt pressure-sensitive adhesive for waterproof materials and preparation method thereof | |
| CN107083200A (en) | A kind of flame-retardant high-molecular self-adhesion glued membrane waterproof roll and preparation method thereof | |
| CN109401727B (en) | Asphalt mastic and preparation method and application thereof | |
| CN112175555A (en) | Polar hot melt adhesive and preparation method thereof | |
| CN112920714A (en) | Waterproof coating material and preparation method thereof | |
| CN110724387A (en) | Modified asphalt pavement repair material suitable for high-temperature rainy areas and preparation method thereof | |
| KR101748492B1 (en) | Asphalt modifier and preparing thereof | |
| CN106893529B (en) | A kind of weather-proof thermotropic pressure sensitive glue and preparation method thereof | |
| CN109096934A (en) | A kind of high temperature resistant waterproof butyl rubber belt | |
| CN111139004B (en) | Long-acting anti-ultraviolet hot-melt pressure-sensitive adhesive for non-asphalt-based high-polymer waterproof coiled material and preparation method thereof | |
| CN111075120B (en) | Special exposed self-adhesive waterproof roll for metal roof | |
| CN104293244A (en) | Transparent nail-free glue and preparation method thereof | |
| CN104449494A (en) | SIS-b-PEO hot-melt pressure-sensitive adhesive and preparation method thereof | |
| CN110358452A (en) | A kind of room temperature scratches uncured rubber asphalt waterproof coating and preparation method thereof | |
| CN113698897B (en) | Modified butyl rubber composition, modified butyl rubber and preparation method and application thereof | |
| CN116042122A (en) | Exposed non-asphalt-based high polymer self-adhesive waterproof coiled material and preparation method thereof | |
| CN114231225B (en) | Hot melt adhesive for drain board and preparation method thereof | |
| KR101832182B1 (en) | Asphalt crack repair with carbon fiber using self-expandable compound and construction method using the same | |
| CN104277283B (en) | A kind of TPO waterproof membrane of ultraviolet light cross-linking and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |