CN111647334A - Laminated scaly heavy-duty anticorrosive paint and preparation method thereof - Google Patents
Laminated scaly heavy-duty anticorrosive paint and preparation method thereof Download PDFInfo
- Publication number
- CN111647334A CN111647334A CN202010576267.0A CN202010576267A CN111647334A CN 111647334 A CN111647334 A CN 111647334A CN 202010576267 A CN202010576267 A CN 202010576267A CN 111647334 A CN111647334 A CN 111647334A
- Authority
- CN
- China
- Prior art keywords
- parts
- component
- flake
- agent
- aluminum paste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/103—Anti-corrosive paints containing metal dust containing Al
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
Abstract
The invention discloses a layered flake heavy-duty anticorrosive paint and a preparation method thereof, wherein the paint comprises the following components in parts by weight: the component A comprises: 5-20 parts of basalt flakes, 5-20 parts of aluminum paste, 15-40 parts of epoxy resin, 0.5-1 part of thickening agent, 0.5-1 part of dispersing agent, 0.5-1 part of flatting agent, 0.5-1 part of defoaming agent, 0.5-1 part of film-forming assistant and 15-40 parts of solvent; and B component: 20-40 parts of curing agent and 15-40 parts of solvent; the weight ratio of the component A to the component B is 4: 1. After the coating is formed on the base material, the external corrosive medium can corrode the base material by walking a longer way, namely, the labyrinth effect, the abrasion resistance and the chemical stability of the coating can be improved by the basalt flakes, the aluminum paste has the performances of stronger metallic luster, good heat resistance, corrosion resistance and the like, the coating generates the angle-dependent heterochromatic effect, and the combination of the two enables the performance of the coating to be greatly improved.
Description
Technical Field
The invention relates to the technical field of power grid iron tower heavy-duty anticorrosive coatings, in particular to a layered flake heavy-duty anticorrosive coating and a preparation method thereof.
Background
At present, a lot of fillers are developed and applied to the heavy-duty anticorrosive coating for the power grid iron tower, for example, the heavy-duty anticorrosive coating filled with glass flakes has many defects of large brittleness, poor compatibility with epoxy resin and poor weather resistance. Although some metal flake fillers are like stainless steel flake heavy-duty anticorrosive coatings, although brittleness, weather resistance, mechanical strength and wear resistance are improved to a certain extent, the manufacturing process of the stainless steel flakes is high, so that the cost is high, and although the glass flakes and the stainless steel flakes can prevent corrosive media from permeating inwards, the time for the corrosive media to permeate inwards can be prolonged only by increasing the thickness.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides a layered flake heavy-duty anticorrosive coating and a preparation method thereof.
According to a first aspect of the invention, the invention discloses a layered flake type heavy-duty anticorrosive coating, which comprises the following components in parts by weight:
the component A comprises: 5-20 parts of basalt flakes, 5-20 parts of aluminum paste, 15-40 parts of epoxy resin, 0.5-1 part of thickening agent, 0.5-1 part of dispersing agent, 0.5-1 part of flatting agent, 0.5-1 part of defoaming agent, 0.5-1 part of film-forming assistant and 15-40 parts of solvent;
and B component: 20-40 parts of curing agent and 15-40 parts of solvent;
wherein the weight ratio of the component A to the component B is 4: 1.
According to an embodiment of the present invention, the aluminum paste is a floating aluminum paste or a non-floating aluminum paste.
According to one embodiment of the invention, the epoxy resin is one of EP-12, EP-13, EP-16, EP-20, E35, E44, E51.
According to an embodiment of the present invention, the thickener is one of organic bentonite, diatomaceous earth, fumed silica, sodium bentonite, silica gel, polyurethane thickener, and sodium polyacrylate.
According to an embodiment of the present invention, the dispersant is an inorganic powder or a water-soluble organic polymer.
According to an embodiment of the present invention, the leveling agent is one of isophorone, diacetone alcohol, Solvesso150, ethylene glycol monobutyl ether, and polydimethylsiloxane.
According to an embodiment of the present invention, the coalescing agent is one of benzyl alcohol, butyl cellosolve, and propylene glycol phenyl ether.
According to an embodiment of the present invention, the defoaming agent is an inorganic silicon-based defoaming agent or an organic silicon-based defoaming agent.
According to an embodiment of the present invention, the solvent is one of xylene, ethyl acetate, butyl acetate, and n-butanol.
According to an embodiment of the present invention, the curing agent is one of polyamide 300, polyamide 650, and polyamide 651.
According to a second aspect of the present invention, the present invention discloses a method for preparing a laminated flake type heavy duty anticorrosive paint, comprising:
according to the weight part of the component A, adding a solvent into the basalt scales and the aluminum paste according to the weight ratio of 1:1 for pre-dispersion, and slowly and uniformly stirring to prepare a mixed solution of the basalt scales and the aluminum paste.
Under the condition of normal temperature and normal pressure drying, adding epoxy resin, a thickening agent, a dispersing agent, a flatting agent, a defoaming agent and a film forming aid into the prepared basalt flake and aluminum paste mixed solution, and uniformly mixing to obtain a component A solution.
And (3) under the condition of drying at normal temperature and normal pressure, uniformly mixing the curing agent and the solvent according to the weight part of the component B to obtain a component B solution.
Mixing the component A solution and the component B solution according to a weight ratio of 4:1 to obtain the finished coating.
In the invention, when the finished paint product is prepared, the used lamellar fillers are basalt flakes and aluminum paste, and the resin base material is epoxy resin. The basalt flakes are pigments in the finished paint product and are also anti-corrosion media in the finished paint product, and because the basalt flakes are lamellar and exist in the finished paint product in a lap joint mode, after the paint is coated on a substrate, the external corrosion media can be corroded to the substrate by walking a longer path, namely a labyrinth effect, the abrasion resistance and chemical stability of the coating can be improved, the aluminum silver paste has strong metal luster, good heat resistance, corrosion resistance and other properties, the coating can generate a corner-dependent color effect, and the coating performance is greatly improved by the combination of the aluminum silver paste and the aluminum silver paste.
Detailed Description
In the following description, numerous implementation details are set forth in order to provide a thorough understanding of the present invention. It should be understood, however, that these implementation details are not to be interpreted as limiting the invention. That is, in some embodiments of the invention, such implementation details are not necessary.
The invention is further illustrated by the following specific examples.
Example one
Under the condition of normal temperature and normal pressure drying, adding 15 parts of xylene solvent into 5 parts of basalt flakes and 5 parts of aluminum silver paste, uniformly stirring, pre-dispersing to prepare a mixed solution of the basalt flakes and the aluminum silver paste for later use, adding 15 parts of E35 epoxy resin into the prepared mixed solution of the basalt flakes and the aluminum silver paste, then adding 0.5 part of each of an organic bentonite thickener, a water-soluble organic polymer dispersant, an isophorone leveling agent, an organic silicon defoamer and a benzyl alcohol film-forming aid, and uniformly stirring again to obtain a component A solution. And then 20 parts of polyamide 650 is taken, and 15 parts of xylene solvent is added and stirred uniformly to obtain a component B solution. And mixing the component A solution and the component B solution according to the ratio of 4:1 to obtain the laminar flake heavy-duty anticorrosive coating.
The main performance parameters of the scale-type heavy-duty anticorrosive coating prepared in this example are shown in table 1.
| Hardness of coating | 2-3H |
| Impact resistance | 60kg*cm |
| Resistance to salt fog | 1500h |
| Adhesion force | 18-20MPa |
| Resistance to bending | 20mm |
| Acid resistance (50% H2SO4) | 150d |
| Alkali resistance (50%NaOH) | 150d |
| Weather resistance | 1500h |
TABLE 1
Example two
Under the condition of normal temperature and normal pressure drying, 20 parts of basalt scales and 20 parts of aluminum paste are taken, 40 parts of xylene solvent is added and uniformly stirred for pre-dispersion to prepare a mixed solution of the basalt scales and the aluminum paste for later use, then 40 parts of E35 epoxy resin is added into the prepared mixed solution of the basalt scales and the aluminum paste, then 1 part of each of an organic bentonite thickener, a water-soluble organic polymer dispersant, an isophorone leveling agent, an organic silicon defoamer and a benzyl alcohol film forming aid is added, and the mixture is uniformly stirred again to obtain a component A solution. And then 40 parts of polyamide 650 is taken, 40 parts of xylene solvent is added and stirred uniformly to obtain the component B solution. And (3) mixing the component A solution and the component B solution according to the ratio of 4:1 to obtain the laminar flake heavy-duty anticorrosive coating. The main performance parameters of the scale-type heavy-duty anticorrosive coating obtained in this example were measured and are shown in table 2.
| Hardness of coating | 3-4H |
| Impact resistance | 70kg*cm |
| Resistance to salt fog | 1600h |
| Adhesion force | 15-18MPa |
| Resistance to bending | 25mm |
| Acid resistance (50% H2SO4) | 200d |
| Alkali resistance (50% NaOH) | 200d |
| Weather resistance | 1600h |
TABLE 2
EXAMPLE III
Under the condition of normal temperature and normal pressure drying, 10 parts of basalt scales and 10 parts of aluminum paste are taken, 25 parts of xylene solvent is added to be uniformly stirred and pre-dispersed to prepare a mixed solution of the basalt scales and the aluminum paste for later use, 25 parts of E35 epoxy resin is added to the prepared mixed solution of the basalt scales and the aluminum paste, then 0.8 part of each of an organic bentonite thickener, a water-soluble organic polymer dispersant, an isophorone leveling agent, an organic silicon defoamer and a benzyl alcohol film forming aid is added to be uniformly stirred again to obtain a component A solution. And then adding 30 parts of polyamide 650 into 25 parts of xylene solvent and uniformly stirring to obtain a component B solution. And (3) mixing the component A solution and the component B solution according to the ratio of 4:1 to obtain the laminar flake heavy-duty anticorrosive coating. The main performance parameters of the scale-type heavy-duty anticorrosive coating obtained in this example were measured and shown in table 3.
| Hardness of coating | 3-4H |
| Impact resistance | 80kg*cm |
| Resistance to salt fog | 1800h |
| Adhesion force | 20-25MPa |
| Resistance to bending | 30mm |
| Acid resistance (50% H2SO4) | 220d |
| Alkali resistance (50% NaOH) | 220d |
| Weather resistance | 1800h |
TABLE 3
In order to illustrate the effect of aluminum paste in the laminated flake heavy-duty anticorrosive coating, three groups of heavy-duty anticorrosive coatings without aluminum paste were compared and tested for main properties according to the first, second and third examples, and the comparative examples and test results are as follows:
comparative example 1
Under the condition of normal temperature and normal pressure drying, 5 parts of basalt flakes are taken, 15 parts of dimethylbenzene solvent is added and uniformly stirred for pre-dispersion to prepare basalt flake solution for later use, then 15 parts of E35 epoxy resin is added into the prepared basalt flake solution, then 0.5 part of each of an organic bentonite thickening agent, a water-soluble organic polymer dispersing agent, an isophorone leveling agent, an organic silicon defoaming agent and a benzyl alcohol film-forming aid is added, and the mixture is uniformly stirred again to obtain the component A solution. And then 20 parts of polyamide 650 is taken, and 15 parts of xylene solvent is added and stirred uniformly to obtain a component B solution. And mixing the component A solution and the component B solution according to the ratio of 4:1 to obtain the heavy anti-corrosion coating without aluminum paste. The main performance parameters of the heavy duty anticorrosive coating without aluminum paste prepared in this example are shown in table 4.
| Hardness of coating | 1-2H |
| Impact resistance | 50kg*cm |
| Resistance to salt fog | 1200h |
| Adhesion force | 12-15MPa |
| Resistance to bending | 15mm |
| Acid resistance (50% H2SO4) | 100d |
| Alkali resistance (50% NaOH) | 100d |
| Weather resistance | 1200h |
TABLE 4
Comparative example No. two
Under the condition of normal temperature and normal pressure drying, 20 parts of basalt flakes are taken, 40 parts of dimethylbenzene solvent is added and uniformly stirred for pre-dispersion to prepare basalt flake solution for later use, then 40 parts of E35 epoxy resin is added into the prepared basalt flake solution, then 1 part of each of an organic bentonite thickening agent, a water-soluble organic polymer dispersing agent, an isophorone leveling agent, an organic silicon defoaming agent and a benzyl alcohol film-forming aid is added, and the solution A is uniformly stirred again to obtain the component A solution. And then 40 parts of polyamide 650 is taken, 40 parts of xylene solvent is added and stirred uniformly to obtain the component B solution. And mixing the component A solution and the component B solution according to the ratio of 4:1 to obtain the heavy anti-corrosion coating without aluminum paste. The main performance parameters of the heavy duty anticorrosive coating without aluminum paste prepared in this example are shown in table 5.
| Hardness of coating | 2-3H |
| Impact resistance | 55kg*cm |
| Resistance to salt fog | 1300h |
| Adhesion force | 12-16MPa |
| Resistance to bending | 20mm |
| Acid resistance (50% H2S)O4) | 120d |
| Alkali resistance (50% NaOH) | 120d |
| Weather resistance | 1300h |
TABLE 5
Comparative example No. three
Under the condition of normal temperature and normal pressure drying, 10 parts of basalt flakes are taken, 25 parts of xylene solvent is added and uniformly stirred for pre-dispersion to prepare basalt flake solution for later use, then 25 parts of E35 epoxy resin is added into the prepared basalt flake solution, then 0.8 part of each of organic bentonite thickener, water-soluble organic polymer dispersant, isophorone leveling agent, organosilicon defoamer and benzyl alcohol film-forming aid is added, and the component A solution is obtained after uniform stirring again. And then adding 30 parts of polyamide 650 into 25 parts of xylene solvent and uniformly stirring to obtain a component B solution. And mixing the component A solution and the component B solution according to the ratio of 4:1 to obtain the heavy anti-corrosion coating without aluminum paste. The main performance parameters of the heavy duty anticorrosive coating without aluminum paste prepared in this example are shown in table 6.
| Hardness of coating | 2-3H |
| Impact resistance | 60kg*cm |
| Resistance to salt fog | 1500h |
| Adhesion force | 16-18MPa |
| Resistance to bending | 20mm |
| Acid resistance (50% H2SO4) | 150d |
| Alkali resistance (50% NaOH) | 150d |
| Weather resistance | 1300h |
TABLE 6
Compared with the main performance parameters of the two heavy-duty anticorrosive coatings, the lamellar scale type heavy-duty anticorrosive coating has better performances such as hardness, impact resistance, salt fog resistance, acid and alkali resistance, bending resistance and adhesive force compared with the heavy-duty anticorrosive coating only containing basalt scales and not containing aluminum silver paste. This shows that the added aluminum paste plays a role, so that the performance of the coating in all aspects is improved.
The coating prepared by the invention forms a coating on the surface of a substrate, and the wear resistance, corrosion resistance and chemical corrosion resistance of the coating are greatly improved by basalt flakes in the coating. The basalt scale can generate a labyrinth effect in the coating due to the lap joint structure of the basalt scale, so that a corrosive medium can corrode the base material after passing through a longer path, the corrosion time of the base material is greatly delayed, the added aluminum paste has stronger metallic luster, good heat resistance, corrosion resistance and other performances, the coating can be more smooth and bright, the coating can generate an angle-dependent heterochrosis effect, the combination of the two enables the wear resistance and corrosion resistance of the coating to be greatly improved, and the coating also has better flatness.
Claims (11)
1. A layered flake heavy-duty anticorrosive coating is characterized by comprising the following components in parts by weight:
the component A comprises: 5-20 parts of basalt flakes, 5-20 parts of aluminum paste, 15-40 parts of epoxy resin, 0.5-1 part of thickening agent, 0.5-1 part of dispersing agent, 0.5-1 part of flatting agent, 0.5-1 part of defoaming agent, 0.5-1 part of film-forming assistant and 15-40 parts of solvent;
and B component: 20-40 parts of curing agent and 15-40 parts of solvent;
wherein the weight ratio of the component A to the component B is 4: 1.
2. The flake-type heavy-duty coating of claim 1, wherein said aluminum paste is leafing aluminum paste or non-leafing aluminum paste.
3. The flake-type heavy-duty coating material as claimed in claim 1, wherein said epoxy resin is one of EP-12, EP-13, EP-16, EP-20, E35, E44 and E51.
4. The flake-type heavy-duty coating material as claimed in claim 1, wherein said thickener is one of organobentonite, diatomaceous earth, fumed silica, sodium bentonite, silica gel, polyurethane thickener, and sodium polyacrylate.
5. The flake-type heavy-duty coating material according to claim 1, wherein said dispersant is an inorganic powder or a water-soluble organic polymer.
6. The flake-type heavy-duty coating composition according to claim 1, wherein said leveling agent is one of isophorone, diacetone alcohol, Solvesso150, ethylene glycol monobutyl ether, and polydimethylsiloxane.
7. The flake-type heavy-duty coating material according to claim 1, wherein said film-forming aid is one of benzyl alcohol, butyl cellosolve and propylene glycol phenyl ether.
8. The flake-type heavy-duty anticorrosive coating material according to claim 1, wherein the defoaming agent is an inorganic silicon-based defoaming agent or an organic silicon-based defoaming agent.
9. The flake-type heavy-duty anticorrosive coating material according to claim 1, wherein the solvent is one of xylene, ethyl acetate, butyl acetate, and n-butanol.
10. The flake-type heavy-duty anticorrosive coating material according to claim 1, wherein said curing agent is one of polyamide 300, polyamide 650, and polyamide 651.
11. A preparation method of a layered flake heavy-duty anticorrosive paint is characterized by comprising the following steps:
according to the weight part of the component A, adding a solvent into the basalt scales and the aluminum paste according to the weight ratio of 1:1 for pre-dispersion, and slowly and uniformly stirring to prepare a mixed solution of the basalt scales and the aluminum paste.
Under the condition of normal temperature and normal pressure drying, adding epoxy resin, a thickening agent, a dispersing agent, a flatting agent, a defoaming agent and a film forming aid into the prepared basalt flake and aluminum paste mixed solution, and uniformly mixing to obtain a component A solution.
And (3) under the condition of drying at normal temperature and normal pressure, uniformly mixing the curing agent and the solvent according to the weight part of the component B to obtain a component B solution.
Mixing the component A solution and the component B solution according to a weight ratio of 4:1 to obtain the finished coating.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010291333X | 2020-04-14 | ||
| CN202010291333 | 2020-04-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111647334A true CN111647334A (en) | 2020-09-11 |
Family
ID=72340867
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010576267.0A Pending CN111647334A (en) | 2020-04-14 | 2020-06-22 | Laminated scaly heavy-duty anticorrosive paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111647334A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112552796A (en) * | 2020-12-11 | 2021-03-26 | 中国南方电网有限责任公司超高压输电公司柳州局 | Metal flake type bi-component heavy-duty anticorrosive paint and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009031914A1 (en) * | 2007-09-04 | 2009-03-12 | Joint Stock Company 'bazaltoplastic' | Polymer composition for protective anticorrosion barrier-type coating |
| CN103627294A (en) * | 2012-08-24 | 2014-03-12 | 哈尔滨功成科技创业投资有限公司 | Heavy anti-corrosion paint made of epoxy resin and basalt scales |
| CN110172290A (en) * | 2019-06-06 | 2019-08-27 | 烟台华正科信实业有限公司 | A kind of ship epoxy anticorrosive paint of the Scale filler containing basalt |
-
2020
- 2020-06-22 CN CN202010576267.0A patent/CN111647334A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009031914A1 (en) * | 2007-09-04 | 2009-03-12 | Joint Stock Company 'bazaltoplastic' | Polymer composition for protective anticorrosion barrier-type coating |
| CN103627294A (en) * | 2012-08-24 | 2014-03-12 | 哈尔滨功成科技创业投资有限公司 | Heavy anti-corrosion paint made of epoxy resin and basalt scales |
| CN110172290A (en) * | 2019-06-06 | 2019-08-27 | 烟台华正科信实业有限公司 | A kind of ship epoxy anticorrosive paint of the Scale filler containing basalt |
Non-Patent Citations (1)
| Title |
|---|
| 卢生雄等: "《化工商品知识》", 30 November 1985, 福建科学技术出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112552796A (en) * | 2020-12-11 | 2021-03-26 | 中国南方电网有限责任公司超高压输电公司柳州局 | Metal flake type bi-component heavy-duty anticorrosive paint and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101643615B (en) | Polyaniline modified glass flake heavy-duty anti-corrosive coating and preparation method thereof | |
| CN101633808A (en) | High chlorinated polyethylene coating containing stainless steel flakes and preparation method thereof | |
| CN102174291A (en) | Organosilicon-modified alkyd resin paint composite and preparation method thereof | |
| CN108570273B (en) | Solvent-free graphene oxide-glass flake anticorrosive paint and preparation method thereof | |
| WO2015058669A1 (en) | Preparation method for aqueous epoxy ester resin and use thereof | |
| CN106833044A (en) | A kind of aqueous environment protection metal anti-corrosive paint and preparation method thereof | |
| KR100896080B1 (en) | Aqueous anti-corrosion paint composition | |
| KR101465492B1 (en) | Adhesion promoter composition for coating and a coating composition including the same | |
| CN108409932B (en) | Preparation method of modified epoxy resin and application of modified epoxy resin in heavy-duty anticorrosive paint | |
| CN113136022B (en) | Hyperbranched amine compound and preparation method and application thereof | |
| CN108559358B (en) | Solvent-free graphene-glass flake anticorrosive paint and preparation method thereof | |
| CN111647334A (en) | Laminated scaly heavy-duty anticorrosive paint and preparation method thereof | |
| CN113667371B (en) | Water-based epoxy anticorrosive paint for heat exchanger and preparation method thereof | |
| CN112552796A (en) | Metal flake type bi-component heavy-duty anticorrosive paint and preparation method thereof | |
| CN112852214A (en) | Adhesion promoting material and preparation method and application thereof | |
| JP7284586B2 (en) | Water-based paint composition | |
| CN102453403A (en) | Mastic chlorinated rubber corrosion-resistant paint | |
| WO2023207997A1 (en) | Two-component coating composition and method for preparing the same and coated article | |
| JP2004002637A (en) | Zinc powder-containing slurry and water-based coating material | |
| CN115651481A (en) | Water-based two-component epoxy thick-paste paint for anticorrosive coating and preparation method thereof | |
| CN112852260B (en) | Durable epoxy resin anticorrosive paint and preparation method and application thereof | |
| CN108329807A (en) | A kind of single-component water-based acrylic acid -ol acid graphene anticorrosive paint of quick-drying | |
| KR101532201B1 (en) | Anti-corrosive coating composition for metal and articles coated therewith | |
| CN104449198A (en) | Nano anticorrosive paint | |
| CN110295000B (en) | Low-viscosity high-film-thickness vinyl ester coating capable of being recoated and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200911 |
|
| RJ01 | Rejection of invention patent application after publication |