CN111646821B - Convex carving ceramic and coloring manufacturing method thereof - Google Patents
Convex carving ceramic and coloring manufacturing method thereof Download PDFInfo
- Publication number
- CN111646821B CN111646821B CN202010647329.2A CN202010647329A CN111646821B CN 111646821 B CN111646821 B CN 111646821B CN 202010647329 A CN202010647329 A CN 202010647329A CN 111646821 B CN111646821 B CN 111646821B
- Authority
- CN
- China
- Prior art keywords
- ceramic
- parts
- glaze layer
- relief
- ceramic glaze
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 230
- 238000004040 coloring Methods 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title claims description 19
- 238000010304 firing Methods 0.000 claims abstract description 23
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 238000001035 drying Methods 0.000 claims description 18
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 14
- 229910001570 bauxite Inorganic materials 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 13
- 239000010455 vermiculite Substances 0.000 claims description 13
- 229910052902 vermiculite Inorganic materials 0.000 claims description 13
- 235000019354 vermiculite Nutrition 0.000 claims description 13
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 claims description 11
- 229960005235 piperonyl butoxide Drugs 0.000 claims description 11
- 238000005507 spraying Methods 0.000 claims description 11
- 239000005995 Aluminium silicate Substances 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims description 7
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 7
- 239000000920 calcium hydroxide Substances 0.000 claims description 7
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 7
- 239000010459 dolomite Substances 0.000 claims description 7
- 229910000514 dolomite Inorganic materials 0.000 claims description 7
- 239000010433 feldspar Substances 0.000 claims description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 7
- 239000010453 quartz Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
- 239000010975 amethyst Substances 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 238000005498 polishing Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 abstract description 21
- 238000005336 cracking Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000007493 shaping process Methods 0.000 abstract description 2
- 229910052573 porcelain Inorganic materials 0.000 description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 12
- 239000000126 substance Substances 0.000 description 6
- 230000007547 defect Effects 0.000 description 5
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910001648 diaspore Inorganic materials 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 230000013011 mating Effects 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000011990 functional testing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/53—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone involving the removal of at least part of the materials of the treated article, e.g. etching, drying of hardened concrete
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/91—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics involving the removal of part of the materials of the treated articles, e.g. etching
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The invention relates to the technical field of coloring of relief ceramics, and discloses a relief ceramic which comprises a ceramic body, wherein a relief layer is formed on the outer surface of the ceramic body; the first ceramic glaze layer is sprayed on the outer surfaces of the ceramic body and the relief layer; the second ceramic glaze layer is sprayed on the outer surface of the first ceramic glaze layer. The ceramic glaze is sprayed twice, dried twice and fired once, and the water in the ceramic blank is reduced by increasing the firing times, so that cracking during high-temperature firing of the ceramic or cracking during the later use process is avoided. The ceramic blank is slowly solidified in a multi-firing mode, so that the shaping effect is good, and the later use stability is good. Simple process and low cost.
Description
Technical Field
The invention relates to the technical field of manufacturing of relief ceramics, in particular to a relief ceramic and a coloring manufacturing method thereof.
Background
The culture of the convex carving ceramic originates from the tangsheng, and the tangsheng, which is the force of the country, affects the world, and the countries make the festival worry, and trade is slowly established.
Because the special process of the relief porcelain appears as a living painting to be displayed in front of a user, the relief porcelain is used as a classical exquisite gift at the time to be a national gift for various countries.
In the modern ceramic production process, ceramic products are more and more diversified, wherein the relief ceramic is gradually applied to the field of daily life products, in order to highlight stereoscopic impression in actual operation, different painting effects are adopted for the relief on the ceramic and the ceramic base color, the common practice is to wrap the relief on the ceramic with gummed paper for re-coloring, the method has the defects of more time and labor consumption compared with the common ceramic, and the method cannot guarantee uniform coloring of the products due to difficult coloring of the corners of the relief, has insufficient later use stability, is easy to crack or fall off ceramic glaze and needs to be repaired again manually.
Disclosure of Invention
The invention aims to solve the technical problems in the prior art, thereby providing a relief ceramic and a coloring manufacturing method thereof.
To this end, an object of the present invention is to provide a relief ceramic comprising:
a ceramic body, the outer surface of which is formed with a relief layer;
the first ceramic glaze layer is sprayed on the outer surfaces of the ceramic body and the relief layer;
the second ceramic glaze layer is sprayed on the outer surface of the first ceramic glaze layer.
Optionally, the relief layer is a relief pattern.
Optionally, the thickness of the first ceramic glaze layer is smaller than that of the second ceramic glaze layer.
Optionally, the relief ceramic further comprises a matching structure arranged on the first ceramic glaze layer and used for combining and fixing the first ceramic glaze layer and the second ceramic glaze layer.
Optionally, the convex carving ceramic is characterized in that the matching structure is a convex point protruding towards the second ceramic glaze layer or a concave hole recessed towards the second ceramic glaze layer and capable of being matched with the convex point.
Another object of the present invention is to provide a method for coloring a relief ceramic, wherein the relief ceramic is any one of the above-mentioned relief ceramics, and the method comprises the following steps:
s1, manufacturing convex carving ceramic: drawing patterns on the outer surface of the ceramic body in a relief manner to obtain relief ceramic;
s2, polishing the surface of the manufactured convex carving ceramic;
s3, cleaning the polished convex carving ceramic surface, and then placing the ceramic surface into an oven for high-temperature drying;
s4, spraying a first ceramic glaze layer on the surface of the dried relief ceramic, and then pre-drying the sprayed relief ceramic in an oven;
s5, spraying a second ceramic glaze layer on the outer surface of the first ceramic glaze layer of the pre-dried embossed ceramic;
and S6, finally, sending the embossed ceramic into a high-temperature kiln for high-temperature firing, and cooling to finish the coloring of the embossed ceramic.
Optionally, in the method for manufacturing the coloring of the relief ceramic, the high-temperature drying temperature in the step S3 is 180-220 ℃ and the time is 20-40 min.
Optionally, in the coloring manufacturing method of the relief ceramic, ceramic glaze components of the first ceramic glaze layer and the second ceramic glaze layer in the steps S4 and S5 include, in parts by weight:
20-30 parts of feldspar, 10-20 parts of kaolin, 5-15 parts of quartz, 4-10 parts of dolomite, 10-18 parts of sodium carbonate, 8-20 parts of amethyst, 4-10 parts of ammonium fluosilicate, 3-9 parts of aluminum oxide, 5-15 parts of calcium hydroxide, 3-9 parts of piperonyl butoxide, 2-6 parts of sodium hydroxide, 4-12 parts of bauxite and 6-14 parts of vermiculite powder.
Optionally, in the method for manufacturing the coloring of the embossed ceramic, in step S4, a matching structure is formed on the outer surface of the first ceramic glaze layer.
Optionally, in the method for manufacturing the coloring of the relief ceramic, the high-temperature firing temperature in the step S6 is 800-1000 ℃ and the time is 1-2 h.
The technical scheme of the invention has the following advantages:
1. the relief ceramic of the present invention comprises:
a ceramic body, the outer surface of which is formed with a relief layer;
the first ceramic glaze layer is sprayed on the outer surfaces of the ceramic body and the relief layer;
the second ceramic glaze layer is sprayed on the outer surface of the first ceramic glaze layer.
According to the convex carving ceramic with the structure, through the arrangement of the two ceramic glaze layers, high-temperature drying is carried out after spraying, and through twice firing, the moisture of a porcelain blank is reduced, so that the phenomenon that the porcelain blank cracks when being fired at high temperature when not completely dried is avoided. In addition, the stability of the post-use of the relief ceramic can be improved by firing for multiple times.
2. The embossed ceramic further comprises a matching structure which is arranged on the first ceramic glaze layer and used for combining and fixing the first ceramic glaze layer and the second ceramic glaze layer. Through the setting of cooperation structure, can improve the bonding firmness of first ceramic glaze layer and second ceramic glaze layer. Avoiding the falling of the second ceramic glaze layer in the later use.
3. According to the embossed ceramic, the matching structure is a convex point protruding towards the second ceramic glaze layer or a concave hole recessed towards the second ceramic glaze layer and capable of being matched with the convex point. The matching structure is simple, the molding is facilitated, and the manufacturing cost is low.
4. According to the coloring manufacturing method of the relief ceramic, the ceramic glaze is sprayed twice, dried twice and fired once, and the firing times are increased, so that the moisture in the ceramic blank is reduced, and cracking during high-temperature firing or cracking during the later use process of the ceramic is avoided. The ceramic blank is slowly solidified in a multi-firing mode, so that the shaping effect is good, and the later use stability is good.
5. According to the coloring manufacturing method of the relief ceramic, the high-temperature firing is lower than 1000 ℃, so that the ceramic is prevented from retracting and the risk of cracks is prevented from increasing suddenly. The firing temperature is low to high, and the ceramic glaze and the ceramic body are stable.
6. Compared with the lithium porcelain stone in the prior art, the glaze in the components of the ceramic glaze has lower melting temperature and better transparency. The alumina is made of bauxite (Al 2 O 3 ·3H 2 O) and diaspore. The ceramic glaze overcomes the defect of poor bauxite stability in the prior art, is used for increasing the bauxite stability in the ceramic glaze and prevents chemical equilibrium from developing to the alumina direction. The melting point of the alumina is 2054 ℃, the boiling point of the alumina is 2980 ℃, and the existence of the alumina in the ceramic glaze can also increase the high temperature resistance of the ceramic glaze. Alumina is often used as an adsorbent and can also increase the adsorptivity of ceramic glaze on the porcelain body. The piperonyl butoxide is added into the ceramic glaze, so that the mutual dissolution of organic substances in the ceramic glaze is facilitated, the condition that the organic substances in the ceramic glaze are not dissolved occasionally in the prior art is overcome, and the transparency and uniformity of the ceramic glaze are facilitated. The interlaminar water molecules of the vermiculite powder are burnt at high temperature, the volume is increased by 18-25 times, and the defects of high relative density, hardening and the like of the ceramic glaze in the prior art are overcome. After adding vermiculite powder, it standsThe sense of body and layering are obviously improved.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings that are needed in the description of the embodiments or the prior art will be briefly described, and it is obvious that the drawings in the description below are some embodiments of the present invention, and other drawings can be obtained according to the drawings without inventive effort for a person skilled in the art.
FIG. 1 is a schematic view of the structure of the relief ceramic of the present invention;
FIG. 2 is a schematic structural view of a ceramic glaze layer and mating structure of the relief ceramic of the present invention;
FIG. 3 is a process flow diagram of a method for coloring the embossed ceramic according to the present invention.
Reference numerals illustrate:
1-a ceramic body;
2-a first ceramic glaze layer;
3-a second ceramic glaze layer;
4-mating structure.
Detailed Description
The following description of the embodiments of the present invention will be made apparent and fully in view of the accompanying drawings, in which some, but not all embodiments of the invention are shown. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Example 1
Referring to fig. 1 to 2, the embossed ceramic provided by the present invention includes a ceramic body 1, an embossed layer, a ceramic glaze layer and a matching structure 4. Wherein ceramic body 1 is equipped with the cavity in for having the open-ended ceramic body, more specifically, including porcelain body and porcelain neck, porcelain body diameter is greater than the porcelain neck, and the opening is offered on the porcelain neck, and ceramic body 1 is the throat form structure promptly. The outer surface of the ceramic body 1 is formed with a relief layer (not shown) by a relief process, and in particular, the relief layer is a drawn relief pattern, and the detailed pattern is not described or limited in detail, such as plum blossom, chinese painting, etc. The ceramic glaze layer comprises two layers, namely a first ceramic glaze layer 2 and a second ceramic glaze layer 3, wherein the first ceramic glaze layer 2 is formed on the outer surfaces of the ceramic body 1 and the relief patterns in a spraying mode, and the second ceramic glaze layer 3 is formed on the outer surface of the first ceramic glaze layer 2 in the same spraying mode. The matching structure 4 is arranged on the outer surface of the first ceramic glaze layer 2 and is used for fixing the first ceramic glaze layer 2 and the second ceramic glaze layer 3 in a matching way. Specifically, the matching structure 4 may be a bump protruding toward the second ceramic glaze layer 3 or a concave hole recessed toward the second ceramic glaze layer 3, where the bump and the concave hole are matched. Optionally, the bottom of the ceramic body 1 is provided with an upwardly concave recess. Alternatively, the thickness of the first ceramic glaze layer 2 is identical to the thickness of the second ceramic glaze layer 3 or slightly smaller than the thickness of the second ceramic glaze layer 3. Without being particularly described or defined in detail, one skilled in the art can choose the thickness required for design according to the actual circumstances.
The relief ceramic of this embodiment is manufactured by manufacturing a ceramic body 1, and drawing a desired relief pattern on the outer surface of the ceramic body by a relief process. And polishing the outer surface of the formed relief ceramic. And cleaning the polished convex carving ceramic, and then drying at a high temperature. And (5) after drying, spraying a first ceramic glaze layer 2, and putting the ceramic glaze layer into an oven for pre-drying. Spraying a second ceramic glaze layer 3, firing at high temperature, and cooling to form the required relief ceramic. The high temperature drying temperature is 180-220 ℃ and the time is 20-40 min. The high-temperature firing temperature is 800-1000 ℃ and the high-temperature firing time is 1-2 h. The components of the ceramic glaze layer are not described and limited in detail herein, and can be conventional ceramic glaze or self-made.
Example 2
The present embodiment provides a method for coloring and manufacturing a relief ceramic, where the relief ceramic is the relief ceramic described in embodiment 1, and referring to fig. 3, the method includes the following steps:
s1, manufacturing convex carving ceramic: drawing patterns on the outer surface of the ceramic body in a relief manner to obtain relief ceramic;
s2, polishing the surface of the manufactured convex carving ceramic;
s3, cleaning the polished convex carving ceramic surface, and then placing the ceramic surface into an oven for high-temperature drying;
s4, spraying a first ceramic glaze layer on the surface of the dried relief ceramic, and then pre-drying the sprayed relief ceramic in an oven;
s5, spraying a second ceramic glaze layer on the outer surface of the first ceramic glaze layer of the pre-dried embossed ceramic;
and S6, finally, sending the embossed ceramic into a high-temperature kiln for high-temperature firing, and cooling to finish the coloring of the embossed ceramic.
In step S4, a mating structure is formed on the outer surface of the first ceramic glaze layer.
Wherein, in the step S3, the high-temperature drying temperature is 180 ℃ and the time is 20min.
The ceramic glaze components of the first ceramic glaze layer and the second ceramic glaze layer in the S4 and the S5 comprise the following components in parts by weight:
20 parts of feldspar, 10 parts of kaolin, 5 parts of quartz, 4 parts of dolomite, 10 parts of sodium carbonate, 8 parts of amethyst, 4 parts of ammonium fluosilicate, 3 parts of aluminum oxide, 5 parts of calcium hydroxide, 3 parts of piperonyl butoxide, 2 parts of sodium hydroxide, 4 parts of bauxite and 6 parts of vermiculite powder.
The high-temperature firing temperature in the step S6 is 800 ℃ and the time is 1h.
In the ceramic glaze component, compared with the lithium porcelain stone in the prior art, the glaze has lower melting temperature and better transparency.
The alumina is made of bauxite (Al 2 O 3 ·3H 2 O) and diaspore. The ceramic glaze overcomes the defect of poor bauxite stability in the prior art, is used for increasing the bauxite stability in the ceramic glaze and prevents chemical equilibrium from developing to the alumina direction. The melting point of the alumina is 2054 ℃, the boiling point of the alumina is 2980 ℃, and the existence of the alumina in the ceramic glaze can also increase the high temperature resistance of the ceramic glaze. Alumina is often used as an adsorbent and can also increase the adsorptivity of ceramic glaze on the porcelain body.
The piperonyl butoxide is added into the ceramic glaze, so that the mutual dissolution of organic substances in the ceramic glaze is facilitated, the condition that the organic substances in the ceramic glaze are not dissolved occasionally in the prior art is overcome, and the transparency and uniformity of the ceramic glaze are facilitated.
The interlaminar water molecules of the vermiculite powder are burnt at high temperature, the volume is increased by 18-25 times, and the defects of high relative density, hardening and the like of the ceramic glaze in the prior art are overcome. After the vermiculite powder is added, the stereoscopic impression, the layering sense and the like of the vermiculite powder are obviously improved.
Example 3
The difference from example 2 is that the high temperature drying temperature in step S3 is 220℃and the time is 40min.
The ceramic glaze components of the first ceramic glaze layer and the second ceramic glaze layer in the S4 and the S5 comprise the following components in parts by weight:
30 parts of feldspar, 20 parts of kaolin, 15 parts of quartz, 10 parts of dolomite, 18 parts of sodium carbonate, 20 parts of amethyst, 10 parts of ammonium fluosilicate, 9 parts of aluminum oxide, 15 parts of calcium hydroxide, 9 parts of piperonyl butoxide, 6 parts of sodium hydroxide, 12 parts of bauxite and 14 parts of vermiculite powder.
The high-temperature firing temperature in the step S6 is 1000 ℃ and the time is 2 hours.
Example 4
The difference from example 2 and example 3 is that the high temperature drying temperature in step S3 is 190 ℃ for 25min.
The ceramic glaze components of the first ceramic glaze layer and the second ceramic glaze layer in the S4 and the S5 comprise the following components in parts by weight:
22 parts of feldspar, 12 parts of kaolin, 7 parts of quartz, 6 parts of dolomite, 11 parts of sodium carbonate, 10 parts of enamel fruit, 5 parts of ammonium fluosilicate, 4 parts of aluminum oxide, 7 parts of calcium hydroxide, 4 parts of piperonyl butoxide, 3 parts of sodium hydroxide, 6 parts of bauxite and 7 parts of vermiculite powder.
The high-temperature firing temperature in the step S6 is 850 ℃ and the time is 1h.
Example 5
The difference from example 2, example 3 and example 4 is that the high temperature drying temperature in step S3 is 210 ℃ for 35min.
The ceramic glaze components of the first ceramic glaze layer and the second ceramic glaze layer in the S4 and the S5 comprise the following components in parts by weight:
28 parts of feldspar, 18 parts of kaolin, 13 parts of quartz, 8 parts of dolomite, 15 parts of sodium carbonate, 15 parts of amethyst, 9 parts of ammonium fluosilicate, 8 parts of aluminum oxide, 12 parts of calcium hydroxide, 8 parts of piperonyl butoxide, 5 parts of sodium hydroxide, 10 parts of bauxite and 12 parts of vermiculite powder.
The high-temperature firing temperature in the step S6 is 950 ℃ and the time is 2 hours.
Example 6
The difference from example 2, example 3, example 4 and example 5 is that the high temperature drying temperature in step S3 is 200 ℃ and the time is 30min.
The ceramic glaze components of the first ceramic glaze layer and the second ceramic glaze layer in the S4 and the S5 comprise the following components in parts by weight:
25 parts of feldspar, 15 parts of kaolin, 10 parts of quartz, 7 parts of dolomite, 14 parts of sodium carbonate, 14 parts of amethyst, 7 parts of ammonium fluosilicate, 6 parts of aluminum oxide, 10 parts of calcium hydroxide, 6 parts of piperonyl butoxide, 4 parts of sodium hydroxide, 8 parts of bauxite and 10 parts of vermiculite powder.
The high-temperature firing temperature in the step S6 is 900 ℃ and the time is 1.5h.
Test examples
Functional test data of the relief ceramic prepared by the coloring preparation method of the embodiment of the application are as follows:
the porcelain grade assessment method comprises the following steps: GB/T3532-2009 domestic porcelain;
the glossiness measuring method comprises the following steps: GB/T15614-2015 (method for measuring glossiness of domestic ceramic pigment);
the anti-skid performance evaluation method comprises the following steps: GB/T37798-2019 (evaluation of the anti-skid property grade of ceramic tiles).
Table 1 results of the ceramic Performance test of the examples
From the test data, each index reaches the superior product. The gloss of the glaze fruit and piperonyl butoxide is close to 90 degrees, and the glaze fruit and piperonyl butoxide are the first products of the same class. As the vermiculite powder is added, the three-dimensional effect is enhanced, the fluffiness is increased, the anti-slip performance of the ceramic is improved, the static friction coefficient (dry state) is about 0.55, and the anti-slip grade is about C d The method comprises the steps of carrying out a first treatment on the surface of the The pendulum type slip resistance (wet state) (S rubber) was around 40, and the slip resistance level was about P3, whereby it was seen that the entire slip resistance had reached a moderate level.
The foregoing is only a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art, who is within the scope of the present invention, should make equivalent substitutions or modifications according to the technical scheme of the present invention and the inventive concept thereof, and should be covered by the scope of the present invention.
Claims (5)
1. A relief ceramic, comprising:
a ceramic body (1) with an embossed layer formed on the outer surface thereof;
the first ceramic glaze layer (2) is sprayed on the outer surfaces of the ceramic body (1) and the relief layer;
the second ceramic glaze layer (3) is sprayed on the outer surface of the first ceramic glaze layer (2);
the matching structure (4) is arranged on the outer surface of the first ceramic glaze layer (2) and is suitable for fixing the first ceramic glaze layer (2) and the second ceramic glaze layer (3), and the matching structure (4) is a convex point protruding towards the second ceramic glaze layer (3) or a concave hole recessed towards the second ceramic glaze layer (3) and capable of being matched with the convex point;
wherein, the ceramic glaze components of the first ceramic glaze layer and the second ceramic glaze layer comprise the following components in parts by weight: 20-30 parts of feldspar, 10-20 parts of kaolin, 5-15 parts of quartz, 4-10 parts of dolomite, 10-18 parts of sodium carbonate, 8-20 parts of amethyst, 4-10 parts of ammonium fluosilicate, 3-9 parts of aluminum oxide, 5-15 parts of calcium hydroxide, 3-9 parts of piperonyl butoxide, 2-6 parts of sodium hydroxide, 4-12 parts of bauxite and 6-14 parts of vermiculite powder;
the coloring manufacturing method of the relief ceramic comprises the following steps:
s1, manufacturing convex carving ceramic: drawing patterns on the outer surface of the ceramic body in a relief manner to obtain relief ceramic;
s2, polishing the surface of the manufactured convex carving ceramic;
s3, cleaning the polished convex carving ceramic surface, and then placing the ceramic surface into an oven for high-temperature drying;
s4, spraying a first ceramic glaze layer on the surface of the dried relief ceramic, and then pre-drying the sprayed relief ceramic in an oven;
s5, spraying a second ceramic glaze layer on the outer surface of the first ceramic glaze layer of the pre-dried embossed ceramic;
and S6, finally, sending the embossed ceramic into a high-temperature kiln for high-temperature firing, and cooling to finish the coloring of the embossed ceramic.
2. The relief ceramic according to claim 1 wherein said relief layer is a relief pattern.
3. A relief ceramic according to claim 1, characterized in that the thickness of the first ceramic glaze layer (2) is smaller than the second ceramic glaze layer (3).
4. The embossed ceramic according to claim 1, wherein the high temperature drying temperature in step S3 is 180-220 ℃ for 20-40 min.
5. The embossed ceramic according to claim 1, wherein the high temperature firing temperature in step S6 is 800 to 1000 ℃ for 1 to 2 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010647329.2A CN111646821B (en) | 2020-07-07 | 2020-07-07 | Convex carving ceramic and coloring manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010647329.2A CN111646821B (en) | 2020-07-07 | 2020-07-07 | Convex carving ceramic and coloring manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111646821A CN111646821A (en) | 2020-09-11 |
| CN111646821B true CN111646821B (en) | 2023-12-19 |
Family
ID=72345751
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010647329.2A Active CN111646821B (en) | 2020-07-07 | 2020-07-07 | Convex carving ceramic and coloring manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111646821B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112159252B (en) * | 2020-10-10 | 2021-04-06 | 潮州市三华陶瓷实业有限公司 | Preparation method of color wiping pottery with protruding patterns |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0303403A2 (en) * | 1987-08-10 | 1989-02-15 | Inax Corporation | Tile glaze, glazing method, and method of producing tiles |
| CN104355675A (en) * | 2014-10-24 | 2015-02-18 | 青岛拓联信息技术有限公司 | Special ceramic glaze for ceramic |
| CN106045577A (en) * | 2016-05-30 | 2016-10-26 | 泉州阳光创艺陶瓷股份有限公司 | Medium-temperature snowflake glaze ceramic and manufacturing method thereof |
| CN107417304A (en) * | 2017-08-18 | 2017-12-01 | 佛山市东鹏陶瓷有限公司 | A kind of preparation technology of the strong dry granular brick of brick face third dimension |
| CN108863329A (en) * | 2018-08-02 | 2018-11-23 | 德化县如瓷生活文化有限公司 | A kind of hacking ceramic whiteware and preparation method thereof |
| CN109400217A (en) * | 2018-12-12 | 2019-03-01 | 清远市坚瓷陶瓷有限公司 | A kind of finishing impression vitreous brick and preparation method thereof |
| CN110171986A (en) * | 2019-07-01 | 2019-08-27 | 广东易成陶瓷实业有限公司 | A kind of production method of garland ceramics colouring |
| CN110317084A (en) * | 2019-07-05 | 2019-10-11 | 福建省德化县腾艺陶瓷有限公司 | A kind of pearl Air Bubble Glaze ceramics and preparation method thereof |
-
2020
- 2020-07-07 CN CN202010647329.2A patent/CN111646821B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0303403A2 (en) * | 1987-08-10 | 1989-02-15 | Inax Corporation | Tile glaze, glazing method, and method of producing tiles |
| CN104355675A (en) * | 2014-10-24 | 2015-02-18 | 青岛拓联信息技术有限公司 | Special ceramic glaze for ceramic |
| CN106045577A (en) * | 2016-05-30 | 2016-10-26 | 泉州阳光创艺陶瓷股份有限公司 | Medium-temperature snowflake glaze ceramic and manufacturing method thereof |
| CN107417304A (en) * | 2017-08-18 | 2017-12-01 | 佛山市东鹏陶瓷有限公司 | A kind of preparation technology of the strong dry granular brick of brick face third dimension |
| CN108863329A (en) * | 2018-08-02 | 2018-11-23 | 德化县如瓷生活文化有限公司 | A kind of hacking ceramic whiteware and preparation method thereof |
| CN109400217A (en) * | 2018-12-12 | 2019-03-01 | 清远市坚瓷陶瓷有限公司 | A kind of finishing impression vitreous brick and preparation method thereof |
| CN110171986A (en) * | 2019-07-01 | 2019-08-27 | 广东易成陶瓷实业有限公司 | A kind of production method of garland ceramics colouring |
| CN110317084A (en) * | 2019-07-05 | 2019-10-11 | 福建省德化县腾艺陶瓷有限公司 | A kind of pearl Air Bubble Glaze ceramics and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111646821A (en) | 2020-09-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US11001534B2 (en) | Semi-transparent ceramic sheet decorated with ink light-absorbance and preparation method thereof | |
| CN205011655U (en) | Porcelain matter brick with entire body texture and texture | |
| CN107793028B (en) | One-time fired partial glaze relief ceramic product and preparation process thereof | |
| CN107235704B (en) | Manufacturing method of large ball clay underglaze high-temperature double-layer cup | |
| CN102731169A (en) | Fully glazed ceramic chip and preparation method thereof | |
| CN104261897A (en) | Ceramic tile having antiskid effect and manufacturing method thereof | |
| CN104130032B (en) | A kind of manufacture method of glazed tile and products thereof | |
| CN107857475A (en) | A kind of ceramic whiteware glaze | |
| CN111646821B (en) | Convex carving ceramic and coloring manufacturing method thereof | |
| CN105732124B (en) | A kind of production method for the peacock feather line decoration ceramic tile that changes colour | |
| CN110372214A (en) | A kind of imitative pitch fine sand face skid-proof ceramic tile and its manufacturing method | |
| CN109400217A (en) | A kind of finishing impression vitreous brick and preparation method thereof | |
| CN110577415A (en) | ceramic tile with antique surface stone texture effect and manufacturing process thereof | |
| KR100360624B1 (en) | Making method of ceramic plate for building materials and that articles | |
| KR100914496B1 (en) | Ceramic composition containing sandy soil and manufacturing method of punch'ong porcelain using the same | |
| CN107986747A (en) | The aging crack ceramic and its manufacture craft of no glaze decoration | |
| CN110156495A (en) | A kind of glazing process of 3D glaze | |
| CN110963786B (en) | Colored artistic porcelain based on De-white porcelain body and preparation process thereof | |
| CN106431504A (en) | Multi-colored peacock feather grain decoration ceramic tile and preparation method | |
| CN106587619A (en) | Ceramic product with bas-relief patterns and preparing technology | |
| CN202543089U (en) | Glazed ceramic tile with stereoscopic and level impressions | |
| CN105601343A (en) | Production method for color-changing engraved-design archaized brick | |
| CN212315955U (en) | Embossed ceramic | |
| CN103342546A (en) | Production method of ceramic tile | |
| CN106626932A (en) | Once shaped electroplating stained paper, preparation method thereof and ceramic decoration method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |