CN111606702A - 一种高稳定性的硅酸锌定位结晶陶瓷及其制造工艺 - Google Patents

一种高稳定性的硅酸锌定位结晶陶瓷及其制造工艺 Download PDF

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CN111606702A
CN111606702A CN202010348928.4A CN202010348928A CN111606702A CN 111606702 A CN111606702 A CN 111606702A CN 202010348928 A CN202010348928 A CN 202010348928A CN 111606702 A CN111606702 A CN 111606702A
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ceramic
powder
ultraviolet
borax
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陈伟雄
谢建歆
许日勤
潘丹敏
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Chaozhou Ceramic Research Institute
Chaozhou Changchengshijia Ceramics Industry Co ltd
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Chaozhou Ceramic Research Institute
Chaozhou Changchengshijia Ceramics Industry Co ltd
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Abstract

本发明公开了一种高稳定性的硅酸锌定位结晶陶瓷及其制造工艺，陶瓷由氧化锌、钾长石、高岭土、膨润土、低膨胀剂、硼砂、骨瓷粉、氧化锡、硅胶粉、三聚磷酸钠、丙三醇和防紫外线剂组成，其重量份数的组分为：氧化锌30‑80份；钾长石20‑35份；高岭土15‑25份；膨润土4‑10份；低膨胀剂7‑12份；硼砂6‑15份；骨瓷粉3‑10份；氧化锡1‑6份；硅胶粉3‑9份。本发明在原料中添加了氧化锌，可使本陶瓷具有大型扇形纹样，并可得到各种形状、色彩的结晶花纹，提高了陶瓷外形的多样性和美观性，添加的三聚磷酸钠和丙三醇能提高本陶瓷整体的抗菌性，添加的防紫外线剂能提高本陶瓷的防紫外线能力，从而延长了其使用寿命，扩大了其市场竞争力，符合企业自身的利益。

Description

一种高稳定性的硅酸锌定位结晶陶瓷及其制造工艺
技术领域
本发明涉及陶瓷技术领域，具体为一种高稳定性的硅酸锌定位结晶陶瓷及其制造工艺。
背景技术
陶瓷是以天然粘土以及各种天然矿物为主要原料经过粉碎混炼、成型和煅烧制得的材料的各种制品，由于陶瓷是由粘土或含有粘土的混合物经混炼、成形、煅烧而制成，所以其整体稳定性较高，在高温和低温环境下不容易开裂，但现有的陶瓷其杀菌、防紫外线等能力较差，从而限制了其使用范围，为此，我们提出一种高稳定性的硅酸锌定位结晶陶瓷。
发明内容
本发明的目的在于提供一种高稳定性的硅酸锌定位结晶陶瓷及其制造工艺，以解决上述背景技术中提出的问题。
为实现上述目的，本发明提供如下技术方案：一种高稳定性的硅酸锌定位结晶陶瓷，陶瓷由氧化锌、钾长石、高岭土、膨润土、低膨胀剂、硼砂、骨瓷粉、氧化锡、硅胶粉、三聚磷酸钠、丙三醇和防紫外线剂组成，其重量份数的组分为：氧化锌30-80份；钾长石20-35份；高岭土15-25份；膨润土4-10份；低膨胀剂7-12份；硼砂6-15份；骨瓷粉3-10份；氧化锡1-6份；硅胶粉3-9份；三聚磷酸钠1-4份；丙三醇2-7份；防紫外线剂2-8份。
优选的，所述陶瓷由氧化锌、钾长石、高岭土、膨润土、低膨胀剂、硼砂、骨瓷粉、氧化锡、硅胶粉、三聚磷酸钠、丙三醇和防紫外线剂组成，其重量份数的组分为：氧化锌40-70份；钾长石25-30份；高岭土18-22份；膨润土6-8份；低膨胀剂9-11份；硼砂8-14份；骨瓷粉5-7份；氧化锡2-5份；硅胶粉5-7份；三聚磷酸钠2-3份；丙三醇4-5份；防紫外线剂4-6份。
优选的，所述陶瓷由氧化锌、钾长石、高岭土、膨润土、低膨胀剂、硼砂、骨瓷粉、氧化锡、硅胶粉、三聚磷酸钠、丙三醇和防紫外线剂组成，其重量份数的组分为：氧化锌55份；钾长石28份；高岭土20份；膨润土7份；低膨胀剂10份；硼砂12份；骨瓷粉6份；氧化锡4份；硅胶粉6份；三聚磷酸钠3份；丙三醇4份；防紫外线剂5份。
优选的，所述防紫外线剂由邻苯二甲酸二丁酯、壬基酚聚氧乙烯醚、银粉、二甲基乙酰胺、羟乙基纤维素、丙烯酸树脂、氟烯烃和二氧化钛组成，其重量份数的组分为：邻苯二甲酸二丁酯10-20份；壬基酚聚氧乙烯醚10-15份；银粉5-15份；二甲基乙酰胺3-10份；羟乙基纤维素5-15份；丙烯酸树脂30-50份；氟烯烃20-40份；二氧化钛10-15份。
一种高稳定性的硅酸锌定位结晶陶瓷的制造工艺，其制造工艺包括以下步骤：
A、将氧化锌、钾长石、高岭土、膨润土、硼砂、骨瓷粉、氧化锡、硅胶粉和三聚磷酸钠分别放入球磨机中进行球磨处理，且球磨粒径为100-200目；
B、将球磨后的钾长石、高岭土、膨润土、硼砂和骨瓷粉按重量份数投入马弗炉中煅烧30-45min，且温度为700-800℃；
C、将低膨胀剂、丙三醇和防紫外线剂以及球磨后的氧化锌、氧化锡、硅胶粉和三聚磷酸钠按重量份数投入马弗炉中煅烧20-30min，且温度为1200-1350℃，得到熔融料；
D、将熔融料倒入模具中，成型后脱模，得到坯料；
E、将坯料放入真空烧结炉中煅烧40-80min，且温度为1700-2000℃，同时，真空烧结炉中所填充的气体为氮气。
与现有技术相比，本发明的有益效果如下：
本发明在原料中添加了氧化锌，可使本陶瓷具有大型扇形纹样，并可得到各种形状、色彩的结晶花纹，提高了陶瓷外形的多样性和美观性，添加的三聚磷酸钠和丙三醇能提高本陶瓷整体的抗菌性，添加的防紫外线剂能提高本陶瓷的防紫外线能力，从而延长了其使用寿命，扩大了其市场竞争力，符合企业自身的利益。
具体实施方式
下面将结合本发明的实施例，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例一：
一种高稳定性的硅酸锌定位结晶陶瓷，陶瓷由氧化锌、钾长石、高岭土、膨润土、低膨胀剂、硼砂、骨瓷粉、氧化锡、硅胶粉、三聚磷酸钠、丙三醇和防紫外线剂组成，其重量份数的组分为：氧化锌30-80份；钾长石20-35份；高岭土15-25份；膨润土4-10份；低膨胀剂7-12份；硼砂6-15份；骨瓷粉3-10份；氧化锡1-6份；硅胶粉3-9份；三聚磷酸钠1-4份；丙三醇2-7份；防紫外线剂2-8份。
在原料中添加了氧化锌，可使本陶瓷具有大型扇形纹样，并可得到各种形状、色彩的结晶花纹，提高了陶瓷外形的多样性和美观性，添加的三聚磷酸钠和丙三醇能提高本陶瓷整体的抗菌性，添加的防紫外线剂能提高本陶瓷的防紫外线能力，从而延长了其使用寿命，扩大了其市场竞争力，符合企业自身的利益。
防紫外线剂由邻苯二甲酸二丁酯、壬基酚聚氧乙烯醚、银粉、二甲基乙酰胺、羟乙基纤维素、丙烯酸树脂、氟烯烃和二氧化钛组成，其重量份数的组分为：邻苯二甲酸二丁酯10份；壬基酚聚氧乙烯醚10份；银粉5份；二甲基乙酰胺3份；羟乙基纤维素5份；丙烯酸树脂30份；氟烯烃20份；二氧化钛10份。
一种高稳定性的硅酸锌定位结晶陶瓷的制造工艺，其制造工艺包括以下步骤：
A、将氧化锌、钾长石、高岭土、膨润土、硼砂、骨瓷粉、氧化锡、硅胶粉和三聚磷酸钠分别放入球磨机中进行球磨处理，且球磨粒径为100目；
B、将球磨后的钾长石、高岭土、膨润土、硼砂和骨瓷粉按重量份数投入马弗炉中煅烧30min，且温度为800℃；
C、将低膨胀剂、丙三醇和防紫外线剂以及球磨后的氧化锌、氧化锡、硅胶粉和三聚磷酸钠按重量份数投入马弗炉中煅烧20min，且温度为1350℃，得到熔融料；
D、将熔融料倒入模具中，成型后脱模，得到坯料；
E、将坯料放入真空烧结炉中煅烧40min，且温度为2000℃，同时，真空烧结炉中所填充的气体为氮气。
实施例二：
一种高稳定性的硅酸锌定位结晶陶瓷，陶瓷由氧化锌、钾长石、高岭土、膨润土、低膨胀剂、硼砂、骨瓷粉、氧化锡、硅胶粉、三聚磷酸钠、丙三醇和防紫外线剂组成，其重量份数的组分为：氧化锌40-70份；钾长石25-30份；高岭土18-22份；膨润土6-8份；低膨胀剂9-11份；硼砂8-14份；骨瓷粉5-7份；氧化锡2-5份；硅胶粉5-7份；三聚磷酸钠2-3份；丙三醇4-5份；防紫外线剂4-6份。
在原料中添加了氧化锌，可使本陶瓷具有大型扇形纹样，并可得到各种形状、色彩的结晶花纹，提高了陶瓷外形的多样性和美观性，添加的三聚磷酸钠和丙三醇能提高本陶瓷整体的抗菌性，添加的防紫外线剂能提高本陶瓷的防紫外线能力，从而延长了其使用寿命，扩大了其市场竞争力，符合企业自身的利益。
防紫外线剂由邻苯二甲酸二丁酯、壬基酚聚氧乙烯醚、银粉、二甲基乙酰胺、羟乙基纤维素、丙烯酸树脂、氟烯烃和二氧化钛组成，其重量份数的组分为：邻苯二甲酸二丁酯15份；壬基酚聚氧乙烯醚12份；银粉10份；二甲基乙酰胺7份；羟乙基纤维素10份；丙烯酸树脂40份；氟烯烃30份；二氧化钛13份。
一种高稳定性的硅酸锌定位结晶陶瓷的制造工艺，其制造工艺包括以下步骤：
A、将氧化锌、钾长石、高岭土、膨润土、硼砂、骨瓷粉、氧化锡、硅胶粉和三聚磷酸钠分别放入球磨机中进行球磨处理，且球磨粒径为150目；
B、将球磨后的钾长石、高岭土、膨润土、硼砂和骨瓷粉按重量份数投入马弗炉中煅烧37min，且温度为750℃；
C、将低膨胀剂、丙三醇和防紫外线剂以及球磨后的氧化锌、氧化锡、硅胶粉和三聚磷酸钠按重量份数投入马弗炉中煅烧25min，且温度为1280℃，得到熔融料；
D、将熔融料倒入模具中，成型后脱模，得到坯料；
E、将坯料放入真空烧结炉中煅烧60min，且温度为1850℃，同时，真空烧结炉中所填充的气体为氮气。
实施例三：
一种高稳定性的硅酸锌定位结晶陶瓷，陶瓷由氧化锌、钾长石、高岭土、膨润土、低膨胀剂、硼砂、骨瓷粉、氧化锡、硅胶粉、三聚磷酸钠、丙三醇和防紫外线剂组成，其重量份数的组分为：氧化锌55份；钾长石28份；高岭土20份；膨润土7份；低膨胀剂10份；硼砂12份；骨瓷粉6份；氧化锡4份；硅胶粉6份；三聚磷酸钠3份；丙三醇4份；防紫外线剂5份。
在原料中添加了氧化锌，可使本陶瓷具有大型扇形纹样，并可得到各种形状、色彩的结晶花纹，提高了陶瓷外形的多样性和美观性，添加的三聚磷酸钠和丙三醇能提高本陶瓷整体的抗菌性，添加的防紫外线剂能提高本陶瓷的防紫外线能力，从而延长了其使用寿命，扩大了其市场竞争力，符合企业自身的利益。
防紫外线剂由邻苯二甲酸二丁酯、壬基酚聚氧乙烯醚、银粉、二甲基乙酰胺、羟乙基纤维素、丙烯酸树脂、氟烯烃和二氧化钛组成，其重量份数的组分为：邻苯二甲酸二丁酯20份；壬基酚聚氧乙烯醚15份；银粉15份；二甲基乙酰胺10份；羟乙基纤维素15份；丙烯酸树脂50份；氟烯烃40份；二氧化钛15份。
一种高稳定性的硅酸锌定位结晶陶瓷的制造工艺，其制造工艺包括以下步骤：
A、将氧化锌、钾长石、高岭土、膨润土、硼砂、骨瓷粉、氧化锡、硅胶粉和三聚磷酸钠分别放入球磨机中进行球磨处理，且球磨粒径为200目；
B、将球磨后的钾长石、高岭土、膨润土、硼砂和骨瓷粉按重量份数投入马弗炉中煅烧45min，且温度为700℃；
C、将低膨胀剂、丙三醇和防紫外线剂以及球磨后的氧化锌、氧化锡、硅胶粉和三聚磷酸钠按重量份数投入马弗炉中煅烧30min，且温度为1200℃，得到熔融料；
D、将熔融料倒入模具中，成型后脱模，得到坯料；
E、将坯料放入真空烧结炉中煅烧80min，且温度为1700℃，同时，真空烧结炉中所填充的气体为氮气。
尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限定。

Claims (5)

1.一种高稳定性的硅酸锌定位结晶陶瓷，其特征在于：陶瓷由氧化锌、钾长石、高岭土、膨润土、低膨胀剂、硼砂、骨瓷粉、氧化锡、硅胶粉、三聚磷酸钠、丙三醇和防紫外线剂组成，其重量份数的组分为：氧化锌30-80份；钾长石20-35份；高岭土15-25份；膨润土4-10份；低膨胀剂7-12份；硼砂6-15份；骨瓷粉3-10份；氧化锡1-6份；硅胶粉3-9份；三聚磷酸钠1-4份；丙三醇2-7份；防紫外线剂2-8份。
2.根据权利要求1所述的一种高稳定性的硅酸锌定位结晶陶瓷，其特征在于：所述陶瓷由氧化锌、钾长石、高岭土、膨润土、低膨胀剂、硼砂、骨瓷粉、氧化锡、硅胶粉、三聚磷酸钠、丙三醇和防紫外线剂组成，其重量份数的组分为：氧化锌40-70份；钾长石25-30份；高岭土18-22份；膨润土6-8份；低膨胀剂9-11份；硼砂8-14份；骨瓷粉5-7份；氧化锡2-5份；硅胶粉5-7份；三聚磷酸钠2-3份；丙三醇4-5份；防紫外线剂4-6份。
3.根据权利要求1所述的一种高稳定性的硅酸锌定位结晶陶瓷，其特征在于：所述陶瓷由氧化锌、钾长石、高岭土、膨润土、低膨胀剂、硼砂、骨瓷粉、氧化锡、硅胶粉、三聚磷酸钠、丙三醇和防紫外线剂组成，其重量份数的组分为：氧化锌55份；钾长石28份；高岭土20份；膨润土7份；低膨胀剂10份；硼砂12份；骨瓷粉6份；氧化锡4份；硅胶粉6份；三聚磷酸钠3份；丙三醇4份；防紫外线剂5份。
4.根据权利要求1所述的一种高稳定性的硅酸锌定位结晶陶瓷，其特征在于：所述防紫外线剂由邻苯二甲酸二丁酯、壬基酚聚氧乙烯醚、银粉、二甲基乙酰胺、羟乙基纤维素、丙烯酸树脂、氟烯烃和二氧化钛组成，其重量份数的组分为：邻苯二甲酸二丁酯10-20份；壬基酚聚氧乙烯醚10-15份；银粉5-15份；二甲基乙酰胺3-10份；羟乙基纤维素5-15份；丙烯酸树脂30-50份；氟烯烃20-40份；二氧化钛10-15份。
5.一种高稳定性的硅酸锌定位结晶陶瓷的制造工艺，其特征在于：其制造工艺包括以下步骤：
A、将氧化锌、钾长石、高岭土、膨润土、硼砂、骨瓷粉、氧化锡、硅胶粉和三聚磷酸钠分别放入球磨机中进行球磨处理，且球磨粒径为100-200目；
B、将球磨后的钾长石、高岭土、膨润土、硼砂和骨瓷粉按重量份数投入马弗炉中煅烧30-45min，且温度为700-800℃；
C、将低膨胀剂、丙三醇和防紫外线剂以及球磨后的氧化锌、氧化锡、硅胶粉和三聚磷酸钠按重量份数投入马弗炉中煅烧20-30min，且温度为1200-1350℃，得到熔融料；
D、将熔融料倒入模具中，成型后脱模，得到坯料；
E、将坯料放入真空烧结炉中煅烧40-80min，且温度为1700-2000℃，同时，真空烧结炉中所填充的气体为氮气。
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