CN111587265B - 用于smc模塑的热塑性复合材料的应用的液体组合物 - Google Patents

用于smc模塑的热塑性复合材料的应用的液体组合物 Download PDF

Info

Publication number
CN111587265B
CN111587265B CN201880087081.XA CN201880087081A CN111587265B CN 111587265 B CN111587265 B CN 111587265B CN 201880087081 A CN201880087081 A CN 201880087081A CN 111587265 B CN111587265 B CN 111587265B
Authority
CN
China
Prior art keywords
meth
acrylic
material according
weight
fibrous material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201880087081.XA
Other languages
English (en)
Chinese (zh)
Other versions
CN111587265A (zh
Inventor
P.热拉尔
G.克莱达
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France SA filed Critical Arkema France SA
Publication of CN111587265A publication Critical patent/CN111587265A/zh
Application granted granted Critical
Publication of CN111587265B publication Critical patent/CN111587265B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
    • C08J2333/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/222—Magnesia, i.e. magnesium oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Reinforced Plastic Materials (AREA)
  • Polymerisation Methods In General (AREA)
  • Moulding By Coating Moulds (AREA)
CN201880087081.XA 2017-11-21 2018-11-21 用于smc模塑的热塑性复合材料的应用的液体组合物 Active CN111587265B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1761024 2017-11-21
FR1761024A FR3073855B1 (fr) 2017-11-21 2017-11-21 Composition liquide adaptee a des applications de composites thermoplastiques moulees a base de smc
PCT/FR2018/052943 WO2019102145A1 (fr) 2017-11-21 2018-11-21 Composition liquide adaptee a des applications de composites thermoplastiques moulees a base de smc

Publications (2)

Publication Number Publication Date
CN111587265A CN111587265A (zh) 2020-08-25
CN111587265B true CN111587265B (zh) 2023-12-22

Family

ID=61599327

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201880087081.XA Active CN111587265B (zh) 2017-11-21 2018-11-21 用于smc模塑的热塑性复合材料的应用的液体组合物

Country Status (10)

Country Link
US (2) US11807703B2 (https=)
EP (1) EP3713976A1 (https=)
JP (2) JP2021504506A (https=)
KR (2) KR20200079329A (https=)
CN (1) CN111587265B (https=)
BR (1) BR112020009810A2 (https=)
CA (1) CA3082482A1 (https=)
FR (1) FR3073855B1 (https=)
MX (1) MX2020004964A (https=)
WO (1) WO2019102145A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3082845B1 (fr) * 2018-06-21 2021-01-15 Arkema France Composition liquide comprenant trois initiateurs, son procede de polymerisation, son utilisation et materiau obtenu apres polymerisation de la composition
CN112644041A (zh) * 2019-10-12 2021-04-13 西安新三力汽车零部件有限公司 一种适合石墨烯分散的合成方法
CN118406335A (zh) * 2023-01-28 2024-07-30 慈溪七诺新材料科技有限公司 一种阻燃型连续纤维增强丙烯酸类热塑性纳米复合材料及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0967495A (ja) * 1995-06-21 1997-03-11 Nippon Shokubai Co Ltd （メタ）アクリル系成形材料およびその製造方法
CN1894355A (zh) * 2003-12-18 2007-01-10 日本瑞翁株式会社 导热性压敏粘合剂组合物、导热性发泡片状模塑件及其制造方法
CN102177206A (zh) * 2008-10-08 2011-09-07 乐金华奥斯株式会社 树脂浆、含有硬化形式的树脂浆的人造大理石及其制造方法
CN105377972A (zh) * 2013-03-11 2016-03-02 阿肯马法国公司 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍纤维基材的方法、在聚合预浸渍基材后获得的复合材料

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR0185028B1 (ko) * 1995-06-21 1999-05-15 아이다 겐지 (메트)아크릴계 성형재료 및 그의 제조방법
JP3685857B2 (ja) * 1996-01-11 2005-08-24 株式会社日本触媒 樹脂組成物の製造方法
JP2001009829A (ja) * 1999-07-02 2001-01-16 Nippon Shokubai Co Ltd （メタ）アクリル系成形材料の製造方法
FR2981652B1 (fr) 2011-10-21 2015-03-27 Arkema France Composites via la polymerisation in-situ de resines thermoplastiques methacryliques
FR2993581B1 (fr) 2012-07-18 2016-01-22 Arkema France Procede d'impregnation pour un substrat fibreux, sirop (meth)acrylique liquide pour le procede d'impregnation, son procede de polymerisation et produit structure obtenu a partir de celui-ci
FR3002941B1 (fr) * 2013-03-08 2015-04-10 Arkema France Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne
FR3002940B1 (fr) 2013-03-08 2016-01-22 Arkema France Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux et son procede de fabrication, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne.

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0967495A (ja) * 1995-06-21 1997-03-11 Nippon Shokubai Co Ltd （メタ）アクリル系成形材料およびその製造方法
CN1894355A (zh) * 2003-12-18 2007-01-10 日本瑞翁株式会社 导热性压敏粘合剂组合物、导热性发泡片状模塑件及其制造方法
CN102177206A (zh) * 2008-10-08 2011-09-07 乐金华奥斯株式会社 树脂浆、含有硬化形式的树脂浆的人造大理石及其制造方法
CN105377972A (zh) * 2013-03-11 2016-03-02 阿肯马法国公司 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍纤维基材的方法、在聚合预浸渍基材后获得的复合材料

Also Published As

Publication number Publication date
US12187831B2 (en) 2025-01-07
KR20250057948A (ko) 2025-04-29
US20240076433A1 (en) 2024-03-07
KR20200079329A (ko) 2020-07-02
WO2019102145A1 (fr) 2019-05-31
BR112020009810A2 (pt) 2020-11-03
US20200317843A1 (en) 2020-10-08
CN111587265A (zh) 2020-08-25
MX2020004964A (es) 2020-08-27
JP2024038050A (ja) 2024-03-19
FR3073855A1 (fr) 2019-05-24
JP2021504506A (ja) 2021-02-15
FR3073855B1 (fr) 2020-12-18
CA3082482A1 (fr) 2019-05-31
EP3713976A1 (fr) 2020-09-30
US11807703B2 (en) 2023-11-07

Similar Documents

Publication Publication Date Title
CN110088388B (zh) 包含两种引发剂的液体组合物、其聚合方法、用途以及在组合物聚合后获得的材料或组合物
US12187831B2 (en) Liquid composition for applications of SMC-moulded thermoplastic composites
KR20140080503A (ko) 열가소성 (메트) 아크릴 수지의 제자리 중합을 통한 복합 물질 및 그 용도
KR102495651B1 (ko) 액체 (메트)아크릴 시럽, 상기 시럽으로의 섬유 기재의 함침 방법 및 상기 함침 시럽의 중합 후 제조된 복합 재료
CN115636905A (zh) 液体(甲基)丙烯酸系浆液，用上述浆液印刷纤维基材的方法，和获得的复合材料
CN112805318A (zh) 用于复合材料的(甲基)丙烯酸系聚合物组合物、其制备方法和用途
KR102832929B1 (ko) 아크릴 열가소성 복합재용 전구체 조성물 및 이의 제조 방법 및 용도
CN106459433B (zh) 官能纤维基材的浸渍方法、用于浸渍方法的液体单体浆料、其聚合方法和由其获得的结构化制品
CN112585180A (zh) 包含三种引发剂的液体组合物、其聚合方法、用途和在组合物聚合后获得的材料或组合物
CA2971543A1 (en) Method for impregnating a fibrous substrate with a (meth)acrylic mixture, composition of said (meth)acrylic mixture, and composite material produced after polymerisation of said (meth)acrylic mixture
JP2025084749A (ja) ワックス化合物を含む液体組成物、その重合方法、使用および材料、または組成物の重合後に得られる組成物

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant