CN111485435A - Environment-friendly antioxidant bronzing-imitating metal mucilage and preparation method thereof - Google Patents
Environment-friendly antioxidant bronzing-imitating metal mucilage and preparation method thereof Download PDFInfo
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Abstract
The invention relates to the technical field of printing mucilage, and relates to an environment-friendly antioxidant bronzing-imitating metal mucilage which comprises the following components in parts by weight: 25-35 parts of water-based acrylic emulsion; 25-35 parts of a water-based polyurethane emulsion; 10-15 parts of metallic mica powder; 4-10 parts of a thickening agent. Also relates to a preparation method of the environment-friendly antioxidant bronzing-imitating metal mucilage, which comprises the following steps: step (1), adding aqueous acrylic emulsion and aqueous polyurethane resin into a reaction vessel, and stirring for 10-20min to form a premix; and (2) adding metal mica powder into the premix, stirring for 30-50min, adding a thickening agent, stirring for 20-30min, and filtering to obtain the environment-friendly antioxidant bronzing-imitating metal adhesive cement. The invention has the effect that the bronzing-like metal mucilage is less prone to being oxidized and is beneficial to better maintaining the metal color.
Description
Technical Field
The invention relates to the technical field of printing adhesive cement, in particular to environment-friendly antioxidant bronzing-imitating metal adhesive cement and a preparation method thereof.
Background
At present, the bronzing-like adhesive cement is a common printing adhesive cement and is firmly attached to a fabric mainly under the action of a medium of gel, so that the attractive effect is achieved.
The existing bronzing-imitating mucilage generally takes acrylic ester copolymer or polyurethane copolymer as a binder, metal powder and other auxiliary agents are added, and the metal luster of the metal powder is utilized to realize the metal-imitating effect of the mucilage.
However, because the oxidation resistance of the metal powder is poor, the metal powder is easily oxidized and discolored or even blackened after being exposed in the air for a long time, so that the mucilage attached to the surface of the fabric easily loses the aesthetic effect, and even the fabric attached with the bronzing-like metal mucilage is difficult to reuse, therefore, there is still room for improvement.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide the environment-friendly antioxidant bronzing-imitating metal adhesive cement.
Aiming at the defects in the prior art, the invention also aims to provide a preparation method of the environment-friendly antioxidant bronzing-like metal adhesive cement.
The above object of the present invention is achieved by the following technical solutions:
the environment-friendly antioxidant bronzing-imitating metal mucilage comprises the following components in parts by mass:
25-35 parts of water-based acrylic emulsion;
25-35 parts of a water-based polyurethane emulsion;
10-15 parts of metallic mica powder;
4-10 parts of a thickening agent.
By adopting the technical scheme, the stability of the mica powder is higher by adopting the metallic mica powder, so that the mica powder is less prone to oxidation, and meanwhile, the metallic luster of the prepared bronzing-imitating metal adhesive cement is less prone to oxidation, the service life of the bronzing-imitating metal adhesive cement is favorably prolonged, and the service life of the fabric printed with the bronzing-imitating metal adhesive cement is favorably prolonged.
By adopting the synergistic cooperation of the aqueous acrylic emulsion and the aqueous polyurethane emulsion, the bonding strength of the prepared bronzing-imitating metal adhesive cement can be better improved, the bronzing-imitating metal adhesive cement can be more easily and firmly attached to a fabric, and the washing fastness and the rubbing fastness of the bronzing-imitating metal adhesive cement are higher.
Meanwhile, the aqueous acrylic emulsion and the aqueous polyurethane emulsion are mutually cooperated, so that the flash degree of the prepared bronzing-simulated metal adhesive cement is favorably and better improved, the covering capacity of the bronzing-simulated metal adhesive cement is more difficult to influence, the bronzing-simulated metal adhesive cement is simultaneously suitable for the fabric with ground color or dark color, the application range of the bronzing-simulated metal adhesive cement is favorably expanded, the printing effect of the bronzing-simulated metal adhesive cement is better, the attractiveness of the fabric is favorably improved, and the fabric printed with the bronzing-simulated metal adhesive cement is more easily popular with consumers.
The thickening agent is added, so that the consistency of the bronzing-imitating metal adhesive cement can be better adjusted, the thixotropic performance of the bronzing-imitating metal adhesive cement can be better improved, the metal mica powder is less prone to precipitation in the bronzing-imitating metal adhesive cement which is placed for a long time, the metal mica powder can be better and uniformly dispersed in the bronzing-imitating metal adhesive cement, the glittering degree of the bronzing-imitating metal adhesive cement is more uniform, and the printing effect of the bronzing-imitating metal adhesive cement can be better improved.
The bronzing-imitating metal mucilage does not contain formaldehyde and other substances which are not environment-friendly, is safe and environment-friendly, and is not easy to influence the environment and the human health.
The present invention in a preferred example may be further configured to: the thickening agent comprises the following components in parts by mass:
1-4 parts of polyurethane thickening and leveling agent;
0.5-2 parts of magnesium aluminum silicate;
2.5-4 parts of alkali swelling acrylic acid associative thickener.
By adopting the technical scheme, the polyurethane thickening and leveling agent, the magnesium aluminum silicate and the alkali swelling acrylic acid associated thickener in a specific proportion are cooperatively matched, so that the consistency of the prepared bronzing-imitating metal adhesive cement is favorably improved, the thixotropic performance of the bronzing-imitating metal adhesive cement is better, metal mica powder is favorably and uniformly dispersed in the bronzing-imitating metal adhesive cement, the flash degree of the prepared bronzing-imitating metal adhesive cement is more uniform, and the printing effect of the bronzing-imitating metal adhesive cement is favorably and better improved.
In addition, the washing fastness and the rubbing fastness of the gilding-imitating metal mucilage can be improved to a certain extent, the service life of the gilding-imitating metal mucilage can be prolonged, the attractiveness of the gilding-imitating metal mucilage is enabled to be less prone to being affected, and the service life of the fabric can be prolonged.
The present invention in a preferred example may be further configured to: the paint also comprises the following components in parts by mass:
1-4 parts of sodium salt dispersant.
By adopting the technical scheme, the sodium salt dispersant is added, so that the metallic mica powder can be better and uniformly dispersed in the bronzing-imitating metal adhesive cement, the flash degree of the prepared metal adhesive cement is more uniform, the printing effect of the bronzing-imitating metal adhesive cement can be better improved, and the fabric obtained by printing the adhesive cement is more attractive and is more easily popular with consumers.
The present invention in a preferred example may be further configured to: the sodium salt dispersing agent comprises one or more of polycarboxylic acid sodium salt dispersing agent, acrylic acid sodium salt dispersing agent, sodium tetraborate, sodium thiosulfate, sodium bicarbonate, sodium silicate, 2- (diethanolamino) sodium ethanesulfonate, sodium caprate and sodium hyaluronate.
By adopting the technical scheme, one or more of the substances are adopted as the sodium salt dispersing agent, so that the dispersing uniformity of the metal mica powder is favorably improved, and the printing effect of the bronzing-imitating metal adhesive cement is not easily influenced.
The present invention in a preferred example may be further configured to: the dispersing agent comprises the following components in parts by mass:
0.5-1 part of 2- (diethanolamino) sodium ethanesulfonate;
0.2-0.5 part of sodium caprate;
0.3-2.5 parts of sodium hyaluronate.
By adopting the technical scheme, the 2- (diethanolamino) sodium ethanesulfonate, the sodium caprate and the sodium hyaluronate which are in specific proportion are matched with each other in a synergistic manner, so that the dispersion uniformity of the metal mica powder is favorably improved, the washing fastness and the friction fastness of the bronzing-like metal adhesive cement are favorably improved, the bronzing-like metal adhesive cement is less prone to being separated from the fabric in the washing process, the service life of the bronzing-like metal adhesive cement is favorably prolonged, the attractiveness of the bronzing-like metal adhesive cement attached to the fabric is less prone to being influenced, and the service life of the fabric is favorably prolonged.
The present invention in a preferred example may be further configured to: the paint also comprises the following components in parts by mass:
0.2-0.8 part of methylisothiazolinone;
0.3-0.7 part of benzisothiazolinone.
By adopting the technical scheme, the methyl isothiazolinone and the styrene-acrylic isothiazolinone in a specific proportion are matched in a synergistic manner, so that the anti-corrosion performance of the bronzing-imitating adhesive cement can be better improved, the bronzing-imitating adhesive cement attached to the fabric is more difficult to corrode, the service life of the bronzing-imitating adhesive cement can be better prolonged, the attractive effect of the bronzing-imitating adhesive cement is more difficult to influence, and the service life of the fabric can be better prolonged.
In addition, the synergistic cooperation of methylisothiazolinone and styrene-acrylic isothiazolinone is beneficial to better improving the washing fastness and the rubbing fastness of the bronzing-like metal mucilage to a certain extent.
The present invention in a preferred example may be further configured to: the paint also comprises the following components in parts by mass:
1-5 parts of 2-amino-2-methyl-1-propanol.
By adopting the technical scheme, the 2-amino-2 methyl-1-propanol is added, so that the stability of the bronzing-imitating metal adhesive cement is favorably and better improved, the aggregation of the metal mica powder is more difficultly caused, the dispersity of the metal mica powder is favorably and better improved, the flash degree of the prepared bronzing-imitating metal adhesive cement is more uniform, the printing effect of the bronzing-imitating metal adhesive cement is favorably and better improved, the overprinting effect of the bronzing-imitating metal adhesive cement is better, and the printing effect of the bronzing-imitating metal adhesive cement is more difficultly influenced by a fabric with a base color or a dark color.
The present invention in a preferred example may be further configured to: the paint also comprises the following components in parts by mass:
1-3 parts of water-based wax emulsion.
By adopting the technical scheme, the anti-sticking performance of the gilding-imitating metal mucilage printed on the fabric can be better enhanced by adding the water-based wax emulsion, and a layer of film can be formed on the surface of the gilding-imitating metal mucilage, so that the adhesion force of the gilding-imitating metal mucilage and the fabric is not easily influenced, and the problem of sticking hands of the gilding-imitating metal mucilage can be better solved; meanwhile, the flexibility of the gilding-imitating metal adhesive cement can be better enhanced, so that the gilding-imitating metal adhesive cement can be deformed along with the fabric more easily after being printed on the fabric, and the situation that the gilding-imitating metal adhesive cement is more difficult to crack is further facilitated.
The present invention in a preferred example may be further configured to: the paint also comprises the following components in parts by mass:
15-20 parts of a humectant;
0.5-2 parts of a defoaming agent.
By adopting the technical scheme, the humectant is added, so that the moisture retention and the lubrication degree of the bronzing-like metal mucilage can be improved better, and the surface printed by the bronzing-like metal mucilage is softer and smoother.
By adding the defoaming agent, the phenomenon of bubbles in the gilding-imitating metal mortar is favorably reduced better, so that the phenomenon of potholes on the surface of the gilding-imitating metal mortar is favorably reduced better, and the attractive effect of the gilding-imitating metal mortar is favorably improved better.
In the invention, the humectant can be one or more of glycerin, butanediol, polyethylene glycol, propylene glycol, hexanediol, xylitol, polypropylene glycol, amino acid, sodium lactate, urea and environment-friendly solvent oil; preferably, the humectant is a mixture of glycerin, propylene glycol and environmentally friendly solvent oil.
In the invention, the defoaming agent can be one or more of non-silicon defoaming agent, organic silicon defoaming agent, polyether defoaming agent and polyether modified organic silicon defoaming agent; preferably, the defoamer is a silicone polyether defoamer.
The second aim of the invention is realized by the following technical scheme:
the preparation method of the environment-friendly antioxidant bronzing-imitating metal mucilage comprises the following steps:
step (1), mixing the aqueous acrylic emulsion and the aqueous polyurethane resin, and stirring for 10-20min to form a premix;
and (2) adding metal mica powder into the premix, stirring for 30-50min, adding a thickening agent, stirring for 20-30min, and filtering to obtain the environment-friendly antioxidant bronzing-imitating metal adhesive cement.
By adopting the technical scheme, the components are favorably and uniformly dispersed mutually better by controlling the adding sequence of the components, so that the components are favorably and cooperatively matched with each other better, the gilding-imitating metal adhesive cement is favorably firmly adhered to the fabric, the evenness of the flash degree of the gilding-imitating metal adhesive cement is favorably and better improved, and the printing effect of the prepared gilding-imitating metal adhesive cement is less likely to be influenced.
In summary, the invention includes at least one of the following beneficial technical effects:
1. by adopting the metallic mica powder, the stability of the mica powder is higher, and the mica powder is not easy to oxidize, so that the metallic luster of the prepared bronzing-imitating metal adhesive cement is not easy to change color or blacken, the service life of the bronzing-imitating metal is favorably prolonged, and the service life of the fabric printed with the bronzing-imitating metal adhesive cement is favorably prolonged to a certain extent;
2. by adopting the synergistic cooperation of the aqueous acrylic emulsion and the aqueous polyurethane emulsion, the bonding strength of the prepared bronzing-imitating metal adhesive cement is favorably improved, so that the bronzing-imitating metal adhesive cement is more easily and firmly attached to a fabric, and the washing fastness and the friction fastness of the bronzing-imitating metal adhesive cement are higher;
3. by utilizing the synergistic cooperation of the aqueous acrylic emulsion and the aqueous polyurethane emulsion, the sparkling degree of the prepared bronzing-imitating metal mucilage is favorably improved, the covering capacity of the bronzing-imitating metal mucilage is more difficult to be influenced, the bronzing-imitating metal mucilage is simultaneously suitable for the fabric with ground color or dark color, the application range of the bronzing-imitating metal mucilage is favorably expanded, the printing effect of the bronzing-imitating metal mucilage is better, the attractiveness of the fabric is favorably improved, and the fabric printed with the bronzing-imitating metal mucilage is more easily welcomed by consumers;
4. the thickening agent is added, so that the consistency of the bronzing-imitating metal adhesive cement can be better adjusted, the thixotropic performance of the bronzing-imitating metal adhesive cement can be better improved, the metal mica powder is less prone to precipitation in the long-standing bronzing-imitating metal adhesive cement, the metal mica powder can be better and uniformly dispersed in the bronzing-imitating metal adhesive cement, the sparkling degree of the bronzing-imitating metal adhesive cement is more uniform, and the printing effect of the bronzing-imitating metal adhesive cement can be better improved;
5. the bronzing-imitating metal mucilage does not contain formaldehyde and other substances which are not environment-friendly, is safe and environment-friendly, and is not easy to influence the environment and the human health.
Drawings
FIG. 1 is a process flow diagram of a preparation method of the environment-friendly antioxidant bronzing-imitating metal mucilage.
Detailed Description
The present invention will be described in further detail with reference to the accompanying drawings.
In the following examples, an aqueous acrylic emulsion having a model number of 2817 was used as the aqueous acrylic emulsion.
In the following examples, 1654 type aqueous polyurethane emulsion from Qingdao Rui scientific materials Co.
In the following examples, the golden mica powder is 70 model mica powder produced by Shijialingwu mineral product trade company Limited.
In the following examples, the silver mica powder was manufactured by the Lingzhou Lingzui mineral processing factory, model 237.
In the following examples, the polyurethane thickening and leveling agent is a polyurethane thickening and leveling agent of 999 model number from Nantong Yongle chemical Co.
In the following examples, the magnesium aluminum silicate used is 88778706 by Jinan Jiabin chemical Limited.
In the following examples, alkali-swellable acrylic acid associative thickeners of type TT-935 from Yachu trade, Guangzhou, Inc. were used.
In the following examples, a sodium polycarboxylate dispersant of 5040, which is a type manufactured by Guangzhou Meicheng New Material science and technology Co., Ltd, was used as the sodium polycarboxylate dispersant.
In the following examples, sodium 2- (diethanolamino) ethanesulfonate is prepared from sodium 2- (diethanolamino) ethanesulfonate of 66992-27-6, available from Hubei Xindeno sanden materials science and technology Co., Ltd.
In the following examples, sodium caprate was obtained from Shanghai leaf Biotech Co., Ltd, having a product number of S30699.
In the following examples, sodium hyaluronate with a product number of 9067-32-7 from Nanjing Sanshu Biotech Co., Ltd was used.
In the following examples, methylisothiazolinone was selected from methylisothiazolinone available from Langtson Biotech Co.Ltd of Zhongshan under the trade name 2682-20-4.
In the following examples, benzisothiazolinone available from Jinan Rongxin Fine chemical Co., Ltd under the product number 3634-33-5 was used.
In the following examples, 2-amino-2-methyl-1-propanol having a product number of 2854-16-2 from Hubei Xinkang pharmaceutical chemical Co., Ltd was used.
In the following examples, an aqueous wax emulsion having a trade name of ENCOR7605 by Jining HuaKai resin Co., Ltd was used as the aqueous wax emulsion.
In the following examples, the polyethylene glycol used was a polyethylene glycol having a product number of 25322-68-3 from Nantong Jiuzzize chemical Co.
In the following examples, glycerol having a product number of 56-81-5 from Junteng chemical Co., Ltd, Jinan province is used as glycerol.
In the following examples, propylene glycol of 57-55-6, a product number of Jiangsu Jiaren chemical Co., Ltd, was used.
In the following examples, the environment-friendly solvent oil is 125487 available from Jinan Xiangtai chemical Limited.
In the following examples, the silicone defoaming agent used was a silicone defoaming agent of HY-2042 available from Beijing Meier chemical technology Co.
In the following examples, a silicone polyether defoaming agent of AT2021, available from Antai Fine chemical Co., Ltd, Dongguan, was used as the silicone polyether defoaming agent.
Example 1
The components and the content of the raw materials of the environment-friendly antioxidant bronzing-imitating metal mucilage are shown in the table 1, and the content unit of each component in the table 1 is kg.
Referring to fig. 1, the preparation method of the environment-friendly antioxidant bronzing-imitating metal cement disclosed by the invention comprises the following steps:
and (1) cleaning a dispersion tank, adding the aqueous acrylic emulsion and the aqueous polyurethane resin into the dispersion tank, stirring at the rotating speed of 1500r/min for 10min, and uniformly mixing and dispersing to form a premix.
And (2) adding the metal mica powder into the premix while stirring, stirring and dispersing for 30min, adding the thickening agent, stirring and dispersing for 20min, and filtering by using a 180-mesh gauze to obtain the environment-friendly antioxidant bronzing-imitating metal adhesive cement.
In this embodiment, the thickener is a polyurethane thickening and leveling agent; the metallic mica powder is golden mica powder.
Example 2
The difference from example 1 is that:
the components and contents of the raw materials are shown in table 1;
the stirring time in the step (1) is 15 min;
adding metal mica powder in the step (2), and stirring for 40 min; adding thickener, and stirring for 25 min; the filtered gauze was 190 mesh.
In the present embodiment, the metallic mica powder is silver mica powder.
Example 3
The difference from example 1 is that:
the components and contents of the raw materials are shown in table 1;
the stirring time in the step (1) is 20 min;
adding metal mica powder in the step (2), and stirring for 50 min; adding thickener, and stirring for 30 min; the gauze was 200 mesh.
In the present embodiment, the metallic mica powder is silver mica powder.
Example 4
The difference from example 1 is that:
the components and contents of the raw materials are shown in table 1;
the stirring time in the step (1) is 17 min;
(2) adding metal mica powder, and stirring for 45 min; adding thickener, and stirring for 26 min; the gauze was 185 mesh.
In the present embodiment, the metallic mica powder is golden mica powder.
TABLE 1
Examples 5 to 15
The difference from example 4 is that: the components and contents of the thickener are shown in table 2, and the unit of the content of each component in table 2 is kg.
TABLE 2
Examples 16 to 31
The components and the contents of the raw materials of the environment-friendly antioxidant bronzing-imitating metal mucilage are shown in a table 3, and the content unit of each component in the table 3 is kg.
The preparation method of the environment-friendly antioxidant bronzing-imitating metal mucilage comprises the following steps:
and (1) cleaning a dispersion tank, adding the aqueous acrylic emulsion and the aqueous polyurethane resin into the dispersion tank, stirring at a rotating speed of 1500r/min, adding the sodium salt dispersing agent while stirring, stirring for 17min, and uniformly mixing and dispersing to form a premix.
And (2) adding the metal mica powder into the premix while stirring, stirring and dispersing for 45min, adding the thickening agent, stirring and dispersing for 26min, and filtering by using a 185-mesh gauze to obtain the environment-friendly antioxidant bronzing-imitating metal adhesive cement.
In the above examples, the thickener is a polyurethane thickening and leveling agent; the metallic mica powder is golden mica powder.
TABLE 3
Examples 32 to 39
The components and the contents of the raw materials of the environment-friendly antioxidant bronzing-imitating metal mucilage are shown in the table 4, and the content unit of each component in the table 4 is kg.
The preparation method of the environment-friendly antioxidant bronzing-imitating metal mucilage comprises the following steps:
and (1) cleaning a dispersion cylinder, adding aqueous acrylic emulsion and aqueous polyurethane resin into the dispersion cylinder, stirring at a rotating speed of 1500r/min, adding methylisothiazolinone and benzisothiazolinone while stirring, stirring for 17min, and uniformly mixing and dispersing to form a premix.
And (2) adding the metal mica powder into the premix while stirring, stirring and dispersing for 45min, adding the thickening agent, stirring and dispersing for 26min, and filtering by using a 185-mesh gauze to obtain the environment-friendly antioxidant bronzing-imitating metal adhesive cement.
In the above examples, the thickener is a polyurethane thickening and leveling agent; the metallic mica powder is golden mica powder.
TABLE 4
Examples 40 to 43
The components and the contents of the raw materials of the environment-friendly antioxidant bronzing-imitating metal mucilage are shown in the table 5, and the content unit of each component in the table 5 is kg.
The preparation method of the environment-friendly antioxidant bronzing-imitating metal mucilage comprises the following steps:
and (1) cleaning a dispersion tank, adding the aqueous acrylic emulsion and the aqueous polyurethane resin into the dispersion tank, stirring at a rotating speed of 1500r/min, adding 2-amino-2-methyl-1-propanol while stirring, stirring for 17min, and uniformly mixing and dispersing to form a premix.
And (2) adding the metal mica powder into the premix while stirring, stirring and dispersing for 45min, adding the thickening agent, stirring and dispersing for 26min, and filtering by using a 185-mesh gauze to obtain the environment-friendly antioxidant bronzing-imitating metal adhesive cement.
In the above examples, the thickener is a polyurethane thickening and leveling agent; the metallic mica powder is golden mica powder.
TABLE 5
Examples 44 to 47
The components and the contents of the raw materials of the environment-friendly antioxidant bronzing-imitating metal mucilage are shown in the table 6, and the content unit of each component in the table 6 is kg.
The preparation method of the environment-friendly antioxidant bronzing-imitating metal mucilage comprises the following steps:
and (1) cleaning a dispersion tank, adding the aqueous acrylic emulsion and the aqueous polyurethane resin into the dispersion tank, stirring at a rotating speed of 1500r/min, adding the aqueous wax emulsion while stirring, stirring for 17min, and uniformly mixing and dispersing to form a premix.
And (2) adding the metal mica powder into the premix while stirring, stirring and dispersing for 45min, adding the thickening agent, stirring and dispersing for 26min, and filtering by using a 185-mesh gauze to obtain the environment-friendly antioxidant bronzing-imitating metal adhesive cement.
In the above examples, the thickener is a polyurethane thickening and leveling agent; the metallic mica powder is golden mica powder.
TABLE 6
Examples 48 to 51
The components and the content of the raw materials of the environment-friendly antioxidant bronzing-imitating metal mucilage are shown in a table 7, and the content unit of each component in the table 7 is kg.
The preparation method of the environment-friendly antioxidant bronzing-imitating metal mucilage comprises the following steps:
and (1) cleaning a dispersion tank, adding the aqueous acrylic emulsion and the aqueous polyurethane resin into the dispersion tank, stirring at a rotating speed of 1500r/min, adding the humectant and the defoamer while stirring, stirring for 17min, and uniformly mixing and dispersing to form a premix.
And (2) adding the metal mica powder into the premix while stirring, stirring and dispersing for 45min, adding the thickening agent, stirring and dispersing for 26min, and filtering by using a 185-mesh gauze to obtain the environment-friendly antioxidant bronzing-imitating metal adhesive cement.
In the above examples, the thickener is a polyurethane thickening and leveling agent; the metal mica powder is golden mica powder; the humectant is a mixture of glycerin, propylene glycol and environment-friendly solvent oil; the defoaming agent is a silicon polyether defoaming agent.
TABLE 7
Examples 52 to 55
The components and the content of the raw materials of the environment-friendly antioxidant bronzing-imitating metal mucilage are shown in the table 8, and the content unit of each component in the table 8 is kg.
The preparation method of the environment-friendly antioxidant bronzing-imitating metal mucilage comprises the following steps:
step (1), cleaning a dispersion cylinder, adding aqueous acrylic emulsion and aqueous polyurethane resin into the dispersion cylinder, stirring at a rotating speed of 1500r/min, sequentially adding a sodium salt dispersing agent, a humectant, 2-amino-2-methyl-1-propanol, a defoaming agent, aqueous wax emulsion, methylisothiazolinone and benzisothiazolinone while stirring, stirring for 17min, and uniformly mixing and dispersing to form a premix.
And (2) adding the metal mica powder into the premix while stirring, stirring and dispersing for 45min, adding the thickening agent, stirring and dispersing for 26min, and filtering by using a 185-mesh gauze to obtain the environment-friendly antioxidant bronzing-imitating metal adhesive cement.
In the above examples, the thickener is a polyurethane thickening and leveling agent; the metal mica powder is golden mica powder; the humectant is a mixture of glycerin, propylene glycol and environment-friendly solvent oil; the defoaming agent is a silicon polyether defoaming agent.
TABLE 8
Comparative examples 1 to 5
The difference from example 4 is that: the components and contents of the raw materials are shown in table 9.
TABLE 9
Experiment 1
The pH values of the bronzing-imitating metal cements prepared in the above examples and comparative examples were measured by a PHS-2C type acidimeter using a two-point calibration method.
Experiment 2
The viscosities (mPa. s) of the bronzing-imitating mortars prepared in the above examples and comparative examples were measured by a rotary viscometer model NDJ-1.
Experiment 3
Firstly, a black cloth fabric is ironed and laid on a printing table, the bronzing-imitating metal mucilage prepared by the above embodiments and comparative examples is adopted, an 800-mesh full-size screen plate is selected, is subjected to scraping printing once, is dried by hot air, is baked for 3min at the high temperature of 150 ℃, and then the printing overprinting capability of the bronzing-imitating metal mucilage prepared by the above embodiments and comparative examples is detected according to GB/T250-2008 'Grey sample card for color change test evaluation of textiles'.
In addition, after drying and forming the bronzing-imitating metal mucilage, placing the bronzing-imitating metal mucilage in an environment with the oxygen concentration of 80% for 2 days, observing the flash degree of the bronzing-imitating metal mucilage printing, randomly selecting 20 volunteers to manually evaluate the grade of the flash degree, and taking the average value of all people's evaluations. Wherein, the grade is 5 grade, 1 grade is that the metallic luster is extremely uneven, and the luster effect is dark; the 2 grade is that the metal luster is relatively uniform and the luster effect is dark; the grade 3 is that the metal luster is completely uniform, and the luster effect is dark; the grade 4 is that the metal luster is relatively uniform and the luster effect is bright; the 5 grade is that the metal luster is completely uniform and the luster effect is bright.
Experiment 4
The washing fastness grade (60 ℃) of the printed patterns of the bronzing-imitating metal mucilage prepared in the above examples and comparative examples is detected as follows:
the principle is as follows: the textile sample is sewed with lining fabric, placed in soap solution, mechanically stirred under the condition of specified time and temperature, washed and dried, and then the color change of the sample and the staining of the lining fabric are evaluated by using a gray card.
And (4) testing standard: ISO 105C 03;
sample preparation, four sides of 4 × 10cm are sewed;
multi-fiber lining: acetate, cotton, nylon, terylene, acrylic fiber and wool;
and (3) testing conditions are as follows: temperature: 60 ℃, sweat content: 1:50, time: and (3) 30 min.
The preparation standards of the reagents are 4 g/L synthetic detergent and 2 g/L anhydrous sodium carbonate.
The method comprises the following operation steps:
the prepared combination sample is placed in a container, and soap solution preheated to a predetermined temperature (bath ratio: 1:50) is injected and treated at a predetermined temperature for a predetermined time.
And taking out the combined sample, washing the combined sample twice by using cold water, then flushing the combined sample in flowing water for 10min, squeezing out water, disassembling the combined sample, connecting the linings of the samples by only one short-edge suture line, and suspending the combined sample in air at 30 ℃ for drying.
The samples were evaluated for change as received (fading) and for the tack of the lining fabric using a grey sample card.
Experiment 5
The rubbing fastness grade of the bronzing-imitating metal mucilage prepared in the above examples and comparative examples is detected by a rubbing fastness tester according to GB3920-1983 method for testing rubbing fastness of textiles.
The data from the above experiments are shown in Table 10.
Watch 10
According to the comparison of the data of the embodiments 4 to 15 in the table 10, the polyurethane thickening and leveling agent, the magnesium aluminum silicate and the alkali swelling acrylic acid associative thickener in a specific proportion are adopted to cooperate with each other, so that the consistency of the bronzing-like metal adhesive cement can be better adjusted, the metallic mica powder can be more easily and uniformly dispersed, the printing flash of the bronzing-like metal adhesive cement can be more uniform, the printing effect of the bronzing-like metal adhesive cement can be better, and the attractiveness of the fabric can be better improved; meanwhile, the washing fastness and the rubbing fastness of the bronzing-imitating metal adhesive cement can be better improved, and the washing fastness and the rubbing fastness of the bronzing-imitating metal adhesive cement are easily influenced due to the lack of any component or the change of any proportion.
According to the comparison of the data of the embodiment 4 and the embodiments 16 to 31 in table 10, the 2- (diethanolamino) sodium ethanesulfonate, the sodium caprate and the sodium hyaluronate are adopted to cooperate with each other in a specific ratio, so that the dispersion uniformity of the metallic color master powder is favorably improved, the printing flash of the bronzing-imitated metal cement is more uniform, the printing effect of the bronzing-imitated metal cement is better, and the printing attractiveness of the bronzing-imitated metal cement is favorably improved; meanwhile, the washing fastness and the rubbing fastness of the bronzing-imitating metal adhesive cement can be better improved, and the washing fastness and the rubbing fastness of the bronzing-imitating metal adhesive cement are easily influenced due to the lack of any component or the change of any proportion.
According to the comparison of the data of the example 4 and the examples 32 to 39 in the table 10, the methyl isothiazolinone and the phenyl isothiazolinone in a specific ratio are adopted to cooperate with each other, so that the washing fastness and the rubbing fastness of the bronzing-like metal mucilage can be improved to a certain extent, the service life of the bronzing-like metal mucilage printing can be prolonged to a certain extent, and the service life of the fabric can be prolonged to a certain extent.
According to the comparison of the data of the embodiment 4 and the embodiments 40 to 43 in the table 10, the 2-amino-2 methyl-1-propanol is added, so that the stability of the bronzing-like metal adhesive paste is improved better, the metallic mica powder is less prone to aggregation, the metallic mica powder is dispersed in the bronzing-like metal adhesive paste more uniformly, the printing flash of the bronzing-like metal adhesive paste is more uniform, and the printing effect of the bronzing-like metal adhesive paste is improved better.
According to the comparison of the data of the example 4 and the comparative examples 1-2 in the table 10, the glittering degree of the metallic color master powder can be better improved only when the aqueous acrylic emulsion and the aqueous polyurethane emulsion are cooperatively matched with each other, so that the printing effect of the bronzing-like metal paste is better, and the bronzing-like metal paste is easy to influence due to the lack of any component.
According to the comparison of the data of the embodiment 4 and the comparative example 3 in the table 10, the addition of the metallic mica powder is beneficial to better improving the oxidation resistance of the bronzing-like metal adhesive cement, so that the printing flash of the bronzing-like metal adhesive cement is more uniform, and the printing effect of the bronzing-like metal adhesive cement is better.
According to the comparison of the data of the embodiment 4 and the comparative examples 4-5 in the table 10, only when the aqueous acrylic emulsion, the aqueous polyurethane emulsion, the metallic mica powder and the thickener are cooperatively matched in a specific ratio, the dispersion effect of the metallic mica powder can be better improved, and meanwhile, the washing fastness and the rubbing fastness of the bronzing-like metal adhesive cement can be better improved.
The embodiments of the present invention are preferred embodiments of the present invention, and the scope of the present invention is not limited by these embodiments, so: all equivalent changes made according to the structure, shape and principle of the invention are covered by the protection scope of the invention.
Claims (10)
1. An environment-friendly antioxidant bronzing-imitating metal adhesive cement is characterized in that: the paint comprises the following components in parts by mass:
25-35 parts of water-based acrylic emulsion;
25-35 parts of a water-based polyurethane emulsion;
10-15 parts of metallic mica powder;
4-10 parts of a thickening agent.
2. The environment-friendly antioxidant bronzing-resistant metal mucilage as recited in claim 1, is characterized in that: the thickening agent comprises the following components in parts by mass:
1-4 parts of polyurethane thickening and leveling agent;
0.5-2 parts of magnesium aluminum silicate;
2.5-4 parts of alkali swelling acrylic acid associative thickener.
3. The environment-friendly antioxidant bronzing-imitating metal cement as claimed in any one of claims 1-2, wherein: the paint also comprises the following components in parts by mass:
1-4 parts of sodium salt dispersant.
4. The environment-friendly antioxidant bronzing-resistant metal mucilage as recited in claim 3, is characterized in that: the sodium salt dispersing agent comprises one or more of polycarboxylic acid sodium salt dispersing agent, acrylic acid sodium salt dispersing agent, sodium tetraborate, sodium thiosulfate, sodium bicarbonate, sodium silicate, 2- (diethanolamino) sodium ethanesulfonate, sodium caprate and sodium hyaluronate.
5. The environment-friendly antioxidant bronzing-resistant metal mucilage as recited in claim 4, is characterized in that: the dispersing agent comprises the following components in parts by mass:
0.5-1 part of 2- (diethanolamino) sodium ethanesulfonate;
0.2-0.5 part of sodium caprate;
0.3-2.5 parts of sodium hyaluronate.
6. The environment-friendly antioxidant bronzing-imitating metal cement as claimed in any one of claims 1-2, wherein: the paint also comprises the following components in parts by mass:
0.2-0.8 part of methylisothiazolinone;
0.3-0.7 part of benzisothiazolinone.
7. The environment-friendly antioxidant bronzing-resistant metal mucilage as recited in claim 6, is characterized in that: the paint also comprises the following components in parts by mass:
1-5 parts of 2-amino-2-methyl-1-propanol.
8. The environment-friendly antioxidant bronzing-imitating metal cement as claimed in any one of claims 1-2, wherein: the paint also comprises the following components in parts by mass:
1-3 parts of water-based wax emulsion.
9. The environment-friendly antioxidant bronzing-imitating metal cement as claimed in any one of claims 1-2, wherein: the paint also comprises the following components in parts by mass:
15-20 parts of a humectant;
0.5-2 parts of a defoaming agent.
10. The preparation method of the environment-friendly antioxidant bronzing-imitating metal mucilage as claimed in claim 1 is characterized in that: the method comprises the following steps:
step (1), mixing the aqueous acrylic emulsion and the aqueous polyurethane resin, and stirring for 10-20min to form a premix;
and (2) adding metal mica powder into the premix, stirring for 30-50min, adding a thickening agent, stirring for 20-30min, and filtering to obtain the environment-friendly antioxidant bronzing-imitating metal adhesive cement.
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