CN107956160A - A kind of luminous print paste and preparation method thereof - Google Patents
A kind of luminous print paste and preparation method thereof Download PDFInfo
- Publication number
- CN107956160A CN107956160A CN201711120365.8A CN201711120365A CN107956160A CN 107956160 A CN107956160 A CN 107956160A CN 201711120365 A CN201711120365 A CN 201711120365A CN 107956160 A CN107956160 A CN 107956160A
- Authority
- CN
- China
- Prior art keywords
- print paste
- aqueous adhesives
- luminous
- rare earth
- luminescent material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/39—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5228—Polyalkenyl alcohols, e.g. PVA
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5285—Polyurethanes; Polyurea; Polyguanides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5292—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds containing Si-atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/67341—Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of luminous print paste, the mass ratio of the component of the print paste is：Rare earth luminescent material 1；Dispersant 0.25~1；Mediator 0.8~3；Initiator 0.1~0.3；Dyestuff≤0.05；Aqueous Adhesives 0.8~2；Thickener 0.1~0.5；Wherein, the rare earth luminescent material includes Sr (NO3)2、Al(NO3)3·9H2O、Eu2O3And Dy2O3In one or more.The characteristics of present invention combines printing in textiles, obtained mill base is applied on textile fabric, the printed fabric containing such a rare earth luminescent material and coated fabric fabric is made, product not only has conventional textile stamp, the appearance of coated fabric and properties, and after illumination, decalcomania or view picture fabric itself can shine in the dark of dull thread.
Description
Technical field
The present invention relates to technical field of textile printing, is specially a kind of luminous print paste and preparation method thereof.
Background technology
With the development of the social economy, style, pattern and style requirement of the people for fabric and clothes becomes constantly
Change and improve, the particularly improvement of people's living standards, life taste has significant increase.Do not required nothing more than for garment material easypro
It is moderately high, and require more special functions.
Luminescent material is divided into two class of emissive type and hair long light type, and the basis of emissive type luminescent material is radioactivity
Material, it is not necessary to absorb energy from outside, no matter night or daytime can continuous illumination, but because contain radioactive material
Matter, does not meet the requirement of environmental protection.Hair long light type luminescent material is zinc sulphide luminescent material, and latest developments are dilute faster
Native aluminate serial luminescent material.Rare earth aluminate luminescent material has fluorescent lifetime length, brightness is high, nontoxic "dead"
And chemical property it is more stable the advantages that, its luminescent properties is substantially better than zinc sulphide.For molecular structure, rare earth element has
Abundant electron energy level, can produce the leap between a variety of energy levels, when radiation of visible light rare earth ion, electronics from ground state or under
The supreme energy level of energy level transition, occurs the absorption of light, luminous energy is stored.When there is no visible ray, electronics energy level transition from excitation state
To lower energy level or ground state, the transmitting of light is produced, the energy of storage is discharged.Energy difference between rare earth ion transition energy level is not
Together, with regard to the light of different colours can be sent, three-primary colours (red, yellow, blue) coloured light is subjected to certain way using photochromic composition principle
Combination, enriches, bright and colourful effect so as to form color and luster.But when rare earth luminescent material is printed on the fabric at present, color is satisfied
There is loss with degree, and easily come off after washing.
The content of the invention
In view of the deficiencies of the prior art, it is an object of the present invention to provide one kind to have good luminous performance, aqueous, environmental protective, adhesion
Property it is strong, cost is low, production method simply shine printing adhesive, solve the problems, such as proposed in the above background technology.
To achieve the above object, the present invention provides following technical solution：
A kind of luminous print paste, the mass ratio of the component of the luminous print paste are：Rare earth luminescent material 1；It is scattered
Agent 0.25~1；Mediator 0.8~3；Initiator 0.1~0.3；Dyestuff≤0.05；Aqueous Adhesives 0.8~2；Thickener 0.1~
0.5；Wherein, the rare earth luminescent material includes Sr (NO3)2、Al(NO3)3·9H2O、Eu2O3And Dy2O3In one or more.
Preferably, the dispersant is selected from synthesis high score subclass, polyvalent carboxylic acid's class, coupling agent class, silicates, described
The pH value of dispersant is 6~7.
Preferably, the mediator is selected from polyurethane polymer or acrylic polymer.
Preferably, the initiator is selected from sodium peroxydisulfate, Ammonium Persulfate 98.5 or acyl anhydride group class.
Preferably, the dyestuff is neutral dye or acidic complex dye.
Preferably, the Aqueous Adhesives are polyvinyl alcohol Aqueous Adhesives, vinyl acetate esters Aqueous Adhesives, third
Olefin(e) acid class Aqueous Adhesives, polyurethanes Aqueous Adhesives, epoxy Aqueous Adhesives, phenolic aldehyde Aqueous Adhesives, organic silicon water
One or more in property adhesive and rubber Aqueous Adhesives.
Preferably, the thickener is polyacrylic compounds thickener.
A kind of preparation method of luminous print paste, comprises the following steps：
A. dispersant, mediator, dyestuff, the integral mill base of uniform stirring are added in rare earth luminescent material；
B. before the production of upper machine, then Aqueous Adhesives and thickener are added in mill base, uniform stirring obtains the hair
Light print paste, so that the luminous print paste slows down the mutual of various composition in slurry in the time that machine produces in wait
Effect, keeps the stabilization of light print paste properties.
Preferably, between 400~700nm, the fiber exists emission spectrum the smooth print paste after light excitation
Receive visible ray or ultraviolet light after 0.5~2 minute, can with continuous illumination 10~15 it is small when.
Compared with prior art, the beneficial effects of the invention are as follows：
1st, with reference to the characteristics of printing in textiles, obtained luminous print paste is applied on textile fabric, is made and contains
There are the printed fabric and coated fabric fabric of such a rare earth luminescent material, product not only has conventional textile stamp, coated fabric
Appearance and properties, and after illumination, decalcomania or view picture fabric itself can shine in the dark of dull thread.
2nd, the luminous print paste of the present invention can keep the due color of the dyestuff under visible light, but in the condition of dull thread
Under, when rare earth luminescent material shines, do not hinder it to shine, it is kept the characteristics of luminescence；Light print paste is after light excitation
Emission spectrum is between 400~700nm, and the fiber is after visible ray or ultraviolet light 0.5~2 minute is received, Ke Yichi
When supervention light 10~15 is small.
3rd, since the present invention selects the characteristic of every material, it is necessary to using the method different from conventional production, so waiting
In the time for treating machine production, the properties of slurry are stablized, and add dispersant in upper machine, make each component in slurry normal
Effect, reaches print, the production purpose of upper painting.
4th, luminous printing slurry and illuminating at night printed fabric items environment monitoring index provided by the present invention is qualified,
Meet environmental protection standard requirement, it is environmentally friendly.
Embodiment
The invention discloses a kind of luminous print paste and preparation method and application.
Embodiment one
A kind of luminous print paste, including following ingredients：
Wherein, the rare earth luminescent material is Sr (NO3)2Rare earth luminescent material, rare earth luminous material described in other embodiments
Material can also be Al (NO3)3·9H2O、Eu2O3And Dy2O3In one or more.
Wherein, the dispersant is high score subclass dispersant, and dispersant described in other embodiments can also be that synthesis is high
Molecule class, polyvalent carboxylic acid's class, coupling agent class, silicates, the pH value of the dispersant is 6~7.
Wherein, the mediator is polyurethane polymer.Mediator described in other embodiments can also be acrylic acid
Esters polymer.
Wherein, the initiator is sodium peroxydisulfate.Initiator described in other embodiments can also be ammonium persulfate or acyl
Anhydride group class.
Wherein, the dyestuff is neutral dye.Dyestuff described in other embodiments can also be acidic complex dye.
Wherein, the Aqueous Adhesives are polyvinyl alcohol Aqueous Adhesives.Aqueous Adhesives described in other embodiments
Can also be water-based for vinyl acetate esters Aqueous Adhesives, acrylic compounds Aqueous Adhesives, polyurethanes Aqueous Adhesives, epoxy
One or more in adhesive, phenolic aldehyde Aqueous Adhesives, organic silicon Aqueous Adhesives and rubber Aqueous Adhesives.
Wherein, the thickener is polyacrylic compounds thickener.
The preparation method of the luminous print paste of the present invention, comprises the following steps：
A. dispersant, mediator, dyestuff, the integral mill base of uniform stirring are added in rare earth luminescent material；
B. before the production of upper machine, then Aqueous Adhesives and thickener are added in mill base, uniform stirring obtains the hair
Light print paste, so that the luminous print paste slows down the mutual of various composition in slurry in the time that machine produces in wait
Effect, keeps the stabilization of luminous print paste properties.Wherein, during specifically used luminous print paste printing, it is kept stirring
State so that used luminous print paste is in a uniform state of system, final to obtain more excellent printing quality.
Embodiment two
A kind of luminous print paste, including following ingredients：
Wherein, the rare earth luminescent material is Sr (NO3)2Rare earth luminescent material.The dispersant disperses for high score subclass
Agent.The mediator is polyurethane polymer.Mediator described in other embodiments can also be acrylic polymer.
The initiator is ammonium persulfate.The dyestuff is acidic complex dye.The Aqueous Adhesives are polyvinyl alcohol water-base cement
Glutinous agent.The thickener is polyacrylic compounds thickener.
The preparation method of the luminous print paste of the present invention, comprises the following steps：
A. dispersant, mediator, dyestuff, the integral mill base of uniform stirring are added in rare earth luminescent material；
B. before the production of upper machine, then Aqueous Adhesives and thickener are added in mill base, uniform stirring obtains the hair
Light print paste, so that the luminous print paste slows down the mutual of various composition in slurry in the time that machine produces in wait
Effect, keeps the stabilization of luminous print paste properties.
Embodiment three
A kind of luminous print paste, including following ingredients：
Wherein, the rare earth luminescent material is Eu2O3 rare earth luminescent materials.The dispersant is silicates dispersant.
The mediator is polyurethane polymer.Mediator described in other embodiments can also be acrylic polymer.Institute
It is ammonium persulfate to state initiator.The dyestuff is acidic complex dye.The Aqueous Adhesives are the water-based gluing of polyvinyl alcohol
Agent.The thickener is polyacrylic compounds thickener.
The preparation method of luminous print paste of the present invention, comprises the following steps：
A. dispersant, mediator, dyestuff, the integral mill base of uniform stirring are added in rare earth luminescent material；
B. before the production of upper machine, then Aqueous Adhesives and thickener are added in mill base, uniform stirring obtains the hair
Light print paste, so that the luminous print paste slows down the mutual of various composition in slurry in the time that machine produces in wait
Effect, keeps the stabilization of luminous print paste properties.
Example IV
A kind of luminous print paste, including following ingredients：
Wherein, the rare earth luminescent material is Eu2O3Rare earth luminescent material.The dispersant is polyvalent carboxylic acid's class.In described
Mediator is acrylic polymer.Mediator described in other embodiments can also be acrylic polymer.It is described to draw
Hair agent is sodium peroxydisulfate.The dyestuff is acidic complex dye.The Aqueous Adhesives are phenolic aldehyde Aqueous Adhesives.The thickening
Agent is polyacrylic compounds thickener.
The preparation method of mill base of the present invention, comprises the following steps：
A. dispersant, mediator, dyestuff, the integral mill base of uniform stirring are added in rare earth luminescent material；
B. before the production of upper machine, then Aqueous Adhesives and thickener are added in mill base, uniform stirring obtains the hair
Light print paste, so that the luminous print paste slows down the mutual of various composition in slurry in the time that machine produces in wait
Effect, keeps the stabilization of luminous print paste properties.
Embodiment five
A kind of luminous print paste, including following ingredients：
Wherein, the rare earth luminescent material is Al (NO3)3·9H2O rare earth luminescent materials.The dispersant is polyvalent carboxylic acid
Class.The mediator is acrylic polymer.Mediator described in other embodiments can also be that esters of acrylic acid polymerize
Thing.The initiator is sodium peroxydisulfate.The dyestuff is acidic complex dye.The Aqueous Adhesives are the water-based gluing of phenolic aldehyde
Agent.The thickener is polyacrylic compounds thickener.
The preparation method of mill base of the present invention, comprises the following steps：
A. dispersant, mediator, dyestuff, the integral mill base of uniform stirring are added in rare earth luminescent material；
B. before the production of upper machine, then Aqueous Adhesives and thickener are added in mill base, uniform stirring obtains the hair
Light print paste, so that the luminous print paste slows down the mutual of various composition in slurry in the time that machine produces in wait
Effect, keeps the stabilization of luminous print paste properties.
Test case
By above-mentioned printing paste by PLATE SCREAM PRINTING mode the stamp on raw material fabric, after stamp at a temperature of 145-155 DEG C
Processing 2.5-3.5 minutes is baked, then carries out tentering soft treatment, luminous PRINTED FABRIC is made.
The raw material fabric is one kind in bleached cotton fabric, stained clot-h and calico.Specifically, the requirement to raw material fabric
It is that the cloth cover finish of bleached cotton fabric will be got well, capillary effect is high, generally in 10cm/30min or so, otherwise can influence illumination effect.Print
Every dye fastness index of figured cloth or stained clot-h will reach normal requirement, especially sublimation reliability and get well, and otherwise bake
When can influence illumination effect.
Luminescent properties test is carried out using the PRINTED FABRIC that shines made from the above method：
Print paste of the present invention can keep the due color of the dyestuff under visible light, but under conditions of dull thread, when
When rare earth luminescent material shines, do not hinder it to shine, it is kept the characteristics of luminescence；Light print paste launches light after light excitation
For spectrum between 400~700nm, the fiber, can be with continuous illumination after visible ray or ultraviolet light 0.5~2 minute is received
10~15 it is small when.
Luminous PRINTED FABRIC is put into washing machine, remains to keep certain luminosity after repeatedly washing.Its reason
Be use luminescent material stamp after, a part of luminescent material, which has been penetrated into fiber, forms stable structure, after washing these
Luminescent material will not fall off.The preparation method of luminous print paste provided by the invention, before the production of upper machine again by mill base with it is water-based
Luminescent material, quickly can uniformly be dispersed into Aqueous Adhesives system, at the same time by adhesive and thickener mixing
The viscous product quality and dispersion effect of luminous concentrator product can be taken into account.
Luminous printing slurry and illuminating at night printed fabric items environment monitoring index provided by the present invention is qualified, full
Sufficient environmental protection standard requirement, it is environmentally friendly.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of changes, modification, replace
And modification, the scope of the present invention is defined by the appended.
Claims (9)
1. a kind of luminous print paste, it is characterised in that the mass ratio of the component of the print paste is：
Rare earth luminescent material 1；
Dispersant 0.25~1；
Mediator 0.8~3；
Initiator 0.1~0.3；
Dyestuff≤0.05；
Aqueous Adhesives 0.8~2；
Thickener 0.1~0.5；
Wherein, the rare earth luminescent material includes Sr (NO3)2、Al(NO3)3·9H2O、Eu2O3And Dy2O3In one or more.
2. luminous print paste according to claim 1, it is characterised in that：The dispersant is selected from synthesis macromolecule
Class, polyvalent carboxylic acid's class, coupling agent class, silicates, the pH value of the dispersant is 6~7.
3. luminous print paste according to claim 1, it is characterised in that：The mediator is selected from polyurethane polymer
Or acrylic polymer.
4. luminous print paste according to claim 1, it is characterised in that：The initiator is selected from sodium peroxydisulfate, over cure
Acid amide or acyl anhydride group class.
5. luminous print paste according to claim 1, it is characterised in that：The dyestuff is neutral dye or acid complexing
Dyestuff.
6. luminous print paste according to claim 1, it is characterised in that：The Aqueous Adhesives are polyvinyl alcohol water
Property adhesive, vinyl acetate esters Aqueous Adhesives, acrylic compounds Aqueous Adhesives, polyurethanes Aqueous Adhesives, epoxy water
One or more in property adhesive, phenolic aldehyde Aqueous Adhesives, organic silicon Aqueous Adhesives and rubber Aqueous Adhesives.
7. luminous print paste according to claim 1, it is characterised in that：The thickener is polyacrylic compounds
Thickener.
The preparation method of print paste 8. claim 1~7 any one of them shines, it is characterised in that comprise the following steps：
A. dispersant, mediator, dyestuff, the integral mill base of uniform stirring are added in rare earth luminescent material；
B. before the production of upper machine, then Aqueous Adhesives and thickener are added in mill base, uniform stirring obtains the luminous print
Pattern is starched, so that mill base slows down the interaction of various composition in slurry in the time that machine produces in wait, keeps light stamp
The stabilization of mill base properties.
9. the preparation method for the print paste that shone according to claim 8 any one of them, it is characterised in that：The smooth stamp color
For emission spectrum between 400~700nm, the fiber is receiving visible ray or ultraviolet light 0.5~2 to slurry after light excitation
Minute after, can with continuous illumination 10~15 it is small when.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711120365.8A CN107956160A (en) | 2017-11-14 | 2017-11-14 | A kind of luminous print paste and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711120365.8A CN107956160A (en) | 2017-11-14 | 2017-11-14 | A kind of luminous print paste and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107956160A true CN107956160A (en) | 2018-04-24 |
Family
ID=61964532
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711120365.8A Pending CN107956160A (en) | 2017-11-14 | 2017-11-14 | A kind of luminous print paste and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107956160A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110820364A (en) * | 2018-07-20 | 2020-02-21 | 宁波凯丽安科技股份有限公司 | Photochromic dye emitting blue light |
| CN114703684A (en) * | 2022-04-12 | 2022-07-05 | 绍兴市柯桥区信和数码纺织技术有限公司 | Printing process of ultrathin fabric |
| CN114960219A (en) * | 2022-06-30 | 2022-08-30 | 厦门安踏体育用品有限公司 | Application of mechanoluminescence material to garment fabric and accessories |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1210171A (en) * | 1998-09-02 | 1999-03-10 | 国营吴江绸缎炼染一厂 | Printing or coating color paste of energy-storage luminous textile fabric and manufacturing process thereof |
| CN102978976A (en) * | 2012-11-20 | 2013-03-20 | 江南大学 | Method for preparing water-based UV (Ultraviolet) pigment printing paste for textile use |
| CN104264503A (en) * | 2014-10-10 | 2015-01-07 | 东莞市橄榄树家具有限公司 | Nano far infrared negative ion pigment printing paste and preparation method thereof |
| CN104695237A (en) * | 2015-02-10 | 2015-06-10 | 海门市明阳实业有限公司 | Print paste for energy storage and light emission type textile fabric as well as manufacturing technology and application of print paste |
-
2017
- 2017-11-14 CN CN201711120365.8A patent/CN107956160A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1210171A (en) * | 1998-09-02 | 1999-03-10 | 国营吴江绸缎炼染一厂 | Printing or coating color paste of energy-storage luminous textile fabric and manufacturing process thereof |
| CN102978976A (en) * | 2012-11-20 | 2013-03-20 | 江南大学 | Method for preparing water-based UV (Ultraviolet) pigment printing paste for textile use |
| CN104264503A (en) * | 2014-10-10 | 2015-01-07 | 东莞市橄榄树家具有限公司 | Nano far infrared negative ion pigment printing paste and preparation method thereof |
| CN104695237A (en) * | 2015-02-10 | 2015-06-10 | 海门市明阳实业有限公司 | Print paste for energy storage and light emission type textile fabric as well as manufacturing technology and application of print paste |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110820364A (en) * | 2018-07-20 | 2020-02-21 | 宁波凯丽安科技股份有限公司 | Photochromic dye emitting blue light |
| CN114703684A (en) * | 2022-04-12 | 2022-07-05 | 绍兴市柯桥区信和数码纺织技术有限公司 | Printing process of ultrathin fabric |
| CN114703684B (en) * | 2022-04-12 | 2024-05-17 | 绍兴市柯桥区信和数码纺织技术有限公司 | Printing technology of ultrathin fabric |
| CN114960219A (en) * | 2022-06-30 | 2022-08-30 | 厦门安踏体育用品有限公司 | Application of mechanoluminescence material to garment fabric and accessories |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Khattab et al. | Smart textile framework: Photochromic and fluorescent cellulosic fabric printed by strontium aluminate pigment | |
| CN103993504B (en) | Application of multifunctional carbon quantum dots as fluorescent whitening agent | |
| CN108468096B (en) | Thermochromic noctilucent fiber and preparation method thereof | |
| CN106243869B (en) | A kind of sand wall-like fluorescent aqueous paint and preparation method | |
| CN107956160A (en) | A kind of luminous print paste and preparation method thereof | |
| EP3174953B1 (en) | Environmentally responsive chromatic luminescent compositions with improved hand | |
| Sayeb et al. | Investigation of photochromic pigment used for smart textile fabric | |
| RU2365318C2 (en) | Special warning clothes, luminescent alarming element and material for its manufacture | |
| CN102041698A (en) | Method for preparing noctilucent printed fabric | |
| CN103397542B (en) | A kind of preparation method of near-infrared camouflage painting fabric | |
| CN1333402A (en) | Method for producing luminous fabric | |
| CN1314855C (en) | Printing discharge dyeing paste for coating material to discharge dye silk broadcloth, and discharge printing technique of extracting activity of coating material | |
| CN110373738A (en) | A kind of preparation method of warm colour light luminescent fibre | |
| CN111118931A (en) | Preparation method of color-changing silk | |
| CN106978641A (en) | RE luminous fiber and preparation method thereof and the yarn fabric based on the luminous fiber | |
| CN104695237A (en) | Print paste for energy storage and light emission type textile fabric as well as manufacturing technology and application of print paste | |
| CN1210171A (en) | Printing or coating color paste of energy-storage luminous textile fabric and manufacturing process thereof | |
| CN103790042A (en) | Comfort pigment printing method of textile | |
| CN106928999A (en) | The preparation method of photochromic adjustable warm colour light long afterglow luminous material | |
| CN105297485A (en) | Printing method by using dye/polymer hollow complex microspheres | |
| CN113123146A (en) | Waterless dyeing preparation method of temperature/ultraviolet light color-changing yarn | |
| CN109295517A (en) | A kind of dope dyeing superelevation strength noctilucence silk and preparation method thereof | |
| CN105040465A (en) | Pigment dyeing liquor for dyeing superfine fibers and method for improving dyeing color depth of superfine fibers | |
| CN105001769A (en) | Preparation method for long-afterglow water-borne alkyd resin coating | |
| CN103614901B (en) | A kind of preparation method of soft type noctilucent coating fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180424 |
|
| RJ01 | Rejection of invention patent application after publication |