CN102041698A - Method for preparing noctilucent printed fabric - Google Patents
Method for preparing noctilucent printed fabric Download PDFInfo
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- CN102041698A CN102041698A CN2009102292662A CN200910229266A CN102041698A CN 102041698 A CN102041698 A CN 102041698A CN 2009102292662 A CN2009102292662 A CN 2009102292662A CN 200910229266 A CN200910229266 A CN 200910229266A CN 102041698 A CN102041698 A CN 102041698A
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Abstract
The invention provides a method for preparing a noctilucent printed fabric, comprising the following steps of: fully mixing golden and silver powder binder with water; then adding a rare earth aluminate luminescent material and fully mixing; then adding a pigment printing thickening agent HIT and fully mixing to obtain printing paste; printing a raw material fabric in a plate screan printing mode by using the printing paste, and then baking; and carrying out tentering softening treatment to prepare the noctilucent printed fabric. The noctilucent printed fabric prepared with the method is suitable for manufacturing decorations and children products. The adopted noctilucent material is a rare-earth activated aluminate luminescent material and has a stable crystal structure; and for the luminescence performance, the processes of light absorption, energy storage and luminescence can be permanently kept on the premise that the crystal structure is not damaged. The material does not contain any radioactive element and has the characteristics of rapidness of light absorption, high start brightness, long afterglow time, safety, practicability and the like.
Description
Technical field
The invention provides a kind of preparation method of PRINTED FABRIC, especially a kind of luminous printing process for making such fabric.
Background of invention
Ancient Times in China just has " noctilucence wall " and " legendary luminous pearl ", and this some shiner that is occurring in nature exists forms; Since rare, so become human world jewellery.And modern age along with science and technology development, can manually make similar shiner, promptly photoluminescent body also is Noctilucent material.This material can send versicolor light in no luminous environment, it is applied in can be luminous at the dark place after penetrated by illumination, but luminous the certain hour restriction is arranged, and the luminous lasting time is called twilight sunset.
Noctilucent material is divided into emissive type and holds light emitting-type two classes; the basis of emissive type Noctilucent material is radioactive material, does not need to absorb from the outside energy, no matter night or daytime can continue luminous; but, do not meet requirement on environmental protection because contain radioactive substance.Holding the light emitting-type Noctilucent material is the zinc sulphide luminescent material, and latest developments rare earth aluminate series luminescent material faster.Advantages such as the rare earth aluminate luminescent material has that fluorescent lifetime is long, brightness is high, nontoxic "dead" and chemical property is stable, its luminescent properties obviously is better than zinc sulphide.With regard to molecular structure, rare earth element has abundant electron energy level, can produce making a leapleap forward of multiple energy inter-stage, and when the radiation of visible light rare earth ion, electronics from ground state or the following supreme energy level of energy level transition the absorption of light takes place, and luminous energy is stored.When not having visible light, to following energy level or ground state, the emission that produces light discharges the energy of storing to electronics from energy level transition on the excitation state.The energy difference difference of rare earth ion transition energy inter-stage just can be sent the light of different colours, utilizes photochromic composition principle that three-primary colours (red, yellow, indigo plant) coloured light is carried out the combination of certain way, thereby it is abundant to form color and luster, bright and colourful effect.But the at present not suitable method that rare earth aluminate series luminescent material is imprinted on the fabric.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of luminous printing process for making such fabric, to improve the ornamental of fabric.
The present invention realizes like this, a kind of luminous printing process for making such fabric, described method is, the metal powder adhesive is fully mixed with water, add rare earth aluminate luminescent material and fully mixing again, adding paint thickener for printing HIT at last fully mixes, obtain printing paste, each proportion of raw materials is in the printing paste, metal powder adhesive 380-420 weight portion, rare earth aluminate luminescent material 90-110 weight portion, paint thickener for printing HIT 10-30 weight portion, water 460-480 weight portion, above-mentioned printing paste is passed through PLATE SCREAM PRINTING mode stamp on the raw material fabric, under 145-155 ℃ of temperature, bake behind the stamp and handled 2.5-3.5 minute, carry out the tentering soft treatment again, make the luminous printing fabric.
The luminous printing fabric that this preparation method makes is applicable to and makes ornament and articles for children, and evening is luminous to make animal, flower type life-like, and the wonderful of crucial touch arranged, and gives the sensation of the extraordinary splendour unusual fluctuation of pattern.The Noctilucent material that is adopted is rare-earth activated aluminate luminescent material, has stable crystalline texture, luminescent properties can forever keep extinction, accumulation of energy, luminous process under crystal structure is not damaged prerequisite, this material does not contain any radioactive element, it is fast to have extinction, initial brightness height, characteristics such as persistence is long, safe and practical.
The specific embodiment
Further specify the present invention below.
Described raw material fabric is a kind of in bleached cotton fabric, stained clot-h and the calico.
The product that paint thickener for printing HIT adopts German BASF group to produce.
Requirement to the raw material fabric is, the cloth cover fineness of bleached cotton fabric will be got well, and it is high that capillary effect is wanted, and generally about 10cm/30min, otherwise can influence illumination effect.Every dye fastness index of calico or stained clot-h all will reach normal requirement, and especially sublimation reliability will be got well, otherwise can influence illumination effect when baking.
The luminous printing fabric that adopts said method to make carries out the luminescent properties test, and discovery is continuous in the dark after luminous 10 hours, and fabric still keeps good luminosity.The luminous printing fabric is put into washing machine, through repeatedly still keeping certain luminosity after the washing.Its reason is that a part of Noctilucent material has penetrated into and formed stable structure in the fiber after adopting the Noctilucent material stamp, and these Noctilucent materials of washing back can not come off.
Embodiment 1
A kind of luminous printing process for making such fabric, described method is, the metal powder adhesive is fully mixed with water, add rare earth aluminate luminescent material and fully mixing again, adding paint thickener for printing HIT at last fully mixes, obtain printing paste, each proportion of raw materials is in the printing paste, metal powder adhesive 380 weight portions, rare earth aluminate luminescent material 110 weight portions, paint thickener for printing HIT 10 weight portions, water 480 weight portions, above-mentioned printing paste is passed through PLATE SCREAM PRINTING mode stamp on the raw material fabric, under 145 ℃ of temperature, bake behind the stamp and handled 3.5 minutes, carry out the tentering soft treatment again, make the luminous printing fabric.Used raw material fabric is a bleached cotton fabric.
Embodiment 2
A kind of luminous printing process for making such fabric, described method is, the metal powder adhesive is fully mixed with water, add rare earth aluminate luminescent material and fully mixing again, adding paint thickener for printing HIT at last fully mixes, obtain printing paste, each proportion of raw materials is in the printing paste, metal powder adhesive 420 weight portions, rare earth aluminate luminescent material 90 weight portions, paint thickener for printing HIT 30 weight portions, water 460 weight portions, above-mentioned printing paste is passed through PLATE SCREAM PRINTING mode stamp on the raw material fabric, under 155 ℃ of temperature, bake behind the stamp and handled 2.5 minutes, carry out the tentering soft treatment again, make the luminous printing fabric.Used raw material fabric is a stained clot-h.
Embodiment 3
A kind of luminous printing process for making such fabric, described method is, the metal powder adhesive is fully mixed with water, add rare earth aluminate luminescent material and fully mixing again, adding paint thickener for printing HIT at last fully mixes, obtain printing paste, each proportion of raw materials is in the printing paste, metal powder adhesive 400 weight portions, rare earth aluminate luminescent material 100 weight portions, paint thickener for printing HIT 20 weight portions, water 470 weight portions, above-mentioned printing paste is passed through PLATE SCREAM PRINTING mode stamp on the raw material fabric, under 150 ℃ of temperature, bake behind the stamp and handled 3 minutes, carry out the tentering soft treatment again, make the luminous printing fabric.Used raw material fabric is a calico.
Claims (2)
1. luminous printing process for making such fabric, it is characterized in that, described method is, the metal powder adhesive is fully mixed with water, add rare earth aluminate luminescent material and fully mixing again, adding paint thickener for printing HIT at last fully mixes, obtain printing paste, each proportion of raw materials is in the printing paste, metal powder adhesive 380-420 weight portion, rare earth aluminate luminescent material 90-110 weight portion, paint thickener for printing HIT 10-30 weight portion, water 460-480 weight portion, above-mentioned printing paste is passed through PLATE SCREAM PRINTING mode stamp on the raw material fabric, under 145-155 ℃ of temperature, bake behind the stamp and handled 2.5-3.5 minute, carry out the tentering soft treatment again, make the luminous printing fabric.
2. luminous printing process for making such fabric as claimed in claim 1 is characterized in that, described raw material fabric is a kind of in bleached cotton fabric, stained clot-h and the calico.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009102292662A CN102041698A (en) | 2009-10-21 | 2009-10-21 | Method for preparing noctilucent printed fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009102292662A CN102041698A (en) | 2009-10-21 | 2009-10-21 | Method for preparing noctilucent printed fabric |
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| Publication Number | Publication Date |
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| CN102041698A true CN102041698A (en) | 2011-05-04 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2009102292662A Pending CN102041698A (en) | 2009-10-21 | 2009-10-21 | Method for preparing noctilucent printed fabric |
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| CN (1) | CN102041698A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104532610A (en) * | 2014-12-23 | 2015-04-22 | 包文波 | Formula and method for pigment printing |
| CN104562739A (en) * | 2014-12-30 | 2015-04-29 | 绍兴大发布业有限公司 | Long-acting luminous foaming printing paste and long-acting luminous foaming printing production process |
| CN105647275A (en) * | 2016-03-25 | 2016-06-08 | 辛向奎 | Luminous printing sizing agent, night light-emitting decorated plus material and preparation methods of luminous printing sizing agent and night light-emitting decorated plus material |
| CN105887510A (en) * | 2016-05-18 | 2016-08-24 | 太仓市好心情印务有限公司 | Long-acting luminous non-woven fabric bag |
| JP2020186502A (en) * | 2019-05-16 | 2020-11-19 | 青▲島▼永利良品国▲際▼▲貿▼易有限公司 | Luminous woven fabric, and preparation method and application thereof |
-
2009
- 2009-10-21 CN CN2009102292662A patent/CN102041698A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104532610A (en) * | 2014-12-23 | 2015-04-22 | 包文波 | Formula and method for pigment printing |
| CN104562739A (en) * | 2014-12-30 | 2015-04-29 | 绍兴大发布业有限公司 | Long-acting luminous foaming printing paste and long-acting luminous foaming printing production process |
| CN105647275A (en) * | 2016-03-25 | 2016-06-08 | 辛向奎 | Luminous printing sizing agent, night light-emitting decorated plus material and preparation methods of luminous printing sizing agent and night light-emitting decorated plus material |
| CN105887510A (en) * | 2016-05-18 | 2016-08-24 | 太仓市好心情印务有限公司 | Long-acting luminous non-woven fabric bag |
| JP2020186502A (en) * | 2019-05-16 | 2020-11-19 | 青▲島▼永利良品国▲際▼▲貿▼易有限公司 | Luminous woven fabric, and preparation method and application thereof |
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Application publication date: 20110504 |