CN111453991A - Golden crystal glaze and preparation method thereof - Google Patents
Golden crystal glaze and preparation method thereof Download PDFInfo
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- CN111453991A CN111453991A CN202010178447.3A CN202010178447A CN111453991A CN 111453991 A CN111453991 A CN 111453991A CN 202010178447 A CN202010178447 A CN 202010178447A CN 111453991 A CN111453991 A CN 111453991A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Abstract
The invention discloses a golden crystalline glaze and a preparation method thereof, wherein the glaze used by the golden crystalline glaze comprises the following components in parts by mass: 20-25 parts of potassium feldspar; 10-17 parts of albite; 5-10 parts of calcite; 13-17 parts of spodumene; 13-17 parts of titanium oxide; 10-20 parts of ferric oxide; 5-7 parts of barium carbonate; it is fired in a drawer kiln, and has a temperature-homogenizing and holding time of 1290 ℃ of 10 minutes in the firing process. The gold crystal glaze is golden in color and luster, is spread over the whole body, enables the golden crystal glaze to have layering, and glitters under the irradiation of sunlight, and laminated iron-titanium crystals can be seen no matter visible to naked eyes or by observation through a magnifying glass.
Description
Technical Field
The invention relates to a golden crystalline glaze and a preparation method thereof.
Background
At present, as early as the period of business weeks, phase splitting phenomenon has been observed in the original celadon glaze, and the south-ward Liang Tang Huaian kiln produced phase splitting glazed porcelain 1400 years ago; the successful crystallized glaze is sintered in Song dynasty, and is a rare microcrystalline glaze with temmoku, tea dust, rust flowers, grape dots, sesame and the like, and the main body of the microcrystalline glaze is a product which is subject to iron element and has a yellow color tone.
The crystallization was studied abroad beginning in about the 19 th century, mostly to study the zinc-silicon-zinc ore crystallized glaze series products.
The golden crystal glaze product has no large amount of exhibition in domestic and foreign markets for the following reasons: instability of firing, cause two: the formula of the golden crystal glaze has difficulty; the third reason is that: the gold-colored crystalline glaze crystals are not distributed throughout completely.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a golden crystalline glaze, the glaze surface of the golden crystalline glaze is golden yellow, the golden crystalline glaze is spread over the whole body, the golden crystalline glaze is more layered, and the gold flashes under the irradiation of sunlight, so that the laminated ferrotitanium crystal can be seen no matter the golden crystalline glaze is visible by naked eyes or observed by using a magnifying glass.
In order to solve the technical problems, the technical scheme of the invention is as follows: a golden crystal glaze comprises the following components in parts by mass:
20-25 parts of potassium feldspar; 10-17 parts of albite; 5-10 parts of calcite; 13-17 parts of spodumene; 13-17 parts of titanium oxide; 10-20 parts of ferric oxide; 5-7 parts of barium carbonate; it is fired in a drawer kiln, and has a temperature-homogenizing and holding time of 1290 ℃ of 10 minutes in the firing process.
The invention also provides a preparation method of the golden crystalline glaze, which comprises the following steps:
a) preparing the following components in parts by mass:
b) wet ball milling is carried out for 10-12 hours according to the mass ratio of material: ball: water being 1: 1.6: 0.7, and glaze slurry with the Baume concentration of 51-53 is prepared for standby after the ball milled glaze material is sieved by a 140-mesh sieve;
c) taking a clean blank body, and spraying glaze slurry;
d) and firing the blank sprayed with the glaze slip in a drawer kiln at 1290 ℃, and uniformly heating and preserving heat for 10 minutes.
By adopting the technical scheme, the glaze surface of the golden crystalline glaze prepared by the invention is golden yellow in color, is spread over the whole body, is more layered, and is glittered under the irradiation of sunlight, so that the laminated ferrotitanium crystal can be seen no matter the ferrotitanium crystal is visible by naked eyes or observed by using a magnifying glass.
Detailed Description
The invention provides a golden crystal glaze and a preparation method thereof, and a person skilled in the art can use the contents of the golden crystal glaze to appropriately improve the process parameters for realization. It is expressly intended that all such similar substitutes and modifications apparent to those skilled in the art are deemed to be within the scope of the invention. While the methods and applications of this invention have been described in terms of preferred embodiments, it will be apparent to those of ordinary skill in the art that variations and modifications in the methods and applications described herein, as well as other suitable variations and combinations, may be made to implement and use the techniques of this invention without departing from the spirit and scope of the invention.
A golden crystal glaze comprises the following components in parts by mass:
20-25 parts of potassium feldspar; 10-17 parts of albite; 5-10 parts of calcite; 13-17 parts of spodumene; 13-17 parts of titanium oxide; 10-20 parts of ferric oxide; 5-7 parts of barium carbonate; it is fired in a drawer kiln, and has a temperature-homogenizing and holding time of 1290 ℃ of 10 minutes in the firing process.
The preparation method of the golden crystalline glaze comprises the following steps:
a) preparing the following components in parts by mass:
b) wet ball milling is carried out for 10-12 hours according to the mass ratio of material: ball: water being 1: 1.6: 0.7, and glaze slurry with the Baume concentration of 51-53 is prepared for standby after the ball milled glaze material is sieved by a 140-mesh sieve;
c) taking a clean blank body, and spraying glaze slurry;
d) and firing the blank sprayed with the glaze slip in a drawer kiln at 1290 ℃, and uniformly heating and preserving heat for 10 minutes.
The glaze surface of the golden crystalline glaze prepared by the invention is golden yellow in color, and is distributed throughout the blank body, so that the golden crystalline glaze has more layering, and the gold flashes under the irradiation of sunlight, so that the laminated ferrotitanium crystal can be seen no matter the golden crystalline glaze is visible by naked eyes or observed by using a magnifying glass.
The golden crystal glaze has greater optimization than the same series of crystals in the aspects of manufacturing and sintering:
1. no special raw materials are needed, the ball milling time is short, the allowable fineness range is wide, and the operation is convenient and simple;
2. the sintering does not need extra heat preservation time, and the integral precipitation of the crystal can be ensured in the process of temperature equalization for 10 minutes.
In order that the present invention may be more clearly understood, the following detailed description of the present invention is given with reference to specific examples.
Example one
A golden crystal glaze comprises the following components in parts by mass:
20 parts of potassium feldspar; 10 parts of albite; 5 parts of calcite; 13 parts of spodumene; 13 parts of titanium oxide; 10 parts of iron oxide; 5 parts of barium carbonate; it is fired in a drawer kiln, and has a temperature-homogenizing and holding time of 1290 ℃ of 10 minutes in the firing process.
The preparation method of the golden crystalline glaze comprises the following steps:
a) preparing the following components in parts by mass:
b) wet ball milling is carried out for 10 hours according to the mass ratio of material: ball: water being 1: 1.6: 0.7, and glaze slurry with the Baume concentration of 51-53 is prepared for standby after the ball milled glaze material is sieved by a 140-mesh sieve;
c) taking a clean blank body, and spraying glaze slurry;
d) and firing the blank sprayed with the glaze slip in a drawer kiln at 1290 ℃, and uniformly heating and preserving heat for 10 minutes.
The specific firing data are as follows:
example two
A golden crystal glaze comprises the following components in parts by mass:
25 parts of potassium feldspar; 17 parts of albite; 10 parts of calcite; 17 parts of spodumene; 17 parts of titanium oxide; 20 parts of iron oxide; 7 parts of barium carbonate; it is fired in a drawer kiln, and has a temperature-homogenizing and holding time of 1290 ℃ of 10 minutes in the firing process.
The preparation method of the golden crystalline glaze comprises the following steps:
a) preparing the following components in parts by mass:
b) wet ball milling is carried out for 12 hours according to the mass ratio of material: ball: water being 1: 1.6: 0.7, and glaze slurry with the Baume concentration of 51-53 is prepared for standby after the ball milled glaze material is sieved by a 140-mesh sieve;
c) taking a clean blank body, and spraying glaze slurry;
d) and firing the blank sprayed with the glaze slip in a drawer kiln at 1290 ℃, and uniformly heating and preserving heat for 10 minutes.
The firing data of this example are the same as those of the first example.
EXAMPLE III
A golden crystal glaze comprises the following components in parts by mass:
22 parts of potassium feldspar; 14 parts of albite; 7 parts of calcite; 14 parts of spodumene; 15 parts of titanium oxide; 15 parts of iron oxide; 6 parts of barium carbonate; it is fired in a drawer kiln, and has a temperature-homogenizing and holding time of 1290 ℃ of 10 minutes in the firing process.
The preparation method of the golden crystalline glaze comprises the following steps:
a) preparing the following components in parts by mass:
b) wet ball milling is carried out for 11 hours according to the mass ratio of material: ball: water being 1: 1.6: 0.7, and glaze slurry with the Baume concentration of 51-53 is prepared for standby after the ball milled glaze material is sieved by a 140-mesh sieve;
c) taking a clean blank body, and spraying glaze slurry;
d) and firing the blank sprayed with the glaze slip in a drawer kiln at 1290 ℃, and uniformly heating and preserving heat for 10 minutes.
The firing data of this example are the same as those of the first example.
The golden crystal glaze prepared by the three embodiments has golden crystals throughout the whole body, and 50 products have no sticky plate phenomenon.
Comparative example 1
A golden crystal glaze comprises the following components in parts by mass:
20 parts of potassium feldspar; 10 parts of albite; 12 parts of calcite; 20 parts of spodumene; 13 parts of titanium oxide; 10 parts of iron oxide; and 5 parts of barium carbonate.
The preparation method of the golden crystalline glaze comprises the following steps:
a) preparing the following components in parts by mass:
b) wet ball milling is carried out for 10 hours according to the mass ratio of material: ball: water being 1: 1.6: 0.7, and glaze slurry with the Baume concentration of 51-53 is prepared for standby after the ball milled glaze material is sieved by a 140-mesh sieve;
c) taking a clean blank body, and spraying glaze slurry;
d) and firing the blank sprayed with the glaze slip in a drawer kiln.
The firing data for this comparative example is as follows:
the product of this comparative example had gold crystals on the right and black crystals on the left with gold crystals and was too fluid.
Comparative example No. two
A golden crystal glaze comprises the following components in parts by mass:
20 parts of potassium feldspar; 10 parts of albite; 5 parts of calcite; 13 parts of spodumene; 13 parts of titanium oxide; 10 parts of iron oxide; and 5 parts of barium carbonate.
The preparation method of the golden crystalline glaze comprises the following steps:
a) preparing the following components in parts by mass:
b) wet ball milling is carried out for 10 hours according to the mass ratio of material: ball: water being 1: 1.6: 0.7, and glaze slurry with the Baume concentration of 51-53 is prepared for standby after the ball milled glaze material is sieved by a 140-mesh sieve;
c) taking a clean blank body, and spraying glaze slurry;
d) and firing the blank sprayed with the glaze slip in a drawer kiln.
The firing data for this comparative example is as follows:
the whole product of the comparative example is golden crystal, but the high-temperature sintering time is too long, so that the plate is stuck.
Comparative example No. three
A golden crystal glaze comprises the following components in parts by mass:
20 parts of potassium feldspar; 10 parts of albite; 12 parts of calcite; 13 parts of spodumene; 13 parts of titanium oxide; 10 parts of iron oxide; and 5 parts of barium carbonate.
The preparation method of the golden crystalline glaze comprises the following steps:
a) preparing the following components in parts by mass:
b) wet ball milling is carried out for 10 hours according to the mass ratio of material: ball: water being 1: 1.6: 0.7, and glaze slurry with the Baume concentration of 51-53 is prepared for standby after the ball milled glaze material is sieved by a 140-mesh sieve;
c) taking a clean blank body, and spraying glaze slurry;
d) and firing the blank sprayed with the glaze slip in a drawer kiln.
The firing data for this example is as follows:
the product of this comparative example exhibited golden crystals throughout the whole body, and had a reduced flow property, but also had a plate sticking phenomenon.
Comparative example No. four
The glaze formulation and method of this comparative example are essentially the same as example two, except that: the firing data are as follows:
the product of the comparative example has golden crystals throughout the whole body, and has the phenomena of over-low glaze temperature and plate sticking.
The above embodiments are described in further detail to solve the technical problems, technical solutions and advantages of the present invention, and it should be understood that the above embodiments are only examples of the present invention and are not intended to limit the present invention, and any modifications, equivalent substitutions, improvements and the like made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (2)
1. The golden crystal glaze is characterized in that the glaze used by the golden crystal glaze comprises the following components in parts by mass:
20-25 parts of potassium feldspar; 10-17 parts of albite; 5-10 parts of calcite; 13-17 parts of spodumene; 13-17 parts of titanium oxide; 10-20 parts of ferric oxide; 5-7 parts of barium carbonate; it is fired in a drawer kiln, and has a temperature-homogenizing and holding time of 1290 ℃ of 10 minutes in the firing process.
2. The method for preparing a gold-colored crystalline glaze according to claim 1, characterized in that the method comprises the steps of:
a) preparing the following components in parts by mass:
b) wet ball milling is carried out for 10-12 hours according to the mass ratio of material: ball: water being 1: 1.6: 0.7, and glaze slurry with the Baume concentration of 51-53 is prepared for standby after the ball milled glaze material is sieved by a 140-mesh sieve;
c) taking a clean blank body, and spraying glaze slurry;
d) and firing the blank sprayed with the glaze slip in a drawer kiln at 1290 ℃, and uniformly heating and preserving heat for 10 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN202010178447.3A CN111453991A (en) | 2020-03-14 | 2020-03-14 | Golden crystal glaze and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010178447.3A CN111453991A (en) | 2020-03-14 | 2020-03-14 | Golden crystal glaze and preparation method thereof |
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| CN111453991A true CN111453991A (en) | 2020-07-28 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112142326A (en) * | 2020-09-10 | 2020-12-29 | 醴陵陶润实业发展有限公司 | Iron-cobalt-nickel crystal system crystal glaze and preparation method thereof |
| CN114656287A (en) * | 2022-03-15 | 2022-06-24 | 河北金厂峪矿业有限责任公司 | Method for preparing pseudobrookite type crystalline glaze by using gold tailings |
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| CN102173869A (en) * | 2011-01-19 | 2011-09-07 | 江苏高淳陶瓷股份有限公司 | Preparation method of non-ferrous tea dust crystalline glaze |
| CN102432342A (en) * | 2011-09-20 | 2012-05-02 | 江苏高淳陶瓷股份有限公司 | Preparation method of vanadium-titanium-iron system golden crystal glaze |
| CN105753321A (en) * | 2016-03-08 | 2016-07-13 | 武汉理工大学 | Molybdenum-based metal luster crystal glaze and preparation method thereof |
| CN108101367A (en) * | 2017-12-04 | 2018-06-01 | 李经文 | Transmutation crystalline glaze and preparation method thereof |
| CN108147665A (en) * | 2017-12-11 | 2018-06-12 | 程莉 | Microcrystal grain glaze and preparation method thereof |
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2020
- 2020-03-14 CN CN202010178447.3A patent/CN111453991A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102173869A (en) * | 2011-01-19 | 2011-09-07 | 江苏高淳陶瓷股份有限公司 | Preparation method of non-ferrous tea dust crystalline glaze |
| CN102432342A (en) * | 2011-09-20 | 2012-05-02 | 江苏高淳陶瓷股份有限公司 | Preparation method of vanadium-titanium-iron system golden crystal glaze |
| CN105753321A (en) * | 2016-03-08 | 2016-07-13 | 武汉理工大学 | Molybdenum-based metal luster crystal glaze and preparation method thereof |
| CN108101367A (en) * | 2017-12-04 | 2018-06-01 | 李经文 | Transmutation crystalline glaze and preparation method thereof |
| CN108147665A (en) * | 2017-12-11 | 2018-06-12 | 程莉 | Microcrystal grain glaze and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112142326A (en) * | 2020-09-10 | 2020-12-29 | 醴陵陶润实业发展有限公司 | Iron-cobalt-nickel crystal system crystal glaze and preparation method thereof |
| CN114656287A (en) * | 2022-03-15 | 2022-06-24 | 河北金厂峪矿业有限责任公司 | Method for preparing pseudobrookite type crystalline glaze by using gold tailings |
| CN114656287B (en) * | 2022-03-15 | 2022-12-06 | 河北金厂峪矿业有限责任公司 | Method for preparing pseudobrookite crystalline glaze by using gold tailings |
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