CN111419737A - Solid hair care agent and preparation method thereof - Google Patents
Solid hair care agent and preparation method thereof Download PDFInfo
- Publication number
- CN111419737A CN111419737A CN202010280639.5A CN202010280639A CN111419737A CN 111419737 A CN111419737 A CN 111419737A CN 202010280639 A CN202010280639 A CN 202010280639A CN 111419737 A CN111419737 A CN 111419737A
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- CN
- China
- Prior art keywords
- hair care
- trimethyl ammonium
- alkyl radical
- alkoxy
- solid hair
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000007787 solid Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 20
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 13
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 10
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- AISMNBXOJRHCIA-UHFFFAOYSA-N trimethylazanium;bromide Chemical compound Br.CN(C)C AISMNBXOJRHCIA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 6
- SZYJELPVAFJOGJ-UHFFFAOYSA-N trimethylamine hydrochloride Chemical compound Cl.CN(C)C SZYJELPVAFJOGJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 10
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 claims description 6
- QMGAJHYFGBHHRR-UHFFFAOYSA-M trimethyl(3-octadecoxypropyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCOCCC[N+](C)(C)C QMGAJHYFGBHHRR-UHFFFAOYSA-M 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 229960000541 cetyl alcohol Drugs 0.000 claims description 4
- -1 hexadecyloxybutyltrimethylammonium chloride Chemical compound 0.000 claims description 4
- MWKJFRHPWKQUKM-UHFFFAOYSA-M CCCCCCCCCCCCCCCCCCCCCCOCCC[N+](C)(C)C.[Cl-] Chemical compound CCCCCCCCCCCCCCCCCCCCCCOCCC[N+](C)(C)C.[Cl-] MWKJFRHPWKQUKM-UHFFFAOYSA-M 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 229960000735 docosanol Drugs 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000002304 perfume Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- 125000002091 cationic group Chemical group 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 10
- 238000009472 formulation Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 2
- 229920002560 Polyethylene Glycol 3000 Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 235000003715 nutritional status Nutrition 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to the technical field of hair care products in daily chemical industry, in particular to a solid hair care agent and a preparation method thereof. The hair conditioner comprises the following components in percentage by weight: 5% -30% of fatty alcohol and alkoxy C 14‑22Alkyl radical C 2‑5Trimethyl ammonium chloride or alkoxy C 14‑22Alkyl radical C 2‑54.5 to 45 percent of trimethyl ammonium bromide and 25 to 90.5 percent of polyethylene glycol; the fatty alcohol is C 14‑22The molecular weight of fatty alcohol and polyethylene glycol is 200-120000. The hair conditioner of the invention has a unique ternary complex mixed system, and is formed into a solid hair conditioner with hair care effect by compounding the surfactant, the cationic conditioner and the fat-increasing agent, thereby solving the problem that the components of the existing hair conditioner are difficult to become solid And achieves the same hair care effect as the liquid hair care product.
Description
Technical Field
The invention relates to the technical field of hair care products in daily chemical industry, in particular to a solid hair care agent and a preparation method thereof.
Background
The hair care product is a personal care product commonly used by consumers, and the current hair care products are in a fluid or paste state by taking water as a medium because grease and cationic surfactant cannot be mixed into a solid state, so that the hair care products appear on the market. Liquid hair care products are not portable, as is common in airplanes, which limits the ability of liquid products to carry only 100 ml. On the premise of ensuring the hair care effect, how to prepare a solid hair care product becomes a new research and development hotspot and also has important application value.
Disclosure of Invention
In order to solve the defects in the prior art, the invention provides a solid hair conditioner and a preparation method thereof.
In order to realize the purpose, the invention adopts the following technical scheme:
The invention provides a solid hair conditioner which comprises the following components in percentage by weight: 5% -30% of fatty alcohol and alkoxy (C) 14-22) Alkyl radical (C) 2-5) Trimethyl ammonium chloride or alkoxy (C) 14-22) Alkyl radical (C) 2-5) 4.5 to 45 percent of trimethyl ammonium bromide and 25 to 90.5 percent of polyethylene glycol; the fatty alcohol is (C) 14-22) Fatty alcohol, the molecular weight of the polyethylene glycol is 200-120000, and the trialkoxy (C) 14-22) Alkyl radical (C) 2-5) Trimethyl ammonium chloride has the general formula:
The alkoxy group (C) 14-22) Alkyl radical (C) 2-5) Trimethyl ammonium bromide has the following general formula:
Optionally, the solid hair conditioner comprises the following components in percentage by weight: 15% of stearyloxypropyltrimethylammonium chloride, 25% of octadecanol and PEG 300059%.
Optionally, the solid hair conditioner comprises the following components in percentage by weight: 20% of hexadecyloxybutyltrimethylammonium chloride, 30% of hexadecanol and 250049% of PEG.
Optionally, the solid hair conditioner comprises the following components in percentage by weight: 15% of stearyloxypropyl trimethyl ammonium chloride, 5% of behenyloxypropyl trimethyl ammonium chloride, 10% of cetyl alcohol, 20% of behenyl alcohol, 20% of PEG 40020% and PEG 800029%.
Optionally, the solid hair conditioner further comprises 1 wt% of essence.
In another aspect, the present invention provides a method for preparing a solid hair care agent, the method comprising: proportionally mixing fatty alcohol and alkoxy C 14-22Alkyl radical C 2-5Trimethyl ammonium chloride or alkoxy C 14-22Alkyl radical C 2-5Mixing trimethyl ammonium bromide and polyethylene glycol, heating to a temperature higher than 50 deg.C, heating to liquid state, and cooling.
The invention has the beneficial effects that: the hair conditioner has a unique ternary compound mixed system, is compounded by the surfactant, the cationic conditioner and the fat-increasing agent to form the solid hair conditioner with the hair care effect, can perform the functions of emulsification, softening, antistatic, moisturizing and conditioning the hair, improves the nutritional status of the hair, enables the hair to be bright and is easy to comb. The invention well solves the problem that the existing hair care ingredients are difficult to become solid, and achieves the same hair care effect as a liquid hair care product.
Drawings
FIG. 1 solid state diagram of hair conditioner of example 1 of the present invention.
Detailed Description
The invention is further illustrated but is not in any way limited by the following specific examples.
Example 1
A solid hair conditioner was prepared, which had the following formulation: the weight percentage of the stearic acid oxygen propyl trimethyl ammonium chloride is 15 percent, the octadecanol is 25 percent, the PEG 300059 percent and the essence is 1 percent.
The preparation process comprises the following steps: mixing stearyloxypropyltrimethylammonium chloride, octadecanol, PEG3000 and essence, heating to liquid state at a temperature higher than 55 ℃, and cooling to obtain the solid hair conditioner.
The using method comprises the following steps: after shampooing, the product is soaked and then directly smeared on hair.
Example 2
A solid hair conditioner was prepared, which had the following formulation: according to the weight percentage, the product comprises 20 percent of hexadecyloxy butyl trimethyl ammonium chloride, 30 percent of cetyl alcohol, 250049 percent of PEG and 1 percent of essence. The preparation method is the same as example 1.
Example 3
A solid hair conditioner was prepared, which had the following formulation: 15 percent of stearyloxypropyl trimethyl ammonium chloride, 5 percent of behenyloxypropyl trimethyl ammonium chloride, 10 percent of cetyl alcohol, 20 percent of behenyl alcohol, 20 percent of PEG 40020 percent, 1 percent of PEG 800029 percent of essence. The preparation method is the same as example 1.
It will be apparent to those skilled in the art from this disclosure that many changes and modifications can be made, or equivalents modified, in the embodiments of the invention without departing from the scope of the invention. Therefore, any simple modification, equivalent change and modification made to the above embodiments according to the technical essence of the present invention shall still fall within the protection scope of the technical solution of the present invention, unless the contents of the technical solution of the present invention are departed.
Claims (6)
1. The solid hair care agent is characterized by comprising the following components in percentage by weight: 5% -30% of fatty alcohol and alkoxy C 14-22Alkyl radical C 2-5Trimethyl ammonium chloride or alkoxy C 14-22Alkyl radical C 2-54.5 to 45 percent of trimethyl ammonium bromide and 25 to 90.5 percent of polyethylene glycol; the fatty alcohol is C 14-22Fatty alcohol, the molecular weight of the polyethylene glycol is 200-120000, and the alkoxy C 14-22Alkyl radical C 2-5Trimethyl ammonium chloride has the general formula:
The alkoxy group C 14-22Alkyl radical C 2-5Trimethyl ammonium bromide has the following general formula:
2. A solid hair care composition according to claim 1, comprising the following components in percentage by weight: 15% of stearyloxypropyltrimethylammonium chloride, 25% of octadecanol and PEG 300059%.
3. A solid hair care composition according to claim 1, comprising the following components in percentage by weight: 20% of hexadecyloxybutyltrimethylammonium chloride, 30% of hexadecanol and 250049% of PEG.
4. A solid hair care composition according to claim 1, comprising the following components in percentage by weight: 15% of stearyloxypropyl trimethyl ammonium chloride, 5% of behenyloxypropyl trimethyl ammonium chloride, 10% of cetyl alcohol, 20% of behenyl alcohol, 20% of PEG 40020% and PEG 800029%.
5. A solid hair care composition according to any one of claims 1 to 4, further comprising 1% by weight of a perfume.
6. A process for preparing a solid hair conditioner according to claim 1, characterized in that it comprises: proportionally mixing fatty alcohol and alkoxy C 14-22Alkyl radical C 2-5Trimethyl ammonium chloride or alkoxy C 14-22Alkyl radical C 2-5Mixing trimethyl ammonium bromide and polyethylene glycol, heating to a temperature higher than 50 deg.C, heating to liquid state, and cooling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010280639.5A CN111419737A (en) | 2020-04-10 | 2020-04-10 | Solid hair care agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010280639.5A CN111419737A (en) | 2020-04-10 | 2020-04-10 | Solid hair care agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111419737A true CN111419737A (en) | 2020-07-17 |
Family
ID=71553837
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010280639.5A Pending CN111419737A (en) | 2020-04-10 | 2020-04-10 | Solid hair care agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111419737A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69727628D1 (en) * | 1996-08-06 | 2004-03-25 | Veda Corp A | Solid hair care product |
| ES2316720T3 (en) * | 2002-01-11 | 2009-04-16 | Cosmetic Warriors, Ltd. | SOLID HAIR CONDITIONING PRODUCT. |
| CN102112102A (en) * | 2008-08-08 | 2011-06-29 | 株式会社资生堂 | Hair conditioner composition |
| CN102170854A (en) * | 2009-02-03 | 2011-08-31 | 株式会社资生堂 | Hair conditioner composition and low-energy manufacturing method for the same |
-
2020
- 2020-04-10 CN CN202010280639.5A patent/CN111419737A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69727628D1 (en) * | 1996-08-06 | 2004-03-25 | Veda Corp A | Solid hair care product |
| ES2316720T3 (en) * | 2002-01-11 | 2009-04-16 | Cosmetic Warriors, Ltd. | SOLID HAIR CONDITIONING PRODUCT. |
| CN102112102A (en) * | 2008-08-08 | 2011-06-29 | 株式会社资生堂 | Hair conditioner composition |
| CN102170854A (en) * | 2009-02-03 | 2011-08-31 | 株式会社资生堂 | Hair conditioner composition and low-energy manufacturing method for the same |
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| Date | Code | Title | Description |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20200717 |