CN103211721B - Hair-care composition with automatic anti-corrosion function - Google Patents
Hair-care composition with automatic anti-corrosion function Download PDFInfo
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Abstract
The invention belongs to the field of chemicals for daily use and relates to a hair-care composition with an automatic anti-corrosion function. The hair-care composition with the automatic anti-corrosion function comprises the following components in percentage by weight: 0.5%-15.0% of fatty alcohol, 0.5%-5.0% of mono long alkyl quaternary ammonium salt, 0.1%-5.0% of bionic phospholipid, 0.1%-10.0% of siloxane compound, 0.02%-0.5% of a chelating agent and the balance of water-containing carrier. The hair-care composition with the automatic anti-corrosion function disclosed by the invention not only has the characteristic of conserving hairs, but also has the automatic anti-corrosion characteristic, and can be used for effectively inhibiting the growth of microorganisms without adding any preservative component.
Description
Technical field
The invention belongs to filed of daily-use chemical industry, relate to a kind of Haircare composition with self-corrosion protection function.
Background technology
At present, on market, developed very eurypalynous hair products, comprised hair conditioner, hairdressing gel and send out film etc.Those skilled in the art conventional technical method is in formula, to add quaternary ammonium salt, cationic polymer, fatty alcohol, silicone compounds, some grease compounds, antiseptic, chelating agen, essence, nutrient substance and water, these Haircare compositions can provide various conditioning effects, as the wet lifting of sending out and doing cardability, softness and the smooth feeling sent out, during use, these conditioners can provide the effect of conditioning hair.
In hair products, contain a certain amount of oils and fats and nutrient substance, microorganism is easily grown, and therefore, General Requirements adds a certain amount of antiseptic, and to reach the effect that suppresses growth of microorganism, some antiseptic also have direct sterilization functions.Conventional antiseptic comprises: Methylisothiazolinone, methylchloroisothiazandnone, methyl parahydroxybenzoate, ethylparaben, propyl p-hydroxybenzoate, butyl p-hydroxybenzoate, benzyl alcohol, phenoxyethanol, DMDM Hydantoin, imidazolidinyl urea, sodium benzoate etc.
As everyone knows; there is side effect in most antiseptic; bring certain trouble likely to people's health; the antiseptic of most is all synthetic; some antiseptic even contain micro-toxin, and life-time service exists health crisis containing the product of this antiseptic, and the antiseptic of part has stronger zest; even if denier in product, also may cause anaphylactic reaction! Some antiseptic contain a certain amount of impurity, larger for human body skin zest.Even as one of generally acknowledged in the world safety antiseptic sorbic acid and potassium sorbate, also may affect the metabolic balance of human body skin.
At present, has higher requirement in industry for antiseptic kind and consumption, some formaldehyde releaser antiseptical application are restricted, and people more and more trend towards using safer not containing the cosmetics of antiseptic.
Summary of the invention
The object of the invention is to solve the deficiencies in the prior art, provide a kind of not containing the Haircare composition of antiseptic, it has better safety to human body, is better than existing hair products.
A kind of Haircare composition with self-corrosion protection function of the present invention, comprises following component by mass percentage: fatty alcohol, 0.5～15.0%; Single long alkyl quaternary ammonium salts, 0.5～5.0%; Bionic phospholipid, 0.1～5.0%; Silicone compounds, 0.1～10.0%; Chelating agen, 0.02～0.5%; All the other are aqueous carrier.
According to the further feature of Haircare composition of the present invention, described fatty alcohol is selected from: the mixture of one or more in spermol, stearyl alcohol and behenyl alcohol; Be preferably the mixture of spermol and stearyl alcohol; Consumption accounts for 2.0～10.0% of composition quality.
According to the further feature of Haircare composition of the present invention, the described long alkyl quaternary ammonium salts of list is selected from: Dodecyl trimethyl ammonium chloride, dodecyl trimethyl sulfuric ester ammonium, CTAB, cetyl trimethyl sulfuric ester ammonium, stearyl trimethyl ammonium chloride, stearyl trimethyl sulfuric ester ammonium, mountain Yu base trimethyl ammonium chloride and mountain Yu base trimethyl sulfuric ester ammonium; Be preferably CTAB; Consumption accounts for 0.5～5.0% of composition quality.
According to the further feature of Haircare composition of the present invention, described bionic phospholipid is selected from: cocamidopropyl propyl amide pg dimonium chloride phosphate ester, myristamide propyl group pg dimonium chloride phosphate ester and sub-oleamide propyl group pg dimonium chloride phosphate ester; Be preferably cocamidopropyl propyl amide pg dimonium chloride phosphate ester; Consumption accounts for 0.1～2.0% of composition quality.
According to the further feature of Haircare composition of the present invention, described silicone compounds is selected from: the mixture of one or more of polydimethylsiloxane, dimethiconol and amino modified polydimethylsiloxane.
According to the further feature of Haircare composition of the present invention, the interior phase viscosity of described polydimethylsiloxane is 50cst to 300000cst, preferred 300cst to 100000cst, and consumption accounts for 0.5～5.0% of composition quality; The ammonia value of described amino modified polydimethylsiloxane is 0.1 to 0.3, and consumption accounts for 0.1～3.0% of composition quality.
According to the further feature of Haircare composition of the present invention, described chelating agen is selected from disodiumedetate or tetrasodium ethylenediamine tetraacetate, preferred disodiumedetate, and consumption accounts for 0.05～0.2% of composition quality.
According to the further feature of Haircare composition of the present invention, described aqueous carrier comprises: one or more above mixture of water, essence, citric acid, glycerol, polyhydric alcohol, aminoacid and hydrolyzed protein.
According to the preferred embodiment of Haircare composition of the present invention, said composition comprises following component by mass percentage: spermol 0.5～5.0%; Stearyl alcohol 0.5%～5.0%; CTAB 0.5%～5.0%; Cocamidopropyl propyl amide pg dimonium chloride phosphoesterase 30 .1%～2.0%; Polydimethylsiloxane 0.5%～5.0%; Amino modified polydimethylsiloxane 0.1%～3.0%; Disodiumedetate 0.05%～0.2%; Water surplus.
The beneficial effect of Haircare composition of the present invention is: except having the characteristic of maintenance hair, also have from Anticorrosive Character.In compositions of the present invention, CTAB belongs to cation quaternary ammonium salt, cocamidopropyl propyl amide pg dimonium chloride phosphate ester belongs to bionical phosphide, both are mainly used in improving cardability and smooth feeling and the flexibility of hair in compositions, meanwhile, when both are used in conjunction with, can also effectively suppress the effect of growth of microorganism, utilize both antibiotic property characteristics can reach good antiseptic effect, therefore do not need to add any antiseptic composition.
The specific embodiment
Embodiment 1
The present embodiment is to prepare Haircare composition according to table one.
Table one:
| Raw material | Quality percentage composition (%) |
| Spermol | 3.0 |
| Stearyl alcohol | 3.0 |
| CTAB | 2.5 |
| Cocamidopropyl propyl amide pg dimonium chloride phosphate ester | 1.0 |
| Polydimethylsiloxane | 3.0 |
| Amino modified polydimethylsiloxane | 0.5 |
| Disodiumedetate | 0.15 |
| Essence | 0.5 |
| Hydrolyzed wheat protein | 0.5 |
| Glycerol | 5.0 |
| Citric acid | In right amount |
| Water | Surplus |
Technique:
(1) spermol, stearyl alcohol and CTAB are added in oil phase container, be heated to 73～78 ℃, be incubated 30 minutes, standby;
(2) water is added in water container, add glycerol, citric acid, disodiumedetate and cocamidopropyl propyl amide pg dimonium chloride phosphate ester, be stirred to completely and dissolve, be heated to 73～78 ℃, be incubated 30 minutes, standby;
(3) by polydimethylsiloxane and amino modified polydimethylsiloxane mixing and stirring, standby;
(4) the water mixed solution in step (2) is added in mixing and emulsifying container, under stirring condition, the oil mixture in step (1) is added in mixing and emulsifying container, control 73～78 ℃ of temperature, stir homogenizing 3 minutes 15 minutes, be cooled to 55～60 ℃, the mixture that adds polydimethylsiloxane to mix with amino modified polydimethylsiloxane, homogenizing 3 minutes, is cooled to 40～45 ℃, add essence and hydrolyzed wheat protein, stir 15 minutes.
Analyzing and testing the results are shown in Table two.
Table two:
Attached: test microbes strain:
(1) antibacterial: Pseudomonas aeruginosa (Pseudomonas aeruginosa) ATCC 9027; Colon bacillus (Escherichia coli) ATCC 8739; Staphylococcus aureus (Staphylococcus aureus) ATCC 6538;
(2) mycete and yeast: candida albicans (Candida albicans) ATCC 10231; Aspergillus niger (Aspergillus niger) ATCC 16404.
Embodiment 2
The present embodiment is to prepare Haircare composition according to table three.
Table three:
| Raw material | Quality percentage composition (%) |
| Spermol | 1.5 |
| Stearyl alcohol | 3.0 |
| CTAB | 1.6 |
| Cocamidopropyl propyl amide pg dimonium chloride phosphate ester | 0.5 |
| Polydimethylsiloxane | 1.5 |
| Amino modified polydimethylsiloxane | 0.5 |
| Disodiumedetate | 0.1 |
| Essence | 0.1 |
| Serine | 0.5 |
| Propylene glycol | 3.0 |
| Citric acid | In right amount |
| Water | Surplus |
Technique:
(1) spermol, stearyl alcohol and hard base trimethyl ammonium chloride are added in oil phase container, be heated to 73～78 ℃, be incubated 30 minutes, standby;
(2) water is added in water container, add glycerol, citric acid, disodiumedetate and cocamidopropyl propyl amide pg dimonium chloride phosphate ester, be stirred to completely and dissolve, be heated to 73～78 ℃, be incubated 30 minutes, standby;
(3) by polydimethylsiloxane and amino modified polydimethylsiloxane mixing and stirring, standby;
(4) the water mixed solution in step 2 is added in mixing and emulsifying container, under stirring condition, oil mixture in step 1 is added in mixing and emulsifying container, controlling 73～78 ℃ of temperature stirs 15 minutes, homogenizing 3 minutes, is cooled to 55～60 ℃, the mixture that adds polydimethylsiloxane to mix with amino modified polydimethylsiloxane, homogenizing 3 minutes, be cooled to 40～45 ℃, add essence and serine, stir 15 minutes.
Analyzing and testing the results are shown in Table 4.
Table four:
Attached: test microbes strain:
(1) antibacterial: Pseudomonas aeruginosa (Pseudomonas aeruginosa) ATCC 9027; Colon bacillus (Escherichia coli) ATCC 8739; Staphylococcus aureus (Staphylococcus aureus) ATCC 6538;
(2) mycete and yeast: candida albicans (Candida albicans) ATCC 10231; Aspergillus niger (Aspergillus niger) ATCC 16404.
Embodiment 3
The present embodiment is to prepare Haircare composition according to table five.
Table five:
| Raw material | Quality percentage composition (%) |
| Spermol | 1.5 |
| Stearyl alcohol | 3.0 |
| CTAB | 1.2 |
| Myristamide propyl group pg dimonium chloride phosphate ester | 1.0 |
| Polydimethylsiloxane | 1.0 |
| Amino modified polydimethylsiloxane | 0.8 |
| Disodiumedetate | 0.1 |
| Essence | 0.1 |
| Citric acid | In right amount |
| Water | Surplus |
Technique:
(1) spermol, stearyl alcohol and CTAB are added in oil phase container, be heated to 73～78 ℃, be incubated 30 minutes, standby;
(2) water is added in water container, add glycerol, citric acid, disodiumedetate and myristamide propyl group pg dimonium chloride phosphate ester, be stirred to completely and dissolve, be heated to 73～78 ℃, be incubated 30 minutes, standby;
(3) by polydimethylsiloxane and amino modified polydimethylsiloxane mixing and stirring, standby;
(4) the water mixed solution in step 2 is added in mixing and emulsifying container, under stirring condition, oil mixture in step 1 is added in mixing and emulsifying container, controlling 73～78 ℃ of temperature stirs 15 minutes, homogenizing 3 minutes, is cooled to 55～60 ℃, the mixture that adds polydimethylsiloxane to mix with amino modified polydimethylsiloxane, homogenizing 3 minutes, be cooled to 40～45 ℃, add essence, stir 15 minutes.
Analyzing and testing the results are shown in Table six.
Table six:
Attached: test microbes strain:
(1) antibacterial: Pseudomonas aeruginosa (Pseudomonas aeruginosa) ATCC 9027; Colon bacillus (Escherichia coli) ATCC 8739; Staphylococcus aureus (Staphylococcus aureus) ATCC 6538;
(2) mycete and yeast: candida albicans (Candida albicans) ATCC 10231; Aspergillus niger (Aspergillus niger) ATCC 16404.
Embodiment 4
The present embodiment is to prepare Haircare composition according to table seven.
Table seven:
| Raw material | Quality percentage composition (%) |
| Spermol | 1.0 |
| Stearyl alcohol | 3.0 |
| CTAB | 1.0 |
| Myristamide propyl group pg dimonium chloride phosphate ester | 1.5 |
| Polydimethylsiloxane | 2.0 |
| Amino modified polydimethylsiloxane | 0.8 |
| Disodiumedetate | 0.1 |
| Essence | 0.1 |
| Citric acid | In right amount |
| Water | Surplus |
Technique is identical with embodiment 3.
Analyzing and testing the results are shown in Table eight.
Table eight:
Attached: test microbes strain:
(1) antibacterial: Pseudomonas aeruginosa (Pseudomonas aeruginosa) ATCC 9027; Colon bacillus (Escherichia coli) ATCC 8739; Staphylococcus aureus (Staphylococcus aureus) ATCC 6538;
(2) mycete and yeast: candida albicans (Candida albicans) ATCC 10231; Aspergillus niger (Aspergillus niger) ATCC 16404.
Above-described embodiment 1 to 4 is preferred embodiment, according to the selection of practical application and reagent performance similarity, can also make following adjustment:
(1) fatty alcohol, except selecting spermol, stearyl alcohol, also can adopt behenyl alcohol.The content of fatty alcohol can account for 0.5～15.0%, and preferably 2.0～10.0%.
(2) single long alkyl quaternary ammonium salts, except selecting CTAB, also can adopt: Dodecyl trimethyl ammonium chloride, dodecyl trimethyl sulfuric ester ammonium, CTAB, stearyl trimethyl ammonium chloride, stearyl trimethyl sulfuric ester ammonium, mountain Yu base trimethyl ammonium chloride and mountain Yu base trimethyl sulfuric ester ammonium.The content of single long alkyl quaternary ammonium salts can account for 0.5～5.0%, and preferably 0.5～5.0%.
(3) bionic phospholipid, except selecting cocamidopropyl propyl amide pg dimonium chloride phosphate ester, myristamide propyl group pg dimonium chloride phosphate ester, also can adopt sub-oleamide propyl group pg dimonium chloride phosphate ester.Bionic phospholipid can account for 0.1～5.0%, and preferably 0.1～2.0%.
(4) silicone compounds, except selecting polydimethylsiloxane, amino modified polydimethylsiloxane, also can adopt dimethiconol.Silicone compounds can account for 0.1～10.0%.When selecting polydimethylsiloxane, the interior phase viscosity of polydimethylsiloxane is 50cst to 300000cst, preferred 300cst to 100000cst, and consumption accounts for 0.5～5.0% of composition quality.When selecting amino modified polydimethylsiloxane, the ammonia value of amino modified polydimethylsiloxane is 0.1 to 0.3, and consumption accounts for 0.1～3.0% of composition quality.
(5) chelating agen, except selecting disodiumedetate, also can adopt tetrasodium ethylenediamine tetraacetate.Chelating agen can account for 0.02～0.5%, and preferably 0.05～0.2%.
(6) aqueous carrier can comprise: water, essence, citric acid, polyhydric alcohol (for example propylene glycol), aminoacid (for example serine) and hydrolyzed protein (for example hydrolyzed wheat protein).
Claims (1)
1. a Haircare composition with self-corrosion protection function, is characterized in that, comprises following component by mass percentage:
Fatty alcohol 0.5～15.0%;
Single long alkyl quaternary ammonium salts 0.5～5.0%;
Bionic phospholipid 0.1～5.0%;
Silicone compounds 0.1～10.0%;
Chelating agen 0.02～0.5%;
All the other are aqueous carrier;
Described bionic phospholipid is selected from: cocamidopropyl propyl amide pg dimonium chloride phosphate ester, myristamide propyl group pg dimonium chloride phosphate ester and sub-oleamide propyl group pg dimonium chloride phosphate ester;
The described long alkyl quaternary ammonium salts of list is selected from: Dodecyl trimethyl ammonium chloride, dodecyl trimethyl sulfuric ester ammonium, CTAB, cetyl trimethyl sulfuric ester ammonium, stearyl trimethyl ammonium chloride, stearyl trimethyl sulfuric ester ammonium, mountain Yu base trimethyl ammonium chloride and mountain Yu base trimethyl sulfuric ester ammonium.
2. Haircare composition according to claim 1, is characterized in that, described fatty alcohol is selected from: the mixture of one or more in spermol, stearyl alcohol and behenyl alcohol; Consumption accounts for 2.0～10.0% of composition quality.
3. Haircare composition according to claim 2, is characterized in that: described fatty alcohol is the mixture of spermol and stearyl alcohol.
4. Haircare composition according to claim 1, is characterized in that: the described long alkyl quaternary ammonium salts of list is CTAB.
5. Haircare composition according to claim 1, is characterized in that: the consumption of described bionic phospholipid accounts for 0.1～2.0% of composition quality.
6. Haircare composition according to claim 1, is characterized in that: described bionic phospholipid is cocamidopropyl propyl amide pg dimonium chloride phosphate ester.
7. Haircare composition according to claim 1, is characterized in that, described silicone compounds is selected from: the mixture of one or more of polydimethylsiloxane, dimethiconol and amino modified polydimethylsiloxane.
8. Haircare composition according to claim 7, is characterized in that: the interior phase viscosity of described polydimethylsiloxane is 50cst to 300000cst, and consumption accounts for 0.5～5.0% of composition quality; The ammonia value of described amino modified polydimethylsiloxane is 0.1 to 0.3, and consumption accounts for 0.1～3.0% of composition quality.
9. Haircare composition according to claim 8, is characterized in that: the interior phase viscosity of described polydimethylsiloxane is 300cst to 100000cst.
10. Haircare composition according to claim 1, is characterized in that: described chelating agen is selected from disodiumedetate or tetrasodium ethylenediamine tetraacetate, and consumption accounts for 0.05～0.2% of composition quality.
11. Haircare compositions according to claim 10, is characterized in that: described chelating agen is disodiumedetate.
12. Haircare compositions according to claim 1, is characterized in that, described aqueous carrier comprises: one or more above mixture of water, essence, citric acid, polyhydric alcohol, aminoacid and hydrolyzed protein.
13. Haircare compositions according to claim 1, is characterized in that, comprise following component by mass percentage:
Spermol 0.5～5.0%;
Stearyl alcohol 0.5～5.0%;
CTAB 0.5～5.0%;
Cocamidopropyl propyl amide pg dimonium chloride phosphoesterase 30 .1～2.0%;
Polydimethylsiloxane 0.5～5.0%;
Amino modified polydimethylsiloxane 0.1～3.0%;
Disodiumedetate 0.05～0.2%;
Water surplus.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104000749B (en) * | 2014-05-30 | 2016-09-07 | 纳爱斯集团有限公司 | A kind of scalp nursing solution |
| CN106811335B (en) * | 2016-11-21 | 2019-05-14 | 浙江雅思丽化妆品有限公司 | A kind of environmental protection low foam laundry jelly |
| WO2019142194A1 (en) * | 2018-01-17 | 2019-07-25 | Sharon Laboratories Ltd. | Antimicrobial preservative compositions |
| CN110934759B (en) * | 2019-11-26 | 2022-06-21 | 马祥全 | Application of cocamidopropyl PG-dimethyl ammonium chloride as bacteriostatic agent and application of cocamidopropyl PG-dimethyl ammonium chloride as bacteriostatic agent in daily chemical products |
| CN111000743B (en) * | 2019-11-26 | 2022-08-12 | 马祥全 | Cocoamidopropyl PG-dimethyl ammonium chloride and polyalcohol compound and application thereof |
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| US5683683A (en) * | 1995-09-21 | 1997-11-04 | Helene Curtis, Inc. | Body wash composition to impart conditioning properties to skin |
| CN1263456A (en) * | 1997-06-09 | 2000-08-16 | 欧莱雅股份有限公司 | Aqueous carrier systems for water-insoluble materials |
| CN1513435A (en) * | 2002-12-20 | 2004-07-21 | �ź㴫 | Composition of hair |
| CN101467530A (en) * | 2007-12-20 | 2009-07-01 | 罗门哈斯公司 | Synergistic microbicidal compositions |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5683683A (en) * | 1995-09-21 | 1997-11-04 | Helene Curtis, Inc. | Body wash composition to impart conditioning properties to skin |
| CN1263456A (en) * | 1997-06-09 | 2000-08-16 | 欧莱雅股份有限公司 | Aqueous carrier systems for water-insoluble materials |
| CN1513435A (en) * | 2002-12-20 | 2004-07-21 | �ź㴫 | Composition of hair |
| CN101467530A (en) * | 2007-12-20 | 2009-07-01 | 罗门哈斯公司 | Synergistic microbicidal compositions |
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