CN111413650B - Composite coating magnetic measurement optical fiber and preparation method thereof - Google Patents

Composite coating magnetic measurement optical fiber and preparation method thereof Download PDF

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Publication number
CN111413650B
CN111413650B CN202010231382.4A CN202010231382A CN111413650B CN 111413650 B CN111413650 B CN 111413650B CN 202010231382 A CN202010231382 A CN 202010231382A CN 111413650 B CN111413650 B CN 111413650B
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coating
optical fiber
acrylic resin
alloy
indium
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CN111413650A (en
Inventor
戴少涛
方埼磊
张腾
莫思铭
蔡渊
袁文
马韬
王邦柱
胡磊
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Dongbu Superconducting Technology Suzhou Co ltd
Beijing Jiaotong University
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Dongbu Superconducting Technology Suzhou Co ltd
Beijing Jiaotong University
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R33/00Arrangements or instruments for measuring magnetic variables
    • G01R33/0052Manufacturing aspects; Manufacturing of single devices, i.e. of semiconductor magnetic sensor chips
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R33/00Arrangements or instruments for measuring magnetic variables
    • G01R33/02Measuring direction or magnitude of magnetic fields or magnetic flux
    • G01R33/032Measuring direction or magnitude of magnetic fields or magnetic flux using magneto-optic devices, e.g. Faraday or Cotton-Mouton effect
    • G01R33/0327Measuring direction or magnitude of magnetic fields or magnetic flux using magneto-optic devices, e.g. Faraday or Cotton-Mouton effect with application of magnetostriction
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R33/00Arrangements or instruments for measuring magnetic variables
    • G01R33/02Measuring direction or magnitude of magnetic fields or magnetic flux
    • G01R33/10Plotting field distribution ; Measuring field distribution
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R33/00Arrangements or instruments for measuring magnetic variables
    • G01R33/12Measuring magnetic properties of articles or specimens of solids or fluids
    • G01R33/1238Measuring superconductive properties
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R33/00Arrangements or instruments for measuring magnetic variables
    • G01R33/12Measuring magnetic properties of articles or specimens of solids or fluids
    • G01R33/18Measuring magnetostrictive properties

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Measuring Magnetic Variables (AREA)

Abstract

The invention relates to a composite coating magneto-optical fiber, which comprises a bare fiber and a coating layer, wherein the coating layer is a composite coating layer consisting of acrylic resin, iron-gallium alloy and indium-bismuth alloy. The preparation method of the composite coating magnetic measurement optical fiber comprises the following steps: 1. coating acrylic resin on the surface of the bare fiber by adopting a dip coating-ultraviolet light curing process to form an acrylic resin coating on the surface of the bare fiber; 2. uniformly mixing iron-gallium alloy powder prepared by a gas atomization method and an indium-bismuth alloy, melting at 80 ℃, and putting into a coating cup; 3. and (3) passing the optical fiber coated with the acrylic resin coating through the coating cup prepared in the step (2), coating the metal alloy melt on the surface of the acrylic resin coating, and then cooling to prepare the composite coating magnetic measuring optical fiber. The invention solves the problems of lower strain of the traditional material and low sensitivity of the optical fiber magnetic field sensor at low temperature, and obviously improves the measurement precision and sensitivity of the magnetic measurement optical fiber at low temperature.

Description

Composite coating magnetic measurement optical fiber and preparation method thereof
Technical Field
The invention belongs to the technical field of optical fiber magnetic field sensors for superconducting magnets, and particularly relates to a magnetic measurement optical fiber for measuring the magnetic field change of a superconducting magnet at low temperature and a preparation method thereof.
Background
The magnetic field is an important parameter reflecting the operating state of the superconducting magnet in the operation of the superconducting equipment, and the quench fault of the superconducting magnet can be timely found through the real-time monitoring of the magnetic field, so that the normal operation of the superconducting magnet is facilitated. However, the superconducting magnet is in a complex electromagnetic environment with a strong magnetic field and a large current, and although the traditional electric magnetic field sensors (flux gate magnetometers, hall sensors, induction coil magnetometers, giant magneto-impedance magnetic sensors, and the like) have mature application modes in many occasions, due to the influence of the magneto-resistance effect, the conventional electric magnetic field sensors are difficult to apply to the superconducting magnet with the complex electromagnetic environment, and the measurement requirement for monitoring the whole magnetic field of the superconducting magnet in a low-temperature environment is difficult to meet.
The optical fiber sensing technology takes optical fibers as sensing media and light waves as carriers, and can detect changes of external environments (magnetic fields, electric fields, temperature, humidity and the like) by demodulating changes of wavelengths, phases, amplitudes and the like of the light waves in the optical fibers; under the action of an external magnetic field, the length and the volume of the magnetostrictive material can change along the direction of the magnetic field. The magnetostrictive material is used as a coating layer and attached to the optical fiber, when an external magnetic field changes, the distributed optical fiber can generate tensile strain in the axial direction, so that the central wavelength of the optical fiber is shifted, and the magnetic field intensity can be monitored by constructing a functional relation between the central wavelength of the optical fiber and the magnetic field intensity. The optical fiber magnetic field sensor has strong anti-electromagnetic interference capability, is very suitable for monitoring precise instruments such as a superconducting magnet and the like, can realize distributed multiplexing, can effectively overcome the defects of the traditional electrical magnetic field sensing system in the aspects of long-term stability, durability and distribution range, and realizes high-precision, long-distance, distributed and long-term magnetic field environment monitoring.
The optical fiber magnetic field sensor is applied to monitoring of the superconducting magnet at low temperature, and the sensor can not avoid irreversible damage to superconducting equipment caused by quench fault to the maximum extent only by responding in time when the magnetic field of the magnet is abnormal, but the accurate measurement of the magnetic field at low temperature and the monitoring application in the superconducting magnet are not realized at present.
Disclosure of Invention
The invention overcomes the defect that the existing optical fiber magnetic field sensor can only carry out point-mode measurement, and adopts the distributed optical fiber sensor based on magnetostrictive materials to realize the magnetic field sensing demodulation of the whole optical fiber link. Meanwhile, the optical frequency domain reflection method is combined with the low-temperature sensitive magnetostrictive iron gallium alloy (Fe-Ga) coated optical fiber, so that high spatial resolution and high sensitivity monitoring of a weak magnetic field at low temperature is realized.
In order to achieve the above purposes, the technical scheme adopted by the invention is as follows:
the utility model provides a compound coating surveys magnetic fiber, includes bare fiber and coating, the coating is: the inner layer is an acrylic resin coating, and the outer layer is a composite coating of a metal alloy coating; the metal alloy coating is an iron-gallium alloy coating and an indium-bismuth alloy coating.
The bare fiber is a quartz core single-mode fiber only containing a fiber core.
The mass ratio of the iron-gallium alloy to the indium-bismuth alloy is 85-95: 15 to 5.
The mass ratio of iron to gallium in the iron-gallium alloy is 5: 1.
the mass ratio of indium to bismuth in the indium-bismuth alloy is 2: 1.
the preparation method of the composite coating magnetic measurement optical fiber comprises the following steps:
step 1, coating acrylic resin on the surface of a bare fiber by adopting a dip coating-ultraviolet curing process to form an acrylic resin coating on the surface of the bare fiber;
step 2, mixing the iron-gallium alloy powder and the indium-bismuth alloy powder prepared by a gas atomization method according to a mass ratio of 85-95: 15-5, uniformly mixing, melting at 80 ℃, and putting into a coating cup;
and 3, passing the optical fiber coated with the acrylic resin coating through the coating cup prepared in the step 2, coating the metal alloy melt on the surface of the acrylic resin coating, and then cooling.
And 4, finally, preparing the composite coating magnetism measuring optical fiber with the inner layer of the acrylic resin coating and the outer layer of the metal alloy coating.
In the step 1, the thickness of the acrylic resin coating is 10-200 μm.
In the step 2, the grain sizes of the iron-gallium alloy and the indium-bismuth alloy are 5-80 μm.
In the step 2, the mass ratio of iron to gallium in the iron-gallium alloy is 5: 1, the mass ratio of indium to bismuth in the indium-bismuth alloy is 2: 1.
in step 3, the thickness of the cooled metal alloy coating is 10-200 μm.
The invention has the beneficial effects that:
1. the magnetostrictive material adopted by the invention is the iron-gallium alloy, has the advantages of high strain, small hysteresis, high stress sensitivity and the like under a low magnetic field, and solves the problems of low strain of the traditional material and low sensitivity of the optical fiber magnetic field sensor at a low temperature.
2. The invention adopts a composite coating magnetism-measuring optical fiber with an inner layer of acrylic resin coating and an outer layer of magnetostrictive metal coating. When the external magnetic field changes, the outer magnetostrictive metal coating deforms, and the strain is amplified through the inner high-elasticity acrylic resin coating; and further, the measurement precision and sensitivity of the magnetic measurement optical fiber at low temperature are obviously improved.
3. The optical fiber adopted by the invention is a fully distributed optical fiber, is not limited to the traditional point measurement, can realize the full-line monitoring of the optical fiber through Rayleigh scattering, realizes the overall magnetic field detection of the superconducting magnet, and can timely feed back the magnetic field mutation of the superconducting magnet.
Drawings
The invention has the following drawings:
FIG. 1 is a composite coated magnetic sensing fiber of the present invention;
wherein, 1 is a bare optical fiber, and 2 is a coating layer containing acrylic resin, iron-gallium alloy and indium-bismuth alloy.
Detailed Description
The present invention will be described in further detail with reference to the accompanying drawings.
As shown in fig. 1, the composite coating magnetic measurement fiber of the present invention includes a bare fiber 1 and a coating layer 2, wherein the coating layer 2 is: the inner layer is a composite coating layer of an acrylic resin coating and the outer layer is a metal alloy coating; the metal alloy coating is an iron-gallium alloy coating and an indium-bismuth alloy coating.
The bare fiber is a quartz core single-mode fiber only containing a fiber core.
The mass ratio of the iron-gallium alloy to the indium-bismuth alloy is 85-95: 15 to 5.
The mass ratio of iron to gallium in the iron-gallium alloy is 5: 1.
the mass ratio of indium to bismuth in the indium-bismuth alloy is 2: 1.
the preparation method of the composite coating magnetic measurement optical fiber comprises the following steps:
1. coating acrylic resin on the surface of the bare fiber by adopting a dip coating-ultraviolet light curing process to form an acrylic resin coating with the thickness of 10-200 mu m on the surface of the bare fiber;
2. mixing iron-gallium alloy powder (Fe-Ga, the mass ratio of Fe to Ga is 5: 1) and indium-bismuth alloy powder (In, Bi is 2: 1) with the particle size of 5-80 mu m prepared by a gas atomization method according to the mass ratio of 85-95: 15-5, uniformly mixing, melting at 80 ℃, and putting into a coating cup;
3. and (3) coating the optical fiber coated with the acrylic resin coating with a metal alloy melt on the surface of the acrylic resin coating by using the coating cup containing the molten metal alloy (Fe-Ga and InBi) prepared in the step (2), and cooling to obtain the metal alloy coating with the thickness of 10-200 mu m.
4. Finally, the composite coating magnetism-measuring optical fiber with the inner layer of the acrylic resin coating and the outer layer of the magnetostrictive metal alloy coating is prepared.
Example 1
1. Coating acrylic resin on the surface of the bare fiber by adopting a dip coating-ultraviolet light curing process to form a polymer coating with the thickness of 100 mu m on the surface of the bare fiber;
2. preparing iron-gallium alloy powder (Fe-Ga) with the particle size of 25 mu m and indium-bismuth alloy powder by a gas atomization method according to the mass ratio of 95: 5, uniformly mixing, melting at 80 ℃, and putting into a coating cup;
3. the optical fiber coated with the acrylic resin coating was passed through a coating cup containing molten metal alloys (Fe-Ga and InBi), and a metal melt was coated on the surface of the acrylic resin coating, and the thickness of the metal alloy coating after cooling was 100. mu.m.
Example 2
1. Coating acrylic resin on the surface of the bare fiber by adopting a dip coating-ultraviolet light curing process to form a polymer coating with the thickness of 200 mu m on the surface of the bare fiber;
2. preparing iron-gallium alloy powder (Fe-Ga) with the particle size of 80 mu m and indium-bismuth alloy powder by a gas atomization method according to the mass ratio of 90: 10, uniformly mixing, melting at 80 ℃, and putting into a coating cup;
3. the optical fiber coated with the acrylic resin coating was passed through a coating cup containing molten metal alloys (Fe-Ga and InBi), and a metal melt was coated on the surface of the acrylic resin coating, and the thickness of the metal alloy coating after cooling was 200. mu.m.
Example 3
1. Coating acrylic resin on the surface of the bare fiber by adopting a dip coating-ultraviolet light curing process to form a polymer coating with the thickness of 10 mu m on the surface of the bare fiber;
2. preparing iron-gallium alloy powder (Fe-Ga) with the particle size of 5 mu m and indium-bismuth alloy powder by a gas atomization method according to the mass ratio of 85: 15, uniformly mixing, melting at 80 ℃, and putting into a coating cup;
3. the optical fiber coated with the acrylic resin coating was passed through a coating cup containing molten metal alloys (Fe-Ga and InBi), and a metal melt was coated on the surface of the acrylic resin coating, and the thickness of the metal alloy coating after cooling was 10 μm.
The composite coating magnetism measuring optical fiber prepared by the invention is placed in a liquid nitrogen environment (77K), the change of an external magnetic field is measured by Rayleigh scattering spectrum drift in OFDR, and when the variation of the measured magnetic induction intensity is delta M which is 12mT, the drift of the detected Rayleigh scattering spectrum is 2.5 GHz. In the process that the change of the measured magnetic induction intensity is increased from 0mT to 200mT, the spectrum drift degree of Rayleigh scattering is gradually increased, the rayleigh scattering spectrum drift amount and the magnetic induction intensity have better linear correlation, and the method can realize the measurement of the change of the magnetic field at low temperature. In addition, a plurality of variable magnetic fields are arranged at multiple points along the length direction of the optical fiber, and the spectrum drift amounts at different positions are different, so that the magnetic measurement optical fiber can realize fully-distributed monitoring.
Those not described in detail in this specification are within the skill of the art.

Claims (8)

1. The composite coating magnetic measurement optical fiber is characterized by comprising a bare optical fiber and a coating layer, wherein the coating layer is as follows: the inner layer is an acrylic resin coating, and the outer layer is a composite coating of a metal alloy coating; the metal alloy coating is an iron-gallium alloy coating and an indium-bismuth alloy coating; the mass ratio of the iron-gallium alloy to the indium-bismuth alloy is 85-95: 15 to 5.
2. The composite coated magnetic fiber of claim 1, wherein: the bare fiber is a quartz core single-mode fiber only containing a fiber core.
3. The composite coated magnetic fiber of claim 1, wherein: the mass ratio of iron to gallium in the iron-gallium alloy is 5: 1.
4. the composite coated magnetic fiber of claim 1, wherein: the mass ratio of indium to bismuth in the indium-bismuth alloy is 2: 1.
5. the method for preparing the composite coating magnetic measuring optical fiber according to claim 1, which comprises the following steps:
step 1, coating acrylic resin on the surface of a bare fiber by adopting a dip coating-ultraviolet curing process to form an acrylic resin coating on the surface of the bare fiber;
step 2, mixing the iron-gallium alloy powder and the indium-bismuth alloy powder prepared by a gas atomization method according to a mass ratio of 85-95: 15-5, uniformly mixing, melting at 80 ℃, and putting into a coating cup;
step 3, passing the optical fiber coated with the acrylic resin coating through the coating cup prepared in the step 2, coating a metal alloy melt on the surface of the acrylic resin coating, and then cooling;
step 4, finally, preparing a composite coating magnetism measuring optical fiber with an acrylic resin coating as an inner layer and a metal alloy coating as an outer layer;
in the step 1, the thickness of the acrylic resin coating is 10-200 μm.
6. The method for preparing the composite coating magnetic measuring optical fiber according to claim 5, wherein the method comprises the following steps: in the step 2, the grain sizes of the iron-gallium alloy and the indium-bismuth alloy are 5-80 μm.
7. The method for preparing the composite coating magnetic measuring optical fiber according to claim 5, wherein the method comprises the following steps: in the step 2, the mass ratio of iron to gallium in the iron-gallium alloy is 5: 1, the mass ratio of indium to bismuth in the indium-bismuth alloy is 2: 1.
8. the method for preparing the composite coating magnetic measuring optical fiber according to claim 5, wherein the method comprises the following steps: in step 3, the thickness of the cooled metal alloy coating is 10-200 μm.
CN202010231382.4A 2020-03-27 2020-03-27 Composite coating magnetic measurement optical fiber and preparation method thereof Expired - Fee Related CN111413650B (en)

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