CN111394198A - Color-protecting concentrated laundry detergent and preparation method thereof - Google Patents
Color-protecting concentrated laundry detergent and preparation method thereof Download PDFInfo
- Publication number
- CN111394198A CN111394198A CN202010144155.8A CN202010144155A CN111394198A CN 111394198 A CN111394198 A CN 111394198A CN 202010144155 A CN202010144155 A CN 202010144155A CN 111394198 A CN111394198 A CN 111394198A
- Authority
- CN
- China
- Prior art keywords
- laundry detergent
- wheat germ
- polysaccharide
- color
- germ protein
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 241000209140 Triticum Species 0.000 claims abstract description 70
- 235000021307 Triticum Nutrition 0.000 claims abstract description 70
- 150000004676 glycans Chemical class 0.000 claims abstract description 60
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 60
- 239000005017 polysaccharide Substances 0.000 claims abstract description 60
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 108010009736 Protein Hydrolysates Proteins 0.000 claims abstract description 28
- 239000003531 protein hydrolysate Substances 0.000 claims abstract description 28
- 241000196324 Embryophyta Species 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 22
- 239000008367 deionised water Substances 0.000 claims abstract description 17
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 17
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims abstract description 17
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 17
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 17
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 17
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 17
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 claims abstract description 14
- 239000000047 product Substances 0.000 claims abstract description 14
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000006184 cosolvent Substances 0.000 claims abstract description 10
- 239000003755 preservative agent Substances 0.000 claims abstract description 5
- 230000002335 preservative effect Effects 0.000 claims abstract description 5
- 102000004169 proteins and genes Human genes 0.000 claims description 26
- 108090000623 proteins and genes Proteins 0.000 claims description 26
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 25
- 108091005658 Basic proteases Proteins 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 19
- 230000003301 hydrolyzing effect Effects 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 16
- 239000012460 protein solution Substances 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 229920002752 Konjac Polymers 0.000 claims description 12
- 235000010485 konjac Nutrition 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 240000003377 Shepherdia canadensis Species 0.000 claims description 10
- 235000018324 Shepherdia canadensis Nutrition 0.000 claims description 10
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 9
- 102000004190 Enzymes Human genes 0.000 claims description 9
- 108090000790 Enzymes Proteins 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 9
- 241001474374 Blennius Species 0.000 claims description 8
- 230000000415 inactivating effect Effects 0.000 claims description 8
- 239000004365 Protease Substances 0.000 claims description 5
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 claims description 5
- 244000247812 Amorphophallus rivieri Species 0.000 claims description 4
- 235000001206 Amorphophallus rivieri Nutrition 0.000 claims description 4
- 244000068988 Glycine max Species 0.000 claims description 4
- 235000010469 Glycine max Nutrition 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000000252 konjac Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- RMCIOPRDYJLIQM-XMTFNYHQSA-N (2r,3r,4s,5r)-1,2,3,4,5-pentahydroxyoctadecan-6-one Chemical compound CCCCCCCCCCCCC(=O)[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO RMCIOPRDYJLIQM-XMTFNYHQSA-N 0.000 claims description 3
- 108091005804 Peptidases Proteins 0.000 claims description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 3
- 239000004744 fabric Substances 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 7
- 230000037303 wrinkles Effects 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 14
- 238000012360 testing method Methods 0.000 description 11
- 229940088598 enzyme Drugs 0.000 description 8
- 238000005406 washing Methods 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 239000006260 foam Substances 0.000 description 4
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- XOFYZVNMUHMLCC-ZPOLXVRWSA-N prednisone Chemical compound O=C1C=C[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 XOFYZVNMUHMLCC-ZPOLXVRWSA-N 0.000 description 2
- 235000019419 proteases Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 description 1
- 108010004032 Bromelains Proteins 0.000 description 1
- 229920002581 Glucomannan Polymers 0.000 description 1
- 108090000526 Papain Proteins 0.000 description 1
- 101710202013 Protein 1.5 Proteins 0.000 description 1
- 102000005158 Subtilisins Human genes 0.000 description 1
- 108010056079 Subtilisins Proteins 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 235000019835 bromelain Nutrition 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229940046240 glucomannan Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- -1 neutralizer Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 235000019834 papain Nutrition 0.000 description 1
- 229940055729 papain Drugs 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a color-protecting concentrated laundry detergent and a preparation method thereof, wherein the color-protecting concentrated laundry detergent comprises the following raw materials: fatty alcohol-polyoxyethylene ether AEO-920-30%, dodecyl glucoside 5-10%, fatty acid methyl ester ethoxylate sulfonate FMES 20-30%, sodium dodecyl benzene sulfonate 10-15%, triethanolamine 3-5%, plant polysaccharide 0.05-0.15%, wheat germ protein hydrolysate 0.5-2%, cosolvent 4-10%, preservative 0-1%, essence 0-1%, and deionized water 10-25%. The concentrated laundry detergent prepared by the invention has high concentration multiple, good stability and strong dirt-removing power, has good fabric color protection, wrinkle resistance and softening effect, and is a concentrated laundry detergent product with high added value.
Description
Technical Field
The invention relates to the technical field of detergents, in particular to a color-protecting concentrated laundry detergent and a preparation method thereof.
Background
The concentrated laundry detergent is a liquid laundry detergent with high active ingredient content, has the advantages of saving water and reducing waste discharge in the production process, is beneficial to reducing packaging materials, saving cost and being convenient to store and transport, has extremely high market competitive advantage compared with the common laundry detergent, and has become the mainstream of technical innovation in the field of detergents. However, because the surfactant content in the high-concentration laundry detergent is very high, in order to maintain good dissolution stability and dirt-removing power, an additive is not added or is added little, so that the additional performances of color protection, wrinkle resistance, softness and the like of the laundry detergent are limited, the performance of the high-concentration laundry detergent is single, and the demand of the market on high value-added concentrated laundry detergent products is difficult to meet.
Disclosure of Invention
Based on the technical problems in the background art, the invention provides a color-protecting concentrated laundry detergent and a preparation method thereof.
The invention provides a color-protecting concentrated laundry detergent which comprises the following raw materials in percentage by mass:
fatty alcohol-polyoxyethylene ether AEO-920-30%, dodecyl glucoside 5-10%, fatty acid methyl ester ethoxylate sulfonate FMES 20-30%, sodium dodecyl benzene sulfonate 10-15%, triethanolamine 3-5%, plant polysaccharide 0.05-0.15%, wheat germ protein hydrolysate 0.5-2%, cosolvent 4-10%, preservative 0-1%, essence 0-1%, and deionized water 10-25%.
Preferably, the wheat germ protein hydrolysate is prepared by hydrolyzing wheat germ protein with protease.
Preferably, the protease is at least one of papain, bromelain and alcalase.
Preferably, the wheat germ protein hydrolysate is prepared by the following method:
(1) fully dissolving wheat germ protein in water to prepare a wheat germ protein solution with the mass fraction of 3-5%;
(2) adding alkaline protease into the wheat germ protein solution to ensure that the mass ratio of the alkaline protease to the wheat germ protein is (1-2): 100, hydrolyzing for 2-4h under the conditions that the pH is 7.5-8.5 and the temperature is 40-55 ℃, inactivating enzyme and drying to obtain the product.
Preferably, the plant polysaccharide is at least one of konjac polysaccharide, soybean polysaccharide, algal polysaccharide and soapberry polysaccharide; preferably, the plant polysaccharide is prepared from konjak polysaccharide, seaweed polysaccharide and soapberry polysaccharide according to a mass ratio of 100: (20-30): (5-10).
Preferably, the cosolvent is at least one of ethanol, glycol and glycerol.
Preferably, the preservative is casone or methylisothiazolinone.
The preparation method of the color-protecting concentrated laundry detergent comprises the following steps:
s1, adding fatty alcohol-polyoxyethylene ether AEO-9, dodecyl glucose, fatty acid methyl ester ethoxylate sulfonate FMES, sodium dodecyl benzene sulfonate and a cosolvent into deionized water, and heating and stirring uniformly;
s2, adding plant polysaccharide and wheat germ protein hydrolysate into the material obtained in the step S1, and heating and stirring uniformly;
s3, adding the rest raw materials into the material obtained in the step S1, and uniformly stirring to obtain the material.
Preferably, in the step S1, the stirring temperature is 45-50 ℃; in the step S2, the stirring temperature is 30-40 ℃.
The invention has the following beneficial effects:
the concentrated laundry detergent with excellent color protection effect and washing performance is prepared by compounding a proper amount of anionic surfactant, nonionic surfactant, neutralizer, cosolvent, plant polysaccharide and wheat germ protein hydrolysate. The wheat germ protein hydrolysate is a product prepared by hydrolyzing wheat germ protein through enzyme, has certain emulsifying property, low foam and low foam stability, is properly compounded with the rest of surfactants and cosolvents in the invention, has good decontamination capability and low foam effects, also has higher polar group content and proper molecular weight, has good solubility, can keep higher stability in a system, can interact with fabric fibers, and plays roles of crease resistance, color fixation and smoothness; the plant polysaccharide has excellent hydrophilicity and film-forming property, can interact with fabric fibers, is combined with the surfaces of the fibers to form a protective layer, reduces the loss of dye, plays a role in color fixation, is favorable for improving the stability of a compound system due to the addition of a proper amount of plant polysaccharide, plays a synergistic effect with wheat germ protein hydrolysate, and better improves the color fixation and color protection effects of the concentrated laundry detergent. The concentrated laundry detergent prepared by the invention has high concentration multiple, the dilution multiple can reach 1/4-1/6, good stability can be kept under high concentration multiple, and the concentrated laundry detergent has low foam, strong dirt-removing power, excellent dye fixation and color protection effects, can play a role in crease resistance and smoothness, and is a concentrated laundry detergent product with high added value.
Detailed Description
The technical solution of the present invention will be described in detail below with reference to specific examples.
Example 1
The color-protecting concentrated laundry detergent comprises the following raw materials in percentage by mass:
fatty alcohol-polyoxyethylene ether AEO-920-30%, dodecyl glucoside 5-10%, fatty acid methyl ester ethoxylate sulfonate FMES 20-30%, sodium dodecyl benzene sulfonate 10-15%, triethanolamine 3-5%, plant polysaccharide 0.05-0.15%, wheat germ protein hydrolysate 0.5-2%, cosolvent 4-10%, methylisothiazolinone 0-1%, essence 0-1%, and deionized water 10-25%.
Example 2
The color-protecting concentrated laundry detergent comprises the following raw materials in percentage by mass:
fatty alcohol-polyoxyethylene ether AEO-920%, dodecyl glucoside 10%, fatty acid methyl ester ethoxylate sulfonate FMES 30%, sodium dodecyl benzene sulfonate 10%, triethanolamine 3%, konjac glucomannan 0.05%, wheat germ protein hydrolysate 2%, ethanol 5%, and deionized water to make up to 100%.
Wherein the wheat germ protein hydrolysate is prepared by hydrolyzing wheat germ protein with alkaline protease, and the preparation method comprises the following steps:
(1) fully dissolving wheat germ protein in water to prepare a wheat germ protein solution with the mass fraction of 3%;
(2) adding alkaline protease into the wheat germ protein solution, wherein the mass ratio of the alkaline protease to the wheat germ protein is 1: 100, hydrolyzing for 4 hours under the conditions of pH 7.5 and temperature 40 ℃, inactivating enzyme and drying to obtain the product.
The preparation method of the color-protecting concentrated laundry detergent comprises the following steps:
s1, adding fatty alcohol-polyoxyethylene ether AEO-9, dodecyl glucoside, fatty acid methyl ester ethoxylate sulfonate FMES, sodium dodecyl benzene sulfonate and ethanol into deionized water, and stirring at 45 ℃;
s2, adding konjac polysaccharide and wheat germ protein hydrolysate into the material obtained in the step S1, and uniformly stirring at 30 ℃;
s3, adding the rest raw materials into the material obtained in the step S1, and uniformly stirring to obtain the material.
Example 3
The color-protecting concentrated laundry detergent comprises the following raw materials in percentage by mass:
fatty alcohol-polyoxyethylene ether AEO-925%, dodecyl glucoside 5%, fatty acid methyl ester ethoxylate sulfonate FMES 20%, sodium dodecyl benzene sulfonate 15%, triethanolamine 5%, soybean polysaccharide 0.15%, wheat germ protein hydrolysate 0.5%, glycerol 10%, Kathon 1%, essence 1% and deionized water to make up to 100%.
Wherein the wheat germ protein hydrolysate is prepared by hydrolyzing wheat germ protein with alkaline protease, and the preparation method comprises the following steps:
(1) fully dissolving wheat germ protein in water to prepare a wheat germ protein solution with the mass fraction of 5%;
(2) adding alkaline protease into the wheat germ protein solution, wherein the mass ratio of the alkaline protease to the wheat germ protein is 2: 100, hydrolyzing for 4 hours under the conditions of pH of 8.5 and temperature of 55 ℃, inactivating enzyme and drying to obtain the finished product.
The preparation method of the color-protecting concentrated laundry detergent comprises the following steps:
s1, adding fatty alcohol-polyoxyethylene ether AEO-9, dodecyl glucoside, fatty acid methyl ester ethoxylate sulfonate FMES, sodium dodecyl benzene sulfonate and glycerol into deionized water, and stirring at 50 deg.C;
s2, adding soybean polysaccharide and wheat germ protein hydrolysate into the material obtained in the step S1, and uniformly stirring at 40 ℃;
s3, adding the rest raw materials into the material obtained in the step S1, and uniformly stirring to obtain the material.
Example 4
The color-protecting concentrated laundry detergent comprises the following raw materials in percentage by mass:
fatty alcohol-polyoxyethylene ether AEO-930%, dodecyl glucoside 8%, fatty acid methyl ester ethoxylate sulfonate FMES 30%, sodium dodecyl benzene sulfonate 12%, triethanolamine 4%, plant polysaccharide 0.1%, wheat germ protein hydrolysate 1.5%, ethylene glycol 4%, methylisothiazolinone 0.2%, essence 0.2%, and deionized water to make up to 100%.
Wherein the wheat germ protein hydrolysate is prepared by hydrolyzing wheat germ protein with alkaline protease, and the preparation method comprises the following steps:
(1) fully dissolving wheat germ protein in water to prepare a wheat germ protein solution with the mass fraction of 4%;
(2) adding alkaline protease into the wheat germ protein solution to enable the mass ratio of the alkaline protease to the wheat germ protein to be 1.5: 100, hydrolyzing for 3 hours under the conditions of pH 8 and temperature of 50 ℃, inactivating enzyme and drying to obtain the product.
Wherein the plant polysaccharide is prepared from konjak polysaccharide, seaweed polysaccharide and soapberry polysaccharide according to the mass ratio of 100: 25: 5.
The preparation method of the color-protecting concentrated laundry detergent comprises the following steps:
s1, adding fatty alcohol-polyoxyethylene ether AEO-9, dodecyl glucose, fatty acid methyl ester ethoxylate sulfonate FMES, sodium dodecyl benzene sulfonate and glycol into deionized water, and stirring uniformly at 48 ℃;
s2, adding plant polysaccharide and wheat germ protein hydrolysate into the material obtained in the step S1, and stirring uniformly at 35 ℃;
s3, adding the rest raw materials into the material obtained in the step S1, and uniformly stirring to obtain the material.
Comparative example 1
The difference between the comparative example 1 and the example 4 is only the difference of the raw material formula, specifically: the composite material comprises the following raw materials in percentage by mass: fatty alcohol-polyoxyethylene ether AEO-930%, dodecyl glucoside 8%, fatty acid methyl ester ethoxylate sulfonate FMES 30%, sodium dodecyl benzene sulfonate 12%, triethanolamine 4%, plant polysaccharide 0.1%, ethylene glycol 4%, methylisothiazolinone 0.2%, essence 0.2%, and deionized water to make up to 100%.
Wherein the plant polysaccharide is prepared from konjak polysaccharide, seaweed polysaccharide and soapberry polysaccharide according to the mass ratio of 100: 25: 5.
Comparative example 2
The difference between the comparative example 2 and the example 4 is only that the raw material formula is different, specifically: the composite material comprises the following raw materials in percentage by mass: fatty alcohol-polyoxyethylene ether AEO-930%, dodecyl glucoside 8%, fatty acid methyl ester ethoxylate sulfonate FMES 30%, sodium dodecyl benzene sulfonate 12%, triethanolamine 4%, wheat germ protein hydrolysate 1.5%, ethylene glycol 4%, methylisothiazolinone 0.2%, essence 0.2%, and deionized water to make up to 100%.
Wherein the plant polysaccharide is prepared from konjak polysaccharide, seaweed polysaccharide and soapberry polysaccharide according to the mass ratio of 100: 25: 5.
Wherein the wheat germ protein hydrolysate is prepared by hydrolyzing wheat germ protein with alkaline protease, and the preparation method comprises the following steps:
(1) fully dissolving wheat germ protein in water to prepare a wheat germ protein solution with the mass fraction of 4%;
(2) adding alkaline protease into the wheat germ protein solution to enable the mass ratio of the alkaline protease to the wheat germ protein to be 1.5: 100, hydrolyzing for 3 hours under the conditions of pH 8 and temperature of 50 ℃, inactivating enzyme and drying to obtain the product.
Comparative example 3
The difference between the comparative example 3 and the example 4 is only that the raw material formula is different, specifically: the composite material comprises the following raw materials in percentage by mass: fatty alcohol-polyoxyethylene ether AEO-930%, dodecyl glucoside 8%, fatty acid methyl ester ethoxylate sulfonate FMES 30%, sodium dodecyl benzene sulfonate 12%, triethanolamine 4%, plant polysaccharide 0.1%, wheat germ protein 1.5%, ethylene glycol 4%, methylisothiazolinone 0.2%, essence 0.2%, and deionized water to make up to 100%.
Wherein the plant polysaccharide is prepared from konjak polysaccharide, seaweed polysaccharide and soapberry polysaccharide according to the mass ratio of 100: 25: 5.
Comparative example 4
The difference between the comparative example 4 and the example 4 is only that the raw material formula is different, specifically: the composite material comprises the following raw materials in percentage by mass: fatty alcohol-polyoxyethylene ether AEO-930%, dodecyl glucoside 8%, fatty acid methyl ester ethoxylate sulfonate FMES 30%, sodium dodecyl benzene sulfonate 12%, triethanolamine 4%, plant polysaccharide 0.02%, wheat germ protein hydrolysate 0.23%, ethylene glycol 4%, methylisothiazolinone 0.2%, essence 0.2%, and deionized water to make up to 100%.
Wherein the plant polysaccharide is prepared from konjak polysaccharide, seaweed polysaccharide and soapberry polysaccharide according to the mass ratio of 100: 25: 5.
Wherein the wheat germ protein hydrolysate is prepared by hydrolyzing wheat germ protein with alkaline protease, and the preparation method comprises the following steps:
(1) fully dissolving wheat germ protein in water to prepare a wheat germ protein solution with the mass fraction of 4%;
(2) adding alkaline protease into the wheat germ protein solution to enable the mass ratio of the alkaline protease to the wheat germ protein to be 1.5: 100, hydrolyzing for 3 hours under the conditions of pH 8 and temperature of 50 ℃, inactivating enzyme and drying to obtain the product.
Comparative example 5
The difference between the comparative example 5 and the example 4 is only that the raw material formula is different, specifically: the composite material comprises the following raw materials in percentage by mass: fatty alcohol-polyoxyethylene ether AEO-930%, dodecyl glucoside 8%, fatty acid methyl ester ethoxylate sulfonate FMES 30%, sodium dodecyl benzene sulfonate 12%, triethanolamine 4%, plant polysaccharide 0.2%, wheat germ protein hydrolysate 2.5%, ethylene glycol 4%, methylisothiazolinone 0.2%, essence 0.2%, and deionized water to make up to 100%.
Wherein the plant polysaccharide is prepared from konjak polysaccharide, seaweed polysaccharide and soapberry polysaccharide according to the mass ratio of 100: 25: 5.
Wherein the wheat germ protein hydrolysate is prepared by hydrolyzing wheat germ protein with alkaline protease, and the preparation method comprises the following steps:
(1) fully dissolving wheat germ protein in water to prepare a wheat germ protein solution with the mass fraction of 4%;
(2) adding alkaline protease into the wheat germ protein solution to enable the mass ratio of the alkaline protease to the wheat germ protein to be 1.5: 100, hydrolyzing for 3 hours under the conditions of pH 8 and temperature of 50 ℃, inactivating enzyme and drying to obtain the product.
Test examples
The prepared laundry detergent was tested, and the results were as follows:
(1) stability of
Cold resistance stability: placing in a refrigerator at (-5 +/-2) deg.C for 24h, taking out, recovering to room temperature, observing, and determining whether the product is qualified as non-layering, non-precipitation, transparent and non-turbid; heat resistance stability: and (3) taking out the house in an incubator at the temperature of (40 +/-2) ℃ for 24 hours, recovering to room temperature, and observing to obtain a product which is qualified by no layering, no precipitation, transparency and no turbidity. The results are shown in table 1:
table 1 stability test results
(2) Color protection capability test
The laundry detergents prepared in the example 4, the comparative example 1 and the comparative example 4 and a commercial six-time concentrated laundry detergent are subjected to a color protection test, the dilution factor is 6 times, the test conditions are that the water temperature is 30 +/-2 ℃, the water quality is 250mg/kg of hard water, the washing time is 20min, the test material is 6 × 6cm colored cloth (made by EMPA132 direct black dye), the colorimetric value of the colored cloth is measured by a colorimeter before the washing is started, the colored cloth is rinsed for 10min by clean water after the washing, the colorimetric value of the colored cloth is measured again after the drying, the colorimetric difference between the colored cloth before the washing and after the washing is marked as delta E, wherein the delta E represents the color fixing performance of the laundry detergent, the smaller the value is, the stronger the color fixing performance of the laundry detergent is, and the test results are shown in Table:
TABLE 2 color protection test results
| Example 4 | Comparative example 1 | Comparative example 4 | Commercially available laundry detergent | |
| ΔE | 0.45 | 0.63 | 0.69 | 0.76 |
(3) Detergency test
The laundry detergent prepared in example 4 and a commercial six-time concentrated laundry detergent are subjected to a dirt-removing power test, wherein the dilution time is 6 times, and the test standard refers to QB/T1224-. The water quality is 250mg/kg hard water.
The results are shown in Table 3:
TABLE 3 detergency test results
| Example 4 | Commercially available laundry detergent | |
| Detergency to carbon black | 13.50 | 13.25 |
| Detergency to protein | 16.45 | 14.15 |
| Detergency to sebum | 12.35 | 11.70 |
In table 3, the larger the detergency value, the better the detergency effect.
Therefore, compared with the conventional high-concentration laundry detergent, the laundry detergent prepared by the invention has stronger decontamination capability and good color protection effect, and has high stability.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.
Claims (8)
1. The color-protecting concentrated laundry detergent is characterized by comprising the following raw materials in percentage by mass:
fatty alcohol-polyoxyethylene ether AEO-920-30%, dodecyl glucoside 5-10%, fatty acid methyl ester ethoxylate sulfonate FMES 20-30%, sodium dodecyl benzene sulfonate 10-15%, triethanolamine 3-5%, plant polysaccharide 0.05-0.15%, wheat germ protein hydrolysate 0.5-2%, cosolvent 4-10%, preservative 0-1%, essence 0-1%, and deionized water 10-25%.
2. The color protecting concentrated laundry detergent of claim 1, wherein the wheat germ protein hydrolysate is obtained by hydrolyzing wheat germ protein with protease.
3. The color-protecting concentrated laundry detergent of claim 1, wherein the wheat germ protein hydrolysate is prepared by the following method:
(1) fully dissolving wheat germ protein in water to prepare a wheat germ protein solution with the mass fraction of 3-5%;
(2) adding alkaline protease into the wheat germ protein solution to ensure that the mass ratio of the alkaline protease to the wheat germ protein is (1-2): 100, hydrolyzing for 2-4h under the conditions that the pH is 7.5-8.5 and the temperature is 40-55 ℃, inactivating enzyme and drying to obtain the product.
4. The color-protecting concentrated laundry detergent according to claim 1, wherein the plant polysaccharide is at least one of konjac polysaccharide, soybean polysaccharide, algal polysaccharide and soapberry polysaccharide; preferably, the plant polysaccharide is prepared from konjak polysaccharide, seaweed polysaccharide and soapberry polysaccharide according to a mass ratio of 100: (20-30): (5-10).
5. The color-protecting concentrated laundry detergent according to claim 1, wherein the cosolvent is at least one of ethanol, ethylene glycol and glycerol.
6. The color-protecting concentrated laundry detergent according to claim 1, wherein the preservative is cason or methylisothiazolinone.
7. A process for the preparation of a color care concentrated laundry detergent according to any of claims 1-6, comprising the steps of:
s1, adding fatty alcohol-polyoxyethylene ether AEO-9, dodecyl glucose, fatty acid methyl ester ethoxylate sulfonate FMES, sodium dodecyl benzene sulfonate and a cosolvent into deionized water, and heating and stirring uniformly;
s2, adding plant polysaccharide and wheat germ protein hydrolysate into the material obtained in the step S1, and heating and stirring uniformly;
s3, adding the rest raw materials into the material obtained in the step S1, and uniformly stirring to obtain the material.
8. The method for preparing a color-protecting concentrated laundry detergent according to claim 7, wherein in the step S1, the stirring temperature is 45-50 ℃; in the step S2, the stirring temperature is 30-40 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010144155.8A CN111394198A (en) | 2020-03-04 | 2020-03-04 | Color-protecting concentrated laundry detergent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010144155.8A CN111394198A (en) | 2020-03-04 | 2020-03-04 | Color-protecting concentrated laundry detergent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111394198A true CN111394198A (en) | 2020-07-10 |
Family
ID=71434476
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010144155.8A Pending CN111394198A (en) | 2020-03-04 | 2020-03-04 | Color-protecting concentrated laundry detergent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111394198A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6191087B1 (en) * | 1999-09-03 | 2001-02-20 | Vertec Biosolvents, Llc | Environmentally friendly solvent |
| CN104911046A (en) * | 2015-07-03 | 2015-09-16 | 陈明志 | Soft-type clothes detergent |
| CN105062703A (en) * | 2015-07-27 | 2015-11-18 | 东莞市香与化工有限公司 | Protease super-concentrated laundry detergent and preparation method thereof |
| CN109554251A (en) * | 2017-09-27 | 2019-04-02 | 冉丽容 | A kind of preparation method of antimicrobial laundry liquid |
| CN109810796A (en) * | 2019-01-24 | 2019-05-28 | 北京日光旭升精细化工技术研究所 | A kind of color protection exempts from brush liquid detergent and preparation method thereof |
-
2020
- 2020-03-04 CN CN202010144155.8A patent/CN111394198A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6191087B1 (en) * | 1999-09-03 | 2001-02-20 | Vertec Biosolvents, Llc | Environmentally friendly solvent |
| CN104911046A (en) * | 2015-07-03 | 2015-09-16 | 陈明志 | Soft-type clothes detergent |
| CN105062703A (en) * | 2015-07-27 | 2015-11-18 | 东莞市香与化工有限公司 | Protease super-concentrated laundry detergent and preparation method thereof |
| CN109554251A (en) * | 2017-09-27 | 2019-04-02 | 冉丽容 | A kind of preparation method of antimicrobial laundry liquid |
| CN109810796A (en) * | 2019-01-24 | 2019-05-28 | 北京日光旭升精细化工技术研究所 | A kind of color protection exempts from brush liquid detergent and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102242022A (en) | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof | |
| CN106350268A (en) | Laundry condensate bead and preparation method thereof | |
| CN111088121A (en) | Washing gel bead containing alcohol ether solvent and preparation method thereof | |
| CN109652228A (en) | A kind of High-concentration laundry detergent and its preparation method and application | |
| CN112175754A (en) | Biological enzyme laundry detergent and preparation method thereof | |
| CN110396457A (en) | A kind of anti-colour contamination is done washing solidifying pearl and preparation method thereof | |
| CN112251298A (en) | Super-concentrated laundry detergent and preparation method of diluent thereof | |
| CN107312658A (en) | A kind of hand clothes washing soap powder easily rinsed | |
| CN111394198A (en) | Color-protecting concentrated laundry detergent and preparation method thereof | |
| CN111690471B (en) | High-concentration laundry detergent without gel and precipitation and preparation method thereof | |
| CN113214909A (en) | Concentrated high-foam car washing gel bead and preparation method and application thereof | |
| CN111304015A (en) | Antibacterial high-concentration laundry detergent and preparation method thereof | |
| CN114395450B (en) | Environment-friendly solid washing tablet and preparation method thereof | |
| CN111635835A (en) | Disinfecting laundry detergent and preparation method thereof | |
| CN102561028A (en) | Refining agent for colored cotton | |
| CN101463294A (en) | Hyperconcentration oil stain rapid cleaning agent and production method thereof | |
| CN106753866A (en) | Good laundry sheet of a kind of solubility property and preparation method thereof | |
| CN112877148A (en) | Bacteriostatic laundry detergent containing natural plant components | |
| US9169457B2 (en) | Washing or cleaning agent with cellulose or a cellulose derivative | |
| CN102181330A (en) | Biological cleaning agent and preparation method thereof | |
| CN111778118A (en) | Method for preparing infant laundry detergent | |
| CN115322842B (en) | Concentrated alcohol detergent and preparation method thereof | |
| CN109112020B (en) | Instant soap flakes and preparation method thereof | |
| CN117946821A (en) | Stable weak acid concentrated laundry detergent and preparation method thereof | |
| CN115387126B (en) | Preparation method of high-stability low-solvent softening agent for cotton |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200710 |