CN111346037B - Preparation and application of plant composition with ultraviolet light protection, color protection and hair care effects - Google Patents

Preparation and application of plant composition with ultraviolet light protection, color protection and hair care effects Download PDF

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CN111346037B
CN111346037B CN202010032472.0A CN202010032472A CN111346037B CN 111346037 B CN111346037 B CN 111346037B CN 202010032472 A CN202010032472 A CN 202010032472A CN 111346037 B CN111346037 B CN 111346037B
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hair
protection
plant composition
percent
seeds
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CN111346037A (en
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成晓松
叶茂权
周龙兵
高珊珊
郭瑜娟
解鹏辉
邱楀锆
朱国飞
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Zhanghua Cosmetics Technology Co ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9794Liliopsida [monocotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9728Fungi, e.g. yeasts
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9771Ginkgophyta, e.g. Ginkgoaceae [Ginkgo family]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions
    • A61K2800/5922At least two compounds being classified in the same subclass of A61K8/18

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
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  • Botany (AREA)
  • Biotechnology (AREA)
  • Engineering & Computer Science (AREA)
  • Dermatology (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Cosmetics (AREA)

Abstract

The invention relates to an ultraviolet light protection, color protection and hair care plant composition, which comprises the following components: sunflower seeds, grape seeds, sweet almond, tea leaves, walnut seeds, ginkgo seeds, aloe leaves, henna flowers, polygonum multiflorum roots, red lucid ganoderma, fructus viticis, ginseng roots and gardenia fruits, and the weight ratio is as follows in sequence: sunflower seeds, grape seeds, sweet almond, tea leaves, walnut seeds: semen Ginkgo, folium Aloe, flos Hemerocallis, radix Polygoni Multiflori, and Ganoderma: chastetree fruit: ginseng root: 2-20: 1-5: 2-10: 1-5: 5-10: 2-8: 1-5: 2-5: 1-3: 2-6: 2-8: 1 to 4. According to the composition, through optimized screening and compounding of the herbal plant extracts, the components generate an obvious synergistic effect, so that the composition can effectively resist oxidation, remove hair free radicals, prevent hair sunburn, supplement hair and scalp nutrition, promote scalp and hair health, maintain natural hair color and effectively slow down the fading of dyed hair; can be used alone or applied to various hair care and cleaning products.

Description

Preparation and application of plant composition with ultraviolet light protection, color protection and hair care effects
Technical Field
The invention belongs to the technical field of cosmetics, and particularly relates to a preparation method and application of an ultraviolet light protection, color protection and hair care plant composition.
Background
With the improvement of the living standard of people in modern society, people who love beauty have the medicine. People who dye and scald hair can see everywhere, and the hair can be damaged to different degrees due to the long-term irradiation of ultraviolet rays. The hair scales are further damaged due to the irradiation of ultraviolet rays, and hair dyed and permed is more prone to fading, hair dryness and dryness, and loss of elasticity and toughness, and even more, hair loss. So the concept of hair care is getting deeper and deeper. People are eagerly increasing for natural, organic, environment-friendly and green consumer products. In the aspect of daily necessities, the demands of consumers with hair dyeing and perming quality on sun-proof, hair-care and color-care products are continuously improved, and on one hand, the requirements are that the sun-proof, hair-care and color-care products can effectively resist oxidation, remove hair free radicals, prevent hair sunburn, simultaneously supplement hair and scalp nutrition, promote scalp and hair health, maintain natural color of hair, and effectively slow down color fading of dyed hair; on the other hand, the product is expected to have milder property, so that the human and the environment reach a harmonious and natural equilibrium state. Therefore, the development of a mild plant-derived hair care and cleaning product for preventing and protecting sun and color, which is harmless to the environment and people, and has the functions of protecting ultraviolet light, protecting hair and color and slowing down hair fading is favored by consumers.
Disclosure of Invention
In view of the above, the present invention provides a plant composition for protecting ultraviolet light and protecting color and hair to solve the above problems.
The invention also provides a preparation method and application of the ultraviolet light protection, color protection and hair care plant composition.
In order to achieve the above objects, the present invention employs such an ultraviolet light-protecting, color-protecting and hair-protecting plant composition. Comprises the following components: sunflower seeds, grape seeds, sweet almond, tea leaves, walnut seeds, ginkgo seeds, aloe leaves, henna flowers, polygonum multiflorum roots, red lucid ganoderma, fructus viticis, ginseng roots and gardenia fruits, and the weight ratio is as follows in sequence: sunflower seeds, grape seeds, sweet almond, tea leaves, walnut seeds: semen Ginkgo, folium Aloe, flos Hemerocallis, radix Polygoni Multiflori, and Ganoderma: chastetree fruit: ginseng root: 2-20: 1-5: 2-10: 1-5: 5-10: 2-8: 1-5: 2-5: 1-3: 2-6: 2-8: 1 to 4.
The invention further provides that: the UV-light protecting, color protecting and hair protecting plant composition according to claim 1, wherein: the sunflower seeds, the grape seeds, the sweet almonds, the tea leaves, the walnut seeds, the ginkgo seeds, the aloe leaves, the henna flowers, the polygonum multiflorum roots, the red ganoderma lucidum, the fructus viticis, the ginseng roots and the gardenia fruits sequentially comprise the following components in percentage by weight: sunflower seeds, grape seeds, sweet almond, tea leaves, walnut seeds: semen Ginkgo, folium Aloe, flos Hemerocallis, radix Polygoni Multiflori, and Ganoderma: chastetree fruit: ginseng root: the ratio of gardenia fruit to gardenia fruit is 8-15: 7-14: 3: 2-7: 4: 7-10: 4-6: 2: 4: 3: 4: 6: 2
The invention further provides that: the sunflower seeds, the grape seeds, the sweet almonds, the tea leaves, the walnut seeds, the ginkgo seeds, the aloe leaves, the henna flowers, the polygonum multiflorum roots, the red ganoderma lucidum, the fructus viticis, the ginseng roots and the gardenia fruits sequentially comprise the following components in percentage by weight: sunflower seeds: grape seeds: sweet almond: tea leaf: walnut seeds: and (3) ginkgo seeds: aloe leaves: henna flower: root of Polygonum multiflorum Thunb: red ganoderma lucidum: chastetree fruit: ginseng root: gardenia fruit 12: 10: 3: 5: 4: 8: 5: 2: 4: 3: 4: 6: 2.
the invention further provides that: the ultraviolet light protection and color protection hair care plant composition is applied to hair care and cleaning products.
The invention further provides that: the ultraviolet light protection and color protection hair care plant composition accounts for 0.1-30 wt% of the hair care and cleaning product.
The invention further provides that: the hair care and cleaning products comprise hair care solution, shampoo, hair mask, hair conditioner, hair dye, permanent wave agent and the like.
The invention further provides that: the hair care liquid product comprises the following components in percentage by weight:
0.5-20% of plant composition for ultraviolet protection and color protection,
0.1 to 0.4 percent of essence,
0.01 to 0.2 percent of citric acid,
0.05 to 0.4 percent of preservative
Balance of deionized water
The invention further provides the shampoo which comprises the following components in percentage by weight:
10.0 to 30 percent of sodium laureth sulfate;
1.0-10.0% of cocamidopropyl betaine;
1.0-5.0% of polydimethylsiloxane;
0.5-3.0% of cocamide MEA;
0.5 to 5.0 percent of lauroyl wheat amino acid potassium;
guar hydroxypropyl trimethyl ammonium chloride 0.05-0.6%;
polyquaternium-470.5-1.0%;
100.1 to 0.4 percent of polyquaternium;
0.1 to 1 percent of fructo-oligosaccharide;
0.1-1% of cetearyl alcohol;
0.1 to 1.0 percent of bis-aminopropyl polydimethylsiloxane;
0.1 to 0.9 percent of sodium citrate;
0.01 to 0.5 percent of citric acid;
0.1 to 3.0 percent of sodium chloride;
the invention relates to 0.5 to 5 percent of plant composition for ultraviolet light protection, color protection and hair protection;
0.01 to 1.0 percent of preservative;
0.1-2.0% of aromatic;
balance of deionized water
The invention further provides a hair dye product which comprises the following components in percentage by weight:
the dye comprises the following components in percentage by weight:
2.00 to 10.00 percent of ammonium hydroxide;
cetostearyl alcohol 6.00-10.00%;
2.00 to 5.00 percent of propylene glycol;
1.50 to 3.00 percent of stearyl trimethyl ammonium chloride;
1.00-4.00% of glycerol stearate;
ceteareth-201.00-4.00%;
1.00-4.00% of mineral oil;
0.05 to 2.00 percent of polydimethylsiloxane;
0.20 to 1.20 percent of essence;
hydrolyzed wheat protein 0.10-1.50%;
0.30 to 0.50 percent of sodium sulfite;
0.30 to 1.00 percent of antioxidant;
0.10-0.30% of EDTA disodium;
0.50 to 5.00 percent of colorant;
0.50-5.00% of plant composition for ultraviolet protection and color protection;
the balance of deionized water and water;
the oxidant comprises the following components in percentage by weight:
12.00 to 18.00 percent of hydrogen peroxide;
cetostearyl alcohol 2.00-6.00%;
2.00 to 5.00 percent of propylene glycol;
ceteareth-201.00-10.00%;
1.00-4.00% of mineral oil;
1.00-4.00% of glycerol stearate;
0.20 to 1.20 percent of phosphoric acid;
0.10-0.30% of EDTA disodium;
0.02-0.2% of disodium hydrogen phosphate;
balance of deionized water
The invention provides a preparation method of an ultraviolet light protection, color protection and hair care plant composition, which comprises the following steps:
1) cleaning sunflower seeds, grape seeds, sweet almond, tea leaves, walnut seeds, ginkgo seeds, aloe leaves, henna flowers, polygonum multiflorum roots, red lucid ganoderma, fructus viticis, ginseng roots and gardenia fruits by using deionized water respectively, and placing in an oven for drying;
2) pulverizing the above dried plants respectively with a traditional Chinese medicine pulverizer to fine powder, sieving with 60 mesh sieve, weighing and mixing at a certain proportion to obtain ultraviolet light-protecting and color-protecting plant composition dry powder;
3) taking 0.5kg of the dry powder of the composition, adding 5L of water into an extraction device, heating to 95 ℃, carrying out condensation reflux for 4h, carrying out reduced pressure concentration to 1kg of concentrated solution, adding 3 times of 95% ethanol while stirring, carrying out condensation reflux for 2h at 80 ℃, filtering, standing for 24h, taking standing solution, carrying out reduced pressure concentration to 0.3kg, thus obtaining the ultraviolet light protection and color protection hair care plant composition, storing at-5 ℃ for later use, and recovering to room temperature before use.
The invention has the beneficial effects that: the composition disclosed by the invention has the advantages that through optimized screening and compounding of the herbal plant extracts, the components generate an obvious synergistic effect, can effectively resist oxidation, remove hair free radicals and prevent hair sunburn, can supplement hair and scalp nutrition, promote scalp and hair health, maintain the natural color of the hair, effectively slow down the fading of the dyed hair, can be used independently, can also be applied to various hair care and cleaning products, and has a very good application prospect.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention more apparent, the technical solutions of the present invention will be clearly and completely described below, and it is apparent that the described embodiments are a part of the embodiments of the present invention, but not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the scheme of the invention: the components used included the following materials, described below:
sunflower seeds: the sunflower seeds contain about 50% of fat, wherein the fat is mainly unsaturated fat and does not contain cholesterol; the content of linoleic acid can reach 70%, and the sunflower seeds have the function of preventing diseases such as anemia and the like due to abundant microelements such as iron, zinc, potassium, magnesium and the like. Besides being rich in unsaturated fatty acid, the sunflower seeds also contain various vitamins, folic acid, iron, potassium, zinc and other nutrient components necessary for human body.
Grape seeds: is seed of Vitis vinifera L.of Vitaceae, and contains low molecular weight procyanidin as main active ingredient. The grape seed extract is a novel high-efficiency natural antioxidant substance which can not be synthesized in a human body and is extracted from grape seeds. The antioxidant and free radical scavenging agent is a substance which is found in nature and has the strongest capacity of resisting oxidation and scavenging free radicals, the antioxidant activity of the antioxidant and free radical scavenging agent is 50 times that of vitamin E and 20 times that of vitamin C, the antioxidant and free radical scavenging agent can effectively scavenge redundant free radicals in a human body, and the antioxidant and free radical scavenging agent has the superstrong functions of delaying senility and enhancing immunity. Resisting oxidation, resisting allergy, relieving fatigue, improving body condition, improving sub-health state, delaying aging, and improving dysphoria, irritability, dizziness, asthenia, and hypomnesis. Is a natural sun-shading material, and can prevent ultraviolet rays from invading skin.
Sweet almond: the semen Pruni Armeniacae is dried seed with sweet taste of part of apricot or wild apricot belonging to Rosaceae. It contains abundant proteins and fatty oils, the main fatty acids are oleic acid and linoleic acid, and it also contains sugar and trace amount of amygdalin. Sweet taste, mild nature, and has effects of moistening lung dryness, relieving cough and asthma, and loosening bowel to relieve constipation. The sweet almond has the beautifying effect and can promote skin microcirculation and make skin ruddy and glossy.
Tea leaf: brownish yellow, yellowish or greenish. The components include tea polyphenols (GTP), caffeine, aromatic oil, water, minerals, pigment, carbohydrate, protein, amino acids, vitamins, etc. Tea Polyphenols (GTP) are the main component of Green Tea, accounting for about 30% of dry matter, and GTP is extracted from Tea leaves leftovers (Tea dust, Tea leaves, old and coarse Tea or trimmed leaves). The original structure of GTP is retained because the extraction is carried out only by food-grade ethyl acetate, and the product is light yellow powder. The main components of the composition comprise catechin, which accounts for 60-80% of the total weight of GTP, and the composition comprises 4-6% of epicatechin (L-EC), 6-8% of gallocatechin (D.L-EC), 10-15% of epigallocatechin (L-EGC), 50-60% of epigallocatechin gallate (L-ECG) and 8-10% of caffeine. The GTP structure is rich in phenolic hydroxyl, active hydrogen can be provided to inactivate free radicals, and free radicals formed by oxidation have higher stability due to the catechol structure. Thus, GTP has the effects of scavenging free radicals and inhibiting lipid peroxidation.
Walnut kernel: walnut (the name of latin science, junglans regia l.) is commonly called walnut. The walnut is rich in nutrition, and contains rich protein, fat, minerals and vitamins. The walnut kernel contains linoleic acid, calcium, phosphorus and iron, is an ideal skin beautifying agent for human bodies, and has the functions of moistening skin, blackening beard and hair and preventing premature whitening and shedding of hair after being eaten frequently. The walnut kernel also contains various trace elements required by human bodies, is an important auxiliary material of Chinese patent medicine, and has the functions of guiding qi downward, enriching blood, relieving cough, reducing phlegm, moistening lung, tonifying kidney and the like. As long as the fatty acid in the walnut is linoleic acid, the walnut is essential fatty acid of a human body and is an ideal skin cosmetic agent for the human body. The walnut contains abundant vitamin B group and vitamin E, and has effects of cell aging, nourishing brain, improving memory and delaying aging.
And (3) ginkgo seeds: antibacterial, disease preventing, cough relieving, waterlogging preventing, insect inhibiting, serum cholesterol reducing, and coronary artery dilating. The flavone component contained in folium Ginkgo can inhibit the formation and deposition of pigment in dermis layer, and has effects of whitening skin and preventing and treating pigment plaque. Besides flavone, trace elements such as zinc, manganese, molybdenum and the like in the ginkgo leaves can also eliminate oxygen free radicals and inhibit the growth of melanin. The flavonoid glycoside and flavonol in folium Ginkgo are free radical scavenger, and can protect dermal layer cells, improve blood circulation, and prevent cells from being oxidized to generate wrinkles. In the process of protecting cells, particularly brain cells, ginkgo biloba plays multiple roles. First, it promotes blood circulation, as well as oxygen and glucose transport to the cells; second, ginkgo biloba protects cells from damage when free radicals threaten the cells and scavenges free radicals out of the body.
Aloe leaves: is perennial evergreen herb of Monocotyledoneae, Africaceae (also known as helioorchid family, Monostroma family) and Aloe genus. Also known as aloe vera. The mucus (protein) in aloe is the core component of polysaccharides such as arboran A Baloe mannasetin, and is an important component for preventing cell aging and treating chronic allergy. It is also effective for hair, and can keep hair moist and smooth and prevent alopecia.
Henna: impatiens balsamina L (academic name: Impatiens balsamina L.): henna. Chemical components: the flowers contain various Anthocyanins (Anthocyanins) from which Cyanidin (Cyanidin), Delphinidin (Delphinidin), Pelargonidin (Pelargonidin) and malvidin (Malvi-din) are separated. It also contains Kaempferol (Kaempferol), Quercetin (Quercetin), and a naphthoquinone component (such as Lawsone). Has antiallergic and antibacterial effects. Seed: anti-fertility, antibacterial and anti-allergy.
Polygonum multiflorum: polygonum multiflorum (known as Fallopia multiflora (Thunb.) Harald.) contains anthraquinone compounds, mainly emodin, chrysophanol and physcion, rhein and chrysophanol anthrone. Radix Polygoni Multiflori has effects in tonifying blood and essence, blackening hair and beard, strengthening tendons and bones, and nourishing liver and kidney.
Red ganoderma lucidum: red Ganoderma lucidum is also known as Dan Zhi, neutral in nature. The ganoderma lucidum is bitter and nontoxic in flavor, contains rich protein, 17 amino acids and organic germanium. In addition, the health food contains saccharides, vitamin B1, vitamin E, vitamin C, alkaloids, dietary fiber, enzymes, steroids, triterpenes, resin, volatile oil, mannitol, stearic acid, fumaric acid, benzoic acid, etc.
Chastetree fruit: the fruit and leaf of Simpleleaf Shrub Chastetree contain volatile oil, main components are camphene and pinene, and contain trace alkaloid and vitamin A; the fruit also contains vitexin, i.e. casticin. The Vitex agnus-castus fruit contains a small amount (0.01%) of Vitex agnus-castus fruit alkali. The Manchu fructus extract has effects of dispelling pathogenic wind and heat, tranquilizing mind, and relieving pain; the book Ben Cao Jing Ji Zhu: "alopecia predominates".
Ginseng: (Panax ginseng C.A. Mey) is a perennial herbaceous plant. The ginseng stem and leaf extract mainly contains various ginsenoside monomers, mainly including Rb1, Rb2, Rd, Rc, Re, Ro, Re, Rf, Rg1, Rg2, Rg3, Rh1, Rh2, etc. Also contains small amount of beta-sitosterol, kaempferol, trifolioside, ginsenosides and luteolin glucoside. The total content of ginsenoside is generally 80-90%. The total ginsenoside is extracted from root, stem and leaf of Panax ginseng C.A. Meyer of Araliaceae, is rich in eighteen ginsenoside monomer, and is soluble in water at 80 deg.C and ethanol. Has cold and heat stress resisting effect. Meanwhile, the product has the effects of enhancing the activity of human surface cells, inhibiting aging and the like.
And (3) gardenia fruit: gardenia kernel, a medicinal material, is the fruit of Gardenia jasminoides Ellis (Gardenia jasminoides Ellis) belonging to Rubiaceae. The gardenia is cold in nature and bitter in taste, and the gardenia fruit extract has the effects of clearing heat and relieving restlessness and can effectively remove heat toxin in human bodies; it contains geniposide, and the obtained substance has tranquilizing effect.
According to the invention, the antioxidant plant composition and the proportion thereof, and the hair-care and color-protection plant composition and the proportion thereof are respectively optimized, and the compound combination is carried out after the respective optimization is finished, so that the synergistic effect is achieved, the antioxidant hair conditioner can effectively and effectively resist oxidation, remove hair free radicals, prevent hair sunburn, simultaneously can supplement hair and scalp nutrition, promote scalp and hair health, maintain the natural color of the hair, and effectively slow down the color fading of the dyed hair.
As a preferred embodiment of the UV-light-protecting, color-protecting and hair-protecting plant composition of the present invention,
the invention adopts the ultraviolet light protection and color protection hair care plant composition. The ultraviolet light protection plant composition comprises the following components: grape seeds, tea leaves, ginkgo seeds and aloe leaves, which are sequentially prepared from the following components in percentage by weight: grape seeds: tea leaf: and (3) ginkgo seeds: aloe leaves = 2-20: 2-10: 5-10: 2-8; the hair care and color protection plant composition comprises the following components: comprises the following components: sunflower seeds, sweet almond, walnut seeds, henna flowers, polygonum multiflorum roots, red ganoderma lucidum, fructus viticis, ginseng roots and gardenia fruits, wherein the weight ratio is as follows in sequence: sunflower seeds: sweet almond: walnut seeds: henna flower: root of Polygonum multiflorum Thunb: red ganoderma lucidum: chastetree fruit: ginseng root: 2-20: 1-5: 2-5: 1-3: 2-6: 2-8: 1-4.
The plant extracts are compounded according to the proportion, so that the plant extracts can mutually promote to achieve effective antioxidation, remove hair free radicals, prevent hair sunburn, supplement hair and scalp nutrition, promote scalp and hair health, keep hair natural color and effectively slow down fading of dyed hair.
As a preferred embodiment of the uv-protective, color-protecting hair-care plant composition of the present invention, the uv-protective plant composition preferably comprises the following components: grape seeds, tea leaves, ginkgo seeds and aloe leaves, which are sequentially prepared from the following components in percentage by weight: grape seeds: tea leaf: and (3) ginkgo seeds: aloe leaves = 7-14: 2-7: 7-10: 4-6; the hair care and color protection plant composition preferably comprises the following components: comprises the following components: sunflower seeds, sweet almond, walnut seeds, henna flowers, polygonum multiflorum roots, red ganoderma lucidum, fructus viticis, ginseng roots and gardenia fruits, wherein the weight ratio is as follows in sequence: sunflower seeds: sweet almond: walnut seeds: henna flower: root of Polygonum multiflorum Thunb: red ganoderma lucidum: chastetree fruit: ginseng root: and (3) preparing gardenia fruit with the weight ratio of 8-15: 3: 4: 2: 4: 3: 4: 6: 2.
Particularly, when the plant extracts are compounded according to the proportion, the plant extracts are effective in resisting oxidation, removing free radicals of hair, supplementing nutrition to the hair, slowing down color fading after dyeing, and have better effects on ultraviolet protection, hair care and color protection.
Preferably, the sunflower seeds, the grape seeds, the sweet almonds, the tea leaves, the walnut seeds, the ginkgo seeds, the aloe leaves, the henna flowers, the polygonum multiflorum roots, the red ganoderma lucidum, the fructus viticis, the ginseng roots and the gardenia fruits sequentially comprise the following components in percentage by weight: sunflower seeds: grape seeds: sweet almond: tea leaf: walnut seeds: and (3) ginkgo seeds: aloe leaves: henna flower: root of Polygonum multiflorum Thunb: red ganoderma lucidum: chastetree fruit: ginseng root: gardenia fruit 12: 10: 3: 5: 4: 8: 5: 2: 4: 3: 4: 6: 2.
through a large amount of experimental researches of the inventor of the application, the plant extracts are found to achieve the best ultraviolet light protection, color protection and hair care effects on hair when being compounded according to the proportion.
The invention also provides application of the ultraviolet light protection and color protection hair care plant composition in preparing hair care and cleaning products. The application of any one of the compositions in the preparation of hair care products also belongs to the protection scope of the invention.
In addition, the invention relates to application of the ultraviolet light protection and color protection plant composition in hair care and cleaning products. The hair care and cleaning product comprises hair care liquid, shampoo and hair dye, and can also comprise other products besides the hair care and cleaning product.
Wherein the ultraviolet light protection and color protection hair care plant composition accounts for 0.1-30 wt% of the hair care and cleaning product.
The invention relates to a hair care liquid product containing an ultraviolet light protection and color protection plant composition, which comprises the following components in percentage by weight:
0.5-20% of ultraviolet light protection, color protection and hair care plant composition,
0.1 to 0.4 percent of essence,
0.01 to 0.2 percent of citric acid,
0.05 to 0.4 percent of preservative
Balance of deionized water
The shampoo comprises ultraviolet light protection and color protection plant composition, and further comprises 0.5-10% of conditioner, 1-6% of thickening agent, 0.1-1.0% of aromatic, 10-30% of surfactant, 0.2-1% of buffering agent, 0.1-0.5% of preservative and the balance of deionized water.
The shampoo comprises the following components in percentage by weight:
10.0 to 30 percent of sodium laureth sulfate;
1.0-10.0% of cocamidopropyl betaine;
1.0-5.0% of polydimethylsiloxane;
0.5-3.0% of cocamide MEA;
0.5 to 5.0 percent of lauroyl wheat amino acid potassium;
guar hydroxypropyl trimethyl ammonium chloride 0.05-0.6%;
polyquaternium-470.5-1.0%;
100.1 to 0.4 percent of polyquaternium;
0.1 to 1 percent of fructo-oligosaccharide;
0.1-1% of cetearyl alcohol;
0.1 to 1.0 percent of bis-aminopropyl polydimethylsiloxane;
0.1 to 0.9 percent of sodium citrate;
0.01 to 0.5 percent of citric acid;
0.1 to 3.0 percent of sodium chloride;
the invention relates to 0.5 to 5 percent of plant composition for ultraviolet light protection, color protection and hair protection;
0.01 to 1.0 percent of preservative;
0.1-2.0% of aromatic;
balance of deionized water
A hair dye product comprises an ultraviolet light protection and color protection plant composition, and comprises the following components in percentage by weight:
the dye comprises the following components in percentage by weight:
2.00 to 10.00 percent of ammonium hydroxide;
cetostearyl alcohol 6.00-10.00%;
2.00 to 5.00 percent of propylene glycol;
1.50 to 3.00 percent of stearyl trimethyl ammonium chloride;
1.00-4.00% of glycerol stearate;
ceteareth-201.00-4.00%;
1.00-4.00% of mineral oil;
0.05 to 2.00 percent of polydimethylsiloxane;
0.20 to 1.20 percent of essence;
hydrolyzed wheat protein 0.10-1.50%;
0.30 to 0.50 percent of sodium sulfite;
0.30 to 1.00 percent of antioxidant;
0.10-0.30% of EDTA disodium;
0.50 to 5.00 percent of colorant;
0.50-5.00% of plant composition for ultraviolet protection and color protection;
the balance of water;
the oxidant comprises the following components in percentage by weight:
12.00 to 18.00 percent of hydrogen peroxide;
cetostearyl alcohol 2.00-6.00%;
2.00 to 5.00 percent of propylene glycol;
ceteareth-201.00-10.00%;
1.00-4.00% of mineral oil;
1.00-4.00% of glycerol stearate;
0.20 to 1.20 percent of phosphoric acid;
0.10-0.30% of EDTA disodium;
0.02-0.2% of disodium hydrogen phosphate;
the balance of water.
The invention provides a preparation method of an ultraviolet light protection, color protection and hair care plant composition, which comprises the following steps:
1) cleaning sunflower seeds, grape seeds, sweet almond, tea leaves, walnut seeds, ginkgo seeds, aloe leaves, henna flowers, polygonum multiflorum roots, red lucid ganoderma, fructus viticis, ginseng roots and gardenia fruits by using deionized water respectively, and placing in an oven for drying;
2) pulverizing the above dried plants respectively with a traditional Chinese medicine pulverizer to fine powder, sieving with 60 mesh sieve, weighing and mixing at a certain proportion to obtain ultraviolet light-protecting and color-protecting plant composition dry powder;
3) taking 0.5kg of the dry powder of the composition, adding 5L of water into an extraction device, heating to 95 ℃, carrying out condensation reflux for 4h, carrying out reduced pressure concentration to 1kg of concentrated solution, adding 3 times of 95% ethanol while stirring, carrying out condensation reflux for 2h at 80 ℃, filtering, standing for 24h, taking standing solution, carrying out reduced pressure concentration to 0.3kg, thus obtaining the ultraviolet light protection and color protection hair care plant composition, storing at-5 ℃ for later use, and recovering to room temperature before use.
Description of the preferred embodiments
The present invention is further described in detail below with reference to specific examples, which are provided for illustration only and are not intended to limit the scope of the present invention. The test methods used in the following examples are all conventional methods unless otherwise specified; the materials, reagents and the like used are, unless otherwise specified, commercially available reagents and materials.
The raw materials in the following examples are all commercially available general-purpose materials unless otherwise specified.
Example 1:
the ultraviolet light protection, color protection and hair care plant composition comprises the following components in parts by weight: sunflower seeds: grape seeds: sweet almond: tea leaf: walnut seeds: and (3) ginkgo seeds: aloe leaves: henna flower: root of Polygonum multiflorum Thunb: red ganoderma lucidum: chastetree fruit: ginseng root: gardenia fruit 12: 10: 3: 5: 4: 8: 5: 2: 4: 3: 4: 6: 2.
the components are prepared by the preparation method of the ultraviolet light protection, color protection and hair care plant composition: the method comprises the following steps:
1) cleaning sunflower seeds, grape seeds, sweet almond, tea leaves, walnut seeds, ginkgo seeds, aloe leaves, henna flowers, polygonum multiflorum roots, red lucid ganoderma, fructus viticis, ginseng roots and gardenia fruits by using deionized water respectively, and placing in an oven for drying;
2) pulverizing the above dried plants respectively with a traditional Chinese medicine pulverizer to fine powder, sieving with 60 mesh sieve, weighing and mixing at a certain proportion to obtain ultraviolet light-protecting and color-protecting plant composition dry powder;
3) taking 0.5kg of the dry powder of the composition, adding 5L of water into an extraction device, heating to 95 ℃, carrying out condensation reflux for 4h, carrying out reduced pressure concentration to 1kg of concentrated solution, adding 3 times of 95% ethanol while stirring, carrying out condensation reflux for 2h at 80 ℃, filtering, standing for 24h, taking standing solution, carrying out reduced pressure concentration to 0.3kg, thus obtaining the ultraviolet light protection and color protection hair care plant composition, storing at-5 ℃ for later use, and recovering to room temperature before use.
The ultraviolet light protection, color protection and hair care plant composition is applied to hair care liquid products.
The hair care solution comprises the following components in percentage by weight:
5 percent of the plant composition for ultraviolet light protection and color protection,
0.2 percent of essence,
0.01 percent of citric acid,
0.1 percent of preservative
Balance of deionized water
The preparation method of the hair care liquid product comprises the following steps:
s1, adding water into a water kettle, and adding the ultraviolet light protection, color protection and hair protection plant composition, essence, citric acid, preservative and the balance of deionized water in sequence according to a proportion and fully and uniformly stirring.
Example 2:
this example differs from example 1 only in the proportions of the uv-protective, color-protecting and hair-care plant compositions. The sunflower seeds, the grape seeds, the sweet almonds, the tea leaves, the walnut seeds, the ginkgo seeds, the aloe leaves, the henna flowers, the polygonum multiflorum roots, the red ganoderma lucidum, the fructus viticis, the ginseng roots and the gardenia fruits sequentially comprise the following components in percentage by weight: sunflower seeds: grape seeds: sweet almond: tea leaf: walnut seeds: and (3) ginkgo seeds: aloe leaves: henna flower: root of Polygonum multiflorum Thunb: red ganoderma lucidum: chastetree fruit: ginseng root: gardenia fruit 2: 1: 5: 2: 1: 2: 2: 1.
the preparation method of the ultraviolet light protection and color protection hair care plant composition is the same as that of the embodiment 1.
Example 3:
this example differs from example 1 only in the proportions of the uv-protective, color-protecting and hair-care plant compositions. The sunflower seeds, the grape seeds, the sweet almonds, the tea leaves, the walnut seeds, the ginkgo seeds, the aloe leaves, the henna flowers, the polygonum multiflorum roots, the red ganoderma lucidum, the fructus viticis, the ginseng roots and the gardenia fruits sequentially comprise the following components in percentage by weight: sunflower seeds: grape seeds: sweet almond: tea leaf: walnut seeds: and (3) ginkgo seeds: aloe leaves: henna flower: root of Polygonum multiflorum Thunb: red ganoderma lucidum: chastetree fruit: ginseng root: gardenia fruit 20: 5: 10: 8: 5: 3: 6: 8: 4.
the preparation method of the ultraviolet light protection and color protection hair care plant composition is the same as that of the embodiment 1.
Example 4:
this example differs from example 1 only in the proportions of the uv-protective, color-protecting and hair-care plant compositions. The sunflower seeds, the grape seeds, the sweet almonds, the tea leaves, the walnut seeds, the ginkgo seeds, the aloe leaves, the henna flowers, the polygonum multiflorum roots, the red ganoderma lucidum, the fructus viticis, the ginseng roots and the gardenia fruits sequentially comprise the following components in percentage by weight: sunflower seeds: grape seeds: sweet almond: tea leaf: walnut seeds: and (3) ginkgo seeds: aloe leaves: henna flower: root of Polygonum multiflorum Thunb: red ganoderma lucidum: chastetree fruit: ginseng root: gardenia fruit 8: 7: 3: 2: 4: 7: 4: 2: 4: 3: 4: 6: 2.
the preparation method of the ultraviolet light protection and color protection hair care plant composition is the same as that of the embodiment 1.
Example 5:
this example differs from example 1 only in the proportions of the uv-protective, color-protecting and hair-care plant compositions. The sunflower seeds, the grape seeds, the sweet almonds, the tea leaves, the walnut seeds, the ginkgo seeds, the aloe leaves, the henna flowers, the polygonum multiflorum roots, the red ganoderma lucidum, the fructus viticis, the ginseng roots and the gardenia fruits sequentially comprise the following components in percentage by weight: sunflower seeds: grape seeds: sweet almond: tea leaf: walnut seeds: and (3) ginkgo seeds: aloe leaves: henna flower: root of Polygonum multiflorum Thunb: red ganoderma lucidum: chastetree fruit: ginseng root: gardenia fruit 15: 14: 3: 7: 4: 10: 6: 2: 4: 3: 4: 6: 2.
the preparation method of the ultraviolet light protection and color protection hair care plant composition is the same as that of the embodiment 1.
Example 6
The difference between this example and example 1 is only that the weight percentage of the uv-protective, color-protecting, and hair-protecting plant composition added to the hair care and cleansing product is different, and the amount of the uv-protective, color-protecting, and hair-protecting plant composition added in this example is 0.1%.
Example 7
The difference between this example and example 1 is only that the weight percentage of the uv-protective, color-protecting, and hair-protecting plant composition added to the hair care and cleansing product is different, and the amount of the uv-protective, color-protecting, and hair-protecting plant composition added in this example is 8%.
Example 8
The difference between this example and example 1 is that the weight percentage of the uv-protective, color-protecting, and hair-protecting plant composition added to the hair care and cleansing product is different, and the amount of the uv-protective, color-protecting, and hair-protecting plant composition added in this example is 18%.
Example 9
The difference between this example and example 1 is only that the weight percentage of the uv-protective, color-protecting, and hair-protecting plant composition added to the hair care and cleansing product is different, and the amount of the uv-protective, color-protecting, and hair-protecting plant composition added in this example is 30%.
Comparative example 1
This comparative example differs from example 1 only in the plant composition and the proportions. The ultraviolet light protection plant composition comprises the following components: grape seeds, tea leaves, ginkgo seeds and aloe leaves, which are sequentially prepared from the following components in percentage by weight: grape seeds: tea leaf: and (3) ginkgo seeds: aloe leaves = 2: 2: 5: 2
The preparation method and the product application of the ultraviolet light protection and color protection hair care plant composition of the comparative example are the same as those of the example 1.
Comparative example 2
This comparative example differs from example 1 only in the plant composition and the proportions. The ultraviolet light protection plant composition comprises the following components: grape seeds, tea leaves, ginkgo seeds and aloe leaves, which are sequentially prepared from the following components in percentage by weight: grape seeds: tea leaf: and (3) ginkgo seeds: aloe leaves = 20: 10: 8
The preparation method and the product application of the ultraviolet light protection and color protection hair care plant composition of the comparative example are the same as those of the example 1.
Comparative example 3
This comparative example differs from example 1 only in the plant composition and the proportions. The ultraviolet light protection plant composition comprises the following components: grape seeds, tea leaves, ginkgo seeds and aloe leaves, which are sequentially prepared from the following components in percentage by weight: grape seeds: tea leaf: and (3) ginkgo seeds: aloe leaves = 7: 2: 7: 4
The preparation method and the product application of the ultraviolet light protection and color protection hair care plant composition of the comparative example are the same as those of the example 1.
Comparative example 4
This comparative example differs from example 1 only in the plant composition and the proportions. The ultraviolet light protection plant composition comprises the following components: grape seeds, tea leaves, ginkgo seeds and aloe leaves, which are sequentially prepared from the following components in percentage by weight: grape seeds: tea leaf: and (3) ginkgo seeds: aloe leaves = 14: 7: 10: 6
The preparation method and the product application of the ultraviolet light protection and color protection hair care plant composition of the comparative example are the same as those of the example 1.
Comparative example 5
This comparative example differs from example 1 only in the plant composition and the proportions. The ultraviolet light protection plant composition comprises the following components: grape seeds, tea leaves, ginkgo seeds and aloe leaves, which are sequentially prepared from the following components in percentage by weight: grape seeds: tea leaf: and (3) ginkgo seeds: aloe leaf = 10: 5: 8: 5
The preparation method and the product application of the ultraviolet light protection and color protection hair care plant composition of the comparative example are the same as those of the example 1.
Comparative example 6
This comparative example differs from example 1 only in the plant composition and the proportions. The hair care and color protection plant composition comprises the following components: comprises the following components: sunflower seeds, sweet almond, walnut seeds, henna flowers, polygonum multiflorum roots, red ganoderma lucidum, fructus viticis, ginseng roots and gardenia fruits, wherein the weight ratio is as follows in sequence: sunflower seeds: sweet almond: walnut seeds: henna flower: root of Polygonum multiflorum Thunb: red ganoderma lucidum: chastetree fruit: ginseng root: 2, 2: 1: 2: 2: 1.
The preparation method and the product application of the ultraviolet light protection and color protection hair care plant composition of the comparative example are the same as those of the example 1.
Comparative example 7
This comparative example differs from example 1 only in the plant composition and the proportions. The hair care and color protection plant composition comprises the following components: comprises the following components: sunflower seeds, sweet almond, walnut seeds, henna flowers, polygonum multiflorum roots, red ganoderma lucidum, fructus viticis, ginseng roots and gardenia fruits, wherein the weight ratio is as follows in sequence: sunflower seeds: sweet almond: walnut seeds: henna flower: root of Polygonum multiflorum Thunb: red ganoderma lucidum: chastetree fruit: ginseng root: the weight ratio of gardenia fruit is 20: 5: 3: 6: 8: 4.
The preparation method and the product application of the ultraviolet light protection and color protection hair care plant composition of the comparative example are the same as those of the example 1.
Comparative example 8
This comparative example differs from example 1 only in the plant composition and the proportions. The hair care and color protection plant composition comprises the following components: comprises the following components: sunflower seeds, sweet almond, walnut seeds, henna flowers, polygonum multiflorum roots, red ganoderma lucidum, fructus viticis, ginseng roots and gardenia fruits, wherein the weight ratio is as follows in sequence: sunflower seeds: sweet almond: walnut seeds: henna flower: root of Polygonum multiflorum Thunb: red ganoderma lucidum: chastetree fruit: ginseng root: gardenia fruit 8: 3: 4: 2: 4: 3: 4: 6: 2.
The preparation method and the product application of the ultraviolet light protection and color protection hair care plant composition of the comparative example are the same as those of the example 1.
Comparative example 9
This comparative example differs from example 1 only in the plant composition and the proportions. The hair care and color protection plant composition comprises the following components: comprises the following components: sunflower seeds, sweet almond, walnut seeds, henna flowers, polygonum multiflorum roots, red ganoderma lucidum, fructus viticis, ginseng roots and gardenia fruits, wherein the weight ratio is as follows in sequence: sunflower seeds: sweet almond: walnut seeds: henna flower: root of Polygonum multiflorum Thunb: red ganoderma lucidum: chastetree fruit: ginseng root: gardenia fruit 15: 3: 4: 2: 4: 3: 4: 6: 2.
The preparation method and the product application of the ultraviolet light protection and color protection hair care plant composition of the comparative example are the same as those of the example 1.
Comparative example 10
This comparative example differs from example 1 only in the plant composition and the proportions. The hair care and color protection plant composition comprises the following components: comprises the following components: sunflower seeds, sweet almond, walnut seeds, henna flowers, polygonum multiflorum roots, red ganoderma lucidum, fructus viticis, ginseng roots and gardenia fruits, wherein the weight ratio is as follows in sequence: sunflower seeds: sweet almond: walnut seeds: henna flower: root of Polygonum multiflorum Thunb: red ganoderma lucidum: chastetree fruit: ginseng root: gardenia fruit 12: 3: 4: 2: 4: 3: 4: 6: 2.
The preparation method and the product application of the ultraviolet light protection and color protection hair care plant composition of the comparative example are the same as those of the example 1.
Comparative example 11
The comparative example is different from example 1 only in the weight percentage of the ultraviolet light protection and color protection plant composition in the hair care and cleaning product, and the addition amount of the ultraviolet light protection and color protection plant composition in the example is 0.05%.
Comparative example 12
The comparative example is different from example 1 only in the weight percentage of the ultraviolet light protection and color protection plant composition in the hair care and cleaning product, and the addition amount of the ultraviolet light protection and color protection plant composition in the example is 30.5%.
Example 10:
the present embodiment is different from embodiment 1 in that: the ultraviolet light protection and color protection hair care plant composition is applied to hair care liquids, and accounts for different added weight percentages, and the adding amount of the ultraviolet light protection and color protection hair care plant composition is increased from 5% to 10%.
Example 11:
the difference between this example and example 1 is that the content of the uv-protective, color-protecting, and hair-protecting plant composition added to the hair care solution is different, and the addition amount of the uv-protective, color-protecting, and hair-protecting plant composition in this example is increased from 5% to 15%.
Comparative example 13
The comparative example differs from example 1 only in that the plant composition for protecting and protecting color and hair, which does not contain ultraviolet light, comprises the following components in percentage by weight: 0.2% of essence, 0.01% of citric acid, 0.1% of preservative and the balance of deionized water.
Preparation method of Hair Care solution of this comparative example
S1, adding water into a water kettle, sequentially adding essence, citric acid, preservative and the balance of deionized water according to a proportion, and fully and uniformly stirring.
Example 12:
the difference between this example and example 1 is that the uv-protective, color-protecting and hair-protecting botanical composition is applied to a shampoo product, and the preparation method and usage amount of the product are different.
The shampoo product comprises the following components in percentage by weight:
20% of sodium laureth sulfate;
cocamidopropyl betaine 5%;
3.0% of polydimethylsiloxane;
1.5% of cocamide MEA;
3.5 percent of lauroyl wheat amino acid potassium;
guar hydroxypropyl trimethyl ammonium chloride 0.3%;
polyquaternium-470.5%;
100.3 percent of polyquaternium;
0.5 percent of fructo-oligosaccharide;
cetostearyl alcohol 0.5%;
0.5 percent of bis-aminopropyl polydimethylsiloxane;
0.5 percent of sodium citrate;
0.6 percent of citric acid;
0.6 percent of sodium chloride;
the invention relates to 1.0 percent of plant composition for ultraviolet light protection, color protection and hair protection;
0.4% of preservative;
0.5% of aromatic;
balance of deionized water
The preparation method of the shampoo comprises the following steps:
s1, adding deionized water into a reaction kettle, adding polyquaternium-10, and stirring until the polyquaternium-10 is dissolved uniformly; adding sodium laureth sulfate, stirring thoroughly, dispersing, adding guar gum hydroxypropyl trimethyl ammonium chloride, stirring at constant speed for 3-5min, and heating;
s2, heating to 70-75 ℃, respectively and sequentially adding cetearyl alcohol, cocamide MEA, sodium citrate, citric acid, sodium chloride and other high-temperature dissolving raw materials, continuously heating to 80-85 ℃, and keeping the temperature and stirring for at least 20 minutes until the raw materials are fully dissolved and uniformly dispersed;
s3, starting to cool, cooling to 70-75 ℃, respectively and sequentially adding surface active raw materials such as cocamidopropyl betaine, lauroyl wheat amino acid potassium and the like, uniformly dispersing, and continuously cooling;
s4, cooling to 45-50 ℃, respectively and sequentially adding polydimethylsiloxane, polyquaternium-47, fructo-oligosaccharide, bis-aminopropyl polydimethylsiloxane, preservative, aromatic, the balance of deionized water and the like, and uniformly stirring;
s5, continuously cooling to 40 ℃, adding the ultraviolet light protection and color protection and hair care plant composition, and uniformly stirring.
The preparation method of the ultraviolet light protection and color protection hair care plant composition is the same as the preparation method of the ultraviolet light protection and color protection hair care plant composition in the embodiment 1.
Example 13:
the present embodiment is different from embodiment 8 in that: the ultraviolet light protection and color protection hair care plant composition is applied to shampoo, and accounts for different added weight percentages, and the adding amount of the ultraviolet light protection and color protection hair care plant composition is increased from 1% to 3%.
Example 14:
the difference between this example and example 8 is that the content of the uv-protective, color-protecting and hair-protecting botanical composition in the shampoo is different, and the addition amount of the uv-protective, color-protecting and hair-protecting botanical composition in this example is increased from 1% to 5%.
Comparative example 14:
the comparative example differs from example 8 only in that the plant composition for protecting and protecting color and hair without ultraviolet light protection comprises the following components in percentage by weight:
the shampoo product comprises the following components in percentage by weight:
20% of sodium laureth sulfate;
cocamidopropyl betaine 5%;
3.0% of polydimethylsiloxane;
1.5% of cocamide MEA;
3.5 percent of lauroyl wheat amino acid potassium;
guar hydroxypropyl trimethyl ammonium chloride 0.3%;
polyquaternium-470.5%;
100.3 percent of polyquaternium;
0.5 percent of fructo-oligosaccharide;
cetostearyl alcohol 0.5%;
0.5 percent of bis-aminopropyl polydimethylsiloxane;
0.5 percent of sodium citrate;
0.6 percent of citric acid;
0.6 percent of sodium chloride;
0.4% of preservative;
0.5% of aromatic;
balance of deionized water
The preparation method of the shampoo comprises the following steps:
s1, adding deionized water into a reaction kettle, adding polyquaternium-10, and stirring until the polyquaternium-10 is dissolved uniformly; adding sodium laureth sulfate, stirring thoroughly, dispersing, adding guar gum hydroxypropyl trimethyl ammonium chloride, stirring at constant speed for 3-5min, and heating;
s2, heating to 70-75 ℃, respectively and sequentially adding cetearyl alcohol, cocamide MEA, sodium citrate, citric acid, sodium chloride and other high-temperature dissolving raw materials, continuously heating to 80-85 ℃, and keeping the temperature and stirring for at least 20 minutes until the raw materials are fully dissolved and uniformly dispersed;
s3, starting to cool, cooling to 70-75 ℃, respectively and sequentially adding surface active raw materials such as cocamidopropyl betaine, lauroyl wheat amino acid potassium and the like, uniformly dispersing, and continuously cooling;
s4, cooling to 45-50 ℃, respectively and sequentially adding polydimethylsiloxane, polyquaternary ammonium salt-47, fructo-oligosaccharide, bis-aminopropyl polydimethylsiloxane, preservative, aromatic and the balance of deionized water and the like, uniformly stirring, and cooling to 40 ℃;
example 15
The difference between the example and the example 1 is only that the product, the product preparation method and the usage amount of the ultraviolet light protection and color protection plant composition are different, and the ultraviolet light protection and color protection plant composition is applied to hair dye products.
The hair dye product comprises the following components in percentage by weight:
the dye comprises the following components in percentage by weight:
8.0 percent of ammonium hydroxide;
cetostearyl alcohol 8.0%;
3.0% of propylene glycol;
2.5 percent of stearyl trimethyl ammonium chloride;
2% of glycerol stearate;
ceteareth-203%;
3% of mineral oil;
0.5% of polydimethylsiloxane;
0.6 percent of essence;
hydrolyzed wheat protein 1%;
0.4 percent of sodium sulfite;
0.7 percent of antioxidant;
0.2% of EDTA disodium;
3% of a coloring agent;
0.50% of plant composition for ultraviolet protection, color protection and hair care;
the balance of water;
the oxidant comprises the following components in percentage by weight:
16% of hydrogen peroxide;
cetostearyl alcohol 4.0%;
3.0% of propylene glycol;
ceteareth-206.5%;
3.0% of mineral oil;
2.5% of glycerol stearate;
0.8 percent of phosphoric acid;
0.2% of EDTA disodium;
0.05 percent of disodium hydrogen phosphate;
the balance of water.
The preparation method of the hair dye comprises the following steps:
s1, preparing a dye, which comprises the following steps:
1) mixing: mixing cetostearyl alcohol, glyceryl stearate, cetostearyl polyether-20, mineral oil and polydimethylsiloxane to form an oil agent, and mixing water, propylene glycol, stearyl trimethyl ammonium chloride, sodium sulfite and disodium EDTA to form an aqueous agent;
2) emulsification: respectively heating and dissolving the oil agent and the water agent, slowly adding the water agent into the oil agent under stirring after the heating temperature is 80-85 ℃, emulsifying, and homogenizing for 5 minutes.
3) And (3) cooling: after preserving the heat for 20 minutes, cooling the mixture to 60 ℃ by using a cooling water jacket;
4) dissolving: adding colorant, ultraviolet light-protecting, color-protecting and hair-caring plant composition, hydrolyzed wheat protein, and antioxidant into the mixture cooled to 60 deg.C in step 3), dissolving, cooling to 45 deg.C
5) Mixing: and 4) adding ammonium hydroxide and essence into the mixture cooled to 45 ℃ in the step 4), and uniformly stirring.
6) And (4) checking: sampling the sample obtained in the step 5) for inspection;
7) filling: and discharging and filling the qualified finished product.
S2, the preparation method of the oxidant comprises the following steps:
1) mixing: mixing cetostearyl alcohol, glyceryl stearate, cetostearyl polyether-20 and mineral oil to form oil, and mixing water, propylene glycol, disodium EDTA and disodium hydrogen phosphate to form aqua;
2) emulsification: respectively heating and dissolving the oil agent and the water agent to 80-85 ℃, slowly adding the water agent into the oil agent under stirring for emulsification, and homogenizing for 5 minutes;
3) and (3) cooling: after preserving the heat for 20 minutes, cooling to 45 ℃ by a cooling water jacket;
4) mixing: adding hydrogen peroxide and phosphoric acid in the step 3), and uniformly stirring;
5) and (4) checking: taking the sample in the step 4) for inspection;
6) filling: and discharging and filling the qualified product.
The preparation method of the ultraviolet light protection and color protection hair care plant composition is the same as the preparation method of the ultraviolet light protection and color protection hair care plant composition in the embodiment 1.
Example 16:
this embodiment is different from embodiment 11 in that: the ultraviolet light protection and color protection hair care plant composition is applied to shampoo, and accounts for different added weight percentages, and the adding amount of the ultraviolet light protection and color protection hair care plant composition is increased from 0.5% to 2%.
Example 17:
this embodiment is different from embodiment 11 in that: the ultraviolet light protection and color protection hair care plant composition is applied to shampoo, and accounts for different added weight percentages, and the adding amount of the ultraviolet light protection and color protection hair care plant composition is increased from 0.5% to 4%.
Comparative example 15:
this comparative example differs from example 11 only in that the plant composition, which does not contain uv protection and which protects the color, comprises the following components in percentage by weight:
the hair dye product comprises the following components in percentage by weight:
the dye comprises the following components in percentage by weight:
8.0 percent of ammonium hydroxide;
cetostearyl alcohol 8.0%;
3.0% of propylene glycol;
2.5 percent of stearyl trimethyl ammonium chloride;
2% of glycerol stearate;
ceteareth-203%;
3% of mineral oil;
0.5% of polydimethylsiloxane;
0.6 percent of essence;
hydrolyzed wheat protein 1%;
0.4 percent of sodium sulfite;
0.7 percent of antioxidant;
0.2% of EDTA disodium;
3% of a coloring agent;
the balance of water;
the oxidant comprises the following components in percentage by weight:
16% of hydrogen peroxide;
cetostearyl alcohol 4.0%;
3.0% of propylene glycol;
ceteareth-206.5%;
3.0% of mineral oil;
2.5% of glycerol stearate;
0.8 percent of phosphoric acid;
0.2% of EDTA disodium;
0.05 percent of disodium hydrogen phosphate;
the balance of water.
The preparation method of the hair dye comprises the following steps:
s1, preparing a dye, which comprises the following steps:
1) mixing: mixing cetostearyl alcohol, glyceryl stearate, cetostearyl polyether-20, mineral oil and polydimethylsiloxane to form an oil agent, and mixing water, propylene glycol, stearyl trimethyl ammonium chloride, sodium sulfite and disodium EDTA to form an aqueous agent;
2) emulsification: respectively heating and dissolving the oil agent and the water agent, slowly adding the water agent into the oil agent under stirring after the heating temperature is 80-85 ℃, emulsifying, and homogenizing for 5 minutes.
3) And (3) cooling: after preserving the heat for 20 minutes, cooling the mixture to 60 ℃ by using a cooling water jacket;
4) dissolving: adding colorant, hydrolyzed wheat protein and antioxidant into the mixture cooled to 60 deg.C in step 3), dissolving, cooling to 45 deg.C
5) Mixing: and 4) adding ammonium hydroxide and essence into the mixture cooled to 45 ℃ in the step 4), and uniformly stirring.
6) And (4) checking: sampling the sample obtained in the step 5) for inspection;
7) filling: and discharging and filling the qualified finished product.
S2, the preparation method of the oxidant comprises the following steps:
1) mixing: mixing cetostearyl alcohol, glyceryl stearate, cetostearyl polyether-20 and mineral oil to form oil, and mixing water, propylene glycol, disodium EDTA and disodium hydrogen phosphate to form aqua;
2) emulsification: respectively heating and dissolving the oil agent and the water agent to 80-85 ℃, slowly adding the water agent into the oil agent under stirring for emulsification, and homogenizing for 5 minutes;
3) and (3) cooling: after preserving the heat for 20 minutes, cooling to 45 ℃ by a cooling water jacket;
4) mixing: adding hydrogen peroxide and phosphoric acid in the step 3), and uniformly stirring;
5) and (4) checking: taking the sample in the step 4) for inspection;
6) filling: and discharging and filling the qualified product.
7) The plant compositions described in examples 1-9 and comparative examples 1-12 were screened, compounded, and optimized through experiments.
8) Screening of ultraviolet light protection and color protection hair care plant composition
9) The ultraviolet light protection and color protection plant composition and the hair protection and color protection plant composition are preferably selected respectively, and are compounded and combined after the selection is finished, so that a synergistic effect is achieved, the ultraviolet light protection and color protection plant composition can effectively resist oxidation, remove hair free radicals, prevent hair sunburn, supplement hair and scalp nutrition, promote scalp hair health, maintain hair natural color and effectively slow down fading of dyed hair.
10) Screening principle of ultraviolet light protection and color protection hair care plant composition
11) Principle 1: the ultraviolet light protection plant composition is screened and optimized by adopting a DPPH free radical scavenging type, DPPH is a macromolecular free radical, the DPPH is purple in methanol or ethanol, An antioxidant is added, the solution color becomes light, the absorbance (An) becomes small, and the free radical scavenging capacity ESC is stronger, as shown in a formula 1. Reaction time: and (3) carrying out a light-shielding reaction on the ultraviolet-protected plant composition and DPPH at room temperature for 30min, and detecting: OD 540nm, and the change in absorbance was detected.
12) ESC = [1-An/A0 ]. 100% (N ≧ 1, N ∈ N +) formula 1
13) Principle 2: the color-protecting and hair-protecting plant composition is characterized by the effect of the change of the surface tension before and after hair treatment, and the color-protecting and hair-protecting plant composition selected in the patent can supplement nutrition for the hair so as to achieve the effect of protecting the hair and the color.
14) Test apparatus and reagents: UV-visible spectrophotometer (model: BH 1603051; manufacturer: Shanghai instruments, Inc. of Youchi); a Diastron tensiometer (hereinafter referred to as tensiometer); 1, 1-diphenyl-2-picrylhydrazino (DPPH) free radical standard, Sigma, usa; absolute ethyl alcohol (99.5%, Water ≤ 300 ppm), Michalin reagent; a test sample solution prepared by the method described in the patent; hair tie (Asian hair quality, source is the same, length 20cm, weight 5 g)
15) Preparing a test sample solution: preparing 0.1mmol/L DPPH solution with absolute ethyl alcohol, and storing in dark; the plant composition sample solutions described in examples and comparative examples were used as test sample solutions, blanks (deionized water)
16) A screening step:
17) screening and optimizing the ultraviolet light protection plant composition:
18) s1: preparing 0.1mmol/L DPPH solution with absolute ethyl alcohol, and storing in dark;
19) s2: adding 2mL of test sample solution and 2mL of 0.1mmol/L DPPH solution into the same test tube, shaking up, and standing for 30min in a dark place at room temperature;
20) s3: the absorbance An was measured at 540nm using a UV spectrophotometer, using 2ml of 0.1mmol/L DPPH solution +2ml of deionized water as the reference reagent A0.
21) Screening and optimizing a color-protecting and hair-protecting plant composition:
22) s1: taking 4 test hair bundles, wherein each hair bundle is divided into 6 parts, and each part is about 5 g;
23) s2: cleaning each hair bundle with deionized water, and naturally drying; respectively taking 10 hairs, carrying out maximum breaking tension test by using a Diastron tension meter, and recording data; the average value of the maximum breaking tension of 10 hairs is recorded as F0 value of each group;
24) s3: respectively spraying each hair bundle from hair root to hair tip by using a blank sample solution, a comparative sample solution and an example test sample solution which are prepared in advance, continuously and uniformly spraying for 5 times, combing the hair bundles uniformly by using a comb after 5 times of spraying, and naturally drying; respectively taking 10 hairs, carrying out maximum breaking tension test by using a Diastron tension meter, and recording data; the average value of the maximum breaking tension of 10 hairs is recorded as F1 value of each group;
25) s4: the above tests were repeated to ensure the authenticity of the data.
26) And (3) data statistics:
Figure 1
TABLE 1
Conclusion of the experiment
As can be seen from Table 1, the UV-light-protecting, color-protecting and hair-protecting plant compositions described in examples 1 to 9 and comparative examples 1 to 12 of the present invention were screened and optimized by the test, and the results were as follows:
c1: compared with the example 1, the screened and optimized ultraviolet light protection plant composition has good effects on scavenging free radicals and resisting oxidation and has insignificant effect on fracture tension resistance, and the ultraviolet light protection plant composition is slightly enhanced in the capability of scavenging free radicals after being compounded with the color-protecting and hair-protecting plant composition;
c2: comparative examples 6-10 in comparison to example 1, the screened optimized color-protecting hair-care plant composition has significant ability to resist breaking tension and insignificant ability to scavenge free radicals through a hair bundle test, and slightly enhances the breaking tension resistance of the hair bundle through being compounded with the ultraviolet light-protecting plant composition.
C3: the ultraviolet light protection plant composition and the color protection and hair protection plant composition are respectively screened and optimized, the components and the proportions are compounded according to the screened and optimized components, the proportion optimization is carried out through the examples 2 to 5, the ultraviolet light protection plant composition and the color protection and hair protection plant composition have good effects on the free radical scavenging capacity and the color protection and hair protection after the compounding, and compared with a single effect component, the compounded plant composition has the functions of ultraviolet light protection and color protection and hair protection synergy.
C4: from the results of examples 6-9 and comparative examples 11-12, it can be seen that with the increase of the content of the ultraviolet light protection and color protection hair care plant composition, the radical scavenging ability and the anti-breaking tension ability are increased, and when the addition amount of the ultraviolet light protection and color protection hair care plant composition is less than 0.1%, the radical scavenging ability and the anti-breaking tension ability are poor; when the addition amount of the ultraviolet light protection and color protection hair care plant composition is more than 30 percent, the free radical scavenging capacity and the anti-fracture tension capacity are poor; when the addition amount of the ultraviolet light protection and color protection hair care plant composition is 0.1-30%, the free radical scavenging capacity and the anti-fracture tension capacity are stronger; therefore, when the addition amount of the ultraviolet light protection and color protection hair care plant composition is 0.1-30%, the ultraviolet light protection, color protection and hair care effects of the plant composition are obvious.
The product application tests of the above example 1, examples 10 to 17 and comparative examples 13 to 15 were carried out, and the specific conditions were as follows:
the test principle is as follows: 1. ultraviolet light resistance (sun protection) and hair care repair test principle: the nature of hair damage is that the structure and components of the hair are damaged, and conditions such as perming, combing and stretching damage can cause hair damage, most notably the loss of hair keratin. Degradation of amino acids by ultraviolet light results in fragmentation of the keratin structure and significant structural changes by the superficial keratinocytes. Ultraviolet and solar radiation cause the destruction of disulfide bonds, which reduces the tensile strength of the hair. Hair stretch-break tension is a common method of characterizing the degradation of hair mechanical properties, reflecting the integrity of the fiber cortex, since a decrease in fiber strength is generally caused by damage to the cortical area. The maximum breaking tension (force required for hair breaking) of normal hair before and after ultraviolet irradiation was measured with a Diastron tensiometer to compare the change in the maximum breaking tension, and the sample was evaluated for the effect of repairing damage to hair caused by ultraviolet irradiation or the like. 2. Color protection test principle: generally, the color of dyed hair gradually fades with time, shampoo, light, and the like. The test adopts a colorimeter, and the protection effect of the test sample on the dyed hair color is evaluated by measuring the change of the chromaticity value of the hair before and after the hair is irradiated by ultraviolet rays.
The main test instruments: a Diastron tensiometer (hereinafter referred to as tensiometer); minolta pedtrophotomotometer CM-2005d colorimeter (hereinafter referred to as colorimeter); hair tresses (Asian hair, same source, length 20cm, weight 5 g); atlas Weather-Ometer ES25 (ultraviolet tester).
(ii) maximum tensile test data statistics and analysis among various products
A. Scalp care liquid type hair product
Test hair tresses: the hair is derived from the hair of the same Asian, the length is about 20cm, and the weight is 25 g; normal hair quality (without any loss treatment such as bleaching, dyeing and perming)
Test samples: preparing and preparing test sample solution required by testing in advance: blank (deionized water), the comparative example 1 solution, and the test sample solutions of examples 1-3
The testing steps are as follows:
s1: taking 1 test hair bundle, and dividing into five parts, wherein each part is about 5 g;
s2: cleaning each hair bundle with deionized water, and naturally drying; respectively taking 10 hairs, carrying out maximum breaking tension test by using a Diastron tension meter, and recording data; the average value of the maximum breaking tension of 10 hairs is recorded as F0 value of each group;
s3: respectively spraying each hair bundle from the hair root to the hair tip by using a blank sample solution prepared in advance, a comparative example 13, test sample solutions of example 1 and test sample solutions of example 10-11, continuously and uniformly spraying for 5 times, combing the hair bundles uniformly by using a comb after 5 times of spraying is finished, and naturally airing; respectively taking 10 hairs, carrying out maximum breaking tension test by using a Diastron tension meter, and recording data; the average value of the maximum breaking tension of 10 hairs is recorded as F1 value of each group;
s4: after the fifth spraying treatment and natural airing, respectively placing each hair bundle under an ultraviolet lamp for irradiating for 48 hours; respectively taking 10 hair strands from each part, carrying out maximum breaking tension test by using a Diastron tension meter, and recording data; the average of the maximum breaking tension of 10 hairs was recorded as F2 values for each group.
And (3) data statistics:
Figure 886248DEST_PATH_IMAGE002
TABLE 2
Conclusion of the experiment
C1: as shown in the data of table 2, when the maximum breaking tension of the sample hair bundle using the hair care liquid product was measured, it was found from the average value of the initial maximum breaking tensions (average value of the force required for breaking the hair) F0 data that the hair quality of the five hair bundles was consistent, the hair bundles were in accordance with the sample requirements, and the test results were reliable.
C2: through analysis of statistical data of F1 and F2 of each group, the fact that F2 is smaller than F1 after the hair bundle is processed by the sample and then is processed by ultraviolet rays can indicate that the ultraviolet rays have obvious damage effect on hair; comparative example 13, example 1, examples 10-11 by comparing the data with the blank, the hair tress damage was greatest for the blank and comparative example 13 samples and the sample for example 11 was smallest;
c3: with the addition of the ultraviolet light protection and color protection hair care plant composition in the examples, the average maximum tensile strength before and after ultraviolet light irradiation treatment of the hair bundles is higher than that of the comparative example and the blank sample, and the change value of the average maximum tensile strength is lower than that of the comparative example and the blank sample, so that the ultraviolet light protection and color protection hair care plant composition has an obvious protection effect on ultraviolet light damage resistance of hair; meanwhile, as the addition of the plant composition for ultraviolet protection and color protection is increased, F1 and F2 are increased, and the change value delta F is reduced, which can show that the ultraviolet protection effect of hair strands is more obvious as the addition of the plant composition is increased.
In conclusion, the ultraviolet light protection and color protection hair care plant composition is added into the hair care liquid type hair product, so that the ultraviolet light damage resistance effect of the hair is greatly improved, the hair can effectively resist oxidation, free radicals of the hair are removed, the hair is prevented from being sunburned, and meanwhile, the hair care liquid type hair product also has an obvious repairing effect on the hair.
B. Shampoo-like hair product
Test hair tresses: the hair is derived from the hair of the same Asian, the length is about 20cm, and the weight is 25 g; normal hair quality (without any loss treatment such as bleaching, dyeing and perming)
Test samples: preparing and preparing test samples required by testing in advance: blank (deionized water), the shampoo of the comparative example 14 and the shampoo of the test samples of the examples 12 to 14
The testing steps are as follows:
s1: taking 1 test hair bundle, and dividing into five parts, wherein each part is about 5 g;
s2: cleaning each hair bundle with deionized water, and naturally drying; respectively taking 10 hairs, carrying out maximum breaking tension test by using a Diastron tension meter, and recording data; the average value of the maximum breaking tension of 10 hairs is recorded as F0 value of each group;
s3: using a blank sample solution prepared in advance, the comparative example 14 and the examples 12 to 14 respectively, normally cleaning hair bundles, naturally airing after washing, washing once every 2 days for 5 times continuously, after the 5 th time of cleaning, combing the hair bundles uniformly by using a comb, naturally airing, taking 10 hair parts respectively, performing a maximum breaking tension test by using a Diastron tension meter, and recording data; the average value of the maximum breaking tension of 10 hairs is recorded as F1 value of each group;
s4: cleaning hair bundles for 5 times, naturally airing, and respectively placing each hair bundle under an ultraviolet lamp for irradiating for 48 hours; respectively taking 10 hair strands from each part, carrying out maximum breaking tension test by using a Diastron tension meter, and recording data; the average of the maximum breaking tension of 10 hairs was recorded as F2 values for each group.
And (3) data statistics:
Figure 856740DEST_PATH_IMAGE003
TABLE 3
And (4) test conclusion:
c1: as shown in table 3, the maximum breaking tension of the hair tresses using the shampoo products was measured, and from the average value of the initial maximum breaking tensions (average value of forces required for breaking hair) F0 data, it was found that the hair qualities of five hair tresses were consistent, the hair tresses were in accordance with the sample requirements, and the test results were reliable.
C2: according to F1 and F2 data, the fact that F2 is smaller than F1 after the hair bundle is processed by the sample and then is processed by ultraviolet rays can indicate that the ultraviolet rays have a certain damage effect on the hair bundle; comparative example 14, examples 12-14 the hair tresses of the blank were the greatest, the comparative example was the next lowest, and example 14 was the lowest by comparison with the blank data;
c3: comparative example 14 comparing the data of the ordinary shampoo (without ultraviolet protection and color protection plant composition) with the blank sample (deionized water), the ordinary shampoo has slight protection effect on ultraviolet light damaged hair;
c4: with the addition of the ultraviolet light protection and color protection hair care plant composition in the examples, the average maximum tensile strength of the hair bundle before and after ultraviolet treatment is higher than that of the comparative example and the blank sample, and the change values of the average maximum tensile strength are lower than that of the comparative example and the blank sample, which indicates that the ultraviolet light protection and color protection hair care plant composition has certain effect on ultraviolet defense of the hair bundle; meanwhile, as the addition of the plant composition for protecting ultraviolet light and protecting color and hair is increased, F1 and F2 of the plant composition are increased, and the change value of delta F is reduced, which can indicate that the ultraviolet protection effect of hair strands is more obvious along with the increase of the addition of the plant composition.
The tests show that the ultraviolet light protection and color protection plant composition can effectively resist oxidation, remove free radicals of hair and prevent the hair from being sunburned by adding the ultraviolet light protection and color protection plant composition into shampoo hair cosmetic products, and greatly improves the ultraviolet light hair protection effect of the hair.
C. Hair product of hair dye type
Test hair tresses: the hair is derived from the hair of the same Asian, the length is about 20cm, and the weight is 25 g; normal hair quality (without any loss treatment such as bleaching, dyeing and perming).
Test samples: preparing and preparing test samples required by testing in advance: blank (deionized water), the comparative example 15 hair dye, and the test samples of examples 15-17 hair dye
The testing steps are as follows:
s1: taking 1 test hair bundle, and dividing into five parts, wherein each part is about 5 g;
s2: cleaning each hair bundle with deionized water, and naturally drying; respectively taking 10 hairs, carrying out maximum breaking tension test by using a Diastron tension meter, and recording data; the average value of the maximum breaking tension of 10 hairs is recorded as F0 value of each group;
s3: respectively using the four hair dye samples and the blank sample (deionized water) prepared in advance in examples 15-17 and comparative example 15, uniformly mixing the dye in the hair dye with the oxidant 1:1 for 25g, then respectively dyeing each hair strand, washing with the deionized water after dyeing, naturally drying, and cleaning the blank sample with the deionized water without dyeing; taking 10 hairs from each part, performing maximum breaking tension test by using a Diastron tension meter, and recording data; the average value of the maximum breaking tension of 10 hairs is recorded as F1 value of each group;
s4: respectively placing the hair bundles above each part under an ultraviolet lamp for irradiating for 48 h; respectively taking 10 hair strands from each part, carrying out maximum breaking tension test by using a Diastron tension meter, and recording data; the average of the maximum breaking tension of 10 hairs was recorded as F2 values for each group.
And (3) data statistics:
Figure 213772DEST_PATH_IMAGE004
TABLE 4
And (4) test conclusion:
c1: table 4 shows that the average maximum breaking tension of the hair strands using the hair cosmetic sample of hair dye type was measured, and from the average of the initial maximum breaking tensions (average of the forces required for breaking the hair) F0 data, it was found that the hair quality of five hair strands was consistent, the hair strands were in accordance with the sample requirements, and the test results were reliable.
C2: the data F0 and F1 of the blank sample, the comparative sample and the example show that the maximum breaking tension of the hair is reduced after the hair is dyed, which indicates that the hair dye has certain damage to the hair;
c3: according to F1 and F2 data, the fact that F2 is smaller than F1 after the hair bundle is processed by the sample and then is processed by ultraviolet rays can indicate that the ultraviolet rays have a certain damage effect on the hair bundle;
c4: comparative example 15, examples 15 to 17, and the blank after treatment with ultraviolet light, the Δ F change value of comparative example 3 was the largest, the hair bundle damage was the largest, and the blank sample was the next to the example sample, which was the smallest; with the addition of the UV-protective, color-protecting and hair-protecting plant compositions of examples 15-17, the average maximum tensile strength of the hair bundles before and after UV treatment was higher than that of comparative example 15, and the change values of the average maximum tensile strength were all lower than that of the comparative example, which indicates that the UV-protective, color-protecting and hair-protecting plant compositions have a certain effect on UV protection of hair bundles for hair dyeing and permanent wave;
c5: meanwhile, as the addition of the plant composition for protecting ultraviolet light and protecting color and hair is increased, F1 and F2 of the plant composition are increased, and the change value of delta F is reduced, which can indicate that the ultraviolet protection effect of hair strands is more obvious along with the increase of the addition of the plant composition. The tests show that the ultraviolet light protection and color protection hair care plant composition is added into hair dye type hair cosmetic products, so that the hair dye and perm substance can be effectively protected, the hair is prevented from being sunburned, and the ultraviolet light hair care effect of the hair dye and perm is greatly improved.
(II) statistics and analysis of colorimetric value test data in various products
A. Scalp care liquid type hair product
Test hair tresses: asian hair is from the same person, 20cm long, 25g heavy, undyed and permed, normal hair quality.
Test samples: preparing and preparing test sample solution required by testing in advance: blank (deionized water), the test sample scalp care solution of comparative example 13 and examples 1, 10-11;
the testing steps are as follows:
s1: firstly, treating the hair bundle: bleaching and dyeing the hair strands. The bleaching agent and the coloring agent used in the test are the same product purchased from a certain known brand on the market.
S2: taking 1 treated hair bundle, dividing into five parts, wherein each part is about 5 g;
s3: washing each part of hair bundle with deionized water respectively, and naturally airing; measuring the chroma value of each hair bundle by using a Minolta pedptometer CM-2005d chroma meter and recording data; averaging the three measurements and recording the average value as A0 value of each group;
s4: respectively spraying each hair bundle from the hair root to the hair tip by using a blank sample solution prepared in advance, a comparative example 13, test sample solutions of example 1 and test sample solutions of example 10-11, continuously and uniformly spraying for 5 times, combing the hair bundles uniformly by using a comb after 5 times of spraying is finished, and naturally airing; measuring the chroma value of each hair bundle by using a Minolta pedptometer CM-2005d chroma meter and recording data; averaging the three measurements and recording the average value as A1 value of each group;
s5: after the fifth spraying treatment and natural airing, respectively placing each hair bundle under an ultraviolet lamp for irradiating for 48 hours; measuring the chroma value of each hair bundle by using a Minolta pedptometer CM-2005d chroma meter and recording data; averaging the three measurements and recording the average value as A2 value of each group;
and (3) data statistics:
Figure 142676DEST_PATH_IMAGE005
TABLE 5
And (4) test conclusion:
c1: as shown in Table 5, by testing the colorimetric values of the test sample hair strands using the hair treatment liquid products, it can be seen from the initial colorimetric values A0 data that the hair quality of the five hair strands is consistent, the hair strands meet the test sample requirements, and the test results are reliable.
C2: the data of A1 and A2 show that the A2 of the hair bundle after being processed by the sample and then being processed by ultraviolet is smaller than A1, which indicates that the ultraviolet has a certain reduction effect on the color of the hair bundle;
c3: comparative example 13 and examples 1 and 10-11 the samples of blank and comparative example 13 exhibited the greatest degree of color reduction in the hair tresses and the least reduction in the color of the samples of examples by comparison with the data Δ A for the blank; in addition, as the ultraviolet light protection and color protection hair care plant composition is added in the embodiment, the colorimetric values of the hair bundle before and after ultraviolet treatment are higher than those of a comparative example and a blank sample, which can show that the ultraviolet light protection and color protection hair care plant composition has a certain protection effect on the color of the hair bundle;
c4: meanwhile, the change value of delta A is reduced along with the increase of the addition of the plant composition for ultraviolet protection and color protection, which can show that the ultraviolet protection effect of hair strands is more obvious along with the increase of the addition of the plant composition. The comparison of the data A1 and A2 with the data delta A of the examples shows that the scalp care solution continuously using the plant composition for protecting ultraviolet light and protecting color and hair can have certain color protection effect on the hair color
The tests show that the ultraviolet light protection and color protection plant composition can effectively play a role in protecting color under the condition of ultraviolet light aiming at hair dyeing and perming.
B. Shampoo-like hair product
Test hair tresses: asian hair is from the same person, 20cm long, 25g heavy, undyed and permed, normal hair quality.
Test samples: preparing and preparing test sample solution required by testing in advance: blank (deionized water), the test sample shampoo of comparative example 14 and examples 12-14;
the testing steps are as follows:
s1: firstly, treating the hair bundle: bleaching and dyeing the hair strands. The bleaching agent and the coloring agent used in the test are the same product purchased from a certain known brand on the market.
S2: taking 1 treated hair bundle, dividing into five parts, wherein each part is about 5 g;
s3: washing each part of hair bundle with deionized water respectively, and naturally airing; measuring the chroma value of each hair bundle by using a Minolta pedptometer CM-2005d chroma meter and recording data; averaging the three measurements and recording the average value as A0 value of each group;
s4: using a blank sample solution prepared in advance, a comparative example 14 and test sample solutions of examples 12 to 14 respectively, using 5g of the four samples of shampoo and 5g of blank deionized water to normally wash hair strands, naturally drying the hair strands after washing, washing the hair strands once in 2 days, continuously using the hair strands for 5 times, measuring the colorimetric value of each hair strand by using a Minolta micropotometer CM-2005d colorimeter after naturally drying the hair strands for 5 times, and recording data; averaging the three measurements and recording the average value as A1 value of each group;
s5: after the sample is used for the fifth time and naturally aired, each hair bundle is respectively placed under an ultraviolet lamp to irradiate for 48 hours; measuring the chroma value of each hair bundle by using a Minolta pedptometer CM-2005d chroma meter and recording data; averaging the three measurements and recording the average value as A2 value of each group;
and (3) data statistics:
Figure 3
TABLE 6
And (4) test conclusion:
c1: by testing the colorimetric values of the test sample hair strands using the shampoo products, the data of the respective initial colorimetric values A0 show that the hair quality conditions of the five hair strands are consistent, the hair strands meet the requirements of the test samples, and the test results are reliable.
C2: the data of A1 and A2 show that the A2 of the hair bundle after being processed by the sample and then being processed by ultraviolet is smaller than A1, which indicates that the ultraviolet has a certain reduction effect on the color of the hair bundle;
c3: comparative example 14, examples 12-14 by comparison with the blank data, the shampoo of comparative example 1 had the lowest Δ a and the lower Δ a of the blank, which were all higher than those of the blank and comparative example 14, before irradiation by the uv lamp, indicating that the shampoo of comparative example 14 (no uv-protective, color-protecting, hair-care plant composition) had the greatest degree of color loss in the hair tresses and the lowest color loss in the samples of the examples;
c4: with the addition of the ultraviolet light protection and color protection hair care plant composition in the examples, the chroma values of the hair bundles before and after ultraviolet treatment are higher than those of the comparative example and the blank sample, which can show that the ultraviolet light protection and color protection hair care plant composition has certain protection effect on the color of the hair bundles;
c5: meanwhile, with the increase of the addition of the plant composition for ultraviolet protection and color protection, A1 and A2 of the plant composition are both increased, and the change value of delta A is reduced, which can indicate that the ultraviolet protection effect of hair strands is more obvious with the increase of the addition of the plant composition. The data of examples A1, A2 and A0 show that the shampoo product containing the ultraviolet light protection and color protection plant composition has good color protection effect on the color protection of hair.
The tests show that the ultraviolet light protection and color protection plant composition can be added into shampoo hair cosmetic products, and the shampoo products can effectively play a color protection effect on hair dyeing and perming quality in the presence of ultraviolet light.
C. Hair product of hair dye type
Test hair tresses: the requirement of hair bundle: asian hair is from the same person, 20cm long, 25g heavy, undyed and permed, normal hair quality.
Test samples: preparing and preparing test samples required by testing in advance: blank (deionized water), the test sample hair dye of comparative example 15 and examples 15-17;
the testing steps are as follows:
s1: taking 1 hair bundle, dividing into five parts, wherein each part is about 5 g;
s2: washing each part of hair bundle with deionized water respectively, and naturally airing; measuring the chroma value of each hair bundle by using a Minolta pedptometer CM-2005d chroma meter and recording data; averaging the three measurements and recording the average value as A0 value of each group;
s3: respectively using a blank sample solution prepared in advance, a test sample hair dye of a comparative example 15 and a test sample of an example 15-17, uniformly mixing a dye and an oxidant 1:1 for 25g, then respectively dyeing each hair bundle, washing the blank sample with deionized water for 1 time, washing the blank sample with clear water after dyeing, measuring the colorimetric value of each hair bundle with a Minolta micropotometer CM-2005d colorimeter after drying in the air, and recording data; the average of three measurements is recorded as the A1 value of each group
S4: respectively placing each hair bundle of the above 5 parts under an ultraviolet lamp for irradiating for 48 hours; measuring the chroma value of each hair bundle by using a Minolta pedptometer CM-2005d chroma meter and recording data; averaging the three measurements and recording the average value as A2 value of each group;
and (3) data statistics:
Figure 2
TABLE 7
And (4) test conclusion:
c1: through testing the colorimetric values of the test sample hair strands using the hair dye products, the data of the respective initial colorimetric values A0 show that the hair quality conditions of the five hair strands are consistent, the hair strands meet the requirements of the test samples, and the test results are reliable.
C2: the data of A1 and A2 show that the A2 of the hair bundle after being processed by the sample and then being processed by ultraviolet is smaller than A1, which indicates that the ultraviolet has a certain reduction effect on the color of the hair bundle;
c3: examples 15-17, comparative example 15, and the blank data are compared, and the hair color values of the hair dye samples of examples 15-17, comparative example 15 increased after use without irradiation with the UV lamp; the delta A of the examples is lower than that of the comparative example 15, which shows that the hair dye of the examples 15-17 (added with the ultraviolet light protection and color protection hair care plant composition) has reduced color reduction after dyeing hair strands, and can show that the ultraviolet light protection and color protection hair care plant composition has certain protection effect on the color of the hair strands;
c4: meanwhile, the change value of delta A is reduced along with the increase of the addition of the plant composition for ultraviolet protection and color protection, which can show that the ultraviolet protection effect of hair strands is more obvious along with the increase of the addition of the plant composition. The comparison of the data of examples A1, A2 and A0 shows that the hair dye containing the ultraviolet light protection and color protection plant composition has good color protection effect on the color protection of the hair, and the color degree of the hair bundle is kept more durable.
The tests show that the ultraviolet light protection and color protection plant composition can effectively play a role in protecting the color of the hair dye products in the presence of ultraviolet light by adding the ultraviolet light protection and color protection plant composition into the hair dye cosmetic products.
To sum up, the following summary: the ultraviolet light protection and color protection hair care plant composition disclosed by the invention can be effectively and effectively resistant to oxidation, can remove hair free radicals and prevent hair sunburn when being applied to products such as scalp care solution, shampoo, hair dye and the like, and can simultaneously supplement hair and scalp nutrition, promote scalp and hair health, keep hair natural color and effectively slow down color fading of dyed hair. Within a certain range, the higher the percentage content of the plant composition for protecting ultraviolet light and protecting color and hair is, the better the effect is not only in the aspects of ultraviolet light protection and color protection, but also the softness and smoothness of the hair of the plant composition are improved in the testing process.
Finally, it should be noted that: the above-mentioned embodiments are only specific embodiments of the present invention, which are used for illustrating the technical solutions of the present invention and not for limiting the same, and the protection scope of the present invention is not limited thereto, although the present invention is described in detail with reference to the foregoing embodiments, those skilled in the art should understand that: any person skilled in the art can modify or easily conceive the technical solutions described in the foregoing embodiments or equivalent substitutes for some technical features within the technical scope of the present disclosure; such modifications, changes or substitutions do not depart from the spirit and scope of the embodiments of the present invention, and they should be construed as being included therein. Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.

Claims (9)

1. A plant composition with ultraviolet light protection and color protection and hair care effects is characterized in that: comprises the following components: the sunflower seeds, the grape seeds, the sweet almonds, the tea leaves, the walnut seeds, the ginkgo seeds, the aloe leaves, the henna, the polygonum multiflorum roots, the red lucid ganoderma, the fructus viticis, the ginseng roots and the gardenia fruits sequentially comprise the following components in percentage by weight: sunflower seeds, grape seeds, sweet almond, tea leaves, walnut seeds: semen Ginkgo, folium Aloe, flos Hemerocallis, radix Polygoni Multiflori, and Ganoderma: chastetree fruit: ginseng root: the ratio of gardenia fruit to gardenia fruit is 8-15: 7-14: 3: 2-7: 4: 7-10: 4-6: 2: 4: 3: 4: 6: 2.
2. the UV-light protecting, color protecting and hair protecting plant composition according to claim 1, wherein: the sunflower seeds, the grape seeds, the sweet almonds, the tea leaves, the walnut seeds, the ginkgo seeds, the aloe leaves, the henna, the polygonum multiflorum roots, the red lucid ganoderma, the fructus viticis, the ginseng roots and the gardenia fruits sequentially comprise the following components in percentage by weight: sunflower seeds, grape seeds, sweet almond, tea leaves, walnut seeds: semen Ginkgo, folium Aloe, flos Hemerocallis, radix Polygoni Multiflori, and Ganoderma: chastetree fruit: ginseng root: gardenia fruit 12: 10: 3: 5: 4: 8: 5: 2: 4: 3: 4: 6: 2.
3. the application of the ultraviolet light protection and color protection plant composition in hair care and cleaning products, wherein the ultraviolet light protection and color protection plant composition is the ultraviolet light protection and color protection plant composition as claimed in claim 1 or 2.
4. The use of the plant composition for protecting, protecting and caring the hair according to claim 3, wherein the plant composition for protecting, protecting and caring the hair is used in the hair care and cleaning product in an amount of 0.1-30% by weight.
5. Use according to claim 3 or 4, characterized in that: the hair care and cleaning products comprise hair care solution, shampoo, hair mask, hair conditioner, hair dye, permanent wave agent and the like.
6. A hair treatment liquid product characterized by: comprises the following components in percentage by weight:
0.5-20% of plant composition for ultraviolet protection and color protection,
0.1 to 0.4 percent of essence,
0.01 to 0.2 percent of citric acid,
0.05 to 0.4 percent of preservative
The balance of deionized water, wherein the ultraviolet light protection and color protection hair care plant composition is the ultraviolet light protection and color protection hair care plant composition as claimed in claim 1 or 2.
7. The shampoo is characterized by comprising the following components in percentage by weight:
10.0 to 30 percent of sodium laureth sulfate;
1.0-10.0% of cocamidopropyl betaine;
1.0-5.0% of polydimethylsiloxane;
0.5-3.0% of cocamide MEA;
0.5 to 5.0 percent of lauroyl wheat amino acid potassium;
guar hydroxypropyl trimethyl ammonium chloride 0.05-0.6%;
polyquaternium-470.5-1.0%;
100.1 to 0.4 percent of polyquaternium;
0.1 to 1 percent of fructo-oligosaccharide;
0.1-1% of cetearyl alcohol;
0.1 to 1.0 percent of bis-aminopropyl polydimethylsiloxane;
0.1 to 0.9 percent of sodium citrate;
0.01 to 0.5 percent of citric acid;
0.1 to 3.0 percent of sodium chloride;
0.5-5% of plant composition for ultraviolet protection, color protection and hair care;
0.01 to 1.0 percent of preservative;
0.1-2.0% of aromatic; the ultraviolet light protection, color protection and hair care plant composition is the ultraviolet light protection, color protection and hair care plant composition as claimed in claim 1 or 2.
8. A hair dye product is characterized in that: comprises the following components in percentage by weight:
the dye comprises the following components in percentage by weight:
2.00 to 10.00 percent of ammonium hydroxide;
cetostearyl alcohol 6.00-10.00%;
2.00 to 5.00 percent of propylene glycol;
1.50 to 3.00 percent of stearyl trimethyl ammonium chloride;
1.00-4.00% of glycerol stearate;
ceteareth-201.00-4.00%;
1.00-4.00% of mineral oil;
0.05 to 2.00 percent of polydimethylsiloxane;
0.20 to 1.20 percent of essence;
hydrolyzed wheat protein 0.10-1.50%;
0.30 to 0.50 percent of sodium sulfite;
0.30 to 1.00 percent of antioxidant;
0.10-0.30% of EDTA disodium;
0.50 to 5.00 percent of colorant;
0.50-5.00% of plant composition for ultraviolet protection and color protection;
the balance of water;
the oxidant comprises the following components in percentage by weight:
12.00 to 18.00 percent of hydrogen peroxide;
cetostearyl alcohol 2.00-6.00%;
ceteareth-201.00-10.00%;
0.20 to 1.20 percent of phosphoric acid;
0.02-0.2% of disodium hydrogen phosphate;
the balance of water; the ultraviolet light protection, color protection and hair care plant composition is the ultraviolet light protection, color protection and hair care plant composition as claimed in claim 1 or 2.
9. The preparation method of the ultraviolet light protection and color protection hair care plant composition is characterized by comprising the following steps: the ultraviolet light protection, color protection and hair care plant composition is the ultraviolet light protection, color protection and hair care plant composition as claimed in claim 1 or 2, and comprises the following steps:
1) cleaning sunflower seeds, grape seeds, sweet almond, tea leaves, walnut seeds, ginkgo seeds, aloe leaves, henna, polygonum multiflorum roots, red lucid ganoderma, fructus viticis, ginseng roots and gardenia fruits by using deionized water respectively, and placing in an oven for drying;
2) pulverizing the above dried plants respectively with a traditional Chinese medicine pulverizer to fine powder, sieving with 60 mesh sieve, weighing and mixing at a certain proportion to obtain ultraviolet light-protecting and color-protecting plant composition dry powder;
3) taking 0.5kg of the composition dry powder, adding 5L of water into an extraction device, heating to 95 ℃, condensing and refluxing for 4h, concentrating under reduced pressure to 1kg of concentrated solution, adding 3 times of 95% ethanol while stirring, condensing and refluxing for 2h at 80 ℃, filtering, standing for 24h, taking the standing solution, concentrating under reduced pressure to 0.3kg to obtain the ultraviolet light protection and color protection hair care plant composition, storing at-5 ℃ for later use, and recovering to room temperature before use.
CN202010032472.0A 2020-01-13 2020-01-13 Preparation and application of plant composition with ultraviolet light protection, color protection and hair care effects Active CN111346037B (en)

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CN107595678A (en) * 2017-09-13 2018-01-19 广州环亚化妆品科技有限公司 A kind of hair care composition and its preparation method and application
CN109589282A (en) * 2019-01-14 2019-04-09 苏州绿叶日用品有限公司 A kind of hair wet tissue feed liquid and preparation method thereof with sun-proof colour-preserving function
CN109692139A (en) * 2017-10-24 2019-04-30 林映霞 A kind of gentle nourishing type shampoo
CN110559235A (en) * 2019-10-10 2019-12-13 章华化妆品科技有限公司 hair treatment and beauty cream and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN107595678A (en) * 2017-09-13 2018-01-19 广州环亚化妆品科技有限公司 A kind of hair care composition and its preparation method and application
CN109692139A (en) * 2017-10-24 2019-04-30 林映霞 A kind of gentle nourishing type shampoo
CN109589282A (en) * 2019-01-14 2019-04-09 苏州绿叶日用品有限公司 A kind of hair wet tissue feed liquid and preparation method thereof with sun-proof colour-preserving function
CN110559235A (en) * 2019-10-10 2019-12-13 章华化妆品科技有限公司 hair treatment and beauty cream and preparation method thereof

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