CN111302626B - Ceramic base film molding paste, preparation method thereof and crystal stack color drawing method - Google Patents
Ceramic base film molding paste, preparation method thereof and crystal stack color drawing method Download PDFInfo
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- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
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- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
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Abstract
The invention provides a ceramic basement membrane molding paste, a preparation method thereof and a crystal stack color drawing method; the ceramic basement membrane molding paste is prepared by mixing raw material powder, silver powder and pearl powder and blending with purified water; the raw material mixed powder comprises the following components: 38-42 parts by weight of quartz; 18-22 parts by weight of sodium carbonate; 13-17 parts by weight of titanium oxide; 8-12 parts by weight of tin oxide; 3-7 parts by weight of zinc oxide; 8 to 12 parts of porcelain clay. The crystal colored drawing pigment used by the crystal superimposed colored drawing method is prepared from raw materials such as crystal, colored glaze, agate and other mineral colored gemstones. The ceramic basement membrane molding paste and the crystal colored drawing pigment can realize the crystal color-stacking drawing and firing imaging on the ceramic vessel to obtain the colored drawing works, and the finished products have concave-convex image layers, three-dimensional and beautiful color rhymes, glittering and translucent colors, have classical crystal texture and luster, and greatly improve the artistic appreciation and commercial value of the ceramic vessel.
Description
Technical Field
The invention relates to the technical field of ceramic artware, in particular to ceramic basement membrane molding paste, a preparation method thereof and a crystal color-stacking drawing method.
Background
The ceramic decoration process comprises overglaze decoration, in-glaze decoration and underglaze decoration; the glazing color is one of the main decoration techniques of the ceramic process, and is formed by drawing various patterns on the fired porcelain glaze by using various color materials, and then putting the porcelain glaze into a kiln for baking and curing; generally comprises colored drawing porcelain, colored decoration porcelain, blue and white colored porcelain, five-color porcelain, pink porcelain, colored ground gold porcelain, enamel color and the like.
In general, a solvent and a diluent are added to each pigment, and then a painting brush is used to dip the pigment for painting. The existing solvent and diluent mainly comprise water and oil solutions such as mastic oil, camphor oil, alcohol, kerosene and the like.
The solvent has the characteristics of simple preparation, convenient use and the like. The ceramic colored drawing works drawn by the overglaze color pigment, the pink pigment and the like prepared by the solvent also have the characteristics of fine composition, bright color, full color and the like, but have some obvious defects.
For example: the new glazed color is easy to infiltrate and disperse pigment to cause less clear picture composition and even to have the phenomenon of 'frying oil' after oil is dispersed because an oily solvent is used; moreover, the warm-tone colored drawing parts such as reddish west, orange, dark yellow, thin yellow and the like colored on the glaze are easy to generate the color fading and flying phenomenon after being baked; if the color is adjusted by the hydrated peach gum, the defects of dull color development, flat color expression, unclear color level and the like are also realized. The overglaze color painting cannot be colored too thick, otherwise pigment delamination or cracks will occur after baking. The powder color painting can enable the picture to present a certain degree of concave-convex three-dimensional imaging, but the defects of insufficient color development, flat color expression and unclear color level exist after part of the pigment is fired; the ceramic works drawn by the ceramic floating color process can form a certain concave-convex three-dimensional gorgeous image on the surface of the ceramic, but the image can only have a point three-dimensional effect, and if the painting area is enlarged, the image cracks are easy to appear during baking. The enamel color is the most famous and precious color porcelain in history, is originated in the Qing Dynasty Kangxi period, belongs to a special art treasure in the royalty, and is divided into porcelain body painting enamel and copper body painting enamel (cloisonne). However, the brilliant color of enamel requires the use of arsenic (formerly known as "arsenic") for color development, which is extremely toxic. Even after high-temperature firing, toxic substances may still exceed the standard during leaching.
The obvious defect is that the traditional ceramic art painting process can not directly paint and burn on the surface layers of black pottery, purple sand, metal, glass, dark glaze porcelain and the like to form bright and bright pictures with rich color layers, and can not make the pictures show light relief crystal color imaging with large block surfaces.
Disclosure of Invention
The ceramic base film molding paste provided by the invention can realize the crystal color-lamination drawing on a ceramic vessel and can be fired and imaged to obtain a colored drawing product, the finished product has a three-dimensional concave-convex bas-relief integral image, and the picture has a clear, bright and translucent visual effect.
The invention provides a ceramic basement membrane molding paste which is prepared by mixing raw material mixed powder, silver powder and pearl powder with purified water;
the raw material mixed powder comprises the following components:
38-42 parts by weight of quartz;
18-22 parts by weight of sodium carbonate;
13-17 parts by weight of titanium oxide;
8-12 parts by weight of tin oxide;
3-7 parts by weight of zinc oxide;
8 to 12 parts of porcelain clay.
Preferably, the mass ratio of the raw material mixed powder, the silver powder and the pearl powder is 100: (8-12): (3-7).
The invention also provides a preparation method of the ceramic basement membrane molding paste, which comprises the following steps:
a) mixing quartz, sodium carbonate, titanium oxide, tin oxide, zinc oxide and porcelain clay, calcining, grinding and sieving to obtain raw material mixed powder;
b) adding silver powder and pearl powder into the raw material mixed powder obtained in the step a), and blending and stirring with purified water to obtain the ceramic basement membrane molding paste.
Preferably, the temperature of the calcination in step a) is 1150 ℃ to 1250 ℃.
Preferably, the size of the mesh of the fine screen in step a) is 230-270 mesh.
Preferably, the degree of tempering in step b) is a creamy, non-running cream.
The invention also provides a crystal stack color drawing method, which comprises the following steps:
a) according to the creation requirement, dipping a bottom film molding paste by using a color drawing pen, and drawing a picture with a shallow relief image on the surface of a blank of a ceramic vessel by a stacking method to obtain a bottom film molding blank; the basement membrane shaping paste is the ceramic basement membrane shaping paste prepared by the preparation method of the technical scheme or the ceramic basement membrane shaping paste prepared by the preparation method of the technical scheme;
b) drying the bottom film molding blank obtained in the step a), firing the bottom film molding blank in a kiln at 830-870 ℃ for 6-9 h, and curing to obtain a blank with a low relief pattern;
or, drying the bottom film molding blank obtained in the step a) to obtain a blank with a bas-relief pattern;
c) drawing the surface of the shallow relief pattern of the green body with the shallow relief pattern obtained in the step b) by adopting an over-glaze color drawing method, and baking and decorating the surface in a kiln at 700-750 ℃ for 5-6 h to obtain the green body with the over-glaze color drawing;
d) filling color painting on the surface of the glazed colored painting of the blank with the glazed colored painting obtained in the step c) by adopting a crystal color pigment mixed by peach gum aqueous solution, and then putting the blank into a kiln to bake and color at 700-730 ℃ for 6-7 h to obtain a ceramic crystal stacked color work;
or, preparing crystal color pigment by using an underglaze color painting modulator, performing color filling painting on the surface of the overglaze color painting of the blank with the overglaze color painting obtained in the step c), spraying a layer of low-temperature transparent oil, and firing in a kiln at 830-860 ℃ for 7-8 hours to obtain the ceramic crystal color-stacked work.
Preferably, the ceramic vessel in the step a) comprises a common ceramic vessel, a black ceramic vessel, a purple sand vessel, a metal vessel, a glass vessel or various artistic colored porcelains.
Preferably, the preparation method of the crystal color pigment blended by the peach gum aqueous solution in the step d) specifically comprises the following steps:
respectively crushing the seeds of all colors, putting the crushed seeds into a glaze grinding machine, adding water, grinding, and sieving through a 230-270-mesh sieve to obtain the crystal color pigment; the seed material comprises one or more of crystal seed material, colored glaze seed material, agate seed material and other mineral substance gem seed material;
and mixing the peach gum and water in a ratio of 1: (8-10) preparing a peach gum aqueous solution, and blending the crystal color pigment into a cream shape which is not easy to flow according to the composition requirement to obtain the peach gum aqueous solution blended crystal color pigment.
Preferably, before drawing a picture with a low-relief image on the surface of the blank of the ceramic vessel in a stacking method in the step a), the method further comprises the following steps:
the raw material mixed powder of the technical scheme is dipped by white cloth, and the surface of the ceramic vessel is wiped clean.
The invention provides a ceramic basement membrane molding paste, a preparation method thereof and a crystal stack color drawing method; the ceramic basement membrane molding paste is prepared by mixing raw material powder, silver powder and pearl powder and blending with purified water; the raw material mixed powder comprises the following components: 38-42 parts by weight of quartz; 18-22 parts by weight of sodium carbonate; 13-17 parts by weight of titanium oxide; 8-12 parts by weight of tin oxide; 3-7 parts by weight of zinc oxide; 8 to 12 parts of porcelain clay. Compared with the prior art, the ceramic basement membrane molding paste provided by the invention can realize crystal color-superposition drawing and firing imaging on a ceramic vessel to obtain a colored drawing work, and the finished product has concave-convex image layer, three-dimensional and beautiful color, crystal clear color, classic crystal texture and luster, and greatly improves the artistic appreciation and commercial value of the ceramic vessel.
In addition, the ceramic basement membrane molding paste provided by the invention has strong coverage, not only can be applied to common ceramic utensils to create and burn ceramic colored drawing works, but also can be applied to dark-colored utensils such as black pottery, purple sand, various artistic colored porcelains and the like to draw and burn three-dimensional charm and glittering and translucent colored drawings, and has unique crystal refraction visual effect on the images.
Drawings
FIG. 1 is a diagram of a "spring look Sanxiang" crystal color-overlapped picture formed on a purple clay tea set by using the ceramic basement membrane molding paste provided by the embodiment of the invention.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the following embodiments of the present invention, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, especially the process of molding the base film using ceramic raw materials according to the technical route of the present invention, which are obtained by those skilled in the art without creative efforts based on the embodiments of the present invention, belong to the protection scope of the present invention.
The invention provides a ceramic basement membrane molding paste which is prepared by mixing raw material mixed powder, silver powder and pearl powder with purified water;
the raw material mixed powder comprises the following components:
38-42 parts by weight of quartz;
18-22 parts by weight of sodium carbonate;
13-17 parts by weight of titanium oxide;
8-12 parts by weight of tin oxide;
3-7 parts by weight of zinc oxide;
8 to 12 parts of porcelain clay.
In the invention, the ceramic basement membrane molding paste is prepared by mixing raw material powder, silver powder and pearl powder and mixing with purified water. In the invention, the raw material mixed powder comprises the following components:
38-42 parts by weight of quartz;
18-22 parts by weight of sodium carbonate;
13-17 parts by weight of titanium oxide;
8-12 parts by weight of tin oxide;
3-7 parts by weight of zinc oxide;
8-12 parts of porcelain clay;
preferably:
40 parts of quartz;
20 parts by weight of sodium carbonate;
15 parts by weight of titanium oxide;
10 parts by weight of tin oxide;
5 parts by weight of zinc oxide;
10 parts of petuntse.
The sources of the quartz, sodium carbonate, titanium oxide, tin oxide, zinc oxide and petuntse are not particularly limited in the present invention, and commercially available products well known to those skilled in the art may be used.
In the invention, the silver powder and the pearl powder can be matched with a subsequent crystal color pigment for filling color, so that the obtained crystal stacked color work has visual effects of intrinsic color, transparent crystal and unique halation. The sources of the silver powder and the pearl powder in the present invention are not particularly limited, and commercially available products of the silver powder and the pearl powder, which are well known to those skilled in the art, may be used.
The pure water is adopted in the invention to ensure that the ceramic basement membrane molding paste presents silvery white after being sintered and cured subsequently; if the water contains excessive impurities such as copper, iron, calcium, etc., the base film after being fired and cured may present dark gray, dark red, blue-green, etc., which may affect the subsequent colored drawing operation. The source of the purified water is not particularly limited in the present invention, and commercially available products or self-products known to those skilled in the art may be used.
In the invention, the mass ratio of the raw material mixed powder, the silver powder and the pearl powder is preferably 100: (8-12): (3-7), more preferably 100: 10: 5.
the ceramic basement membrane molding paste provided by the invention can realize crystal color-superposition drawing and firing imaging on a ceramic vessel to obtain a colored drawing work, and the finished product has concave-convex image layer, three-dimensional and beautiful color rhyme, glittering and translucent color and luster, has classical crystal texture and luster, and greatly improves the artistic appreciation and commercial value of the ceramic vessel.
The invention also provides a preparation method of the ceramic basement membrane molding paste, which comprises the following steps:
a) mixing quartz, sodium carbonate, titanium oxide, tin oxide, zinc oxide and porcelain clay, calcining, grinding and sieving to obtain raw material mixed powder;
b) adding silver powder and pearl powder into the raw material mixed powder obtained in the step a), and blending and stirring with purified water to obtain the ceramic basement membrane molding paste.
The invention firstly mixes quartz, sodium carbonate, titanium oxide, tin oxide, zinc oxide and porcelain clay, calcines, grinds and sieves to obtain raw material mixed powder. In the present invention, the quartz, the sodium carbonate, the titanium oxide, the tin oxide, the zinc oxide and the petuntse are the same as those described in the above technical solution, and are not described herein again. The mixing method is not particularly limited, and the technical scheme of fully mixing and grinding which is well known to those skilled in the art can be adopted.
In the invention, the calcination process preferably comprises the steps of placing the mixed powder in a crucible for calcination and coagulation; the temperature of the calcination is preferably 1150 ℃ to 1250 ℃, more preferably 1200 ℃.
In the present invention, the size of the mesh of the fine screen is preferably 230 to 270 mesh, and more preferably 250 mesh.
After the raw material mixed powder is obtained, silver powder and pearl powder are added into the obtained raw material mixed powder, and the mixture is blended and stirred with purified water to obtain the ceramic basement membrane molding paste. In the present invention, the silver powder, the pearl powder and the purified water are the same as those in the above technical scheme, and are not described herein again.
In the present invention, the degree of tempering is preferably a cream-like state that does not easily flow, by controlling the amount of pure water added.
The preparation method of the ceramic basement membrane molding paste provided by the invention has the advantages of easily available raw materials and low cost, realizes new application of each raw material in preparation of ceramic color-drawing artware, and is simple in preparation process and convenient to use.
The invention also provides a crystal stack color drawing method, which comprises the following steps:
a) according to the creation requirement, dipping a bottom film molding paste by using a color drawing pen, and drawing a picture with a shallow relief image on the surface of a blank of a ceramic vessel by a stacking method to obtain a bottom film molding blank; the basement membrane shaping paste is the ceramic basement membrane shaping paste prepared by the preparation method of the technical scheme or the ceramic basement membrane shaping paste prepared by the preparation method of the technical scheme;
b) drying the bottom film molding blank obtained in the step a), firing the bottom film molding blank in a kiln at 830-870 ℃ for 6-9 h, and curing to obtain a blank with a low relief pattern;
or, drying the bottom film molding blank obtained in the step a) to obtain a blank with a bas-relief pattern;
c) drawing the surface of the shallow relief pattern of the green body with the shallow relief pattern obtained in the step b) by adopting an over-glaze color drawing method, and baking and decorating the surface in a kiln at 700-750 ℃ for 5-6 h to obtain the green body with the over-glaze color drawing;
d) filling color painting on the surface of the overglaze color painting of the blank with the overglaze color painting obtained in the step c) by adopting crystal color pigment mixed by peach gum aqueous solution, and then putting the overglaze color painting into a kiln for baking and painting at 700-730 ℃ for 6-7 h to obtain ceramic crystal stacked color works (ceramic crystal stacked color works);
or, modulating crystal color pigment by adopting an underglaze color painting modulator, performing color filling painting on the surface of the overglaze color painting of the blank with the overglaze color painting obtained in the step c), spraying a layer of low-temperature transparent oil, and firing in a kiln at 830-860 ℃ for 7-8 h to obtain the ceramic crystal stacked color work (ceramic underglaze color crystal stacked color work).
According to the creation requirement, a color drawing pen is dipped with the basement membrane molding paste, and a picture with a bas-relief image is drawn on the surface of a blank of a ceramic vessel by a stacking method to obtain a basement membrane molding blank. In the invention, the basement membrane molding paste is the ceramic basement membrane molding paste in the technical scheme or the ceramic basement membrane molding paste prepared by the preparation method in the technical scheme.
In the present invention, before drawing a picture with a low-relief image on a surface of a blank of a ceramic vessel in a stacking method, it is preferable that the method further includes:
the raw material mixed powder of the technical scheme is dipped by white cloth, and the surface of the ceramic vessel is wiped clean. The invention adopts the process to wipe off oily stains such as oil stains, sweat stains and the like so as to avoid the phenomenon of oily sliding on the surface of a blank body when the basement membrane molding paste is used for three-dimensional molding.
In the invention, the ceramic vessel preferably comprises a common ceramic vessel, a black ceramic vessel, a purple sand vessel, a metal vessel, a glass vessel or various artistic colored porcelains. The ceramic basement membrane molding paste provided by the invention has strong coverage, not only can be applied to common ceramic utensils to create and burn ceramic colored drawing works, but also can be applied to dark-colored utensils such as black pottery, purple sand, various artistic colored porcelains and the like to draw and burn three-dimensional charm and glittering and translucent colored drawings, and has unique crystal refraction visual effect on the images.
After the basement membrane molding blank is obtained, the obtained basement membrane molding blank is dried and then is fired in a kiln at 830-870 ℃ for 6-9 h to be cured, so that a blank with a low relief pattern is obtained; or, drying the bottom film molding blank obtained in the step a) to obtain a blank with a bas-relief pattern; preferably, the obtained plastic base film blank is dried and then is fired in a kiln at 830-870 ℃ for 6-9 h to be cured, so as to obtain a blank with a low relief pattern. In the present invention, the firing temperature is preferably 850 ℃, and the firing time is preferably 7 to 8 hours.
After the green body with the bas-relief pattern is obtained, the invention adopts an enamel painting method to paint the surface of the bas-relief pattern of the obtained green body with the bas-relief pattern, and then the green body is put into a kiln to be baked and painted at 700-750 ℃ for 5-6 h to obtain the green body with the enamel painting. In the present invention, the process of the overglaze color painting method is preferably as follows:
and drawing creation is carried out on the surface of the bas-relief composition of the obtained blank with the bas-relief composition by using an overglaze color pigment according to the steps of drawing a background (line drawing, light shading), colored drawing and the like. In the present invention, the over-glaze coloring pigment is preferably prepared using mastic oil and/or camphor oil, and can obtain a fine and accurate composition.
After the green body with the over-glaze color painting is obtained, filling color painting on the surface of the over-glaze color painting of the obtained green body with the over-glaze color painting by adopting crystal color pigment blended by peach gum aqueous solution, and baking the green body in a kiln at 700-730 ℃ for 6-7 h to obtain a ceramic crystal stacked color work (ceramic over-glaze crystal stacked color work);
or, modulating crystal color pigment by adopting an underglaze color painting modulator, performing color filling painting on the surface of the overglaze color painting of the blank with the overglaze color painting obtained in the step c), spraying a layer of low-temperature transparent oil, and firing in a kiln at 830-860 ℃ for 7-8 h to obtain the ceramic crystal stacked color work (ceramic underglaze color crystal stacked color work); preferably, the crystal color pigment is blended by peach gum aqueous solution, the surface of the obtained glaze colored drawing of the body with the glaze colored drawing is filled with colored drawing, and then the ceramic crystal color-laminated work (ceramic crystal color-laminated work) is obtained after the ceramic crystal color-laminated work is placed in a kiln and is baked for 6 to 7 hours at 700 to 730 ℃.
In the invention, the preferable preparation method of the crystal color pigment blended by the peach gum aqueous solution is as follows:
respectively crushing the seeds of all colors, putting the crushed seeds into a glaze grinding machine, adding water, grinding, and sieving by a 230-270-mesh sieve to obtain crystal color pigment (raw material powder); and mixing the peach gum and water in a ratio of 1: (8-10) preparing a peach gum aqueous solution according to the mass ratio, and blending the crystal color pigment into a cream shape which is not easy to flow according to the composition requirement to obtain the peach gum aqueous solution blended crystal color pigment;
more preferably:
respectively crushing the seeds of all colors, putting the crushed seeds into a glaze grinding machine, adding water, grinding, and sieving by a 250-mesh sieve to obtain a crystal color pigment (raw material powder); and mixing the peach gum and water in a ratio of 1: 9, preparing a peach gum aqueous solution, and blending the crystal color pigment into a cream shape which is not easy to flow according to the composition requirement to obtain the crystal color pigment blended by the peach gum aqueous solution.
In the invention, the seed material preferably comprises one or more of crystal seed material, colored glaze seed material, agate seed material and other mineral gem seed material, and more preferably is crystal seed material. The source of the seed material is not particularly limited in the present invention, and commercially available products of the above-mentioned crystal seed material, vitreous seed material, agate seed material and other mineral gem seed materials known to those skilled in the art may be used. In the present invention, the colors of the various color seeds include, but are not limited to, red, yellow, blue, green, and violet. Compared with the traditional ceramic art colored drawing pigment, the crystal color pigment adopted by the invention is a common mineral pigment without adding various metal components; the raw materials selected by the invention for preparing the crystal color pigment are all applied in the field of ceramic art colored drawing pigments for the first time.
In the invention, the crystal color pigment can also be mixed with peach gum powder as a binder according to the mass ratio of 95: (4-6) (preferably 95: 5), and adding purified water to dilute the mixture into a cream shape which is not easy to flow so as to obtain the crystal color pigment blended by the peach gum aqueous solution, wherein the crystal color pigment can be used as crystal stacked color painting.
In the invention, the processes of filling the color painting and the subsequent baking/oil spraying firing can be repeated for a plurality of times, thereby further improving the effect of the crystal color stacking.
The sources of the overglaze coloring pigment, the underglaze color drawing preparation agent, the peach gum and the low-temperature transparent oil used in the above steps are not particularly limited, and commercially available products known to those skilled in the art may be used.
The invention uses basement membrane molding paste to draw and shape the surface of a blank of a ceramic vessel by a bas-relief process according to creation composition, and then the blank is fired in a kiln to be cured and molded; then preparing overglaze color pigment, drawing the bottom and painting on the fired and molded bas-relief basement membrane, and baking in a kiln; finally, blending crystal materials with red, yellow, blue, green, purple and the like with peach gum aqueous solution on the surface layer of the picture after baking color to fill color and accumulate color, and then putting the picture into a kiln to bake color again to obtain a finished product of the crystal color-stacking process (the color can be filled and baked for many times according to the process requirement); further limiting the firing temperature of the base film after molding the base film molding paste to be 830-870 ℃ for 6-9 h, the color baking temperature on the glaze to be 700-750 ℃ for 5-6 h, the color baking temperature after filling the crystal pigment to be 700-730 ℃ for 6-7 h; on the basis, the base film molding paste can be solidified and is not easy to melt, so that the under-painted colored drawing after the over-glaze colored decoration is kept stable, and the crystal color pigment and the over-glaze colored drawing are fully fused.
The crystal color-superposed painting method provided by the invention adopts the ceramic base film molding paste, can realize crystal color-superposed painting on a ceramic vessel and firing imaging to obtain a color-painted work with a three-dimensional concave-convex bas-relief integral image, and can enable a finished product picture to present clear, bright and translucent visual effects because overglaze color and color crystal pigment are used for gradation iridescence and temperature-graded baking color; in addition, the crystal color-superposed painting method can paint and burn three-dimensional, colorful and light-rhyme unique artistic structure paintings on fine black pottery, artistic colored porcelain, purple sand and other high-grade appliances.
In conclusion, the crystal color-stacking drawing method provided by the invention adopts the three-dimensional modeling of the base film modeling paste and the color-stacking manufacture of the crystal color-stacking, and the product obtained by combining the crystal color-stacking drawing method with the existing ceramic glaze coloring decoration technique has the advantages of stable color deposition, bright and bright color and three-dimensional and clear picture layers; meanwhile, the base film molding paste is added with silver powder, pearl powder and other components, and colored crystal pigment is used for filling, so that the drawn crystal color-superposed works have visual effects of intrinsic color and luster, transparent crystals and unique halation; in addition, because the basement membrane is colored and colored for a plurality of times after being molded, and is baked for a plurality of times for molding, the three-dimensional and bright crystal color-superposed works can be drawn and fired on the dark background of various artistic ceramic materials and ware blanks, and the method is a novel method of ceramic color drawing art.
The invention provides a ceramic basement membrane molding paste, a preparation method thereof and a crystal stack color drawing method; the ceramic basement membrane molding paste is prepared by mixing raw material powder, silver powder and pearl powder and blending with purified water; the raw material mixed powder comprises the following components: 38-42 parts by weight of quartz; 18-22 parts by weight of sodium carbonate; 13-17 parts by weight of titanium oxide; 8-12 parts by weight of tin oxide; 3-7 parts by weight of zinc oxide; 8 to 12 parts of porcelain clay. Compared with the prior art, the ceramic basement membrane molding paste provided by the invention can realize crystal color-superposition drawing and firing imaging on a ceramic vessel to obtain a colored drawing work, and the finished product has concave-convex image layer, three-dimensional and beautiful color, crystal clear color, classic crystal texture and luster, and greatly improves the artistic appreciation and commercial value of the ceramic vessel.
In addition, the ceramic basement membrane molding paste provided by the invention has strong coverage, not only can be applied to common ceramic utensils to create and burn ceramic colored drawing works, but also can be applied to dark-colored utensils such as black pottery, purple sand, various artistic colored porcelains and the like to draw and burn three-dimensional charm and glittering and translucent colored drawings, and has unique crystal refraction visual effect on the images.
To further illustrate the present invention, the following examples are provided for illustration.
Examples
(1) The raw material powder mixing formula of the ceramic basement membrane molding paste is as follows: 40 wt% of quartz, 20 wt% of sodium carbonate, 15 wt% of titanium oxide, 10 wt% of tin oxide, 5 wt% of zinc oxide and 10 wt% of porcelain clay; fully mixing the raw materials, grinding, putting the mixture into a crucible, calcining and condensing at 1200 ℃, grinding, and sieving with a 250-mesh sieve to obtain the raw material mixed powder.
(2) Adding 10 wt% of silver powder and 5 wt% of pearl powder into the raw material mixed powder obtained in the step (1), blending into a non-flowing cream shape by using purified water, and fully stirring to obtain the ceramic basement membrane molding paste.
Application examples
Firstly, dipping white cloth into the raw material mixed powder obtained in the step (1) of the embodiment, wiping the surface of a ceramic vessel (purple sand tea set) clean, then dipping a ceramic basement membrane molding paste provided by the embodiment into a drawing pen, drawing mountain rocks, houses, sailing boats and pavilions by a stacking technique, drawing tree flowering branches by a point color method, and after the tree flowering branches are slightly dried, carrying out wiping and scraping decoration by a bamboo pen to enhance the relief effect of the composition; drying, and firing at 850 ℃ in a kiln for 7-8 h for curing; then drawing on the fired and solidified bas-relief base picture by an enamel color drawing method, drawing lines and making light and shade drafts, then carrying out color accumulation on scenes such as mountain rocks, sailing boats, houses, pavilions and the like, drawing a color picture, and then baking and decorating in a kiln at 700-750 ℃ for 5-6 h; finally, with 1: preparing peach glue solution according to a mass ratio of 9, blending crystal color pigment, performing color filling painting on tree flower branches and the like on the fired on-glaze color picture, drying in the air, and then putting into a kiln to bake color for 6-7 h at 700-730 ℃ (color filling painting and baking color for many times as required) to obtain the ceramic crystal stacked color work.
Referring to fig. 1, fig. 1 is a diagram of a "spring look sanxiang" crystal color-overlapped picture formed on a purple sand tea set by using the ceramic basement membrane modeling paste provided by the embodiment of the invention; the color-baked formed picture has the visual effect of colorful bas-relief with the relief and crystal luster.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.
Claims (10)
1. A ceramic basement membrane molding paste is prepared by mixing raw materials of powder, silver powder and pearl powder, and blending with purified water;
the raw material mixed powder comprises the following components:
38-42 parts by weight of quartz;
18-22 parts by weight of sodium carbonate;
13-17 parts by weight of titanium oxide;
8-12 parts by weight of tin oxide;
3-7 parts by weight of zinc oxide;
8 to 12 parts of porcelain clay.
2. The molding paste of ceramic basement membrane according to claim 1, wherein the mass ratio of the raw material mixed powder, the silver powder and the pearl powder is 100: (8-12): (3-7).
3. A method for preparing the ceramic base film molding paste according to any one of claims 1 to 2, comprising the steps of:
a) mixing quartz, sodium carbonate, titanium oxide, tin oxide, zinc oxide and porcelain clay, calcining, grinding and sieving to obtain raw material mixed powder;
b) adding silver powder and pearl powder into the raw material mixed powder obtained in the step a), and blending and stirring with purified water to obtain the ceramic basement membrane molding paste.
4. The method according to claim 3, wherein the temperature of the calcination in step a) is 1150 ℃ to 1250 ℃.
5. The method according to claim 3, wherein the size of the mesh of the fine screen in step a) is 230 to 270 mesh.
6. The method of claim 3, wherein the degree of tempering in step b) is a non-sagging cream-like state.
7. A crystal color-on-color drawing method comprises the following steps:
a) according to the creation requirement, dipping a bottom film molding paste by using a color drawing pen, and drawing a picture with a shallow relief image on the surface of a blank of a ceramic vessel by a stacking method to obtain a bottom film molding blank; the base film shaping paste is the ceramic base film shaping paste of any one of claims 1 to 2 or the ceramic base film shaping paste prepared by the preparation method of any one of claims 3 to 6;
b) drying the bottom film molding blank obtained in the step a), firing the bottom film molding blank in a kiln at 830-870 ℃ for 6-9 h, and curing to obtain a blank with a low relief pattern;
or, drying the bottom film molding blank obtained in the step a) to obtain a blank with a bas-relief pattern;
c) drawing the surface of the shallow relief pattern of the green body with the shallow relief pattern obtained in the step b) by adopting an over-glaze color drawing method, and baking and decorating the surface in a kiln at 700-750 ℃ for 5-6 h to obtain the green body with the over-glaze color drawing;
d) filling color painting on the surface of the glazed colored painting of the blank with the glazed colored painting obtained in the step c) by adopting a crystal color pigment mixed by peach gum aqueous solution, and then putting the blank into a kiln to bake and color at 700-730 ℃ for 6-7 h to obtain a ceramic crystal stacked color work;
or, preparing crystal color pigment by using an underglaze color painting modulator, performing color filling painting on the surface of the overglaze color painting of the blank with the overglaze color painting obtained in the step c), spraying a layer of low-temperature transparent glaze, and firing in a kiln at 830-860 ℃ for 7-8 hours to obtain the ceramic crystal color-stacked work.
8. The crystal superimposed color drawing method according to claim 7, wherein the ceramic vessel in the step a) comprises a common ceramic vessel, a black pottery vessel, a purple sand vessel or various artistic colored porcelains.
9. The crystal overlay color drawing method according to claim 7, wherein the preparation method of the crystal color pigment blended by the peach gum aqueous solution in the step d) comprises the following specific steps:
respectively crushing the seeds of all colors, putting the crushed seeds into a glaze grinding machine, adding water, grinding, and sieving through a 230-270-mesh sieve to obtain the crystal color pigment; the seed material comprises one or more of crystal seed material, colored glaze seed material, agate seed material and other mineral substance gem seed material;
and mixing the peach gum and water in a ratio of 1: (8-10) preparing a peach gum aqueous solution, and blending the crystal color pigment into a cream shape which is not easy to flow according to the composition requirement to obtain the peach gum aqueous solution blended crystal color pigment.
10. The crystal superimposed color drawing method according to any one of claims 7 to 9, wherein before drawing the picture with the low-relief image on the surface of the blank of the ceramic vessel in the step a) in a stacking method, the method further comprises:
dipping the mixed powder of the raw materials as described in claim 1 with a white cloth, and wiping the surface of the ceramic vessel clean.
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