CN111269589A - 一种涂料及陶瓷用改性锻烧高岭土的制造方法 - Google Patents

一种涂料及陶瓷用改性锻烧高岭土的制造方法 Download PDF

Info

Publication number
CN111269589A
CN111269589A CN202010179008.4A CN202010179008A CN111269589A CN 111269589 A CN111269589 A CN 111269589A CN 202010179008 A CN202010179008 A CN 202010179008A CN 111269589 A CN111269589 A CN 111269589A
Authority
CN
China
Prior art keywords
calcined kaolin
clinker
slurry
kaolin
manufacturing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010179008.4A
Other languages
English (en)
Other versions
CN111269589A8 (zh
Inventor
顾卫兵
雷志刚
李嵩
雷星宇
雷浩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu nading Material Technology Co., Ltd
Original Assignee
Technology Lihai Environmental Protection Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Technology Lihai Environmental Protection Technology Co ltd filed Critical Technology Lihai Environmental Protection Technology Co ltd
Priority to CN202010179008.4A priority Critical patent/CN111269589A/zh
Publication of CN111269589A publication Critical patent/CN111269589A/zh
Publication of CN111269589A8 publication Critical patent/CN111269589A8/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/40—Compounds of aluminium
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/14—Boron; Compounds thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16—Heavy metals; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/04—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
    • C09C3/041—Grinding
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/04—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
    • C09C3/043—Drying, calcination
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/06—Treatment with inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3229—Cerium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3284—Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3409—Boron oxide, borates, boric acids, or oxide forming salts thereof, e.g. borax
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Toxicology (AREA)
  • Structural Engineering (AREA)
  • Paints Or Removers (AREA)
  • Pretreatment Of Seeds And Plants (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Cosmetics (AREA)

Abstract

一种涂料及陶瓷用改性锻烧高岭土的制造方法，所述方包括如下步骤：一、备料；二、制浆；三、喷雾干；四、锻烧；五、粉磨；六、检验包装；七、改性锻烧高岭土产品的制造。本发明所述方法简单，能制造出价格低廉杀菌功能显著，能广泛添加到日常用品制造环节的锻烧高岭土。该方法无需改变陶瓷、涂料生产的工艺也不会对以前生产的工艺指标造成任何影响，按原工艺进行生产即可，所得产品经检测符合JC/T897‑2014 HG/T3950‑2007的标准,对多种病菌均有显著的灭活效果。

Description

一种涂料及陶瓷用改性锻烧高岭土的制造方法
技术领域
本发明公开了一种涂料及陶瓷用改性锻烧高岭土的制造方法，属于非金属矿业和建材领域。
背景技术
过去人们应对病毒传播最为经济有效的手段是注射疫苗，常见的灭活疫苗、重组蛋白疫苗、核酸疫苗等在国际上最快的研发时间也需要18个月之久；目前针对病毒患者的治疗，主要采用中西医结合的方式，其中西药磷酸氯喹、瑞德西韦、法匹拉韦对病毒的抑制得到了临床的验证，特别是中药汤剂对轻度患者的治疗效果非常明显；为减少病菌的传播，切断其传播途径有几个方面：一是通过飞沫传播的：加强呼吸道的保护，如出入公共场所佩戴抗菌口罩，穿着具有抗菌功能的外套，使用功能性洗涤液等；二是通过接触传播的：我们将物品制造成具有自动抗菌的涂料、瓷砖、座椅、办公桌等各类日常用品，从而极大限度地减少了有害病菌的扩繁与传播；
应当指出，早在上个世纪初九十年代初，一场由日本爆发的0-157大肠杆菌引发的抗菌产品热，经过近二十多年市场销售引导已经有了洗衣机、空调等日常用品，但过去大部分均采用银型、光触媒等技术方案，由于上述材料不仅价格昂贵而且添加过程中需要控制的环节繁琐复杂，所以尽管经过了二十多年的发展但市场的普及率不足1%。
发明内容
本发明的目的是提供一种涂料及陶瓷用改性锻烧高岭土的制造方法，以便制造出价格低廉杀菌功能显著，能广泛添加到日常用品制造环节的锻烧高岭土，以及用锻烧高岭土制造出的涂料对常见的病菌具有显著的灭杀功能，给人们的生命健康带来福音。
为实现上述目的，本发明采用的技术方法，包括如下步骤：
步骤一、备料：按重量份备齐如下备料：
高岭土：70~80，硼砂：12~20，氧化锌：4~10，氧化铈：1~5，硅酸钠：1~2；并将上述原料中高岭土备料误差控制在1%，硼砂、氧化锌的配料误差控制在0.5%，氧化铈、硅酸钠配料误差控制在0.1%；
步骤二、制浆：将上述物料投入球磨罐中，其水分控制在28%~32%左右，球磨料浆过200目筛，流速45~60秒时送入料浆仓陈腐待用；
步骤三、喷雾干燥：将合格的浆料在450~550℃喷雾干燥塔中脱去结晶水，其颗粒控制在1~3毫米，转入粉料仓均化待用；
步骤四、锻烧：将均化合格的粉料在900~1100℃烧结成熟料，冷却至室温后运入熟料仓待用；
步骤五、粉磨：将步骤四所得熟料粉磨，当用于制造抗菌陶瓷添加时粉磨过200目，当用于制造抗菌涂料添加时粉磨过400目，当用于造纸制造抗菌卫生纸添加时粉磨过800目，当用于制造抗菌化妆品时粉磨过1200目；
步骤六、检验包装：经检验所生产的粉体配料误差符合设计要求，细度符合使用要求后包装入库；
步骤七、改性锻烧高岭土产品制造：
1. 改性锻烧高岭土的涂料制造：
将改性锻烧高岭土在涂料生产时置换原组方锻烧高岭土的组方或添加3~5%，本产品无需改变涂料生产的工艺也不会对以前生产的工艺指标造成任何影响，按原工艺进行生产即可，所得产品经检测符合HG/T3950-2007的标准,对多种病菌均有显著的灭活效果；
2. 改性锻烧高岭土的陶瓷制造：
将改性锻烧高岭土在陶瓷生产时置换原组方锻烧高岭土的组方或添加3~5%，本产品无需改变陶瓷生产的工艺也不会对以前生产的工艺指标造成任何影响，按原工艺进行生产即可，所得产品经检测符合JC/T897-2014的标准,对多种病菌均有显著的灭活效果。
本发明与现有技术相比有如下显著的进步：
1、采用高岭土与硼砂、氧化锌、氧化铈锻烧改性比传统的银型更具经济性和安全性，
2、采用高岭土与硼砂、氧化锌、氧化铈锻烧改性比传统的光触媒更稳定且时效更长，特别是解决了光触媒陶瓷不能一次性烧成的难题，
3、采用高岭土与硼砂、氧化锌、氧化铈锻烧改性比传统的锻烧高岭土锻烧温度降低300~400℃，节能达50%以上，
4、采用氧化铈激活硼、锌不仅减少了硼添加量的问题，同时也解决了锌的添加量的问题，从而达到了功能性、安全性、经济性的完美统一；同时经过锻烧改性后的锻烧高岭土替代纳米氧化锌解决了涂料、釉浆触变的难题。
本发明所述技术方案的设计配比的理论依据：
1. 高岭土70~80，优选地为72~78，根据广泛的市场调查研究，涂料、陶瓷里面锻烧高岭土的掺量一般都在3~5%左右由于高岭土在锻烧时还会失去表面水和结晶水达30%以上实质上经过锻烧改性后其功能材料的含量已达28~38%此时硼砂、氧化锌、氧化铈的总量在涂料或者陶瓷中已达1~2%，经检测，符合安全性、经济性、功能性的要求；
2. 硼砂12~20，优选地为14~18，当少于12时会降低产品的功能性，当多于20时，减少了氧化锌与氧化铈的配入同样影响了功能性；
3.氧化锌4~10，优选地为5~9，当少于4时会降低产品的功能性，当多于10时会增加无效成本；
4氧化铈1~5，优选地为2~4，当少于1时，对激活硼、锌贡献不足，当多于5是会增加无效的成本；
5硅酸钠1~2，本产品中仅作为解胶剂，增加量为经验值；
6.本发明不仅适用于涂料、陶瓷的添加，同时也适用于塑料、纤维、化妆品的添加，因而具有广泛的市场前景。
具体实施方式
实施例一：涂料及陶瓷用改性锻烧高岭土的制造方法之一，该方法包括如下步骤：
步骤一、备料：按重量份备齐如下物料：
高岭土：70，硼砂：20，氧化锌：6，氧化铈：3，硅酸钠：1，将上述物料中高岭土备料误差控制在1%，硼砂、氧化锌的配料误差控制在0.5%，氧化铈、硅酸钠配料误差控制在0.1%；
步骤二、制浆：将上述物料投入球滤罐中，其水分控制在32%左右，球磨料浆过200目筛，流速60秒时送入料浆仓陈腐待用；
步骤三、喷雾干燥：将合格的浆料在450℃喷雾干燥塔中脱去结晶水，其颗粒控制在3毫米，送入粉料仓均化待用；
步骤四、锻烧：将均化合格的粉料在1100℃烧结成熟料，冷却至室温后运入熟料仓待用；
步骤五、粉磨：将步骤四所得熟料粉磨，用于制造抗菌陶瓷时粉磨过200目；
步骤六、检验包装：经检验所生产的粉体配料误差符合设计要求，细度符合使用要求后包装入库；
步骤七、改性锻烧高岭土陶瓷产品的制造：将改性锻烧高岭土在陶瓷生产时置换原组方中的锻烧高岭土组方或添加3~5%，无需改变陶瓷生产的工艺也不会对以前生产的工艺指标造成任何影响，按原工艺进行生产即可，所得产品经检测符合JC/T897-2014的标准,对多种病菌均有显著的灭活效果。
实施例二：涂料及陶瓷用改性锻烧高岭土的制造方法之二，所述方法包括如下步骤：
步骤一、备料（重量份）：高岭土：80，硼砂：12，氧化锌：4，氧化铈：2，硅酸钠：2，将上述物料中高岭土备料误差控制在1%，硼砂、氧化锌、氧化铈的配料误差控制在0.5%，硅酸钠配料误差控制在0.1%；
步骤二、制浆：将上述物料投入球滤罐中，其水分控制在32%左右，球磨料浆过200目筛，流速60秒时送入料浆仓陈腐待用；
步骤三、喷雾干燥：将合格的浆料在550℃喷雾干燥塔中脱去结晶水，其颗粒控制在1毫米，送入粉料仓均化待用；
步骤四、锻烧：将均化合格的粉料在900℃烧结成熟料，冷却至室温后运入熟料仓待用；
步骤五、粉磨：将步骤四所得熟料粉磨，用于涂料制造抗菌涂料添加时粉磨过400目；
步骤六、检验包装：经检验所生产的粉体配料误差符合设计要求，细度符合使用要求后包装入库；
步骤七、改性锻烧高岭土涂料制造：将改性锻烧高岭土在涂料生产时置换原配方锻烧高岭土的组方或添加3~5%，无需改变涂料生产的工艺也不会对以前生产的工艺指标造成任何影响，按原工艺进行生产即可，所得产品经检测符合HG/T3950-2007的标准,对多种病菌均有显著的灭活效果。
上述仅为本发明的两个具体实施例，但本发明的设计和构思并不局限于此，凡利用此构思对本发明进行非实质性改动，均属于侵犯本发明保护范围。

Claims (3)

1.一种涂料及陶瓷用改性锻烧高岭土的制造方法，其特征是：所述方法包括如下步骤：
步骤一、备料：按重量份备齐如下物料：
高岭土：70~80，硼砂：12~20，氧化锌：4~10，氧化铈：1~5，硅酸钠：1~2；并将上述原料中高岭土备料误差控制在1%，硼砂、氧化锌的配料误差控制在0.5%，氧化铈、硅酸钠配料误差控制在0.1%；
步骤二、制浆：将上述物料投入球磨罐中，其水分控制在28%~32%左右，球磨料浆过200目筛，流速45~60秒时送入料浆仓陈腐待用；
步骤三、喷雾干燥：将合格的浆料在450~550℃喷雾干燥塔中脱去结晶水，其颗粒控制在1~3毫米，转入粉料仓均化待用；
步骤四、锻烧：将均化合格的粉料在900~1100℃烧结成熟料，冷却至室温后运入熟料仓待用；
步骤五、粉磨：将步骤四所得熟料粉磨，当用于制造抗菌陶瓷添加时粉磨过200目，当用于制造抗菌涂料添加时粉磨过400目，当用于造纸制造抗菌卫生纸添加时粉磨过800目，当用于制造抗菌化妆品时粉磨过1200目；
步骤六、检验包装：经检验所生产的粉体配料误差符合设计要求，细度符合使用要求后包装入库；
步骤七、改性锻烧高岭土产品制造：
A、改性锻烧高岭土的涂料制造：将改性锻烧高岭土在涂料生产时置换原组方锻烧高岭土的组方或添加3~5%，本产品无需改变涂料生产的工艺也不会对以前生产的工艺指标造成任何影响，按原工艺进行生产即可，所得产品经检测符合HG/T3950-2007的标准,对多种病菌均有显著的灭活效果；
B、的陶瓷制造：将改性锻烧高岭土在陶瓷生产时置换原组方锻烧高岭土的组分或添加3~5%，本产品无需改变陶瓷生产的工艺也不会对以前生产的工艺指标造成任何影响，按原工艺进行生产即可，所得产品经检测符合JC/T897-2014的标准,对多种病菌均有显著的灭活效果。
2.根据权利要求1所述涂料及陶瓷用改性锻烧高岭土的制造方法，其特征是：所述方法包括如下步骤：
步骤一、备料按重量份备齐如下物料
高岭土：70，硼砂：20，氧化锌：6，氧化铈：3，硅酸钠：1，将上述物料中高岭土备料误差控制在1%，硼砂、氧化锌的配料误差控制在0.5%，氧化铈、硅酸钠配料误差控制在0.1%；
步骤二、制浆：将上述物料投入球滤罐中，其水分控制在32%左右，球磨料浆过200目筛，流速60秒时送入料浆仓陈腐待用；
步骤三、喷雾干燥：将合格的浆料在450℃喷雾干燥塔中脱去结晶水，其颗粒控制在3毫米，送入粉料仓均化待用；
步骤四、锻烧：将均化合格的粉料在1100℃烧结成熟料，冷却至室温后运入熟料仓待用；
步骤五、粉磨：将步骤四所得熟料粉磨，用于制造抗菌陶瓷时粉磨过200目；
步骤六、检验包装：经检验所生产的粉体配料误差符合设计要求，细度符合使用要求后包装入库；
步骤七、改性锻烧高岭土陶瓷产品的制造：将改性锻烧高岭土在陶瓷生产时置换原组方中的锻烧高岭土组方或添加3~5%，无需改变陶瓷生产的工艺也不会对以前生产的工艺指标造成任何影响，按原工艺进行生产即可，所得产品经检测符合JC/T897-2014的标准,对多种病菌均有显著的灭活效果。
3.根据权利要求1所述涂料及陶瓷用改性锻烧高岭土的制造方法，其特征是：所述方法包括如下步骤：
步骤一、备料（重量份）：
高岭土：80，硼砂：12，氧化锌：4，氧化铈：2，硅酸钠：2，将上述物料中高岭土备料误差控制在1%，硼砂、氧化锌、氧化铈的配料误差控制在0.5%，硅酸钠配料误差控制在0.1%；
步骤二、制浆：将上述物料投入球滤罐中，其水分控制在32%左右，球磨料浆过200目筛，流速60秒时送入料浆仓陈腐待用；
步骤三、喷雾干燥：将合格的浆料在550℃喷雾干燥塔中脱去结晶水，其颗粒控制在1毫米，送入粉料仓均化待用；
步骤四、锻烧：将均化合格的粉料在900℃烧结成熟料，冷却至室温后运入熟料仓待用；
步骤五、粉磨：将步骤四所得熟料粉磨，用于涂料制造抗菌涂料添加时粉磨过400目；
步骤六、检验包装：经检验所生产的粉体配料误差符合设计要求，细度符合使用要求后包装入库；
步骤七、改性锻烧高岭土涂料的制造：将改性锻烧高岭土在涂料生产时置换原配方锻烧高岭土的组方或添加3~5%，无需改变涂料生产的工艺也不会对以前生产的工艺指标造成任何影响，按原工艺进行生产即可，所得产品经检测符合HG/T3950-2007的标准,对多种病菌均有显著的灭活效果。
CN202010179008.4A 2020-03-15 2020-03-15 一种涂料及陶瓷用改性锻烧高岭土的制造方法 Pending CN111269589A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010179008.4A CN111269589A (zh) 2020-03-15 2020-03-15 一种涂料及陶瓷用改性锻烧高岭土的制造方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010179008.4A CN111269589A (zh) 2020-03-15 2020-03-15 一种涂料及陶瓷用改性锻烧高岭土的制造方法

Publications (2)

Publication Number Publication Date
CN111269589A true CN111269589A (zh) 2020-06-12
CN111269589A8 CN111269589A8 (zh) 2020-11-24

Family

ID=70997869

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010179008.4A Pending CN111269589A (zh) 2020-03-15 2020-03-15 一种涂料及陶瓷用改性锻烧高岭土的制造方法

Country Status (1)

Country Link
CN (1) CN111269589A (zh)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101367617A (zh) * 2008-09-23 2009-02-18 中国地质大学（武汉） 玻纤用高岭土的制备方法
CN102249694A (zh) * 2011-04-29 2011-11-23 佛山石湾鹰牌陶瓷有限公司 一种轻质陶瓷砖的生产方法
CN105060848A (zh) * 2015-07-29 2015-11-18 安徽鑫润新型材料有限公司 一种轻质节能防腐添加钢渣的陶瓷砖
CN106986541A (zh) * 2017-05-04 2017-07-28 山东省无棣海洋贝瓷有限公司 一种易洁抗菌功能贝瓷釉料及其制备方法
CN108793960A (zh) * 2018-08-23 2018-11-13 广西亚欧瓷业有限公司 一种可释放负离子的耐磨陶瓷砖的制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101367617A (zh) * 2008-09-23 2009-02-18 中国地质大学（武汉） 玻纤用高岭土的制备方法
CN102249694A (zh) * 2011-04-29 2011-11-23 佛山石湾鹰牌陶瓷有限公司 一种轻质陶瓷砖的生产方法
CN105060848A (zh) * 2015-07-29 2015-11-18 安徽鑫润新型材料有限公司 一种轻质节能防腐添加钢渣的陶瓷砖
CN106986541A (zh) * 2017-05-04 2017-07-28 山东省无棣海洋贝瓷有限公司 一种易洁抗菌功能贝瓷釉料及其制备方法
CN108793960A (zh) * 2018-08-23 2018-11-13 广西亚欧瓷业有限公司 一种可释放负离子的耐磨陶瓷砖的制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
舒展，等: "硅酸盐黏土矿物在抗菌方面研究进展", 《材料工程》 *

Also Published As

Publication number Publication date
CN111269589A8 (zh) 2020-11-24

Similar Documents

Publication Publication Date Title
CN111995364B (zh) 一种抗菌岩板及其制备方法
CN106746668B (zh) 一种抗菌陶瓷釉液及其制备方法
CN106957168B (zh) 一种可抗菌瓷砖及其制作方法
CN111116171A (zh) 一种抗菌防霉陶瓷工艺品及其制备方法
CN109399932A (zh) 一种陶瓷釉料和陶瓷
CN107254238A (zh) 一种新型环保涂料及其制备方法
CN110256041A (zh) 一种易清洁的光催化抗菌陶瓷及其制备方法
CN107721382A (zh) 一种抗菌彩陶
CN110256111A (zh) 一种负离子全抛釉及其加工方法
CN1420146A (zh) 新型抗菌保健纳米生态涂料
CN111269589A (zh) 一种涂料及陶瓷用改性锻烧高岭土的制造方法
CN106866103A (zh) 纳米防火装饰板及其制造方法
CN107721174A (zh) 一种具有保健作用的钧瓷釉料的施釉工艺
CN103132370A (zh) 一种抗菌保健功能纸粘土的组成及制备方法和用途
CN113149067B (zh) 一种正钛酸锌粉体及其制备方法
CN102515866A (zh) 一种具有抗菌能力的陶瓷釉及其制备方法
US20230091820A1 (en) Antimicrobial Ceramic Tile and Manufacturing Method Thereof
CN105565669A (zh) 搪瓷涂料及其制备方法和搪瓷产品
CN101580665A (zh) 释放负离子墨汁、墨水及其制备方法
CN104961434A (zh) 一种高抗冲击陶瓷器皿及其制备方法
CN108546079A (zh) 一种电力设备用绝缘陶瓷的制作方法
CN107628778A (zh) 一种多功能室内装修材料的制备工艺
CN109305812A (zh) 负离子钛晶杀菌生态砖
CN110204935A (zh) 一种新型墙体涂料及制备方法
CN104987098A (zh) 一种钛酸铝纤维增强的陶瓷器皿及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CI02 Correction of invention patent application

Correction item: Applicant|Address|Applicant

Correct: Lei Zhigang|410100 404, Good Morning Star City, No. 1, Tianhua South Road, Changsha County, Changsha City, Hunan Province|Jiangsu Lihai Environmental Protection Technology Co., Ltd.

False: Lei Zhigang|410100 404, Good Morning Star City, No. 1, Tianhua South Road, Changsha County, Changsha City, Hunan Province|Technology Lihai Environmental Technology Co., Ltd.

Number: 24-02

Page: The title page

Volume: 36

Correction item: Applicant|Address|Applicant

Correct: Lei Zhigang|410100 404, Good Morning Star City, No. 1, Tianhua South Road, Changsha County, Changsha City, Hunan Province|Jiangsu Lihai Environmental Protection Technology Co., Ltd.

False: Lei Zhigang|410100 404, Good Morning Star City, No. 1, Tianhua South Road, Changsha County, Changsha City, Hunan Province|Technology Lihai Environmental Technology Co., Ltd.

Number: 24-02

Volume: 36

CI02 Correction of invention patent application
TA01 Transfer of patent application right

Effective date of registration: 20201119

Address after: Building 44-101, No.1, Changxing Road, Nantong Development Zone, Jiangsu Province, 226001

Applicant after: Jiangsu nading Material Technology Co., Ltd

Address before: 410100 Morning Star City, No.1, Tianhua South Road, Changsha County, Changsha City, Hunan Province 404

Applicant before: Lei Zhigang

Applicant before: Jiangsu Lihai Environmental Protection Technology Co.,Ltd.

TA01 Transfer of patent application right
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20200612

WD01 Invention patent application deemed withdrawn after publication