CN111264560A - Non-toxic raticide-V type and preparation method thereof - Google Patents
Non-toxic raticide-V type and preparation method thereof Download PDFInfo
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- CN111264560A CN111264560A CN202010184988.7A CN202010184988A CN111264560A CN 111264560 A CN111264560 A CN 111264560A CN 202010184988 A CN202010184988 A CN 202010184988A CN 111264560 A CN111264560 A CN 111264560A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
- A01N25/004—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits rodenticidal
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
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- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Food Science & Technology (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A nontoxic deratization poison bait medicine-V type is prepared by the following components according to the parts by weight: paraffin, calcium silicate, adhesive, carboxymethyl cellulose, grains, attractant and edible preservative calcium propionate. Mixing paraffin, calcium silicate, carboxymethyl cellulose, adhesive, grain, attractant, and edible antiseptic calcium propionate at a certain proportion, stirring, loading into molding equipment, pressing bait, and making into granule, unguent, tracking agent, waterproof pill, block, suspensible agent, and limb adhesive. The carboxymethyl cellulose is used for absorbing water in the stomach and expanding and solidifying with gastric juice, and the water and gastric juice are jointly adhered to the intestines and stomach to cause intestinal obstruction, so that rats can not eat the food, substances in the intestinal tract can not be discharged, and finally the death is caused. The invention has the advantages of no toxicity, no pollution to the environment, no harm to other organisms eating dead mice by mistake, no secondary poisoning, low cost, low content of effective substances, high deratization efficiency and obvious effect, and is applied to the technical field of rodent drug control.
Description
Technical Field
The invention relates to a nontoxic deratization bait-V type and a preparation method thereof, belonging to the technical field of rodent drug control.
Background
Currently, the control of murine population numbers is a long-term task facing the world, since the rate of murine reproduction is incomparable with all mammals on earth, with a large negative impact on the ecological environment and disease transmission. To achieve this goal, the worldwide cost of purchasing large quantities of each type of rodenticide is around 20 billion dollars each year. The application of various rodenticides has a plurality of problems, firstly, the production of various rodenticides consumes manpower and capital, and simultaneously, the production process has the discharge of three wastes in chemical industry, thus causing pressure to the environment; in the application of various medicines, various basic animals in the ecological environment can be injured or killed by mistake, and the harmony of the environment and the ecology is influenced.
At present, the rat has great negative influence on the production and life of human beings, so that the agricultural yield is reduced, a large amount of agricultural and sideline products are consumed, the production of forestry and forest culture is difficult, industrial and water conservancy facilities are damaged and consumed, diseases are infected, the environment is polluted, and the health and life safety of human beings are threatened, so the control of the population quantity of the rats is a long-term task which needs to be faced all over the world. However, the application of various raticides has many problems, the most popular raticides are the highly toxic raticides, the raticides have high toxicity, the problem of chemical three-waste emission exists in the production process, great pressure is caused to the environment and the ecology, and the reports of poisoning caused by mistaken eating of the raticides by people or animals and death of the mice are more rare. Aiming at the problems, the invention aims to develop a novel non-toxic raticide, which achieves the deratization effect without depending on a high-toxicity chemical raticide, and is more favorable for protecting the ecological environment and ensuring the safety of human beings.
The patent No. 201910965736.5 discloses a nontoxic raticide bait-I and a preparation method thereof, wherein the differences between the bait and the invention are that extracted alkaloid is used as an M-receptor blocker to compete with acetylcholine for parasympathetic nerve receptors, the extracted alkaloid in the bait acts on the rat intestinal tract after entering the rat intestinal tract to relieve smooth muscle spasm and slow down the movement of the rat intestinal tract, and the characteristics of easy solidification, difficult digestion and gastrointestinal adhesion of barium sulfate are utilized to cause precipitation and solidification in the rat intestinal tract under the condition of a precursor that the rat intestinal tract does not move, so that the rat intestinal tract is fully filled to cause intestinal obstruction, the rat cannot eat, substances in the intestinal tract cannot be discharged, and finally death is caused.
The invention discloses 201910965698.3 a non-toxic raticide-II and a preparation method thereof, and the non-toxic raticide-II is characterized in that an extracted alkaloid is used as an M-receptor blocking agent to compete with acetylcholine for parasympathetic nerve receptors, the extracted alkaloid in the raticide acts on the rat intestinal tract after entering the rat intestinal tract, so as to relieve smooth muscle spasm and slow down the movement of the rat intestinal tract, and the characteristics of easy solidification, difficult digestion and gastrointestinal adhesion of barium sulfate and carboxymethyl cellulose are utilized to cause precipitation and solidification in the rat intestinal tract under the condition of a precursor that the muscle of the rat intestinal tract does not move, so that the rat intestinal tract is fully filled to cause intestinal obstruction, the rat cannot eat, substances in the intestinal tract cannot be discharged, and finally the rat dies.
The patent No. 201910965708.3 discloses a nontoxic rodenticide bait-III and its preparation method, wherein the bait is prepared by using extracted alkaloid as M-receptor blocker to compete with acetylcholine for parasympathetic nerve receptor, wherein the extracted alkaloid in the bait enters rat intestinal tract to act on the rat intestinal tract to relieve smooth muscle spasm and slow down the movement of rat intestinal tract, barium sulfate is precipitated and solidified in the rat intestinal tract under the condition of non-moving precursor of rat intestinal tract muscle, carboxymethyl cellulose can slowly absorb water, the volume of carboxymethyl cellulose can be continuously expanded and has certain adhesion effect, so that rat intestinal tract is fully filled, and barium sulfate, carboxymethyl cellulose and oxalic acid are used to form calcium oxalate particles which are insoluble in water and precipitate when meeting calcium ions, so as to cause intestinal obstruction, and rat can not eat food and substances in intestinal tract can not be discharged, and finally death can be caused.
The patent No. 201911246556.8 relates to a nontoxic raticide, namely type IV bait and a preparation method thereof, wherein the difference between the bait and the patent of the invention is that extracted alkaloid is used as an M-receptor blocker to compete with acetylcholine for parasympathetic nerve receptors to cause intestinal smooth muscle spasmolysis of intestines and stomach, the extracted alkaloid in the bait acts on the intestinal tract of mice to relieve the smooth muscle spasm after entering the intestinal tract of the mice, so as to slow down the movement of the intestinal tract of the mice, and under the precursor of the intestinal muscle movement of the mice, the characteristics of calcium silicate that calcium silicate does not precipitate, solidify, is difficult to digest and adheres to the intestines and stomach are utilized to cause the intestinal obstruction of the mice, the mice cannot eat, substances in the intestinal tract cannot be discharged, and finally the mice die.
Therefore, the development of a nontoxic deratization bait-V and a preparation method thereof are always a new problem to be solved urgently.
Disclosure of Invention
The invention aims to provide a nontoxic rodenticide bait-type V and a preparation method thereof, wherein calcium silicate and carboxymethyl cellulose are utilized to cause the intestinal obstruction of rats, and the rats cannot defecate and finally die, so that the purpose of no toxicity and no pollution is achieved.
The purpose of the invention is realized as follows: a non-toxic deratization poison bait-V type is prepared by the following components in parts by weight: 20-35 parts of paraffin, 15-45 parts of calcium silicate, 5 parts of adhesive, 5-15 parts of carboxymethyl cellulose, 30-65 parts of grain, 0.3 part of attractant and 0.2 part of edible preservative calcium propionate;
the adhesive is aquatic product adhesive, and plays a role in shaping under the combined action of the aquatic product adhesive and paraffin;
the preservative is edible preservative calcium propionate, the dosage of the preservative does not exceed 1.8g/kg of the dosage of national standard grain, and the preservative is safe and environment-friendly;
the preparation method of the nontoxic deratization bait-V type comprises the steps of mixing and stirring paraffin, calcium silicate, carboxymethyl cellulose, adhesive, grain, attractant and edible preservative calcium propionate uniformly according to a proportion, then loading the mixture into forming equipment to press bait, and then preparing granules, paste, tracer, waterproof pills, blocks, suspensible agents and limb adhesive;
the non-toxic deratization bait-V has the action mechanism that calcium silicate is precipitated, solidified and difficult to digest in intestines and stomach, carboxymethyl cellulose absorbs water in the stomach and expands and solidifies with gastric juice to jointly adhere to the intestines and stomach to cause intestinal obstruction, rats can not eat the bait, substances in the intestines can not be discharged, and finally death is caused; calcium silicate, carboxymethyl cellulose and an adhesive involved in the bait ingredients are nontoxic, the applied attractant and grains have no food calling preference for the rodent, the attractant does not play a food calling role for other animals, the bait does not cause the other animals to eat by mistake, after the dead rat is eaten by natural enemies, the reaction of deposition and expansion in the dead rat is finished, the non-rodent is not damaged, and the harmlessness to the ecological environment is realized; the paraffin and the adhesive give certain shape to the bait, so that the shape of the bait is not easy to damage when the bait is corroded by water; the components of the bait are all natural components, so the bait is easy to mildew and deteriorate in the natural environment, and the problem of mildew and deterioration can be solved by adding the edible preservative calcium propionate, so that the service life of the bait is prolonged under natural complex conditions; the invention is nontoxic, has no pollution to the environment, has no harm to other organisms eating dead mice by mistake, does not cause secondary poisoning, has low cost, high deratization efficiency and obvious effect;
the non-toxic deratization bait-V type experimental method is carried out under the laboratory condition, 200g of deratization bait is taken and placed in a mouse cage, 6 mice are respectively placed in the mouse cage, the feeding condition is observed, after 2 hours, 191.2g of the bait is weighed, 8.8g of the bait is eaten after being stolen, and the average intake of 1.5g of the bait for each mouse is obtained; after 48 hours, 1 dead mouse appeared; 3 mice were killed after 72 hours, and 2 mice remained to be killed for 5 days; 6 intestinal obstructions of the intestines and the stomach are found after dead mice are dissected;
the second experimental method of the non-toxic deratization bait-V type is that 1000g of deratization bait is taken, a pig farm with high rat density is selected to put the deratization bait in 10 piles, the stealing eating condition is observed, 350g of the rest bait is weighed the next day, 650g of the bait is eaten by stealing, after three days, 10 dead rats are found near the feeding place, and the rats are confirmed to die due to intestinal obstruction through anatomy.
The main points of the invention are the weight portion proportion, the preparation method and the action mechanism of each component of the nontoxic deratization bait-V type.
Compared with the prior art, the non-toxic deratization bait-V type and the preparation method thereof have the advantages of non-toxicity, no pollution to the environment, no harm to other organisms eating dead rats by mistake, no secondary poisoning, low cost, low content of effective substances, high deratization efficiency, obvious effect and the like, and can be widely applied to the technical field of rodent drug control.
Detailed Description
A non-toxic deratization poison bait-V type is prepared by the following components in parts by weight: 20-35 parts of paraffin, 15-45 parts of calcium silicate, 5 parts of adhesive, 5-15 parts of carboxymethyl cellulose, 30-65 parts of grain, 0.3 part of attractant and 0.2 part of edible preservative calcium propionate.
The adhesive is aquatic product adhesive, and plays a role in shaping under the combined action of the aquatic product adhesive and paraffin.
The preservative is edible preservative calcium propionate, the dosage of the preservative is not more than 1.8g/kg of national standard grain dosage, and the preservative is safe and environment-friendly.
The preparation method of the nontoxic deratization bait-V type comprises the steps of mixing and stirring paraffin, calcium silicate, carboxymethyl cellulose, adhesive, grain, attractant and edible preservative calcium propionate uniformly according to a proportion, then putting the mixture into forming equipment to press bait, and then preparing granules, paste, tracer, waterproof pills, blocks, suspensible agents and limb adhesive.
The non-toxic deratization bait-V has the action mechanism that calcium silicate is precipitated, solidified and difficult to digest in intestines and stomach, carboxymethyl cellulose absorbs water in the stomach and expands and solidifies with gastric juice to jointly adhere to the intestines and stomach to cause intestinal obstruction, rats can not eat the bait, substances in the intestines can not be discharged, and finally death is caused; calcium silicate, carboxymethyl cellulose and an adhesive involved in the bait ingredients are nontoxic, the applied attractant and grains aim at the eating preference of the rodent, the attractant does not play a food calling role for other animals, the accidental eating of other animals cannot be caused, after the dead rat is eaten by natural enemies (such as snakes and birds), the reaction of deposition and expansion in the dead rat is finished, the non-rodent animal cannot be damaged, and the harmlessness to the ecological environment is realized; the paraffin and the adhesive give certain shape to the bait, so that the shape of the bait is not easy to damage when the bait is corroded by water; the components of the bait are all natural components, so the bait is easy to mildew and deteriorate in the natural environment, and the problem of mildew and deterioration can be solved by adding the edible preservative calcium propionate, so that the service life of the bait is prolonged under natural complex conditions; the invention has no toxicity, no pollution to the environment, no harm to other organisms eating dead mice by mistake, no secondary poisoning, low cost, high efficiency of killing the mice and obvious effect.
The non-toxic deratization bait-V type experimental method is carried out under the laboratory condition, 200g of deratization bait is taken and placed in a mouse cage, 6 mice are respectively placed in the mouse cage, the feeding condition is observed, after 2 hours, 191.2g of the bait is weighed, 8.8g of the bait is eaten after being stolen, and the average intake of 1.5g of the bait for each mouse is obtained; after 48 hours, 1 dead mouse appeared; 3 mice were killed after 72 hours, and 2 mice remained to be killed for 5 days; after the dead mice are dissected, 6 gastrointestinal intestinal obstructions are found.
The second experimental method of the non-toxic deratization bait-V type is that 1000g of deratization bait is taken, a pig farm with high rat density is selected to put the deratization bait in 10 piles, the stealing eating condition is observed, 350g of the rest bait is weighed the next day, 650g of the bait is eaten by stealing, after three days, 10 dead rats are found near the feeding place, and the rats are confirmed to die due to intestinal obstruction through anatomy.
Example one
The preparation method of the nontoxic deratization bait-V type comprises the steps of mixing and stirring 25 kg of paraffin, 30 kg of calcium silicate, 9.5 kg of carboxymethyl cellulose, 5 kg of adhesive, 30 kg of grain, 0.3 kg of attractant and 0.2 kg of edible preservative in proportion, loading the mixture into forming equipment to press bait, and then preparing granules, paste, tracer, waterproof pills, blocks, suspensible agents and limb adhesives.
Example two
28 kg of paraffin, 25.5 kg of calcium silicate, 6 kg of carboxymethyl cellulose, 5 kg of adhesive, 35 kg of grain, 0.3 kg of attractant and 0.2 kg of edible preservative are mixed and stirred uniformly according to a proportion, then the mixture is put into forming equipment to be pressed into bait, and then granules, paste, tracer, waterproof pills, blocks, suspensible agents and limb adhesives are prepared.
20-35 parts of paraffin, 15-45 parts of calcium silicate, 5 parts of adhesive, 5-15 parts of carboxymethyl cellulose, 30-65 parts of grain, 0.3 part of attractant and 0.2 part of preservative.
EXAMPLE III
The preparation method of the nontoxic deratization bait-V type comprises the steps of mixing and stirring 20 kg of paraffin, 29 kg of calcium silicate, 9.5 kg of carboxymethyl cellulose, 5 kg of adhesive, 36 kg of grain, 0.3 kg of attractant and 0.2 kg of edible preservative in proportion, loading the mixture into forming equipment to press the bait, and then preparing granules, paste, tracer, waterproof pills, block agents, suspensible agents and limb adhesives.
Example four
The preparation method of the nontoxic deratization bait-V type comprises the steps of mixing and stirring 22 kg of paraffin, 18 kg of calcium silicate, 12.5 kg of carboxymethyl cellulose, 5 kg of adhesive, 42 kg of grain, 0.3 kg of attractant and 0.2 kg of edible preservative in proportion, loading the mixture into forming equipment to press bait, and then preparing granules, paste, tracer, waterproof pills, blocks, suspensible agents and limb adhesives.
Claims (7)
1. A nontoxic deratization poison bait-V type, which is characterized in that: the nontoxic deratization poison bait-V type is prepared from the following components in parts by weight: 20-35 parts of paraffin, 15-45 parts of calcium silicate, 5 parts of adhesive, 5-15 parts of carboxymethyl cellulose, 30-65 parts of grain, 0.3 part of attractant and 0.2 part of edible preservative calcium propionate.
2. A non-toxic rodenticidal bait-form v according to claim 1, which is characterized in that: the adhesive is aquatic product adhesive, and plays a role in shaping under the combined action of the aquatic product adhesive and paraffin.
3. A non-toxic rodenticidal bait-form v according to claim 1, which is characterized in that: the preservative is edible preservative calcium propionate, the dosage of the preservative is not more than 1.8g/kg of national standard grain dosage, and the preservative is safe and environment-friendly.
4. The method for preparing a non-toxic rodenticide bait-type v according to claim 1, which comprises: the preparation method of the nontoxic deratization bait-V type comprises the steps of mixing and stirring paraffin, calcium silicate, carboxymethyl cellulose, adhesive, grain, attractant and edible preservative calcium propionate uniformly according to a proportion, then putting the mixture into forming equipment to press bait, and then preparing granules, paste, tracer, waterproof pills, blocks, suspensible agents and limb adhesive.
5. A non-toxic rodenticidal bait-form v according to claim 1, which is characterized in that: the non-toxic deratization bait-V has the action mechanism that calcium silicate is precipitated, solidified and difficult to digest in intestines and stomach, carboxymethyl cellulose absorbs water in the stomach and expands and solidifies with gastric juice to jointly adhere to the intestines and stomach to cause intestinal obstruction, rats can not eat the bait, substances in the intestines can not be discharged, and finally death is caused; calcium silicate, carboxymethyl cellulose and an adhesive involved in the bait ingredients are nontoxic, the applied attractant and grains have no food calling preference for the rodent, the attractant does not play a food calling role for other animals, the bait does not cause the other animals to eat by mistake, after the dead rat is eaten by natural enemies, the reaction of deposition and expansion in the dead rat is finished, the non-rodent is not damaged, and the harmlessness to the ecological environment is realized; the paraffin and the adhesive give certain shape to the bait, so that the shape of the bait is not easy to damage when the bait is corroded by water; the components of the bait are all natural components, so the bait is easy to mildew and deteriorate in the natural environment, and the problem of mildew and deterioration can be solved by adding the edible preservative calcium propionate, so that the service life of the bait is prolonged under natural complex conditions; the invention has no toxicity, no pollution to the environment, no harm to other organisms eating dead mice by mistake, no secondary poisoning, low cost, high efficiency of killing the mice and obvious effect.
6. A non-toxic rodenticidal bait-form v according to claim 1, which is characterized in that: the non-toxic deratization bait-V type experimental method is carried out under the laboratory condition, 200g of deratization bait is taken and placed in a mouse cage, 6 mice are respectively placed in the mouse cage, the feeding condition is observed, after 2 hours, 191.2g of the bait is weighed, 8.8g of the bait is eaten after being stolen, and the average intake of 1.5g of the bait for each mouse is obtained; after 48 hours, 1 dead mouse appeared; 3 mice were killed after 72 hours, and 2 mice remained to be killed for 5 days; after the dead mice are dissected, 6 gastrointestinal intestinal obstructions are found.
7. A non-toxic rodenticidal bait-form v according to claim 1, which is characterized in that: the second experimental method of the non-toxic deratization bait-V type is that 1000g of deratization bait is taken, a pig farm with high rat density is selected to put the deratization bait in 10 piles, the stealing eating condition is observed, 350g of the rest bait is weighed the next day, 650g of the bait is eaten by stealing, after three days, 10 dead rats are found near the feeding place, and the rats are confirmed to die due to intestinal obstruction through anatomy.
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Cited By (7)
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| CN112772674A (en) * | 2021-02-24 | 2021-05-11 | 沈阳爱威科技发展股份有限公司 | Nontoxic deratization carboxymethyl cellulose and portland cement compound bait and preparation method thereof |
| CN112841186A (en) * | 2021-02-24 | 2021-05-28 | 沈阳爱威科技发展股份有限公司 | Non-toxic deratization quick-drying cement type bait and preparation method thereof |
| CN112841180A (en) * | 2021-02-24 | 2021-05-28 | 沈阳爱威科技发展股份有限公司 | Nontoxic deratization silicate cement type bait and preparation method thereof |
| CN112868669A (en) * | 2021-02-24 | 2021-06-01 | 沈阳爱威科技发展股份有限公司 | Nontoxic deratization expansive cement type bait and preparation method thereof |
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| CN112868648A (en) * | 2021-02-24 | 2021-06-01 | 沈阳爱威科技发展股份有限公司 | Nontoxic deratization acrylic acid-acrylamide water-absorbing expansion resin type bait and preparation method thereof |
| CN113207566A (en) * | 2021-05-19 | 2021-08-06 | 广东兴源农林有限公司 | Method for binding and cultivating dendrobium officinale broadleaf living tree to prevent damage of rats |
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| CN110583675A (en) * | 2019-10-12 | 2019-12-20 | 沈阳爱威科技发展股份有限公司 | Non-toxic raticide-II and preparation method thereof |
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