CN111138211B - Copper-colored blank particle-combined inkjet penetration decorative polished brick and preparation method thereof - Google Patents
Copper-colored blank particle-combined inkjet penetration decorative polished brick and preparation method thereof Download PDFInfo
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- CN111138211B CN111138211B CN202010036427.2A CN202010036427A CN111138211B CN 111138211 B CN111138211 B CN 111138211B CN 202010036427 A CN202010036427 A CN 202010036427A CN 111138211 B CN111138211 B CN 111138211B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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Abstract
The invention discloses a copper-colored blank particle combined inkjet infiltration decoration polished brick and a preparation method thereof. The raw materials of the copper-colored blank particles comprise: 45-50% of albite, 30-35% of iron phosphate, 5-10% of calcium phosphate, 3-10% of silicon tripolyphosphate and 5-10% of kaolin according to mass percentage.
Description
Technical Field
The invention relates to copper-colored blank particles, a copper-colored blank particle-combined inkjet permeation polished brick and a preparation method thereof, belonging to the technical field of production and manufacturing of ceramic bricks.
Background
In recent years, metal glaze becomes an important branch in the decoration effect of ceramics due to the unique color and texture, can generate the metallic elegant and gorgeous appearance effect when being used on ceramic products, and also covers a plurality of industries such as daily necessities decoration, architectural decoration, ceramics and the like. But the phenomenon of discoloration and black spots is easy to occur because the method is sensitive to a firing system; meanwhile, under the condition of poor wear resistance, certain limitation still exists in practical application, and the ink-jet permeable polished tile has the color of both the glazed tile and the wear resistance of the polished tile, but because no copper permeable ink exists at present, if metal glaze is applied on a glaze line subsequently, the metal glaze cannot be polished; even if the process of later-stage water jet parquet and secondary burning can be realized, no texture is in transition, the problem of cutting lines exists in the middle, the process is complex, and the cost is high.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides copper-colored blank particles, a copper-colored blank particle-combined inkjet infiltration decorative polished brick and a preparation method thereof.
In a first aspect, the present invention provides a copper-colored green body particle, wherein the raw materials of the copper-colored green body particle comprise: 45-50% of albite, 30-35% of iron phosphate, 5-10% of calcium phosphate, 3-10% of silicon tripolyphosphate and 5-10% of kaolin according to mass percentage.
The copper-colored green body particles of the invention have stable color development after being fired, can form a concave embossment three-dimensional effect after being fired, and meanwhile, the metal decoration part can not contact with people, thereby avoiding abrasion and having abundant and durable three-dimensional decoration effect.
Preferably, the particle size of the copper-colored blank particles is 6-20 meshes.
Preferably, the chemical composition of the copper green body particles comprises: by mass percent, SiO2：35～39％、Al2O3：10～12％、Fe2O3：15～17％、TiO2：0.1～0.2％、CaO：3～4％、MgO：0.1～0.2％、K2O：0.1～0.3％、Na2O：5～6％、P2O5: 25-27%, loss on ignition: 1 to 2 percent.
In a second aspect, the present invention provides a method for preparing the above copper-colored green body particles, comprising the steps of:
(1) ball milling: weighing raw materials according to a formula ratio, adding water into the raw materials, and ball-milling the raw materials into slurry;
(2) drying: drying the slurry obtained in the step (1) until the moisture content is 6-8 wt% to obtain a dried material;
(3) and (3) granulation: and (3) granulating the dried material obtained in the step (2) to obtain copper-colored blank particles.
Preferably, the fineness of the slurry in the step (1) is 325 meshes, and the standard sieve residue is 0.6-1.5%.
In a third aspect, the present invention provides a polished tile made using the above-described copper-colored green body particles.
Preferably, the polished tile comprises a green body containing a decorative layer made using the copper-colored green body particles and an inkjet pattern layer.
In a fourth aspect, the present invention provides a method for preparing the above polished tile, comprising the steps of:
(1) distributing the permeable fabric and the copper-colored blank particles, and performing compression molding to obtain a blank;
(2) printing an ink-jet pattern on the blank;
(3) and (5) sintering and polishing.
The polished tile provided by the invention well integrates the copper-colored blank particles and the permeable fabric, has a three-dimensional mold effect, and the texture of the mold changes along with the pattern, so that the cost of opening the mold is saved, and a better effect of decorating a glaze surface is achieved.
Preferably, the chemical components of the permeable fabric comprise: by mass percent, SiO2：65～69％、Al2O3：18～21％、Fe2O3：0.16～0.46％、TiO2：0.3～0.6％、CaO：0.3～0.6％、MgO：0.2～0.5％、K2O：4.5～6％、Na2O：2.5～3.5％、ZrO2: 0.5-2%, loss on ignition: 3.0 to 4.0 percent.
Preferably, in the step (1), the step of distributing the permeable fabric and the copper-colored blank particles by using digital positioning distribution comprises the following steps: and respectively loading the permeable fabric and the copper-colored blank particles into a hopper of digital material distribution equipment, and then positioning and controlling the blanking amount according to the design requirement to distribute the material.
Preferably, the blanking amount of the permeable fabric and the copper blank particles is changed according to the change of the design texture.
Preferably, the blanking amount of the permeable fabric is 1000-2000 g/m2。
Preferably, the blanking amount of the copper-colored blank particles is 100-1000 g/m2。
Preferably, the sintering period is 60-70 min, and the maximum sintering temperature range is 1190-1220 ℃.
The preparation method of the polished tile can adjust the blanking amount of the copper blank particles according to design requirements, combines ink-jet printing patterns, dries, burns and polishes, has simple and easy-to-operate process, and the obtained ink-jet permeable polished tile has a three-dimensional mold effect and can change along with the change of pattern textures, thereby enriching the decorative effect of the ink-jet permeable polished tile. And because the copper-colored blank particles can sink after being fired at a relatively low temperature, the three-dimensional die effect can be realized by distributing a corresponding number of the large copper-colored blank particles at a designed specific position through a digital material distribution technology, and the sunken area presents copper-colored metallic luster.
Drawings
FIG. 1 shows a flow chart for the preparation of a polished tile according to one embodiment of the present invention;
FIG. 2 is a graph showing the tile face effect of the copper green body particles in combination with an inkjet penetrant polished tile of example 1;
fig. 3 shows a brick effect plot of comparative example 1.
Detailed Description
The present invention is further illustrated by the following examples, which are to be understood as merely illustrative and not restrictive. The following percentages are by mass unless otherwise specified. Herein, the ceramic body may also be referred to as a brick or a body. The "copper-colored green body particles" can also be referred to as "copper-colored green body large particles", "copper-colored metal glaze", "metal dry particles" and "metal glaze".
The copper-colored green body particles of one embodiment of the present invention comprise the following raw materials: 45-50% of albite, 30-35% of iron phosphate, 5-10% of calcium phosphate, 3-10% of silicon tripolyphosphate and 5-10% of kaolin according to mass percentage. Compared with the existing metal glaze, the formula has the characteristics of stable color development and good glaze texture; mainly introduces silicon tripolyphosphate in the formula, and simultaneously plays a role in adjusting the silicon-aluminum ratio and the phosphorus-iron ratio in the formula, and the SiO of the system2:Al2O3Is between 3.2 and 3.8, the glaze effect is better, P2O5:Fe2O3The color development is stable between 1.3 and 1.7, the calcium phosphate is introduced to serve as a fluxing agent and the tone adjustment effect, the glossiness of the glaze surface is improved along with the increase of the addition amount of the calcium phosphate, and the formula can show a stable copper color by proper addition.
Wherein albite provides the main glassy phase and is also introduced as a flux; the kaolin mainly plays a role in improving the suspension property of the slurry and enhancing the large particle strength of the green body. Iron phosphate (preferably anhydrous iron phosphate) is introduced as a phase-separating agent and a crystallization agent, and within the above range, the metallic luster of the glaze surface increases with the increase of the content of iron phosphate, and beyond the above range, the metallic luster conversely decreases. The silicon tripolyphosphate mainly plays a role in adjusting the phosphorus-iron ratio and the silicon-aluminum ratio of the formula, so that different glaze luster and colors can be realized. Meanwhile, as the formula has more glass phase, the glass phase sinks in the fabric after being fired, and the glass phase does not contact the sunk part in the polishing and using processes, so that the durability of the decorative effect can be ensured.
In some embodiments, the chemical composition of the particles comprises: by mass percent, SiO2：35～39％、Al2O3：10～12％、Fe2O3：15～17％、TiO2：0.1～0.2％、CaO：3～4％、MgO：0.1～0.2％、K2O：0.1～0.3％、Na2O：5～6％、P2O5: 25-27%, loss on ignition: 1 to 2 percent.
In some embodiments, the copper green body particles do not contain a reddening aid or a yellowing aid, such that the printing of yellow and brown inks on the copper green body particles also does not affect the final result.
Disclosed herein is a method for preparing the above copper-colored green body particles. The preparation method of the copper-colored blank particles comprises the following steps:
(1) ball milling: weighing the raw materials according to the proportion of the formula, adding water into the raw materials, wherein the raw materials comprise: grinding balls: the mass ratio of water can be (1-1.2): (1.5-2.5): (0.5-0.8), and performing ball milling for 7-11 hours to form slurry with the fineness of 325 meshes and the residual content of 0.6-1.5%;
(2) drying: drying the slurry obtained in the step (1) at 100-150 ℃ until the moisture content is 6-8 wt% to obtain a dried material;
(3) and (3) granulation: and (3) granulating the dried material obtained in the step (2) to obtain copper-colored blank particles.
In the ball milling process of the step (1), high alumina ball stones with specifications of 50mm, 40mm, 30mm and 20mm can be used as the grinding balls.
The copper-colored green body particles disclosed herein can be used to make polished tiles. The copper-colored green body particles have a copper-colored effect, and ceramic tiles prepared by using the particles show metal visual sense and stereoscopic impression.
In one embodiment, the copper-colored green body particles are combined with an inkjet infiltration polished tile, which comprises a green body and an inkjet pattern layer, wherein the green body contains a decorative layer made by using the copper-colored green body particles.
The thickness of the blank body can be 5.5-20 mm. The ink-jet pattern layer is obtained by vertically permeating ink into the blank, and because the copper blank particles do not contain the reddening aid and the yellowing aid, the final effect cannot be influenced even if the yellow color and the brown color are printed on the copper particles, and the ceramic tile with fine patterns, good texture and three-dimensional effect can be obtained.
The following is an exemplary description of a method of making copper-colored green body particles in combination with an inkjet-infiltrated polished tile in accordance with one embodiment of the present invention.
As shown in fig. 1, first, a ceramic body is prepared. Specifically, a permeable facing and copper-colored green body particles are distributed on a backing material. The base material is not particularly limited, and a base material commonly used in the field of ceramic tiles can be used.
In some embodiments, the chemical composition of the osmotic facing comprises: by mass percent, SiO2：65～69％、Al2O3：18～21％、Fe2O3：0.16～0.46％、TiO2：0.3～0.6％、CaO：0.3～0.6％、MgO：0.2～0.5％、K2O：4.5～6％、Na2O：2.5～3.5％、ZrO2: 0.5-2%, loss on ignition: 2.6 to 3.0 percent. The permeable fabric has the advantages of good color development, high whiteness and good antifouling performance after polishing. In some embodiments, the firing temperature of the infiltrated fabric is 20 to 50 ℃ higher than the firing temperature of the copper large particles. If the difference of the firing temperature is too small, the obvious effect of sinking the mold is avoided; if the difference is too large, the phenomenon of overburning is easy to occur. In this range, the sinking mold effect can be generated in the fabric after the copper-colored particles are fired, because in the firing process, the copper-colored large particles have more glass phase, so that a part of the copper-colored large particles are melted into the penetrated fabric, and an interlayer with good combination can be formed with the copper-colored large particles, thereby forming the sinking mold effect with good performance. Preferably, the sintering temperature range of the permeable fabric is 1255-1275 ℃.
In some embodiments, the copper-colored green body particles have a particle size of 6 to 20 mesh. The particles are too large and can block the blanking hole of the digital material distribution nozzle; particles are too small to easily cause mottling.
In some embodiments, the particle size of the osmotic facing is consistent with the particle size of other normally produced powders. The large particles of the copper-colored blank are larger than the particle size of the permeable fabric, so that the blanking amount and the blanking position can be well controlled, and the defect of mixed points is avoided.
The permeable fabric and the copper-colored blank particles are respectively loaded into different hoppers, a PS pattern file is loaded according to a pre-designed effect, the digital material distribution vehicle corresponds to the hoppers according to channel information of the pattern file, the principle of the digital material distribution vehicle is similar to that of an ink-jet printer, required materials are distributed on a belt at the same time, and then the required materials are sent to a backing material to be pressed and formed. If the mode of using the metal glaze slip is adopted, only a natural surface can be made, and polishing cannot be carried out, but large metal blank particles are made, the large metal blank particles cannot be thrown due to the sinking effect after firing, the surface can be polished, the feeling similar to water jet parquet can be made, and the decorative effect is richer and more natural.
The pre-designed effect may be to extract a desired portion of the texture in the ink-jet pattern, and other design elements may be added.
The blanking amount of the permeable fabric can be 1000-2000 g/m2. The blanking amount of the copper-colored blank can be 100-1000 g/m2. The ratio of the feed amount of the infiltrated fabric to the copper blank can be adjusted according to the layout effect (such as the gray scale of the layout).
And (3) dry pressing and forming the cloth under the pressure of 15-18 MPa by using a press.
The green body may then be dried, for example in a drying kiln. The drying temperature can be 150-220 ℃, the drying time can be 1-1.5 h, and the moisture of the dried blank is controlled to be 0.3-0.5%.
Then, an inkjet pattern is printed on the blank. For example, a digital ink jet printer may be used for printing. The ink-jet ink used may be blue, brown, yellow, black, penetration aids, and the like. The pattern and color of the ink jet printing is determined by the specific design requirements.
And then drying the obtained green bricks, for example, drying the green bricks by an electric drying oven or a hot air drying oven, wherein the drying temperature can be 100-150 ℃, and the moisture after drying is controlled within 0.9%.
Then, firing is carried out, for example, low-temperature quick firing in a roller kiln. The maximum firing temperature can be 1190-1220 ℃, and the firing period can be 60-70 minutes.
And then, polishing, edging, grading, packaging and warehousing the fired green bricks. Polishing can be carried out using a process that is consistent with normal production of inkjet-infiltrated polished tiles.
The invention prepares the copper-colored green body particles by adjusting the formula of the copper-colored metal glaze, adopts a digital positioning material distribution technology and combines an ink-jet infiltration process, so that the process and the design are perfectly matched, and the glaze effect of the ink-jet infiltration polished tiles is enriched.
FIG. 2 is a graph showing the effect of combining copper green body particles with inkjet infiltrated polished tiles according to one embodiment of the present invention. It can be seen that the copper-colored blank particles and the infiltrated fabric are well fused together, and the metal luster is presented, and the three-dimensional die effect is achieved.
The present invention will be described in detail by way of examples. It is also to be understood that the following examples are illustrative of the present invention and are not to be construed as limiting the scope of the invention, and that certain insubstantial modifications and adaptations of the invention by those skilled in the art may be made in light of the above teachings. The specific process parameters and the like of the following examples are also only one example of suitable ranges, i.e., those skilled in the art can select the appropriate ranges through the description herein, and are not limited to the specific values exemplified below.
Example 1
1. And preparing copper-colored blank particles. Weighing the materials according to the proportion of a raw material formula, wherein the formula comprises the following components in percentage by mass: 48% of albite, 33% of anhydrous iron phosphate, 8% of calcium phosphate, 5% of silicon triphosphate (purchased from synthetic chemical industry, model number YP609) and 6% of kaolin. Ball-milling to 325 mesh, and sieving residue to 1.0% to form slurry; and drying the ball-milled slurry at 150 ℃ until the moisture content is 8% to obtain a dried material. And (4) granulating the dried material to obtain copper-colored blank particles with the particle size of 6-20 meshes.
The chemical components of the prepared copper-colored green body particles comprise: by mass percent, SiO2：36.5％、Al2O3：11.10％、Fe2O3：15.90％、TiO2：0.10％、CaO：3.16％、MgO：0.10％、K2O：0.19％、Na2O：5.27％、P2O5: 25.30%, loss on ignition: 1.56 percent.
2. The permeable fabric and the copper-colored green body particles are respectively loaded into different fabric hoppers, and good-effect net files are loaded in a digital material distribution vehicle (purchased from Sappftait technology Co., Ltd.). The effect web file is a part of the texture required to be extracted in the inkjet pattern by photoshop. The chemical components of the permeable fabric comprise: by mass percent, SiO2：66.74％、Al2O3：18.39％、Fe2O3：0.30％、TiO2：0.34％、CaO：0.50％、MgO：0.23％、K2O：4.86％、Na2O：3.09％、ZrO2: 1.64%, loss on ignition: 3.57 percent.
3. And positioning and distributing through a digital distributing vehicle. The blanking amount of the permeable fabric and the copper blank particles is changed according to the change of the design pattern.
4. And (3) dry pressing and forming under the pressure of 16MPa to obtain a ceramic blank.
5. Drying in a drying kiln at 180 deg.C for 1 hr to obtain dried blank with water content of 0.3%.
6. And printing an ink jet pattern. Ink jet printers are available from Hada. Inkjet penetrant inks are available from METCO corporation.
7. And (5) drying. Drying by electric drying or hot air drying oven at 130 deg.C, and controlling water content within 0.5%.
8. And sintering, wherein the maximum sintering temperature is 1190 ℃, and the sintering period is 65 minutes.
9. Polishing, edging, grading, packaging and warehousing. Polishing was carried out using polishing conditions consistent with those of a normally produced ink jet infiltrated polished tile.
Fig. 2 shows that the obtained copper-colored green body particles are combined with the inkjet infiltration polished brick, and the obtained copper-colored green body particles sink after being sintered to form a three-dimensional mold effect, and meanwhile, the sunk parts cannot be contacted in the polishing and daily use processes, so that the appearance and durability are both achieved.
Example 2
The difference from the embodiment 1 is that: the formula of the copper-colored blank particles is as follows: 47% of albite, 33% of anhydrous iron phosphate, 5% of silicon tripolyphosphate, 10% of kaolin and 5% of calcium phosphate.
Comparative example 1
The difference from the embodiment 1 is that: the formula of the copper-colored blank particles is as follows: 18% of albite, 33% of anhydrous iron phosphate, 5% of silicon tripolyphosphate (purchased from synthetic chemistry, model number YP-609), 38% of kaolin and 6% of calcium phosphate.
The face of the fired tile has no die effect of sinking as shown in figure 3.
Claims (8)
1. The preparation method of the polished tile combined with the copper-colored blank particles and the inkjet infiltration decoration is characterized by comprising the following steps:
(1) distributing the permeable fabric and the copper-colored blank particles, and performing compression molding to obtain a blank; the raw materials of the copper-colored blank particles comprise: 45-50% of albite, 30-35% of iron phosphate, 5-10% of calcium phosphate, 3-10% of silicon tripolyphosphate and 5-10% of kaolin according to mass percentage; the particle size of the copper-colored blank particles is 6-20 meshes; the firing temperature of the permeable fabric is 20-50 ℃ higher than that of the copper green body particles;
(2) printing an ink-jet pattern on the blank;
(3) firing and polishing to obtain the copper-colored blank particles combined with the inkjet infiltration decorative polished tile; wherein, the copper-colored blank particles have the sinking die effect in the fabric after being sintered.
2. The method of claim 1, wherein the copper green body particles have a chemical composition comprising: by mass percent, SiO2：35～39%、Al2O3：10～12%、Fe2O3：15～17%、TiO2：0.1～0.2%、CaO：3～4%、MgO：0.1～0.2%、K2O：0.1～0.3%、Na2O：5～6%、P2O5: 25-27%, loss on ignition: 1 to 2 percent.
3. The method of claim 1, wherein the chemical composition of the permeable facing comprises: in terms of mass percent, SiO2：65～69%、Al2O3：18～21%、Fe2O3：0.16～0.46%、TiO2：0.3～0.6%、CaO：0.3～0.6%、MgO：0.2～0.5%、K2O：4.5～6%、Na2O：2.5～3.5%、ZrO2: 0.5-2%, loss on ignition: 3.0 to 4.0 percent.
4. The preparation method according to claim 1, wherein in the step (1), the penetrating fabric and the copper-colored green body particles are distributed by using a digital positioning cloth, and the preparation method comprises the following steps: and respectively loading the permeable fabric and the copper-colored blank particles into a hopper of digital material distribution equipment, and then controlling the blanking amount according to the design requirement to distribute the material.
5. The method of claim 1, wherein the blanking amounts of the infiltrated fabric and the copper green body particles vary according to the design texture.
6. The preparation method of claim 5, wherein the blanking amount of the permeable fabric is 1000-2000 g/m2The blanking amount of the copper-colored blank particles is 100-1000 g/m2。
7. The preparation method according to claim 1, wherein in the step (3), the firing period is 60-70 min, and the maximum firing temperature of the green brick is 1190-1220 ℃.
8. The copper-colored green body particle-bonded inkjet infiltration decorative polished tile obtained by the production method according to any one of claims 1 to 7, characterized by comprising a green body containing a decorative layer made using the copper-colored green body particles and an inkjet pattern layer.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007131509A (en) * | 2005-11-11 | 2007-05-31 | 幹司 ▲高▼嶋 | Method for producing glaze for pottery |
| TW201236995A (en) * | 2011-03-08 | 2012-09-16 | Nation United University | Ceramic glaze having bronze metallic gloss and its preparation method |
| CN103833419A (en) * | 2014-01-02 | 2014-06-04 | 惠达卫浴股份有限公司 | Purple bronze glaze with metallic luster and preparation method thereof |
| CN105198490A (en) * | 2015-09-11 | 2015-12-30 | 蒙娜丽莎集团股份有限公司 | Preparation method of ink-jet permeable micro-powder polished tile |
| CN106348598A (en) * | 2016-09-20 | 2017-01-25 | 崔松伟 | Copper-red glaze and preparation method thereof |
| CN107915480A (en) * | 2017-11-06 | 2018-04-17 | 蒙娜丽莎集团股份有限公司 | A kind of ink-jet infiltration transparent brick and preparation method thereof |
-
2020
- 2020-01-14 CN CN202010036427.2A patent/CN111138211B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007131509A (en) * | 2005-11-11 | 2007-05-31 | 幹司 ▲高▼嶋 | Method for producing glaze for pottery |
| TW201236995A (en) * | 2011-03-08 | 2012-09-16 | Nation United University | Ceramic glaze having bronze metallic gloss and its preparation method |
| CN103833419A (en) * | 2014-01-02 | 2014-06-04 | 惠达卫浴股份有限公司 | Purple bronze glaze with metallic luster and preparation method thereof |
| CN105198490A (en) * | 2015-09-11 | 2015-12-30 | 蒙娜丽莎集团股份有限公司 | Preparation method of ink-jet permeable micro-powder polished tile |
| CN106348598A (en) * | 2016-09-20 | 2017-01-25 | 崔松伟 | Copper-red glaze and preparation method thereof |
| CN107915480A (en) * | 2017-11-06 | 2018-04-17 | 蒙娜丽莎集团股份有限公司 | A kind of ink-jet infiltration transparent brick and preparation method thereof |
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