CN111196740B - Silver green body particle combined inkjet infiltration decoration polished brick and preparation method thereof - Google Patents
Silver green body particle combined inkjet infiltration decoration polished brick and preparation method thereof Download PDFInfo
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- CN111196740B CN111196740B CN202010036422.XA CN202010036422A CN111196740B CN 111196740 B CN111196740 B CN 111196740B CN 202010036422 A CN202010036422 A CN 202010036422A CN 111196740 B CN111196740 B CN 111196740B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/02—Pretreated ingredients
- C03C1/026—Pelletisation or prereacting of powdered raw materials
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Structural Engineering (AREA)
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Abstract
The invention discloses a silver blank particle combined inkjet infiltration decoration polished brick and a preparation method thereof. The raw materials of the silver green body particles comprise: 45-50% of albite, 33-38% of iron phosphate, 8-13% of silicon tripolyphosphate and 5-10% of kaolin according to mass percentage.
Description
Technical Field
The invention relates to silver green body particles, a silver green body particle combined inkjet permeation polished brick and a preparation method thereof, belonging to the technical field of ceramic brick production and manufacturing.
Background
In recent years, metal glaze becomes an important branch in the decoration effect of ceramics due to the unique color and texture, can generate the metallic elegant and gorgeous appearance effect when being used on ceramic products, and also covers a plurality of industries such as daily necessities decoration, architectural decoration, ceramics and the like. But the phenomenon of discoloration and black spots is easy to occur because the method is sensitive to a firing system; meanwhile, the abrasive resistance is poor, so that the practical application has certain limitation, the ink-jet permeable polished tile has the color of both the glazed tile and the abrasive resistance of the polished tile, but because silver permeable ink is not available at present, if metal glaze is applied on a glaze line subsequently, the metal glaze cannot be polished; even if the process of later-stage water-jet parquet and secondary burning can be realized, the problem of cutting lines in the middle, complex process and high cost are caused because no texture is in transition.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides the silver-colored blank large particles, the silver-colored blank large particles and a digital cloth technology combined inkjet infiltration decorative polished brick and a preparation method thereof.
In a first aspect, the present invention provides a silver green body particle, wherein the raw materials of the silver green body particle comprise: 45-50% of albite, 33-38% of iron phosphate, 8-13% of silicon tripolyphosphate and 5-10% of kaolin according to mass percentage.
The silver green body particles of the invention have stable color development after being fired, can form a concave embossment three-dimensional effect after being fired, and meanwhile, the metal decoration part can not contact with people, thereby avoiding abrasion and having abundant and durable three-dimensional decoration effect.
Preferably, the particle size of the silver green body particles is 4-12 meshes.
Preferably, the chemical composition of the silver green body particles comprises: by mass percent, SiO2：35～39％、Al2O3：10～12％、Fe2O3：15～17％、TiO2：0.1～0.2％、CaO：0.1～0.2％、MgO：0.1～0.2％、K2O：0.1～0.3％、Na2O：5～6％、P2O5: 24-27%, loss on ignition: 1.0 to 2.0 percent.
In a second aspect, the present invention provides a method for preparing the above silver green body particles, comprising the steps of:
(1) ball milling: weighing raw materials according to a formula ratio, adding water into the raw materials, and ball-milling the raw materials into slurry;
(2) drying: drying the slurry obtained in the step (1) until the moisture content is 6-8 wt% to obtain a dried material;
(3) and (3) granulation: and (3) granulating the dried material obtained in the step (2) to obtain silver green body particles.
Preferably, the fineness of the slurry in the step (1) is 325 meshes, and the standard sieve residue is 0.6-1.5%.
In a third aspect, the present invention provides a polished tile made using the above silver-colored green body particles.
Preferably, the polished tile comprises a green body containing a decorative layer made using the silver green body particles and an inkjet pattern layer.
In a fourth aspect, the present invention provides a method for preparing the above polished tile, comprising the steps of:
(1) distributing the permeable fabric and the silver green body particles, and performing compression molding to obtain a green body;
(2) printing an ink-jet pattern on the blank;
(3) and (5) sintering and polishing.
The ink-jet permeable polished tile provided by the invention well fuses the silver blank particles and the permeable fabric together, has a three-dimensional embossment effect, and the embossment texture changes along with the change of the pattern, so that the cost of a mold is saved, and the decoration effect of the ink-jet permeable polished tile is enriched.
Preferably, the chemical components of the permeable fabric comprise: by mass percent, SiO2：65～69％、Al2O3：18～21％、Fe2O3：0.16～0.46％、TiO2：0.3～0.6％、CaO：0.3～0.6％、MgO：0.2～0.5％、K2O：4.5～6％、Na2O：2.5～3.5％、ZrO2: 0.5-2%, loss on ignition: 2.6 to 4.0 percent.
Preferably, in the step (1), the distributing of the infiltrated fabric and the silver green body particles by a digital positioning distributing method comprises the following steps: and respectively loading the permeable fabric and the silver green body particles into a hopper of digital material distribution equipment, and then positioning and controlling the blanking amount according to the design requirement to distribute the material.
Preferably, the blanking amount of the infiltration fabric and the silver green body large particles is changed according to the change of the design texture.
Preferably, the blanking amount of the permeable fabric can be 1000-2000 g/m2。
Preferably, the blanking amount of the silver green body particles can be 100-1000 g/m2。
Preferably, the sintering period is 60-70 min, and the maximum sintering temperature range is 1190-1220 ℃.
The preparation method of the polished tile can adjust the blanking amount of the silver blank particles according to the design requirements, combines ink-jet printing patterns, dries, sinters and polishes, has simple and easy operation process, and the obtained ink-jet permeable polished tile has a three-dimensional mold effect, can change along with the change of pattern textures, and enriches the decorative effect of the ink-jet permeable polished tile. Because the large silver-colored blank particles can sink after being fired at a relatively low temperature, the three-dimensional mold effect can be realized by distributing a corresponding number of the large silver-colored blank particles at a designed specific position through a digital material distribution technology, and the sunk area presents silver-colored metallic luster.
Drawings
FIG. 1 shows a flow chart for the preparation of a polished tile according to one embodiment of the present invention;
FIG. 2 is a graph showing the tile face effect of the silver green body particles of example 1 in combination with an inkjet penetrant polished tile;
fig. 3 shows a brick effect plot of comparative example 1.
Detailed Description
The present invention is further illustrated by the following examples, which are to be understood as merely illustrative and not restrictive. The following percentages are by mass unless otherwise specified. Herein, the ceramic body may also be referred to as a green brick or a green body. The silver green body particles can also be called as silver green body large particles, silver metal glaze, metal dry particles and metal glaze.
The silver green body particles of one embodiment of the present invention comprise the following raw materials: 45-50% of albite, 33-38% of iron phosphate, 8-13% of silicon tripolyphosphate and 5-10% of kaolin according to mass percentage. Compared with the existing metal glaze, the formula has the characteristics of stable color development and good glaze texture; mainly introduces silicon tripolyphosphate in the formula, and simultaneously plays a role in adjusting the silicon-aluminum ratio and the phosphorus-iron ratio in the formula, and the SiO of the system2:Al2O3The glaze surface effect can be better when the content is between 3.2 and 3.8, and P is2O5:Fe2O3The color development is stable between 1.3 and 1.7, the color tone of the formula system is mainly controlled by the firing temperature, compared with the copper-colored particles, calcium phosphate is not introduced to be used as a fluxing agent, under the formula system, the stable silver-colored metal effect can be obtained by adjusting the silicon-aluminum ratio, and the preparation method is simple and easy to operate.
Wherein albite provides the main glassy phase and is also introduced as a flux; the kaolin mainly plays a role in improving the suspension property of the slurry and enhancing the large particle strength of the green body. The iron phosphate (preferably anhydrous iron phosphate) is introduced as a phase separating agent and a crystallization agent, and within a certain range, the metallic luster of the glaze surface is increased along with the increase of the content of the iron phosphate, and beyond the certain range, the metallic luster is reduced on the contrary. The silicon tripolyphosphate mainly plays a role in adjusting the phosphorus-iron ratio and the silicon-aluminum ratio of the formula, so that different glaze luster and colors can be realized, and simultaneously, because the formula is low in temperature, more glass phases are formed after melting, the glass phases sink in the fabric after firing, and the silicon tripolyphosphate does not frequently contact the sinking place in the polishing and using processes, so that the durability of the decorative effect can be ensured.
In some embodiments, the silver green body particles have a chemical composition comprising: by mass percent, SiO2：35～39％、Al2O3：10～12％、Fe2O3：15～17％、TiO2：0.1～0.2％、CaO：0.1～0.2％、MgO：0.1～0.2％、K2O：0.1～0.3％、Na2O：5～6％、P2O5: 24-27%, loss on ignition: 1.0 to 2.0 percent. The color developed after firing varies depending on the firing temperature.
In some embodiments, the silver green body particles do not contain a reddening aid or a yellowing aid, such that printing yellow and brown inks on the silver green body particles also does not affect the final result.
Disclosed herein is a method for preparing the above silver green body particles. The preparation method of the silver green body particles comprises the following steps:
(1) ball milling: weighing the raw materials according to the formula proportion, adding water into the raw materials, wherein the raw materials comprise: grinding balls: the mass ratio of water can be (1-1.2): (1.5-2.5): (0.5-0.8), ball milling for 7-11 hours to form slurry with the fineness of 0.6-1.5% of the residue of a 325-mesh sieve;
(2) drying: drying the slurry obtained in the step (1) at 100-150 ℃ until the moisture content is 6-8 wt% to obtain a dried material;
(3) and (3) granulation: and (3) granulating the dried material obtained in the step (2) to obtain silver green body particles.
In the ball milling process of the step (1), high alumina ball stones with specifications of 50mm, 40mm, 30mm and 20mm can be used as the grinding balls.
The silver green body particles disclosed herein can be used to make polished tiles. The silver green body particles have silver effect, and ceramic tiles prepared by using the particles show metal visual sense and stereoscopic impression.
In one embodiment, the silver green body particles are combined with an inkjet infiltration polished tile, which comprises a green body and an inkjet pattern layer, wherein the green body contains a decorative layer made by using the silver green body particles.
The thickness of the blank body can be 5.5-20 mm. The ink-jet pattern layer is obtained by vertically permeating ink into the blank, and because the silver blank particles do not contain the reddening aid and the yellowing aid, the final effect cannot be influenced even if the yellow color and the brown color are printed on the silver particles, and the ceramic tile with fine patterns, good texture and three-dimensional effect can be obtained.
The method of preparing the silver green body particles in combination with the inkjet infiltrated polished tile according to one embodiment of the present invention is illustrated below.
As shown in fig. 1, first, a ceramic body is prepared. Specifically, the permeable fabric and the silver green body particles are distributed on the base material. The base material is not particularly limited, and a base material commonly used in the field of ceramic tiles can be used.
In some embodiments, the chemical composition of the osmotic facing comprises: by mass percent, SiO2：65～69％、Al2O3：18～21％、Fe2O3：0.16～0.46％、TiO2：0.3～0.6％、CaO：0.3～0.6％、MgO：0.2～0.5％、K2O：4.5～6％、Na2O：2.5～3.5％、ZrO2: 0.5-2%, loss on ignition: 2.6 to 4.0 percent. The permeable fabric has the advantages of good color development, high whiteness and good antifouling performance after polishing. Preferably, the sintering temperature range of the permeable fabric is 1255-1275 ℃. In some embodiments, the firing temperature of the permeable fabric is 20-50 ℃ higher than that of the silver large particles, and if the firing temperature difference between the two firing temperatures is too small, no obvious sinking is causedThe mold effect is too big, and the phenomenon of overburning appears again easily. In this range, the silver-colored particles can have a sagging mold effect in the fabric after firing, because in the firing process, the silver-colored large particles have more glass phase, so that a part of the silver-colored large particles are melted into the fabric and can form an interlayer with good combination with the fabric, thereby forming a sagging mold effect with good performance.
In some embodiments, the silver green body particles have a particle size of 6 to 20 mesh. The particles are too large and can block the blanking hole of the digital material distribution nozzle; particles are too small to easily cause mottling.
In some embodiments, the particle size of the osmotic facing is consistent with the particle size of other normally produced powders. The large particles of the silver blank are larger than the particle size of the permeable fabric, so that the blanking amount and the blanking position can be well controlled, and the defect of mixed points is avoided.
The permeable fabric and the silver green body particles are respectively loaded into different hoppers, a PS pattern file is loaded according to a pre-designed effect, the digital material distribution vehicle corresponds to the hoppers according to channel information of the pattern file, the principle of the digital material distribution vehicle is similar to that of an ink-jet printer, required materials are distributed on a belt at the same time, and then the required materials are sent to a backing material to be pressed and formed. If the metal glaze slip is used, only a natural surface can be made, and polishing cannot be performed, but large metal blank particles are made, and due to the sinking effect after firing, the large metal blank particles cannot be thrown out, the surface can be polished, the feeling similar to water jet parqueting is made, and the decorative effect is richer and more natural.
The pre-designed effect may be to extract a desired portion of the texture in the ink-jet pattern, and other design elements may be added.
The blanking amount of the permeable fabric can be 1000-2000 g/m2. The blanking amount of the silver green body can be 100-1000 g/m2. The ratio of the blanking amount of the permeable fabric to the silver blank can be adjusted according to the layout effect (such as the gray scale of the layout).
And (3) dry pressing and forming the cloth under the pressure of 15-18 MPa by using a press.
The green body may then be dried, for example in a drying kiln. The drying temperature can be 150-220 ℃, the drying time can be 1-1.5 h, and the moisture of the dried blank is controlled to be 0.3-0.5%.
Then, an inkjet pattern is printed on the blank. For example, a digital ink jet printer may be used for printing. The ink-jet ink used may be blue, brown, yellow, black, penetration aids, and the like. The pattern and color of the ink jet printing is dependent on the specific design requirements.
And then drying the obtained green bricks, for example, drying the green bricks by an electric drying oven or a hot air drying oven, wherein the drying temperature can be 100-150 ℃, and the moisture after drying is controlled within 0.9%.
Then, firing is carried out, for example, low-temperature quick firing in a roller kiln. The maximum firing temperature can be 1190-1220 ℃, and the firing period can be 60-70 minutes.
And then, polishing, edging, grading, packaging and warehousing the fired green bricks. Polishing can be carried out using a process that is consistent with normal production of inkjet-infiltrated polished tiles.
The invention prepares the silver-colored blank particles by adjusting the formula of the silver-colored metal glaze, adopts a digital positioning material distribution technology and combines an ink-jet infiltration process, so that the process and the design are perfectly matched, and the glaze effect of the ink-jet infiltration polished tiles is enriched.
FIG. 2 is a graph showing the effect of silver green body particles in combination with inkjet infiltration polished tiles on the tile surface according to one embodiment of the present invention. It can be seen that the silver body particles and the permeable fabric are well fused together, and the fabric presents metallic luster and has a three-dimensional mold effect.
The present invention will be described in detail by way of examples. It is also to be understood that the following examples are illustrative of the present invention and are not to be construed as limiting the scope of the invention, and that certain insubstantial modifications and adaptations of the invention by those skilled in the art may be made in light of the above teachings. The specific process parameters and the like of the following examples are also only one example of suitable ranges, i.e., those skilled in the art can select the appropriate ranges through the description herein, and are not limited to the specific values exemplified below.
Example 1
1. Preparing silver green body particles. Weighing the materials according to the proportion of a raw material formula, wherein the formula comprises the following components in percentage by mass: 46% of albite, 36% of anhydrous iron phosphate, 10% of silicon tripolyphosphate (purchased from synthetic chemical industry, model number YP-609) and 8% of kaolin. Ball-milling to 325 mesh, and sieving residue to 1.0% to form slurry; and drying the ball-milled slurry at 150 ℃ until the moisture content is 8% to obtain a dried material. And (4) granulating the dried material to obtain silver green body particles with the particle size of 6-20 meshes.
The chemical components of the silver green body particles prepared by the method comprise: by mass percent, SiO2：37.10％、Al2O3：10.80％、Fe2O3：16.90％、TiO2：0.10％、CaO：0.12％、MgO：0.10％、K2O：0.22％、Na2O：5.18％、P2O5: 25%, loss on ignition: 1.94 percent.
2. The infiltrated fabric and the silver-colored green body particles are respectively loaded into different fabric hoppers, and a good-effect net file is loaded in a digital distribution vehicle (purchased from seipft technologies ltd.). The effect web file is a part of the texture required to be extracted in the inkjet pattern by photoshop. The chemical components of the permeable fabric comprise: by mass percent, SiO2：66.74％、Al2O3：18.39％、Fe2O3：0.30％、TiO2：0.34％、CaO：0.50％、MgO：0.23％、K2O：4.86％、Na2O：3.09％、ZrO2: 1.64%, loss on ignition: 3.57 percent. The grain diameter of the permeable fabric is consistent with that of other powder materials produced normally.
3. And positioning and distributing through a digital distributing vehicle.
4. And (3) dry pressing and forming under the pressure of 16MPa to obtain a ceramic blank.
5. And (5) drying. Drying in a drying kiln at 180 deg.C for 1 hr to obtain dried blank with water content of 0.3%.
6. And printing an ink jet pattern. Ink jet printers are available from Hada. Inkjet penetrant inks are available from METCO corporation.
7. Drying by electric drying or hot air drying oven at 130 deg.C, and controlling water content within 0.5%.
8. And sintering, wherein the maximum sintering temperature is 1190 ℃, and the sintering period is 65 minutes.
9. Polishing, edging, grading, packaging and warehousing. Polishing was carried out using polishing conditions consistent with those of a normally produced ink jet infiltrated polished tile.
Fig. 2 shows that the obtained silver green body particles are combined with the inkjet infiltration polished brick, and the silver green body particles sink after being fired to form a three-dimensional mold effect, and meanwhile, the sunk parts cannot be contacted in the polishing and daily use processes, so the brick has both aesthetic property and durability.
Example 2
The difference from the embodiment 1 is that: the formula of the silver green body particles is as follows: 46% of albite, 36% of anhydrous iron phosphate, 8% of silicon tripolyphosphate (purchased from synthetic chemical industry, model number YP-609) and 10% of kaolin.
Comparative example 1
The difference from the embodiment 1 is that: the formula of the silver green body particles is as follows: 16% of albite, 36% of anhydrous iron phosphate, 12% of silicon tripolyphosphate (purchased from synthetic chemical industry, model number YP-609) and 36% of kaolin.
The green body particles were shaped as before, and the fired brick surface had no die effect of sagging, as shown in fig. 3.
Claims (9)
1. The preparation method of the silver blank particle combined inkjet infiltration decoration polished tile is characterized by comprising the following steps:
(1) distributing the permeable fabric and the silver green body particles, and performing compression molding to obtain a green body; the raw materials of the silver green body particles comprise: 45-50% of albite, 33-38% of iron phosphate, 8-13% of silicon tripolyphosphate and 5-10% of kaolin according to mass percentage; the particle size of the silver green body particles is 4-12 meshes; the firing temperature range of the permeable fabric is 1255-1275 ℃; the firing temperature of the permeable fabric is 20-50 ℃ higher than that of the silver green body particles;
(2) printing an ink-jet pattern on the blank;
(3) firing and polishing to obtain the silver green body particles combined with the inkjet infiltration decoration polished tile; wherein, the silver green body particles have the sinking die effect in the permeable fabric after being sintered.
2. The method of claim 1, wherein the chemical composition of the permeable facing comprises: by mass percent, SiO2：65～69%、Al2O3：18～21%、Fe2O3：0.16～0.46%、TiO2：0.3～0.6%、CaO：0.3～0.6%、MgO：0.2～0.5%、K2O：4.5～6%、Na2O：2.5～3.5%、ZrO2: 0.5-2%, loss on ignition: 2.6 to 4.0 percent.
3. The preparation method according to claim 1, wherein in the step (1), the permeable fabric and the silver green body particles are distributed by a digital positioning distribution method, and the preparation method comprises the following steps: and respectively loading the permeable fabric and the silver green body particles into a hopper of digital material distribution equipment, and then positioning and controlling the blanking amount according to the design requirement to distribute the material.
4. The method of claim 1, wherein the blanking amount of the infiltrated fabric and the silver body particles is varied according to the variation of the design texture.
5. The preparation method of claim 4, wherein the blanking amount of the permeable fabric is 1000-2000 g/m2The blanking amount of the silver green body particles is 100-1000 g/m2。
6. The production method according to claim 1, wherein the firing period is 60 to 70min, and the maximum firing temperature is 1190 to 1220 ℃.
7. The method for preparing the silver green body particles according to claim 1, wherein the chemical composition of the silver green body particles comprises: by mass percent, SiO2：35～39%、Al2O3：10～12%、Fe2O3：15～17%、TiO2：0.1～0.2%、CaO：0.1～0.2%、MgO：0.1～0.2%、K2O：0.1～0.3%、Na2O：5～6%、P2O5: 24-27%, loss on ignition: 1.0 to 2.0 percent.
8. The silver blank particle combined inkjet infiltration decoration polished tile is characterized by being prepared by the preparation method of any one of claims 1-7.
9. The polished tile of claim 8, comprising a body containing a decorative layer made using the silver-colored body particles, and an ink-jet patterned layer.
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| CN101935233B (en) * | 2010-09-28 | 2011-07-27 | 广东道氏标准制釉股份有限公司 | Low-temperature glaze with silver white metal luster and preparation method thereof |
| CN102249741A (en) * | 2011-07-05 | 2011-11-23 | 佛山欧神诺陶瓷股份有限公司 | Ceramic penetration glaze suitable for spray ink printing and method for using same to produce ceramic tiles |
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| CN104591800A (en) * | 2015-01-26 | 2015-05-06 | 佛山市东鹏陶瓷有限公司 | Method for manufacturing unburned ceramic tile green body having permeable layer |
| CN105198490B (en) * | 2015-09-11 | 2017-12-08 | 蒙娜丽莎集团股份有限公司 | A kind of preparation method of ink-jet infiltration micro powder polished brick |
| CN107033642B (en) * | 2017-05-04 | 2019-11-08 | 广州希森美克新材料科技有限公司 | Antifouling wear-resistant paint and preparation method thereof for metal surface |
| CN107216716A (en) * | 2017-07-11 | 2017-09-29 | 佛山市华力达材料科技有限公司 | A kind of metallic ink and preparation method thereof |
| CN107915480B (en) * | 2017-11-06 | 2020-05-15 | 蒙娜丽莎集团股份有限公司 | Ink-jet permeable light-transmitting brick and preparation method thereof |
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2020
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