CN111111628A - Air odor removal gel and preparation method thereof - Google Patents

Air odor removal gel and preparation method thereof Download PDF

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Publication number
CN111111628A
CN111111628A CN202010008114.6A CN202010008114A CN111111628A CN 111111628 A CN111111628 A CN 111111628A CN 202010008114 A CN202010008114 A CN 202010008114A CN 111111628 A CN111111628 A CN 111111628A
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gel
air
extract
water
plant extract
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张景
姚州威
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Shenzhen Tiandeyi Environment Technology Co ltd
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Shenzhen Tiandeyi Environment Technology Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28047Gels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20Organic adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/304Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/306Organic sulfur compounds, e.g. mercaptans
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/406Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702Hydrocarbons
    • B01D2257/7027Aromatic hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/704Solvents not covered by groups B01D2257/702 - B01D2257/7027

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention discloses an air odor removal gel and a preparation method thereof, and relates to the technical field of air purificant, wherein the air odor removal gel comprises the following raw materials of plant extract, thickening agent and amphoteric surfactant, wherein the plant extract comprises yucca extract, quercitrin, chickpea protein isolate, myricetin and aloe extract.

Description

Air odor removal gel and preparation method thereof
Technical Field
The invention relates to the technical field of air purifiers, in particular to an air odor removal gel and a preparation method thereof.
Background
With the increasing living standard and health consciousness of people, the problem of air pollution gradually emerges. One of the most immediate highlights is the reduced tolerance for air odors.
The odor pollutant is a kind of perception (smell) pollution which is perceived by the fact that the odor in the substances such as atmosphere, water, waste and the like acts on the olfactory thinking of people through air media. Any gaseous substance that can produce an offensive odor that is harmful to the human living environment and intolerable, and that causes it to have an unpleasant sensation, is commonly referred to as an offensive odor pollutant. The malodorous pollutants are of various types, some of which are harmful to human beings, such as thiols, ammonia, hydrogen sulfide, dimethyl disulfide, trimethylamine, formaldehyde, styrene, and the like. The malodorous pollutants can affect the respiration, digestion, cardiovascular, endocrine and nervous systems of human bodies, and the high-concentration malodorous gas can even suffocate and die people, thereby causing great harm to the health of human beings. In addition, the malodors also affect human social life, for example, due to the influence of malodorous substances, the normal production and life of people are disturbed, the working efficiency is reduced, and the life quality is reduced.
Currently, the mainstream odor elimination products on the market include: firstly, essence air fresheners, such as household volatile liquid, air refreshing spray and the like, have the function of covering up odor by releasing fragrance molecules, do not achieve the aim of air purification substantially, but increase the content of total volatile matters in the air; secondly, the adsorption deodorant, such as activated carbon adsorbent, is used for adsorbing odor molecules by utilizing the adsorption effect of the deodorant, but the deodorant needs desorption treatment after the adsorption capacity is saturated, and secondary pollution is easily caused in the desorption process. Therefore, there is a need for a deodorant product that does not cause secondary pollution.
Disclosure of Invention
The invention mainly aims to provide an air odor removing gel and a preparation method thereof, and aims to provide the air odor removing gel which has a good odor removing effect and does not have the problem of secondary pollution.
In order to achieve the purpose, the invention provides an air odor removing gel, which comprises the following raw materials: the plant extract comprises yucca extract, quercetin, chickpea protein isolate, myricetin and aloe extract.
Optionally, in the plant extract, the mass ratio of the yucca extract, the quercitrin, the chickpea protein isolate, the myricetin, and the aloe vera extract comprises one of the following ratios:
4:5:3:1:5, 3:5:3:1:6, 4:5:3:2:6, and 2:5:3:1: 5.
Optionally, the mass percentage of the plant extract in the air odor removing gel is 5-20%;
the mass percentage of the thickening agent in the air odor removing gel is 1-5%;
the mass percentage of the amphoteric surfactant in the air odor removing gel is 1-4%.
Optionally, the thickener comprises one or more of chitosan, methyl glycol chitosan, N-carboxybutyl chitosan, β -cyclodextrin.
Optionally, the amphoteric surfactant comprises one of an amido amino acid, N-dimethyl-N-hexadecyl quaternary ammonium butyl sulfate, N-hexadecyl amino, sodium N, N-dipropyl sulfonate, and N-carboxymethyl-N, N-dimethyl-dodecyl ammonium inner salt.
Optionally, the air odor elimination gel further comprises a humectant, a preservative, a buffer, a nonionic surfactant, and water.
Optionally, the air deodorizing gel comprises the following components in parts by mass: 5-20% of plant extract, 1-5% of thickening agent, 1-4% of amphoteric surfactant, 0.2-0.3% of humectant, 0.01-0.05% of preservative, 0.3-0.5% of buffering agent, 2-8% of nonionic surfactant and the balance of water.
Optionally, the humectant comprises invert sugar, glycerin, or sorbitol; and/or the presence of a gas in the gas,
the preservative comprises sodium erythorbate or phytic acid; and/or the presence of a gas in the gas,
the buffer comprises one or more of citric acid, sodium citrate and sodium bicarbonate; and/or the presence of a gas in the gas,
the nonionic surfactant comprises one of alcohol polyoxyethylene polyoxypropylene ether compounds, and the HLB value of the nonionic surfactant is 8-12.
Optionally, the air deodorizing gel is composed of, by mass, 12% of a plant extract, 3.8% of chitosan, 0.5% of β -cyclodextrin, 0.25% of glycerin, 0.03% of phytic acid, 0.18% of citric acid, 0.12% of sodium citrate, 2.6% of N-carboxymethyl-N, N-dimethyl-dodecylammonium inner salt, 2.3% of polyoxyethylene polyoxypropylene ether alcohol, and 78.22% of water.
The invention also provides a preparation method of the air odor removing gel, which comprises the following steps:
respectively dissolving yucca extract, quercitrin, chickpea protein isolate, myricetin and aloe extract in water to form solutions, and mixing all the solutions to obtain plant extract;
adding a buffering agent into water at the temperature of 20-30 ℃ while stirring, then adding the plant extracting solution, the preservative, the amphoteric surfactant, the nonionic surfactant and the humectant, stirring until the mixture is uniformly mixed, and adding the thickening agent while stirring until air odor removal gel is formed.
In the technical scheme, plant extract containing natural active ingredients of yucca extract, quercitrin, chickpea protein isolate, myricetin and aloe extract is used as a main functional ingredient, active amino compounds in the plant extract can generate β -amino (carbonyl) compounds through addition reaction with active aldehyde harmful gases such as formaldehyde and the like to fix the compounds, and contained organic acid compounds can fix the compounds through condensation reaction with malodorous gas molecules such as trimethylamine and the like to fundamentally decompose the malodorous gas without causing secondary pollution.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below. It is to be understood that the described embodiments are merely a few embodiments of the invention, and not all embodiments.
It should be noted that those whose specific conditions are not specified in the examples were performed according to the conventional conditions or the conditions recommended by the manufacturer. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products available commercially. In addition, the meaning of "and/or" appearing throughout includes three juxtapositions, exemplified by "A and/or B" including either A or B or both A and B. In addition, technical solutions between various embodiments may be combined with each other, but must be realized by a person skilled in the art, and when the technical solutions are contradictory or cannot be realized, such a combination should not be considered to exist, and is not within the protection scope of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Currently, the mainstream odor elimination products on the market include: firstly, essence air fresheners, such as household volatile liquid, air refreshing spray and the like, have the function of covering up odor by releasing fragrance molecules, do not achieve the aim of air purification substantially, but increase the content of total volatile matters in the air; secondly, the adsorption deodorant, such as activated carbon adsorbent, is used for adsorbing odor molecules by utilizing the adsorption effect of the deodorant, but the deodorant needs desorption treatment after the adsorption capacity is saturated, and secondary pollution is easily caused in the desorption process. Therefore, there is a need for a deodorant product that does not cause secondary pollution.
In view of this, the present invention provides an air deodorizing gel, which comprises the following raw materials: the plant extract comprises yucca extract, quercetin, chickpea protein isolate, myricetin and aloe extract.
In the technical scheme, plant extract containing natural active ingredients of yucca extract, quercitrin, chickpea protein isolate, myricetin and aloe extract is used as a main functional ingredient, active amino compounds in the plant extract can generate β -amino (carbonyl) compounds through addition reaction with active aldehyde harmful gases such as formaldehyde and the like to fix the compounds, and contained organic acid compounds can fix the compounds through condensation reaction with malodorous gas molecules such as trimethylamine and the like to fundamentally decompose the malodorous gas without causing secondary pollution.
The plant extract is extracted from stems and leaves of yucca of Yucca of Agavaceae, and has the main active components including polyphenol, yucca saponin, etc. capable of combining directly with harmful gas such as ammonia gas, hydrogen sulfide, methylindole, etc. to reduce the concentration, and the yucca extract is urease inhibitor capable of inhibiting the decomposition of uric acid into ammonia gas and promoting the microbial conversion of ammonia gas, and the quercetin is one of the effective components extracted from bark of Syzygium sambucus, cacumen Platycladi, Malvaceae, etc. and is one of flavonoid monomer compounds capable of undergoing Mannich reaction with formaldehyde to degrade formaldehyde, myricetin, also called myricetin, aloe extract, aloe vera leaf, aloe vera bark, aloe vera extract, aloe vera bark, aloe vera saponin, etc. it has the synergistic effect of absorbing odor of aloe vera, aloe vera saponin, etc. it has the synergistic effect of absorbing the odor of aloe vera molecule, reducing the odor of aloe vera molecule, and the odor of aloe vera saponin, etc. of aloe vera, and the aloe vera molecule of aloe vera, etc. of aloe vera, and the synergistic effect of aloe vera molecule of aloe vera, and the effect of the synergistic effect of the effect.
Further, the inventor researches the proportion of the five components in the plant extract, and finds that when the mass ratio of the yucca extract to the quercitrin to the chickpea protein isolate to the myricetin to the aloe extract is 4:5:3:1:5, or 3:5:3:1:6, or 4:5:3:2:6, or 2:5:3:1:5, the mixed plant extract has a good effect of eliminating malodorous gases and good stability.
Amphoteric surfactants are surfactants that contain both anionic and cationic hydrophilic groups in the same molecule. The surfactant is dissolved in water, and when the concentration of the surfactant exceeds the critical micelle concentration, the hydrophobic parts of a plurality of surfactant molecules attract each other and are associated together to form a micelle. In this embodiment, one of amido amino acid, N-dimethyl-N-hexadecyl quaternary ammonium butyl sulfate, N-hexadecyl amino group, N-dipropyl sodium sulfonate, and N-carboxymethyl-N, N-dimethyl-dodecyl ammonium inner salt is preferably used as the amphoteric surfactant, so that a lipophilic micelle can be formed, and the lipophilic micelle can adsorb and wrap common malodorous gas molecules containing alkyl hydrocarbon structures and higher ester molecules, thereby fixing the malodorous gas molecules in the micelle.
The thickening agent prepared from the substances is rich in hydrophilic groups, can react with bifunctional crosslinking agents such as formaldehyde and glutaraldehyde, and enables carbon-oxygen double bonds between linear molecular chains to be crosslinked to form hydrogel, and the hydrogel has the advantages of biodegradability, no toxicity, wide sources and the like.
It will be appreciated that the present air deodorising gel may comprise, in addition to the plant extract, thickener and amphoteric surfactant, water, or water together with other adjuvants, for example stabilisers, preservatives and the like.
In this embodiment, in the air deodorizing gel, the plant extract is 5 to 20% by mass; the mass percentage of the thickening agent is 1-5%; the weight percentage content of the amphoteric surfactant is 1-4%. Specifically, the mass percentage content of the plant extract can be 5%, 10%, 13%, 15%, 17% or 20%; the mass percentage of the thickening agent can be 1%, 1.2%, 1.8%, 2%, 3%, 3.7%, 4% or 5%; the amphoteric surfactant may be present in an amount of 1%, 1.5%, 1.9%, 2%, 2.3%, 3.5% or 4% by weight.
The plant extract is 5-20% by weight, and the total weight of the yucca extract, the quercitrin, the chickpea protein isolate, the myricetin and the aloe extract accounts for 5-20% by weight of the air deodorant gel.
As a preferred embodiment of the present invention, the air deodorizing gel further comprises a humectant, a preservative, a buffer, a nonionic surfactant, and water to enhance the stability and shelf life of the air deodorizing gel.
In this embodiment, the air deodorizing gel comprises the following components in percentage by mass: 5-20% of plant extract, 1-5% of thickening agent, 1-4% of amphoteric surfactant, 0.2-0.3% of humectant, 0.01-0.05% of preservative, 0.3-0.5% of buffering agent, 2-8% of nonionic surfactant and the balance of water.
Wherein, the humectant is used for preventing water from evaporating and losing to keep gel property, in the embodiment, invert sugar, glycerin or sorbitol can be selected; the preservative is used for prolonging the storage period of the product, and sodium erythorbate or phytic acid can be selected in the embodiment; the buffer is used to adjust the pH to enhance the stability of the gel, and in this embodiment, one of citric acid, sodium citrate and sodium bicarbonate, or a mixture of two or three thereof, may be selected; the nonionic surfactant is preferably one of alcohol polyoxyethylene polyoxypropylene ether compounds, such as alcohol polyoxyethylene polyoxypropylene ether, lauryl alcohol polyoxyethylene polyoxypropylene ether, and sodium alcohol polyoxyethylene polyoxypropylene ether sulfate, and the alcohol polyoxyethylene polyoxypropylene ether compounds have the characteristics of high performance, biodegradability, quick wetting, low odor and low pour point, and the alcohol polyoxyethylene polyoxypropylene ether with the HLB value of 8-12 is preferred in the embodiment.
Specifically, the present invention provides a preferred embodiment, the air deodorising gel comprises, by mass, 12% plant extract, 3.8% chitosan, 0.5% β -cyclodextrin, 0.25% glycerol, 0.03% phytic acid, 0.18% citric acid, 0.12% sodium citrate, 2.6% N-carboxymethyl-N, N-dimethyl-dodecylammonium inner salt, 2.3% alcohol polyoxyethylene polyoxypropylene ether and 78.22% water.
This example was used as a subject to be examined and tested for odor elimination effect as follows.
The detection device comprises: a test chamber in a rectangular parallelepiped shape having a size of 800mm × 1250mm × 1000 mm. The cabin body is made of glass materials with the thickness of 10mm, smooth surface, no adsorption and inert chemical reaction. The heating plate and the fan are arranged in the test chamber, the side wall of the test chamber is provided with an injection hole and a sampling hole, and all gaps existing during the assembly of the chamber body are sealed by silicon rubber so as to ensure that the air leakage rate at the gaps is less than 0.02m3 h.
Two test chambers were prepared for testing, one being a blank chamber and one being a sample chamber.
The detection method comprises the following steps:
1. respectively placing the air odor removal gel and blank base paper (namely the base paper qualified in the blank release test) in the center positions of the sample cabin and the blank cabin, wherein the thickness of the air odor removal gel is not more than 5mm, and then sealing the test cabin by using transparent adhesive;
2. and a certain amount of target object liquid is sucked by a micro-injector and injected onto the heating plate through the injection hole to be instantly volatilized, and meanwhile, the fan is started to enable the gas to flow and be uniformly distributed in the test cabin. And collecting the gas in the cabin after a certain time of treatment, and testing the concentration of the target object in the gas. The target liquid may be trimethylamine, methyl mercaptan or formaldehyde.
3. The concentration of the methyl mercaptan is detected according to the method specified by the gas chromatography method for measuring the mass of the hydrogen sulfide, the methyl mercaptan, the methyl sulfide and the dimethyl disulfide in GB/T14678-1993 air;
the concentration of trimethylamine is determined according to the method prescribed by the gas chromatography method for the determination of air quality trimethylamine in accordance with GB/T14676-1993;
the concentration of formaldehyde was measured according TO the method of TO-5 "high performance liquid chromatography for measuring aldehydes and ketones in ambient air" in European standards.
The results are shown in table 1 below:
TABLE 1 example odor elimination Effect of air odor elimination gels
Figure BDA0002355192040000071
It is apparent that the air deodorizing gel of this example has a remarkable scavenging ability for formaldehyde, methyl mercaptan and trimethylamine, and the air deodorizing gel has a good deodorizing effect of malodorous smell.
Based on the air odor removal gel provided above, the invention also provides a preparation method of the air odor removal gel, and the preparation method of the air odor removal gel comprises the following steps:
step S10, respectively dissolving Yucca extract, Quercetin, chickpea protein isolate, myricetin and Aloe extract in water to form solutions, and mixing Yucca extract water solution, Quercetin water solution, chickpea protein isolate water solution, myricetin water solution and Aloe extract water solution to obtain plant extractive solution;
and step S20, adding a buffering agent into water at the temperature of 20-30 ℃ while stirring, adding a plant extracting solution, a preservative, an amphoteric surfactant, a nonionic surfactant and a humectant, stirring until the mixture is uniformly mixed, and adding a thickening agent while stirring until air odor removal gel is formed.
The method has simple steps and easy operation, and the prepared air odor removing gel has stable quality.
The technical solutions of the present invention are further described in detail with reference to the following specific examples, which should be understood as merely illustrative and not limitative.
Example 1
The materials of the air deodorizing gel of this example include: 12g of plant extract, 3.8g of chitosan, 2.6g of N-carboxymethyl-N, N-dimethyl-dodecyl ammonium inner salt and 81.6g of water, wherein the plant extract consists of 2.4g of yucca extract, 3g of quercetin, 1.8g of chickpea protein isolate, 1.2g of myricetin and 3.6g of aloe extract.
Dividing 25g of water into five parts, and dissolving the weighed yucca extract, quercetin, chickpea protein isolate, myricetin and aloe extract respectively to form respective aqueous solutions. Mixing yucca extract water solution, quercetin water solution, chickpea protein isolate water solution, myricetin water solution and aloe extract water solution to obtain plant extract; adding the plant extract and N-carboxymethyl-N, N-dimethyl-dodecyl ammonium inner salt into 56.6g of water at the temperature of 25 ℃ while stirring, uniformly stirring, and adding chitosan while stirring until air odor removing gel is formed.
Example 2
The air deodorizing gel comprises 12g of plant extract, 3.8g of chitosan, β -cyclodextrin 0.5g, 0.25g of glycerol, 0.03g of phytic acid, 0.18g of citric acid, 0.12g of sodium citrate, 2.6g of N-carboxymethyl-N, N-dimethyl-dodecyl ammonium inner salt, 2.3g of polyoxyethylene polyoxypropylene ether alcohol and 78.22g of water, wherein the plant extract comprises 2g of yucca extract, 3.33g of quercetin, 2g of chickpea isolated protein, 0.67g of myricetin and 4g of aloe extract.
Taking 25g of water, dividing into five parts, respectively dissolving the weighed yucca extract, quercitrin, chickpea protein isolate, myricetin and aloe extract to form respective aqueous solutions, combining the yucca extract aqueous solution, the quercitrin aqueous solution, the chickpea protein isolate aqueous solution, the myricetin aqueous solution and the aloe extract aqueous solution to obtain plant extract, sequentially adding the plant extract, phytic acid, N-carboxymethyl-N, N-dimethyl-dodecyl ammonium inner salt, alcohol polyoxyethylene polyoxypropylene ether and glycerol into 53g of water at the temperature of 25 ℃ while stirring, stirring uniformly, adding chitosan and β -cyclodextrin while stirring to form the air deodorizing gel.
Example 3
The materials of the air deodorizing gel of this example include: 20g of plant extract, 0.3g of sodium citrate, 0.05g of sodium erythorbate, 3.6g of amido amino acid, 2g of polyoxyethylene polyoxypropylene alcohol ether, 0.21g of invert sugar, 1g of N-carboxyl butyl chitosan and 72.84g of water, wherein the plant extract consists of 2.5g of yucca extract, 6.25g of quercetin, 3.75g of chickpea protein isolate, 1.25g of myricetin and 6.25g of aloe extract.
Dividing 25g of water into five parts, and dissolving the weighed yucca extract, quercetin, chickpea protein isolate, myricetin and aloe extract respectively to form respective aqueous solutions. Mixing yucca extract water solution, quercetin water solution, chickpea protein isolate water solution, myricetin water solution and aloe extract water solution to obtain plant extract; adding the plant extract, sodium citrate, sodium erythorbate, amido amino acid, alcohol polyoxyethylene polyoxypropylene ether and invert sugar into 47.84g of water at the temperature of 20 ℃ while stirring, stirring uniformly, adding N-carboxyl butyl chitosan while stirring to form the air deodorizing gel.
Example 4
The materials of the air deodorizing gel of this example include: 9g of plant extract, 0.4g of sodium bicarbonate, 0.02g of sodium erythorbate, 3g of N, N-dimethyl-N-hexadecyl quaternary ammonium butyl sulfate, 4g of polyoxyethylene polyoxypropylene alcohol ether, 0.24g of sorbitol, 2g of methyl glycol chitosan and 81.34g of water, wherein the plant extract consists of 2g of yucca extract, 2.5g of quercetin, 1.5g of chickpea protein isolate, 0.5g of myricetin and 2.5g of aloe extract.
Dividing 25g of water into five parts, and dissolving the weighed yucca extract, quercetin, chickpea protein isolate, myricetin and aloe extract respectively to form respective aqueous solutions. Mixing yucca extract water solution, quercetin water solution, chickpea protein isolate water solution, myricetin water solution and aloe extract water solution to obtain plant extract; adding the plant extract, sodium bicarbonate, sodium erythorbate, N-dimethyl-N-hexadecyl quaternary ammonium butyl sulfate, alcohol polyoxyethylene polyoxypropylene ether and sorbitol into 56.34g of water at 23 ℃ while stirring, stirring uniformly, adding methyl glycol chitosan while stirring to form the air deodorizing gel.
Example 5
The materials of the air deodorizing gel of this example include: 18g of plant extract, 0.2g of citric acid, 0.2g of sodium citrate, 0.1g of sodium bicarbonate, 0.01g of phytic acid, N-hexadecylamine, 2g of N, N-dipropyl sodium sulfonate, 5g of polyoxyethylene polyoxypropylene ether, 0.2g of glycerol, 2g of methyl glycol chitosan, 1.8g of N-carboxybutyl chitosan and 70.49g of water, wherein the plant extract consists of 3g of yucca extract, 5g of quercitrin, 3g of chickpea isolate protein, 1g of myricetin and 6g of aloe extract.
Dividing 25g of water into five parts, and dissolving the weighed yucca extract, quercetin, chickpea protein isolate, myricetin and aloe extract respectively to form respective aqueous solutions. Mixing yucca extract water solution, quercetin water solution, chickpea protein isolate water solution, myricetin water solution and aloe extract water solution to obtain plant extract; the plant extract, citric acid, sodium citrate, sodium bicarbonate, phytic acid, N-hexadecylamine, N, N-dipropyl sodium sulfonate, alcohol polyoxyethylene polyoxypropylene ether and glycerol are sequentially added into 45.49g of water at the temperature of 29 ℃ while stirring, after uniform mixing, the methyl glycol chitosan and the N-carboxyl butyl chitosan are added while stirring until the air odor removing gel is formed.
Example 6
The air deodorizing gel comprises 5g of plant extract, 0.17g of sodium citrate, 0.23g of sodium bicarbonate, 0.05g of phytic acid, 1g of N-carboxymethyl-N, N-dimethyl-dodecyl ammonium inner salt, 6g of alcohol polyoxyethylene polyoxypropylene ether, 0.3g of glycerol, 4g of β -cyclodextrin and 76.25g of water, wherein the plant extract comprises 1g of yucca extract, 1.25g of quercetin, 0.75g of chickpea protein isolate, 0.5g of myricetin and 1.5g of aloe extract.
Taking 25g of water, dividing into five parts, respectively dissolving the weighed yucca extract, quercitrin, chickpea protein isolate, myricetin and aloe extract to form respective aqueous solutions, combining the yucca extract aqueous solution, the quercitrin aqueous solution, the chickpea protein isolate aqueous solution, the myricetin aqueous solution and the aloe extract aqueous solution to obtain plant extract, sequentially adding the plant extract, sodium citrate, sodium bicarbonate, phytic acid, N-carboxymethyl-N, N-dimethyl-dodecyl ammonium inner salt, polyoxyethylene polyoxypropylene ether and glycerol into 51.25g of water at the temperature of 30 ℃ while stirring, uniformly mixing, and adding β -cyclodextrin while stirring to form the air deodorizing gel.
Example 7
The air deodorizing gel comprises 16g of plant extract, 0.5g of citric acid, 0.04g of phytic acid, 4g of N-carboxymethyl-N, N-dimethyl-dodecyl ammonium inner salt, 8g of polyoxyethylene polyoxypropylene alcohol ether, 0.27g of invert sugar, 2.1g of chitosan, 1.5g of methyl glycol chitosan, 0.5g of N-carboxybutyl chitosan, 0.9g of β -cyclodextrin and 78g of water, wherein the plant extract consists of 2g of yucca extract, 5g of quercetin, 3g of chickpea protein isolate, 1g of myricetin and 5g of aloe extract.
Taking 25g of water, dividing into five parts, respectively dissolving the weighed yucca extract, quercitrin, chickpea protein isolate, myricetin and aloe extract to form respective aqueous solutions, combining the yucca extract aqueous solution, the quercitrin aqueous solution, the chickpea protein isolate aqueous solution, the myricetin aqueous solution and the aloe extract aqueous solution to obtain plant extract, sequentially adding the plant extract, citric acid, phytic acid, N-carboxymethyl-N, N-dimethyl-dodecyl ammonium inner salt, alcohol polyoxyethylene polyoxypropylene ether and invert sugar into 56.6g of water at the temperature of 25 ℃ while stirring, uniformly stirring, and then adding chitosan, methyl glycol chitosan, N-carboxybutyl chitosan and β -cyclodextrin while stirring to form the air odor removing gel.
The above-mentioned embodiments use the plant extract containing yucca extract, quercitrin, chickpea protein isolate, myricetin and aloe extract natural active component as main functional component, the active amino compound in the plant extract can be reacted with active aldehyde harmful gas such as formaldehyde to produce β -amino (carbonyl) compound and fix it, the organic acid compound can be reacted with trimethylamine and other malodorous gas molecules to fix it and radically decompose malodorous gas, without secondary pollution, and the synergistic effect produced by the combined use of yucca extract, quercitrin, chickpea protein isolate, myricetin and aloe extract also further improves the deodorizing effect.
The above is only a preferred embodiment of the present invention, and it is not intended to limit the scope of the invention, and various modifications and changes will occur to those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention shall be included in the scope of the present invention.

Claims (10)

1. An air odour-combating gel, comprising the following raw materials: the plant extract comprises yucca extract, quercetin, chickpea protein isolate, myricetin and aloe extract.
2. The air deodorizing gel of claim 1, wherein the mass ratio of said yucca extract, said quercitrin, said chickpea protein isolate, said myricetin, and said aloe vera extract in said plant extract comprises one of the following ratios:
4:5:3:1:5, 3:5:3:1:6, 4:5:3:2:6, and 2:5:3:1: 5.
3. The air odor removing gel as claimed in claim 1, wherein the plant extract is 5-20% by mass of the air odor removing gel;
the mass percentage of the thickening agent in the air odor removing gel is 1-5%;
the mass percentage of the amphoteric surfactant in the air odor removing gel is 1-4%.
4. The air odor elimination gel of claim 1, wherein said thickener comprises one or more of chitosan, methyl glycol chitosan, N-carboxybutyl chitosan, β -cyclodextrin.
5. The air odor removing gel of claim 1 wherein said amphoteric surfactant comprises one of an amido amino acid, N-dimethyl-N-hexadecyl quaternary ammonium butyl sulfate, N-hexadecylamine group, sodium N, N-dipropyl sulfonate, and an inner salt of N-carboxymethyl-N, N-dimethyl-dodecyl ammonium.
6. The air odor elimination gel of any one of claims 1 to 5, wherein said air odor elimination gel further comprises a humectant, a preservative, a buffer, a nonionic surfactant, and water.
7. The air odor elimination gel of claim 6, wherein said air odor elimination gel comprises the following components in parts by mass: 5-20% of plant extract, 1-5% of thickening agent, 1-4% of amphoteric surfactant, 0.2-0.3% of humectant, 0.01-0.05% of preservative, 0.3-0.5% of buffering agent, 2-8% of nonionic surfactant and the balance of water.
8. The air odor elimination gel of claim 6, wherein said humectant comprises invert sugar, glycerin, or sorbitol; and/or the presence of a gas in the gas,
the preservative comprises sodium erythorbate or phytic acid; and/or the presence of a gas in the gas,
the buffer comprises one or more of citric acid, sodium citrate and sodium bicarbonate; and/or the presence of a gas in the gas,
the nonionic surfactant comprises one of alcohol polyoxyethylene polyoxypropylene ether compounds, and the HLB value of the nonionic surfactant is 8-12.
9. An air odour-combating gel according to claim 8, wherein said air odour-combating gel consists of, in mass fraction, 12% plant extract, 3.8% chitosan, 0.5% β -cyclodextrin, 0.25% glycerol, 0.03% phytic acid, 0.18% citric acid, 0.12% sodium citrate, 2.6% N-carboxymethyl-N, N-dimethyl-dodecylammonium inner salt, 2.3% alcohol polyoxyethylene polyoxypropylene ether and 78% water.
10. A method for preparing an air deodorizing gel, comprising the steps of:
respectively dissolving yucca extract, quercitrin, chickpea protein isolate, myricetin and aloe extract in water to form solutions, and mixing all the solutions to obtain plant extract;
adding a buffering agent into water at the temperature of 20-30 ℃ while stirring, then adding the plant extracting solution, the preservative, the amphoteric surfactant, the nonionic surfactant and the humectant, stirring until the mixture is uniformly mixed, and adding the thickening agent while stirring until air odor removal gel is formed.
CN202010008114.6A 2020-01-03 2020-01-03 Air odor removal gel and preparation method thereof Pending CN111111628A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111632483A (en) * 2020-06-29 2020-09-08 山西艾珂灵环境科技有限公司 Gel slow-release type plant sterilization and deodorization device, deodorant and preparation method
CN112007491A (en) * 2020-07-30 2020-12-01 中国船舶重工集团公司第七一八研究所 Aldehyde-removing and odor-removing gel and preparation method thereof
CN113019271A (en) * 2020-12-18 2021-06-25 张家港市济泽化工环保科技有限公司 Formaldehyde-removing hydrogel and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111632483A (en) * 2020-06-29 2020-09-08 山西艾珂灵环境科技有限公司 Gel slow-release type plant sterilization and deodorization device, deodorant and preparation method
CN112007491A (en) * 2020-07-30 2020-12-01 中国船舶重工集团公司第七一八研究所 Aldehyde-removing and odor-removing gel and preparation method thereof
CN112007491B (en) * 2020-07-30 2022-03-25 中国船舶重工集团公司第七一八研究所 Aldehyde-removing and odor-removing gel and preparation method thereof
CN113019271A (en) * 2020-12-18 2021-06-25 张家港市济泽化工环保科技有限公司 Formaldehyde-removing hydrogel and preparation method thereof

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