CN110354665A - A kind of formaldehyde scavenger and preparation method thereof - Google Patents
A kind of formaldehyde scavenger and preparation method thereof Download PDFInfo
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- CN110354665A CN110354665A CN201910530977.7A CN201910530977A CN110354665A CN 110354665 A CN110354665 A CN 110354665A CN 201910530977 A CN201910530977 A CN 201910530977A CN 110354665 A CN110354665 A CN 110354665A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/22—Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/28—Myrtaceae [Myrtle family], e.g. teatree or clove
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/44—Poaceae or Gramineae [Grass family], e.g. bamboo, lemon grass or citronella grass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/58—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
Abstract
The invention discloses a kind of formaldehyde scavenger and preparation method thereof, which is grouped as by the group of following mass parts: bamboo juice: 10~18 parts；Imazalil: 2~7 parts；Hydrogen peroxide: 1~5 part；SODIUM PERCARBONATE: 1~5 part；Quaternary ammonium salt: 1~5 part；Lysozyme: 1~5 part；Plants essential oil: 2~5 parts；Anion miberal powder: 5~10 parts；Water: 180~200 parts.Formaldehyde scavenger of the invention both can be with volatile injurants such as decomposing formaldehyde, ammonia, it again can be with restraining and sterilizing bacteria, anion can also be discharged, indoor environment can be improved from many aspects, effect is lasting, it is at low cost, it is easy to use, it can be widely used in and need except confined spaces such as interior, the cars of formaldehyde.
Description
Technical field
The present invention relates to a kind of formaldehyde scavengers and preparation method thereof.
Background technique
Modern house fitting-up will use a large amount of artificial board, such as compreg, thin plank, fiberboard, particieboard,
These artificial boards have used phenolic resin and urea-formaldehyde resin adhesive mostly, in use can sustained release go out formaldehyde
(deenergized period is up to the several years), it is serious to room air pollution.Formaldehyde, also known as formaldehyde are a kind of colourless irritant gas, tool
There is higher toxicity, to all irritating effect of eye, mucous membrane and respiratory tract, and formaldehyde can also cause chronic respiratory disease, allergy
Property rhinitis, immune function decline etc..In addition, formaldehyde still belongs to carcinogenic and causes deformed material, World Health Organization's international cancer is ground
Study carefully mechanism and is classified as a kind of carcinogenic substance.
Currently, commercially available formaldehyde scavenger is broadly divided into physisorption type and chemical reaction type two major classes: physisorption type
Formaldehyde scavenger is mainly active carbon, and manufacturing cost is low, is most widely used, but its adsorbance is limited, and the formaldehyde adsorbed
It is easy to release again；Chemical reaction type formaldehyde scavenger is mainly titanium dioxide, can be with decomposing formaldehyde, but needs to cooperate
Ultraviolet lamp uses, not only inconvenient to use, but also low efficiency, energy consumption are high, cost is big.
So developing a kind of except formaldehyde speed is fast, high-efficient, at low cost, formaldehyde scavenger easy to use is with important
Meaning.
Summary of the invention
The purpose of the present invention is to provide a kind of formaldehyde scavengers and preparation method thereof.
The technical solution used in the present invention is:
A kind of formaldehyde scavenger is grouped as by the group of following mass parts:
Bamboo juice: 10~18 parts；
Imazalil: 2~7 parts；
Hydrogen peroxide: 1~5 part；
SODIUM PERCARBONATE: 1~5 part；
Quaternary ammonium salt: 1~5 part；
Lysozyme: 1~5 part；
Plants essential oil: 2~5 parts；
Anion miberal powder: 5~10 parts；
Water: 180~200 parts.
Preferably, a kind of formaldehyde scavenger is grouped as by the group of following mass parts:
Bamboo juice: 12~14 parts；
Imazalil: 3~5 parts；
Hydrogen peroxide: 1~3 part；
SODIUM PERCARBONATE: 1~3 part；
Quaternary ammonium salt: 2~4 parts；
Lysozyme: 1~3 part；
Plants essential oil: 2~4 parts；
Anion miberal powder: 6~8 parts；
Water: 180~200 parts.
Preferably, the plants essential oil be lemon, eucalyptus oil, oil of Cymbopogon winterianus, Lavender, Peppermint essential oil,
At least one of Rosa Damascana, refined jasmine oil, Rosemary Oil, grapefruit essential oil, wormwood essential oil, deodar essential oil.
It is further preferred that the plants essential oil is lemon, eucalyptus oil, oil of Cymbopogon winterianus, Peppermint essential oil, grape fruit
At least one of essential oil, wormwood essential oil.
Preferably, the anion miberal powder is bastnasite miberal powder, six ring mountain flours, tourmaline powder, volcano stone flour, opal
At least one of powder, sea-gull mountain flour, snake mountain flour.
Preferably, the partial size of the anion miberal powder is 30~80nm.
The preparation method of above-mentioned formaldehyde scavenger is the following steps are included: first by bamboo juice, hydrogen peroxide, SODIUM PERCARBONATE, quaternary ammonium
Salt and anion miberal powder are added to the water, and mix well, and add imazalil, lysozyme and plants essential oil, mix well to get arriving
Formaldehyde scavenger.
The application method of above-mentioned formaldehyde scavenger is as follows: formaldehyde scavenger is sprayed at furniture, metope, floor and ceiling
On, natural air drying.
The beneficial effects of the present invention are: formaldehyde scavenger of the invention both can with volatile injurants such as decomposing formaldehyde, ammonia,
Anion can also be discharged with restraining and sterilizing bacteria again, indoor environment can be improved from many aspects, effect is lasting, and it is at low cost, make
With conveniently, it can be widely used in and need except confined spaces such as interior, the cars of formaldehyde.
1) in formaldehyde scavenger of the invention be added with bamboo juice, not only can with volatile injurants such as decomposing formaldehyde, ammonia, and
And all there is stronger inhibiting effect to bacterium and fungi；
2) it is added with imazalil and lysozyme in formaldehyde scavenger of the invention, all has to many bacteriums and fungi relatively strong
Inhibiting effect；
3) it is added with plants essential oil in formaldehyde scavenger of the invention, room air can be made pure and fresh pleasant, it is comfortable to calm the nerves,
And eucalyptus oil, oil of Cymbopogon winterianus, Peppermint essential oil and wormwood essential oil also have effects that certain mosquito and insect expelling；
4) it is added with anion miberal powder in formaldehyde scavenger of the invention, anion can be released, can not only be played
The effect of the volatile injurants such as decomposing formaldehyde, ammonia, but also can refresh the mind.
Specific embodiment
The present invention will be further explained combined with specific embodiments below and explanation.
Embodiment 1:
A kind of formaldehyde scavenger, raw material composition are as shown in the table:
A kind of raw material of the formaldehyde scavenger of table 1 forms table
The preparation method of above-mentioned formaldehyde scavenger is the following steps are included: first by bamboo juice, hydrogen peroxide, SODIUM PERCARBONATE, quaternary ammonium
Salt, bastnasite miberal powder and volcano stone flour are added to the water, and mix well, and add imazalil, lysozyme and eucalyptus oil, sufficiently
It mixes to get formaldehyde scavenger is arrived.
Performance test:
1) anion releasing effect is tested: according to HG/T 4109-2009 anion function coating, it is clear that test obtains formaldehyde
Except the negative aeroion amount of inducing of agent is 23251/(scm2)。
2) pollutant removal is tested: according to QB/T 2761-2006 indoor air purification product clean-up effect measurement side
Method, the removal effect of the pollutants such as test formaldehyde scavenger PARA FORMALDEHYDE PRILLS(91,95), test result is as follows shown in table:
2 formaldehyde scavenger of table removes Contaminant measurement result
Note: sample is in 1.5m330W UV illumination is opened in experimental cabin to be tested.
3) antibacterial effect is tested: measuring the antibacterial of stable state antibacterial agent under the conditions of dynamic Contact according to ASTM E 2149-01
Behavior, test obtain sterilizing rate > 99% of formaldehyde scavenger.
Embodiment 2:
A kind of formaldehyde scavenger, raw material composition are as shown in the table:
A kind of raw material of the formaldehyde scavenger of table 3 forms table
The preparation method of above-mentioned formaldehyde scavenger is the following steps are included: first by bamboo juice, hydrogen peroxide, SODIUM PERCARBONATE, quaternary ammonium
Salt, bastnasite miberal powder and tourmaline powder are added to the water, and mix well, and add imazalil, lysozyme and eucalyptus oil, sufficiently
It mixes to get formaldehyde scavenger is arrived.
Performance test:
1) anion releasing effect test (test method is with embodiment 1): the negative aeroion amount of inducing of formaldehyde scavenger
For 22109/(scm2)。
2) pollutant removal test (test method is with embodiment 1): formaldehyde scavenger PARA FORMALDEHYDE PRILLS(91,95), ammonia, benzene and TVOC
Removal rate be followed successively by 80.1%, 81.7%, 86.2% and 86.5%.
3) antibacterial effect test (test method is with embodiment 1): sterilizing rate > 99% of formaldehyde scavenger.
Embodiment 3:
A kind of formaldehyde scavenger, raw material composition are as shown in the table:
A kind of raw material of the formaldehyde scavenger of table 4 forms table
The preparation method of above-mentioned formaldehyde scavenger is the following steps are included: first by bamboo juice, hydrogen peroxide, SODIUM PERCARBONATE, quaternary ammonium
Salt, bastnasite miberal powder and albumen mountain flour are added to the water, and mix well, and add imazalil, lysozyme and lemon, sufficiently
It mixes to get formaldehyde scavenger is arrived.
Performance test:
1) anion releasing effect test (test method is with embodiment 1): the negative aeroion amount of inducing of formaldehyde scavenger
For 23952/(scm2)。
2) pollutant removal test (test method is with embodiment 1): formaldehyde scavenger PARA FORMALDEHYDE PRILLS(91,95), ammonia, benzene and TVOC
Removal rate be followed successively by 84.4%, 85.3%, 89.5% and 89.2%.
3) antibacterial effect test (test method is with embodiment 1): sterilizing rate > 99% of formaldehyde scavenger.
Embodiment 4:
A kind of formaldehyde scavenger, raw material composition are as shown in the table:
A kind of raw material of the formaldehyde scavenger of table 5 forms table
| Raw material | Mass fraction |
| Bamboo juice | 12 |
| Imazalil | 7 |
| Hydrogen peroxide | 2 |
| SODIUM PERCARBONATE | 5 |
| Quaternary ammonium salt | 1 |
| Lysozyme | 2 |
| Oil of Cymbopogon winterianus | 3 |
| Tourmaline powder (30~80nm of partial size) | 6 |
| Deionized water | 200 |
The preparation method of above-mentioned formaldehyde scavenger is the following steps are included: first by bamboo juice, hydrogen peroxide, SODIUM PERCARBONATE, quaternary ammonium
Salt and tourmaline powder are added to the water, and mix well, and add imazalil, lysozyme and oil of Cymbopogon winterianus, mix well to get first is arrived
Aldehyde scavenger.
Performance test:
1) anion releasing effect test (test method is with embodiment 1): the negative aeroion amount of inducing of formaldehyde scavenger
For 19877/(scm2)。
2) pollutant removal test (test method is with embodiment 1): formaldehyde scavenger PARA FORMALDEHYDE PRILLS(91,95), ammonia, benzene and TVOC
Removal rate be followed successively by 80.5%, 80.8%, 87.7% and 85.8%.
3) antibacterial effect test (test method is with embodiment 1): sterilizing rate > 99% of formaldehyde scavenger.
Embodiment 5:
A kind of formaldehyde scavenger, raw material composition are as shown in the table:
A kind of raw material of the formaldehyde scavenger of table 6 forms table
The preparation method of above-mentioned formaldehyde scavenger is the following steps are included: first by bamboo juice, hydrogen peroxide, SODIUM PERCARBONATE, quaternary ammonium
Salt and bastnasite miberal powder are added to the water, and mix well, and add imazalil, lysozyme and Peppermint essential oil, mix well to get
To formaldehyde scavenger.
Performance test:
1) anion releasing effect test (test method is with embodiment 1): the negative aeroion amount of inducing of formaldehyde scavenger
For 18956/(scm2)。
2) pollutant removal test (test method is with embodiment 1): formaldehyde scavenger PARA FORMALDEHYDE PRILLS(91,95), ammonia, benzene and TVOC
Removal rate be followed successively by 84.0%, 84.9%, 88.6% and 90.5%.
3) antibacterial effect test (test method is with embodiment 1): sterilizing rate > 99% of formaldehyde scavenger.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention,
It should be equivalent substitute mode, be included within the scope of the present invention.
Claims (8)
1. a kind of formaldehyde scavenger, it is characterised in that: be grouped as by the group of following mass parts:
Bamboo juice: 10~18 parts；
Imazalil: 2~7 parts；
Hydrogen peroxide: 1~5 part；
SODIUM PERCARBONATE: 1~5 part；
Quaternary ammonium salt: 1~5 part；
Lysozyme: 1~5 part；
Plants essential oil: 2~5 parts；
Anion miberal powder: 5~10 parts；
Water: 180~200 parts.
2. formaldehyde scavenger according to claim 1, it is characterised in that: be grouped as by the group of following mass parts:
Bamboo juice: 12~14 parts；
Imazalil: 3~5 parts；
Hydrogen peroxide: 1~3 part；
SODIUM PERCARBONATE: 1~3 part；
Quaternary ammonium salt: 2~4 parts；
Lysozyme: 1~3 part；
Plants essential oil: 2~4 parts；
Anion miberal powder: 6~8 parts；
Water: 180~200 parts.
3. formaldehyde scavenger according to claim 1 or 2, it is characterised in that: the plants essential oil is lemon, eucalyptus
Essential oil, oil of Cymbopogon winterianus, Lavender, Peppermint essential oil, Rosa Damascana, refined jasmine oil, Rosemary Oil, grapefruit essential oil, Chinese mugwort
At least one of careless essential oil, deodar essential oil.
4. formaldehyde scavenger according to claim 3, it is characterised in that: the plants essential oil is lemon, eucalyptus essence
At least one of oil, oil of Cymbopogon winterianus, Peppermint essential oil, grapefruit essential oil, wormwood essential oil.
5. formaldehyde scavenger according to claim 1 or 2, it is characterised in that: the anion miberal powder is bastnasite
At least one of powder, six ring mountain flours, tourmaline powder, volcano stone flour, albumen mountain flour, sea-gull mountain flour, snake mountain flour.
6. formaldehyde scavenger according to claim 5, it is characterised in that: the partial size of the anion miberal powder be 30~
80nm。
7. the preparation method of formaldehyde scavenger described in any one of claim 1~6, it is characterised in that: including following step
It is rapid: first bamboo juice, hydrogen peroxide, SODIUM PERCARBONATE, quaternary ammonium salt and anion miberal powder being added to the water, mixed well, it is mould to add suppression
Azoles, lysozyme and plants essential oil mix well to get formaldehyde scavenger is arrived.
8. the application method of formaldehyde scavenger described in any one of claim 1~6, it is characterised in that: including following step
It is rapid: formaldehyde scavenger to be sprayed on furniture, metope, floor and ceiling, natural air drying.
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| CN111317759A (en) * | 2020-03-06 | 2020-06-23 | 大连正润环保工程有限公司 | Traditional Chinese medicine anion disinfectant and preparation method thereof |
| CN112205420A (en) * | 2020-09-04 | 2021-01-12 | 秦立新 | Negative oxygen ion disinfectant, and preparation method and application thereof |
| CN115029186A (en) * | 2022-06-08 | 2022-09-09 | 深圳市复绿生物环保科技有限公司 | Volatile organic compound remover, preparation method and removing equipment |
| JP2023028014A (en) * | 2021-08-18 | 2023-03-03 | ズハイ ヘルメシン エンタープライズ シーオー．，エルティーディー | Mosquito-repelling bead and method for preparing the same |
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