CN105709588A - Air freshener and preparation method and application thereof - Google Patents

Air freshener and preparation method and application thereof Download PDF

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Publication number
CN105709588A
CN105709588A CN201610121039.8A CN201610121039A CN105709588A CN 105709588 A CN105709588 A CN 105709588A CN 201610121039 A CN201610121039 A CN 201610121039A CN 105709588 A CN105709588 A CN 105709588A
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Prior art keywords
air freshener
preparation
aqueous solution
polyoxyethylene
alkaline protease
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Granted
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CN201610121039.8A
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Chinese (zh)
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CN105709588B (en
Inventor
沈磊
赵俊杰
潘琪
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Shanghai Shiou Environmental Protection Technology Co Ltd
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Shanghai Shiou Environmental Protection Technology Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84—Biological processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/60—Simultaneously removing sulfur oxides and nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/95—Specific microorganisms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/302—Sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/502—Carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7027—Aromatic hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708—Volatile organic compounds V.O.C.'s
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention provides air freshener. The air freshener comprises lysozyme, alkaline protease, hydrogen peroxide, an auxiliary agent and surfactant. The invention further provides a preparation method and application of the air refresher. The air refresher can eliminate formaldehyde, other harmful volatile organic compounds (VOC) such as benzene and methylbenzene and harmful gas such as ammonia gas, sulfur dioxide, carbon monoxide and other nitrogen, what is the most important, volatility of volatile organic solvent adhering into controlling matter such as panels within a short time can be improved, and the volatile organic solvent is made to volatilize into the space and break away from the controlling matter.

Description

A kind of air freshener and its preparation method and application
Technical field
The present invention relates to a kind of air freshener, particularly relate to a kind of air freshener and its preparation method and application.
Background technology
In daily life; when in indoor, car owing to finishing or inner-decoration component or smoking etc. cause abnormal flavour; and then allow user or people around feel time air is impure and fresh or uncomfortable, it will usually use air freshener to remove the bad smell that finishing, gadget or furniture distribute.Wherein, formaldehyde and other harmful volatile organism (VOC) especially significant, due to its in decoration materials inevitable, and have a strong impact on human health.Therefore, removing of current air gas with foreign flavor mainly eliminates formaldehyde and other harmful volatile organism (VOC) such as benzene, toluene and other harmful gas such as ammonia, sulfur dioxide, carbon monoxide and other nitrogen etc..
Common air abnormal flavour decomposes class freshener has two kinds: one class to be adopt purification work preparation of raw material to form, energy resolving harmful gas, but its antibacterial effect is poor, and the persistent period is short, reaction afterproduct needs to do after-treatment, and environment can be caused secondary pollution by its volatile substance；Equations of The Second Kind is to be formed by the preparation of biological preparation such as natural extracts or enzymatic reaction, can be generally used for ozone decomposition, but speed is slower.
Wherein, CN104274848A discloses a kind of air freshener with the aldehyde effect that disappears, including solubilizing agent, Lignum cinnamomi camphorae quintessence oil, adjuvant, purified water, it is possible to have again the effect in pure and fresh room while eliminating air Free-formaldehyde；CN104117085A discloses a kind of air freshener, and its component includes chlorophyll, linalyl acetate and ethyl acetate etc., and wherein, by adding chlorophyll, chlorophyllous fluorescent effect can releasing negative oxygen ion better；By adding linalyl acetate and ethyl acetate, the pleasant fragrance of a flower and fruital, quick fresh air can be produced.
It is true that for newly-decorated indoor or other like environment, maximum harm is not discrete VOC in space, but in decoration materials the deenergized period of VOC long, continue to endanger the health of people.The partial air freshener sold currently on the market has low toxicity or the shortcoming such as the persistent period is short, accordingly, it would be desirable to research one class environment-friendly type and promote the VOC air freshener quickly discharged.
Summary of the invention
In order to solve the drawback of prior art, meet the demand of people, the invention provides a kind of air freshener, comprise enzyme such as lysozyme and alkaline protease, it itself it is no side effects enzyme, formaldehyde and other harmful volatile organism (VOC) can be eliminated such as benzene, toluene and other is such as harmful gass such as ammonia, sulfur dioxide, carbon monoxide and other nitrogen, most importantly the volatility at short notice of the volatile organic solvent in improvement things such as being attached to sheet material can be improved so that it is evaporate in space as early as possible to depart from improvement thing itself.
Technical scheme includes a kind of air freshener, it is characterised in that its component and quality proportioning thereof include:
In one embodiment of the invention, described auxiliary agent includes any one or a few in thickening agent, pH adjusting agent, preservative, fixastive, emulsifying agent.It is highly preferred that described auxiliary agent includes polyoxyethylene 20 sorbitan monolaurate, polyoxyethylene 20 sorbitan monostearate, aliphatic alcohol polyoxyvinethene phosphate, castor oil polyoxyethylene base ether.
In an embodiment of the present invention, described air freshener also includes water, for a kind of liquid air freshener.
In another embodiment of the presently claimed invention, the specification of described lysozyme is 20,000 μ/mg.
In one embodiment, described alkaline protease specification is 200,000 μ/g.
In one preferred embodiment, component and the quality proportioning thereof of described air freshener include:
In an embodiment more preferably, component and the quality proportioning thereof of described air freshener include:
The preparation method that technical scheme also includes a kind of air freshener described above, it is characterised in that including:
Step 1: the aqueous solution of preparation lysozyme；
Step 2: the aqueous solution of preparation alkaline protease, hydrogen peroxide, auxiliary agent and surfactant；
Step 3: the aqueous solution of blend step 1 and step 2, obtains described air freshener.
In a preferred embodiment, described preparation method includes:
Step 1: the aqueous solution of preparation lysozyme；
Step 2: the aqueous solution of preparation alkaline protease, hydrogen peroxide, polyoxyethylene 20 sorbitan monolaurate, polyoxyethylene 20 sorbitan monostearate, aliphatic alcohol polyoxyvinethene phosphate, castor oil polyoxyethylene base ether and surfactant；
Step 3: the aqueous solution of blend step 1 and step 2, obtains described air freshener.
Technical scheme also includes the application in removing formaldehyde and volatile organism of a kind of air freshener described above.
Wherein, described volatile organism includes benzene, toluene and other is such as harmful gass such as ammonia, sulfur dioxide, carbon monoxide and other nitrogen.
Air freshener of the present invention is a kind of safety, quickly removes the formula of formaldehyde and volatile organism (VOC), comprises lysozyme and alkaline protease.Wherein, lysozyme is as a kind of natural antiseptic agent, there is antibiotic property strong, safety non-toxic, Heat stability is good, the unique advantages such as sphere of action is wide, further, it is nontoxic as one, the protein having no side effect, there is again certain bacteriolysis, sterilization and antiseptical effect can be played, can effectively remove the antibacterial in environment, solubilized bacterial cell, there are the various character of antibiotics, elimination formaldehyde can be played in conjunction with other components while sterilization, benzene, ammonia, sulfur dioxide, the effect of the harmful gass such as carbon monoxide and other nitrogen or volatile components；Alkaline protease is a kind of nontoxic, protein of having no side effect, belongs to serine type endoprotease, and alkaline protease is successfully applied to enzyme for detergent industry, can be added in the middle of liquid detergent, it is possible to effective remove spot and volatile organic matter.Further, the effect adding described surfactant is to make freshener be better dispersed in freshener, quick fresh air.
Detailed description of the invention
The invention provides a kind of air freshener, it is characterised in that its component and quality proportioning thereof include:
In one embodiment of the invention, described auxiliary agent includes any one or a few in thickening agent, pH adjusting agent, preservative, fixastive, emulsifying agent.It is highly preferred that described auxiliary agent includes polyoxyethylene 20 sorbitan monolaurate, polyoxyethylene 20 sorbitan monostearate, aliphatic alcohol polyoxyvinethene phosphate, castor oil polyoxyethylene base ether.
In an embodiment of the present invention, described air freshener also includes water, for a kind of liquid air freshener.
In another embodiment of the presently claimed invention, the specification of described lysozyme is 20,000 μ/mg.
In one embodiment, described alkaline protease specification is 200,000 μ/g.
In one preferred embodiment, component and the quality proportioning thereof of described air freshener include:
In an embodiment more preferably, component and the quality proportioning thereof of described air freshener include:
The preparation method that present invention also offers a kind of air freshener described above, it is characterised in that including:
Step 1: the aqueous solution of preparation lysozyme；
Step 2: the aqueous solution of preparation alkaline protease, hydrogen peroxide, auxiliary agent and surfactant；
Step 3: the aqueous solution of blend step 1 and step 2, obtains described air freshener.
In a preferred embodiment, described preparation method includes:
Step 1: the aqueous solution of preparation lysozyme；
Step 2: the aqueous solution of preparation alkaline protease, hydrogen peroxide, polyoxyethylene 20 sorbitan monolaurate, polyoxyethylene 20 sorbitan monostearate, aliphatic alcohol polyoxyvinethene phosphate, castor oil polyoxyethylene base ether and surfactant；
Step 3: the aqueous solution of blend step 1 and step 2, obtains described air freshener.
Present invention also offers the application in removing formaldehyde and volatile organism of a kind of air freshener described above.
Wherein, described volatile organism includes benzene, toluene and other is such as harmful gass such as ammonia, sulfur dioxide, carbon monoxide and other nitrogen.
Embodiment 1
1, a kind of air freshener, its component and quality proportioning thereof include:
2, the preparation method of above-mentioned air freshener, including:
Step 1: 3kg lysozyme and 32.7kg distilled water are configured to aqueous solution；
Step 2: when stirring, in 32.7kg distilled water, add 300g alkaline protease, 2kg hydrogen peroxide, 10kg polyoxyethylene 20 sorbitan monolaurate, 6kg polyoxyethylene 20 sorbitan monostearate, 5kg aliphatic alcohol polyoxyvinethene phosphate, 8kg castor oil polyoxyethylene base ether and 300g surfactant, be configured to aqueous solution；
Step 3: the aqueous solution of blend step 1 and step 2, stirs at 40-80 DEG C, obtains described air freshener after cooling.
Embodiment 2
1, a kind of air freshener, its component and quality proportioning thereof include:
2, the preparation method of above-mentioned air freshener, including:
Step 1: 1kg lysozyme and 32.7kg distilled water are configured to aqueous solution；
Step 2: when stirring, in 32.7kg distilled water, add 600g alkaline protease, 2kg hydrogen peroxide, 10kg polyoxyethylene 20 sorbitan monolaurate, 6kg polyoxyethylene 20 sorbitan monostearate, 5kg aliphatic alcohol polyoxyvinethene phosphate, 8kg castor oil polyoxyethylene base ether and 300g surfactant, be configured to aqueous solution；
Step 3: the aqueous solution of blend step 1 and step 2, stirs at 40-80 DEG C, obtains described air freshener after cooling.
Embodiment 3
1, a kind of air freshener, its component and quality proportioning thereof include:
2, the preparation method of above-mentioned air freshener, including:
Step 1: 4kg lysozyme and 27.7kg distilled water are configured to aqueous solution；
Step 2: when stirring, in 27.7kg distilled water, add 500g alkaline protease, 2kg hydrogen peroxide, 20kg polyoxyethylene 20 sorbitan monolaurate, 8kg polyoxyethylene 20 sorbitan monostearate, 5kg aliphatic alcohol polyoxyvinethene phosphate, 7kg castor oil polyoxyethylene base ether and 300g surfactant, be configured to aqueous solution；
Step 3: the aqueous solution of blend step 1 and step 2, stirs at 40-80 DEG C, obtains described air freshener after cooling.
Above specific embodiments of the invention being described in detail, but it is intended only as example, the present invention is not restricted to particular embodiments described above.To those skilled in the art, any equivalent modifications that the present invention is carried out and replacement are also all among scope of the invention.Therefore, the equalization made without departing from the spirit and scope of the invention converts and amendment, all should contain within the scope of the invention.

Claims (10)

1. an air freshener, it is characterised in that its component and quality proportioning thereof include:
2. air freshener according to claim 1, it is characterised in that described auxiliary agent includes any one or a few in thickening agent, pH adjusting agent, preservative, fixastive, emulsifying agent.
3. air freshener according to claim 1, it is characterised in that described auxiliary agent includes polyoxyethylene 20 sorbitan monolaurate, polyoxyethylene 20 sorbitan monostearate, aliphatic alcohol polyoxyvinethene phosphate, castor oil polyoxyethylene base ether.
4. air freshener according to claim 1, it is characterised in that the specification of described lysozyme is 20,000 μ/mg.
5. air freshener according to claim 1, it is characterised in that described alkaline protease specification is 200,000 μ/g.
6. air freshener according to claim 1, it is characterised in that its component and quality proportioning thereof include:
7. air freshener according to claim 1, it is characterised in that its component and quality proportioning thereof include:
8. the preparation method of air freshener as described in claim 1-7 any one, it is characterised in that including:
Step 1: the aqueous solution of preparation lysozyme；
Step 2: the aqueous solution of preparation alkaline protease, hydrogen peroxide, auxiliary agent and surfactant；
Step 3: the aqueous solution of blend step 1 and step 2, obtains described air freshener.
9. preparation method according to claim 8, it is characterised in that including:
Step 1: the aqueous solution of preparation lysozyme；
Step 2: the aqueous solution of preparation alkaline protease, hydrogen peroxide, polyoxyethylene 20 sorbitan monolaurate, polyoxyethylene 20 sorbitan monostearate, aliphatic alcohol polyoxyvinethene phosphate, castor oil polyoxyethylene base ether and surfactant；
Step 3: the aqueous solution of blend step 1 and step 2, obtains described air freshener.
10. an air freshener application in removing formaldehyde and volatile organism as described in claim 1-7 any one.
CN201610121039.8A 2016-03-03 2016-03-03 A kind of air freshener and its preparation method and application Active CN105709588B (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106013674A (en) * 2016-07-22 2016-10-12 上海圣峰建材科技股份有限公司 Decorative plate with functions of removing formaldehyde and purifying air
CN106853337A (en) * 2017-01-06 2017-06-16 长沙协浩吉生物工程有限公司 A kind of compound method of biological in-car air freshener
CN110354665A (en) * 2019-06-19 2019-10-22 广州市鑫竹环保科技有限公司 A kind of formaldehyde scavenger and preparation method thereof
CN111389206A (en) * 2020-02-26 2020-07-10 杭州魔力草环保科技有限公司 Air purification compound agent suitable for decoration pollution and preparation method thereof
CN111420102A (en) * 2019-01-10 2020-07-17 广东阜和实业有限公司 Binary packaged non-combustible air freshener and preparation method thereof
CN111790233A (en) * 2019-04-08 2020-10-20 廊坊鹏帮木业有限公司 Anion liquid capable of purifying air and preparation method and application thereof
CN114984746A (en) * 2022-08-05 2022-09-02 山东建筑大学 System method and device for treating VOCs waste gas in disinfectant and aquaculture wastewater pool
CN116173714A (en) * 2023-03-30 2023-05-30 上海腾灵建设集团有限公司 Film-forming air treatment agent and preparation method thereof

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CN1275406A (en) * 1999-05-26 2000-12-06 上海白猫有限公司 Agent for air refreshing and disinfecting
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CN101428172A (en) * 2008-11-04 2009-05-13 陕西科技大学 Methanal capturing agent and preparation method thereof
CN102614538A (en) * 2012-04-28 2012-08-01 上海环境工程技术有限公司 Deodorant for treating domestic garbage and preparation method as well as use method thereof
CN103272461A (en) * 2013-05-21 2013-09-04 赵杰 Technology for producing formaldehyde scavenging agent by using vegetable proteins
CN103960284A (en) * 2014-05-09 2014-08-06 尹无忌 Deodorant disinfectant for household garbage

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CN1275406A (en) * 1999-05-26 2000-12-06 上海白猫有限公司 Agent for air refreshing and disinfecting
CN2503893Y (en) * 2001-05-29 2002-08-07 顺德市阿波罗环保器材有限公司 Sterilizing and deordorizing air filter
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CN101428172A (en) * 2008-11-04 2009-05-13 陕西科技大学 Methanal capturing agent and preparation method thereof
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CN103272461A (en) * 2013-05-21 2013-09-04 赵杰 Technology for producing formaldehyde scavenging agent by using vegetable proteins
CN103960284A (en) * 2014-05-09 2014-08-06 尹无忌 Deodorant disinfectant for household garbage

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106013674A (en) * 2016-07-22 2016-10-12 上海圣峰建材科技股份有限公司 Decorative plate with functions of removing formaldehyde and purifying air
CN106853337A (en) * 2017-01-06 2017-06-16 长沙协浩吉生物工程有限公司 A kind of compound method of biological in-car air freshener
CN111420102A (en) * 2019-01-10 2020-07-17 广东阜和实业有限公司 Binary packaged non-combustible air freshener and preparation method thereof
CN111790233A (en) * 2019-04-08 2020-10-20 廊坊鹏帮木业有限公司 Anion liquid capable of purifying air and preparation method and application thereof
CN110354665A (en) * 2019-06-19 2019-10-22 广州市鑫竹环保科技有限公司 A kind of formaldehyde scavenger and preparation method thereof
CN111389206A (en) * 2020-02-26 2020-07-10 杭州魔力草环保科技有限公司 Air purification compound agent suitable for decoration pollution and preparation method thereof
CN111389206B (en) * 2020-02-26 2023-04-07 杭州魔力草环保科技有限公司 Air purification compound agent suitable for being used after decoration pollution and preparation method thereof
CN114984746A (en) * 2022-08-05 2022-09-02 山东建筑大学 System method and device for treating VOCs waste gas in disinfectant and aquaculture wastewater pool
CN116173714A (en) * 2023-03-30 2023-05-30 上海腾灵建设集团有限公司 Film-forming air treatment agent and preparation method thereof

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