CN111097198A - 一种纺织印染用消泡剂 - Google Patents

一种纺织印染用消泡剂 Download PDF

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CN111097198A
CN111097198A CN201811270570.7A CN201811270570A CN111097198A CN 111097198 A CN111097198 A CN 111097198A CN 201811270570 A CN201811270570 A CN 201811270570A CN 111097198 A CN111097198 A CN 111097198A
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邵玲
龚家全
杨帆
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Hubei New Sihai Chemical Industry Co ltd
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Abstract

本发明属于消泡剂技术领域，特别涉及一种纺织印染用消泡剂。一种纺织印染用消泡剂，包含以下重量份数的原料：聚硅氧烷20～40份、疏水性二氧化硅15～30份、高碳醇5～15份、硬脂酸锌1～3份、磷酸三丁酯5～8份、单甘油脂肪酸酯2～4份、六偏磷酸钠1～3份、过硫酸氢钾0.5～2份、表面活性剂2～5份、增稠剂1.5～3份、杀菌剂0～3份和去离子水70～85份。本发明的纺织印染用消泡剂具有良好的消泡、抑泡特性，且长期储存使用的品质稳定，有很好的使用价值。

Description

一种纺织印染用消泡剂
技术领域
本发明属于消泡剂技术领域，特别涉及一种纺织印染用消泡剂。
背景技术
在油气开采、制浆造纸、纺织印染、生物发酵、污水处理、涂料加工和建筑工业等领域，搅拌产生的泡沫会引起产能下降、反应周期延长和原料浪费等问题。添加消泡剂可在短时间内消除泡沫。消泡剂可以分为矿物油消泡剂、聚醚类消泡剂和有机硅消泡剂等。矿物油消泡剂只能在液体剪切力较小、所含表面活性剂发泡能力较温和的条件下使用，对致密型泡沫的消除能力较差。
聚醚类消泡剂只有当发泡体系的温度超过浊点温度时才能发挥消泡作用。近年来，有机硅类消泡剂因消泡效率高、用量少、无生理毒性而受到广泛关注，但有机硅分散性差，难以乳化，易凝聚成没有消泡活性的、粒度过大的油珠，而纯硅油对水溶液的泡沫无消泡作用。
发明内容
本发明为了解决上述问题，提供一种纺织印染用消泡剂。
本发明采用以下技术方案来实现：
一种纺织印染用消泡剂，包含以下重量份数的原料：聚硅氧烷20～40份、疏水性二氧化硅15～30份、高碳醇5～15份、硬脂酸锌1～3份、磷酸三丁酯5～8份、单甘油脂肪酸酯2～4份、六偏磷酸钠1～3份、过硫酸氢钾0.5～2份、表面活性剂2～5份、增稠剂1.5～3份、杀菌剂0～3份和去离子水70～85份。
优选的方案，还包含以下重量份数的原料：二甘醇月桂酸酯2～4份。
优选的方案，所述聚硅氧烷为聚二甲基硅氧烷、聚甲基三乙氧基硅烷或聚甲基三甲氧基硅烷。
优选的方案，所述表面活性剂为脂肪酸山梨坦、聚山梨酯、聚氧乙烯单硬脂酸酯或甘油脂肪酸酯。
优选的方案，所述增稠剂为羧甲基纤维素、羧乙基纤维素、黄原胶或聚丙烯酸酯。
优选的方案，所述杀菌剂为戊二醛或纳米氧化银。
优选的方案，所述纺织印染用消泡剂在使用时，将其配置成质量分数为0.1～1.0％的水溶液使用。
本发明的有益效果是：
1.本发明的纺织印染用消泡剂，保证了消泡剂整体的消泡、抑泡效果，添加的助剂成分不仅能有效促进主要活性成分效果的发挥，同时又能改善整体长期存放发生粘度变大、出现交联倾向等失效的情况发生，提高了存储、使用时品质的稳定性。最终在各成分的共同配合作用下，本发明制得的纺织印染用消泡剂具有良好的消泡、抑泡特性，且长期储存使用的品质稳定，有很好的使用价值。
2、本发明的纺织印染用消泡剂中添加有疏水性二氧化硅、纳米氧化银和纳米氧化锌等物质，相互配合作用，可以作为消泡核心，起到快速消泡的作用。
具体实施方式
下面将对实施例中的技术方案进行清楚、完整地描述。显然，所描述的实施例仅仅是本发明的一部分实施例，而不是全部的实施例。基于本发明的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1
一种纺织印染用消泡剂，以质量份计，采用如下步骤制成：
S1，将聚二甲基硅氧烷20份、高碳醇8份、硬脂酸锌3份、磷酸三丁酯5份、单甘油脂肪酸酯4份、过硫酸氢钾0.5份混合后，搅拌均匀，制得A液；
S2，将六偏磷酸钠3份、脂肪酸山梨坦2份和羧甲基纤维素3份加入去离子水85份中，搅拌均匀制得B液；
S3，将A液和B液在70℃条件下混合，升温至100℃搅拌均匀后，加入疏水性二氧化硅15份，保温30min，制得纺织印染用消泡剂。
实施例2
一种纺织印染用消泡剂，以质量份计，采用如下步骤制成：
S1，将聚甲基三乙氧基硅烷30份、高碳醇5份、硬脂酸锌1份、磷酸三丁酯8份、单甘油脂肪酸酯2份、过硫酸氢钾2份混合后，搅拌均匀，制得A液；
S2，将六偏磷酸钠3份、聚山梨酯5份和羧乙基纤维素1.5份加入去离子水70份中，搅拌均匀制得B液；
S3，将A液和B液在60℃条件下混合，升温至90℃搅拌均匀后，加入疏水性二氧化硅30份、二甘醇月桂酸酯3份，保温40min，制得纺织印染用消泡剂。
实施例3
一种纺织印染用消泡剂，以质量份计，采用如下步骤制成：
S1，将聚甲基三甲氧基硅烷40份、高碳醇15份、硬脂酸锌2份、磷酸三丁酯6份、单甘油脂肪酸酯4份、过硫酸氢钾1份混合后，搅拌均匀，制得A液；
S2，将六偏磷酸钠2份、甘油脂肪酸酯3份和黄原胶2份加入去离子水75份中，搅拌均匀制得B液；
S3，将A液和B液在65℃条件下混合，升温至95℃搅拌均匀后，加入疏水性二氧化硅20份、二甘醇月桂酸酯2份和戊二醛2份，保温35min，制得纺织印染用消泡剂。
实施例4
一种纺织印染用消泡剂，以质量份计，采用如下步骤制成：
S1，将聚二甲基硅氧烷30份、高碳醇10份、硬脂酸锌2份、磷酸三丁酯7份、单甘油脂肪酸酯3份、过硫酸氢钾1.5份混合后，搅拌均匀，制得A液；
S2，将六偏磷酸钠2.5份、聚氧乙烯单硬脂酸酯4份和聚丙烯酸酯2.5份加入去离子水80份中，搅拌均匀制得B液；
S3，将A液和B液在65℃条件下混合，升温至95℃搅拌均匀后，加入疏水性二氧化硅25份、二甘醇月桂酸酯4份和纳米氧化银3份，保温35min，制得纺织印染用消泡剂。

Claims (7)

1.一种纺织印染用消泡剂，其特征在于：包含以下重量份数的原料：聚硅氧烷20～40份、疏水性二氧化硅15～30份、高碳醇5～15份、硬脂酸锌1～5份、磷酸三丁酯5～8份、单甘油脂肪酸酯2～4份、六偏磷酸钠1～3份、过硫酸氢钾0.5～2份、表面活性剂2～5份、增稠剂1.5～3份、杀菌剂0～3份和去离子水70～85份。
2.根据权利要求1所述的纺织印染用消泡剂，其特征在于：还包含以下重量份数的原料：二甘醇月桂酸酯0.1～0.5份。
3.根据权利要求1所述的纺织印染用消泡剂，其特征在于：所述聚硅氧烷为聚二甲基硅氧烷、聚甲基三乙氧基硅烷或聚甲基三甲氧基硅烷。
4.根据权利要求1所述的纺织印染用消泡剂，其特征在于：所述表面活性剂为脂肪酸山梨坦、聚山梨酯、聚氧乙烯单硬脂酸酯或甘油脂肪酸酯。
5.根据权利要求1所述的纺织印染用消泡剂，其特征在于：所述增稠剂为羧甲基纤维素、羧乙基纤维素、黄原胶或聚丙烯酸酯。
6.根据权利要求1所述的纺织印染用消泡剂，其特征在于：所述杀菌剂为戊二醛或纳米氧化银。
7.根据权利要求1中所述的一种纺织印染用消泡剂，其特征在于，所述纺织印染用消泡剂在使用时，将其配置成质量分数为0.1～1.0％的水溶液使用。
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