CN111073343A - 一种分散荧光橙染料及其应用 - Google Patents

一种分散荧光橙染料及其应用 Download PDF

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CN111073343A
CN111073343A CN201911396830.XA CN201911396830A CN111073343A CN 111073343 A CN111073343 A CN 111073343A CN 201911396830 A CN201911396830 A CN 201911396830A CN 111073343 A CN111073343 A CN 111073343A
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grades
dye
fluorescent orange
disperse
orange dye
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吴礼富
阮永庆
徐建国
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Zhejiang Boao Dyestuff Industry Co ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58—Material containing hydroxyl groups
    • D06P3/60—Natural or regenerated cellulose
    • D06P3/6033—Natural or regenerated cellulose using dispersed dyes
    • D06P3/6041—Natural or regenerated cellulose using dispersed dyes using specified dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1044—Heterocyclic compounds characterised by ligands containing two nitrogen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1044—Heterocyclic compounds characterised by ligands containing two nitrogen atoms as heteroatoms
    • C09K2211/1048—Heterocyclic compounds characterised by ligands containing two nitrogen atoms as heteroatoms with oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1088—Heterocyclic compounds characterised by ligands containing oxygen as the only heteroatom

Abstract

本发明公开了一种分散荧光橙染料，按质量分数包括0.1‑75%的如式(I)所示的染料单体A，0.1‑75%的如式(Ⅱ)所示的染料单体B，以及余量的助剂，
Figure 100004_DEST_PATH_IMAGE002
(Ⅰ)；

Description

一种分散荧光橙染料及其应用
技术领域
本发明涉及杂环染料复合物染料技术领域，具体是一种分散荧光橙染料及其应用。
背景技术
从纺织品面料现状来看，有多种纤维组合而成的面料所占的比例逐年增加，尤其户内外装饰用品、体育用品、特种作业警示服装等面料不断增加，目前市场上供应的分散荧光单体染料较少，该类产品为杂环类分散染料，分子结构复杂，生产工艺复杂，合成难度大，色谱不全，还不能很好的满足该类纺织品的印染需要，市场急需要更多色谱齐全的耐水洗、耐摩擦和耐光色牢度较好的荧光分散染料。
发明内容
本发明针对现有技术不足，提供一种分散荧光橙染料及其应用，这种分散荧光橙染料提供了更多色谱的耐水洗、耐摩擦和耐光色牢度较好的荧光分散染料。
为了解决上述技术问题，本发明通过下述技术方案得以解决：一种分散荧光橙染料，按质量分数包括0.1-75%的如式(I)所示的染料单体A， 0.1-75%的如式(Ⅱ)所示的染料单体B，以及余量的助剂，
Figure 100002_DEST_PATH_IMAGE002
(Ⅰ)；
Figure 100002_DEST_PATH_IMAGE004
(Ⅱ)。这种分散荧光橙染料提供了更多色谱的耐水洗、耐摩擦和耐光色牢度较好的荧光分散染料。
上述技术方案中，优选的，所述的助剂为下列之一或两种以上任意比例的混合物：萘磺酸甲醛缩合物、烷基萘磺酸甲醛缩合物、木质素磺酸盐、苄基萘磺酸盐甲醛缩合物。
上述技术方案中，优选的，所述烷基萘磺酸甲醛缩合物为甲基萘磺酸甲醛缩合物。
上述技术方案中，优选的，所述木质素磺酸盐为木质素磺酸钠。
上述技术方案中，优选的，按质量分数包括30-50%的如式(I)所示的染料单体A，35-55%的如式(Ⅱ)所示的染料单体B，以及余量的助剂，
Figure 100002_DEST_PATH_IMAGE002A
(Ⅰ)；
Figure 100002_DEST_PATH_IMAGE004A
(Ⅱ)。
上述技术方案中，优选的，所述的助剂为下列之一或两种以上任意比例的混合物：萘磺酸甲醛缩合物、烷基萘磺酸甲醛缩合物、木质素磺酸盐。
上述分散荧光橙染料用于织物染色、塑料染色或喷涂的用途。
本发明与现有技术相比，具有如下有益效果：这种分散荧光橙染料提供了更多色谱的耐水洗、耐摩擦和耐光色牢度较好的荧光分散染料。
具体实施方式
下面结合具体实施方式对本发明作进一步详细描述：实施例1-8，按照表1所示计量数据，将染料单体A、染料单体B、分散剂MF、扩散剂CNF、扩散剂NNO和木质素磺酸钠加水拼混后，用研磨机进行研磨分散，喷雾干燥制得分散荧光橙染料。其中染色单体A为
Figure DEST_PATH_IMAGE002AA
(Ⅰ)；
染色单体B为
Figure DEST_PATH_IMAGE004AA
(Ⅱ)。
表1
Figure DEST_PATH_IMAGE006
实施例9-16，按照表2所示计量数据，将C.I.分散黄82（商品染料，单体A含量为50%，其余为助剂）、C.I.分散红277（商品染料，单体B含量为50%，其余为助剂）、分散剂MF、扩散剂CNF和扩散剂NNO加水拼混后，用研磨机进行研磨分散，喷雾干燥制得分散荧光橙染料。
表2
Figure DEST_PATH_IMAGE008
各取0.5克实施例1-16制得的一种复合分散染料，分散在500毫升的水中，吸取20毫升后与60毫升水混合。用醋酸调染浴PH=4.5,升温至70℃同时放入2克涤/棉布进行染色，于50分钟内温度由70℃升至130℃，保温30分钟，冷却到90℃时开始取样。采用国标GB/T3921-1997、GB/T3920-1997、GB/T8427-1998、GB/T5718-1997.分别测试其耐水洗、耐摩擦、耐光色牢度，测试结果见表3。
表3
实施例名称 耐水洗 耐摩擦 耐光
实施例1 3～4级 3～4级 3～4级
实施例2 3～4级 3～4级 3～4级
实施例3 3～4级 3～4级 3～4级
实施例4 3～4级 3～4级 3～4级
实施例5 3～4级 3～4级 3～4级
实施例6 3～4级 3～4级 3～4级
实施例7 3～4级 3～4级 3～4级
实施例8 3～4级 3～4级 3～4级
实施例9 3～4级 3～4级 3～4级
实施例10 3～4级 3～4级 3～4级
实施例11 3～4级 3～4级 3～4级
实施例12 3～4级 3～4级 3～4级
实施例13 3～4级 3～4级 3～4级
实施例14 3～4级 3～4级 3～4级
实施例15 3～4级 3～4级 3～4级
实施例16 3～4级 3～4级 3～4级
这种分散荧光橙染料提供了更多色谱的耐水洗、耐摩擦和耐光色牢度较好的荧光分散染料。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。

Claims (7)

1.一种分散荧光橙染料，其特征在于：按质量分数包括0.1-75%的如式(I)所示的染料单体A， 0.1-75%的如式(Ⅱ)所示的染料单体B，以及余量的助剂，
Figure DEST_PATH_IMAGE002
(Ⅰ)；
Figure DEST_PATH_IMAGE004
(Ⅱ)。
2.如权利要求1所述的一种分散荧光橙染料，其特征在于：所述的助剂为下列之一或两种以上任意比例的混合物：萘磺酸甲醛缩合物、烷基萘磺酸甲醛缩合物、木质素磺酸盐、苄基萘磺酸盐甲醛缩合物。
3.如权利要求2所述的一种分散荧光橙染料，其特征在于：所述烷基萘磺酸甲醛缩合物为甲基萘磺酸甲醛缩合物。
4.如权利要求2所述的一种分散荧光橙染料，其特征在于：所述木质素磺酸盐为木质素磺酸钠。
5.如权利要求1所述的一种分散荧光橙染料，其特征在于：按质量分数包括30-50%的如式(I)所示的染料单体A，35-55%的如式(Ⅱ)所示的染料单体B，以及余量的助剂，
Figure DEST_PATH_IMAGE002A
(Ⅰ)；
Figure DEST_PATH_IMAGE004A
(Ⅱ)。
6.如权利要求5所述的一种分散荧光橙染料，其特征在于：所述的助剂为下列之一或两种以上任意比例的混合物：萘磺酸甲醛缩合物、烷基萘磺酸甲醛缩合物、木质素磺酸盐。
7.如权利要求1-6任意一条所述的分散荧光橙染料用于织物染色、塑料染色或喷涂的用途。
CN201911396830.XA 2019-12-30 2019-12-30 一种分散荧光橙染料及其应用 Pending CN111073343A (zh)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5725363A (en) * 1980-06-12 1982-02-10 Bayer Ag Dye blend and use
JPH1010714A (ja) * 1996-06-21 1998-01-16 Konica Corp 感光性組成物
CN1193241C (zh) * 2000-04-11 2005-03-16 日本电石工业株式会社 荧光性循环反射片
CN110218466A (zh) * 2019-07-04 2019-09-10 九江富达实业有限公司 一种超高强度分散染料及其制备方法以及应用

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5725363A (en) * 1980-06-12 1982-02-10 Bayer Ag Dye blend and use
JPH1010714A (ja) * 1996-06-21 1998-01-16 Konica Corp 感光性組成物
CN1193241C (zh) * 2000-04-11 2005-03-16 日本电石工业株式会社 荧光性循环反射片
CN110218466A (zh) * 2019-07-04 2019-09-10 九江富达实业有限公司 一种超高强度分散染料及其制备方法以及应用

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Application publication date: 20200428