CN110963809B - 一种Al4Si4C-Al2O3质耐火浇注料的制备方法 - Google Patents
一种Al4Si4C-Al2O3质耐火浇注料的制备方法 Download PDFInfo
- Publication number
- CN110963809B CN110963809B CN201911295998.1A CN201911295998A CN110963809B CN 110963809 B CN110963809 B CN 110963809B CN 201911295998 A CN201911295998 A CN 201911295998A CN 110963809 B CN110963809 B CN 110963809B
- Authority
- CN
- China
- Prior art keywords
- equal
- less
- al4si4c
- grain diameter
- alumina
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 229910052593 corundum Inorganic materials 0.000 title claims abstract description 9
- 229910001845 yogo sapphire Inorganic materials 0.000 title claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 19
- 239000000654 additive Substances 0.000 claims abstract description 10
- 230000000996 additive effect Effects 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims abstract description 9
- 229910001570 bauxite Inorganic materials 0.000 claims abstract description 8
- 239000007767 bonding agent Substances 0.000 claims abstract description 8
- 239000010453 quartz Substances 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052751 metal Inorganic materials 0.000 claims abstract description 6
- 239000002184 metal Substances 0.000 claims abstract description 6
- 239000011863 silicon-based powder Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000000498 ball milling Methods 0.000 claims abstract description 4
- 239000002270 dispersing agent Substances 0.000 claims abstract description 4
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 239000004575 stone Substances 0.000 claims description 4
- 238000010276 construction Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004568 cement Substances 0.000 claims description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 2
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 2
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 2
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 2
- 230000003628 erosive effect Effects 0.000 abstract description 6
- 239000011819 refractory material Substances 0.000 abstract description 5
- 238000004321 preservation Methods 0.000 abstract description 3
- 238000007789 sealing Methods 0.000 abstract description 3
- 230000033116 oxidation-reduction process Effects 0.000 abstract description 2
- 238000005299 abrasion Methods 0.000 abstract 1
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 6
- 235000011941 Tilia x europaea Nutrition 0.000 description 6
- 239000004571 lime Substances 0.000 description 6
- 230000006872 improvement Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000005997 Calcium carbide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011044 quartzite Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
- C04B2235/3203—Lithium oxide or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
- C04B2235/3222—Aluminates other than alumino-silicates, e.g. spinel (MgAl2O4)
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3409—Boron oxide, borates, boric acids, or oxide forming salts thereof, e.g. borax
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/40—Metallic constituents or additives not added as binding phase
- C04B2235/402—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/422—Carbon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/428—Silicon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/447—Phosphates or phosphites, e.g. orthophosphate or hypophosphite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/48—Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/74—Physical characteristics
- C04B2235/77—Density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Products (AREA)
Abstract
本发明涉及一种Al4Si4C‑Al2O3质耐火浇注料的制备方法，属于耐火材料领域。首先以工业铝粉、活性炭粉、金属硅粉为原料，以无水乙醇作为分散剂，球磨6～12h，于1100～1300℃保温4‑8h，得到物料A。按照质量百分比配比如下：0.088mm＜粒径≤8mm的高铝矾土45～70%，0.088mm＜粒径≤1mm的A物料10～30%，粒径≤0.088mm的氧化铝0～15%，粒径≤0.088mm的石英石0～10%，结合剂5～15%，外加剂0～1%。本发明产品具有优异的抗侵蚀性、耐磨损性和抗氧化还原性能，可以应用于套筒窑内所有难于施工的部位，有利于保证套筒窑的密封性和窑内压力。
Description
技术领域
本发明涉及制备一种石灰套筒窑用耐火材料，尤其涉及一种Al4Si4C-Al2O3质耐火浇注料的制备方法，属于耐火材料领域。
背景技术
伴随着电石行业及钢铁行业的不断发展和进步，煅烧高品质生石灰的节能环保型石灰窑得到越来越多石灰用户的青睐。环形套筒石灰窑从20世纪90年代自德国引入中国，经过国内众多企业的研究和改进，已成为钢铁和电石行业石灰生产的主要窑型之一。其最大特点是煅烧工艺合理，产品质量高，占地面积小，环保，安全，节能，操作自动化程度高，但由于其耐火材料衬里设计复杂，施工难度较大，整体密封性要求极高，对耐火材料衬里有着较高的要求。
在石灰套筒窑里，难于施工的部位通常采用高铝浇注料，比如下拖圈部位，传统高铝浇注料的抗侵蚀性和耐磨损性能还达不到整座窑炉的寿命要求，需要停炉修补。下拖圈部位，不但对上部起到一个支撑的作用，而且会影响套筒窑炉内的密封性能，一旦发生局部侵蚀剥落，将会改变窑内压力，影响套筒窑的正常操作，必须停窑检修，严重影响套筒窑的运转率。
本发明针对套筒窑的使用环境，采用自制的非氧化物Al4Si4C材料，制备一种套筒窑用Al4Si4C-Al2O3质耐火浇注料，具有优异的抗侵蚀性、耐磨损性、抗氧化还原性，能够满足套筒窑内部所有难于施工部位的使用要求。
发明内容
本发明的目的在于提供一种套筒窑用Al4Si4C-Al2O3质耐火浇注料，解决传统高铝浇注料在套筒窑上使用过程中易出现侵蚀、剥落的问题，提高浇注料的使用寿命，有理由保证套筒窑的密封性和窑内压力。
为了达到以上目的，本发明采用如下技术方案：
一种Al4Si4C-Al2O3质耐火浇注料的制备方法，其特征在于，将工业铝粉、活性炭粉、金属硅粉为原料，以无水乙醇作为分散剂，球磨6～12h，于1100～1300℃保温4-8h，得到物料A。其中，工业铝粉、活性炭粉、金属硅粉三者的比例为n(Al):n(C):n(Si)=4:1:4，物料A的主要物相组成为非氧化物Al4Si4C。
按照质量百分比配比如下：0.088mm＜粒径≤8mm的高铝矾土45～70%，0.088mm＜粒径≤1mm的A物料10～30%，粒径≤0.088mm的氧化铝0～15%，粒径≤0.088mm的石英石0～10%，结合剂5～15%，外加剂0～1%。
结合剂为纯铝酸钙水泥。
外加剂为三聚磷酸钠、六偏磷酸钠、木质素磺酸钠、硼酸、氢氧化锂中的一种或几种。
所述浇注料的制备方法是：将0.088mm＜粒径≤8mm的高铝矾土、0.088mm＜粒径≤1mm的A物料、粒径≤0.088mm的氧化铝、粒径≤0.088mm的石英石和结合剂进行预混合，再加入外加剂，用强制搅拌机搅拌3～5min，添加6wt～9wt%的水，搅拌成具有良好施工性能的浇注料。
本发明的优点：本发明制备的非氧化物Al4Si4C材料，具有高熔点、高强度、高化学稳定性、低密度、低热膨胀系数的特性，以及优异的抗侵蚀性、抗氧化性和抗水化性，以0.088mm＜粒径≤1mm的形式引入到本发明的产品中，起到强化基质的作用，使得本发明产品具有优异的抗侵蚀性、抗氧化还原性和耐磨损性能。
具体实施方式
实施例1：一种Al4Si4C-Al2O3质耐火浇注料的制备方法，其特征在于，将工业铝粉、活性炭粉、金属硅粉为原料，以无水乙醇作为分散剂，球磨8h，于1250℃保温6h，得到主要物相组成为非氧化物Al4Si4C的物料A。
按照质量百分比配比如下：0.088mm＜粒径≤8mm的高铝矾土55%，0.088mm＜粒径≤1mm的A物料25%，粒径≤0.088mm的氧化铝8%，粒径≤0.088mm的石英石5%，结合剂7%，外加剂0.6%，加水量6.5%。检测结果见下表。
实施例2：生产工艺和实施例1相同，不同之处在于：
按照质量百分比配比如下：0.088mm＜粒径≤8mm的高铝矾土50%，0.088mm＜粒径≤1mm的A物料28%，粒径≤0.088mm的氧化铝12%，粒径≤0.088mm的石英石4%，结合剂6%，外加剂0.6%，加水量6.7%。检测结果见下表。
实施例3：生产工艺和实施例1相同，不同之处在于：
按照质量百分比配比如下：0.088mm＜粒径≤8mm的高铝矾土46%，0.088mm＜粒径≤1mm的A物料30%，粒径≤0.088mm的氧化铝13%，粒径≤0.088mm的石英石5%，结合剂6%，外加剂0.5%，加水量6.5%。检测结果见下表。
以上所述仅是本发明的优选实施方式，应当指出对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。
Claims (5)
1.一种Al4Si4C-Al2O3质耐火浇注料，其特征在于，按照质量百分比配比如
下：高铝矾土45～70%、物料A 10～30%、氧化铝0～15%、石英石0～10%、结合剂5～15%、外加剂0～1%；所述物料A的制备方法为：以工业铝粉、活性炭粉、金属硅粉为原料，工业铝粉、活性炭粉、金属硅粉三者的比例为n(Al):n(C):n(Si)=4:1:4，以无水乙醇作为分散剂，球磨6～12h，于1100～1300℃保温4-8h，得到物料A，所述物料A的主要物相组成为非氧化物Al4Si4C。
2.根据权利要求1所述的Al4Si4C-Al2O3质耐火浇注料，其特征在于，所述物料A的粒径为：0.088mm＜粒径≤1mm。
3.根据权利要求1所述的Al4Si4C-Al2O3质耐火浇注料，其特征在于，0.088mm＜所述高铝矾土粒径≤8mm，所述氧化铝粒径≤0 .088mm，所述石英石粒径≤0 .088mm。
4.根据权利要求1所述的Al4Si4C-Al2O3质耐火浇注料，其特征在于，所述结合剂为纯铝酸钙水泥；所述外加剂为三聚磷酸钠、六偏磷酸钠、木质素磺酸钠、硼酸、氢氧化锂中的一种或几种。
5.权利要求1-4任一项所述Al4Si4C-Al2O3质耐火浇注料的制备方法，其特征在于，包括以下步骤：将0 .088mm＜粒径≤8mm的高铝矾土、0 .088mm＜粒径≤1mm的物料A、粒径≤0.088mm的氧化铝、粒径≤0 .088mm的石英石和结合剂进行预混合，再加入外加剂，用强制搅拌机搅拌3～5min，添加6wt%～9wt%的水，搅拌成具有良好施工性能的浇注料。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911295998.1A CN110963809B (zh) | 2019-12-16 | 2019-12-16 | 一种Al4Si4C-Al2O3质耐火浇注料的制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911295998.1A CN110963809B (zh) | 2019-12-16 | 2019-12-16 | 一种Al4Si4C-Al2O3质耐火浇注料的制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110963809A CN110963809A (zh) | 2020-04-07 |
| CN110963809B true CN110963809B (zh) | 2022-05-17 |
Family
ID=70034506
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911295998.1A Active CN110963809B (zh) | 2019-12-16 | 2019-12-16 | 一种Al4Si4C-Al2O3质耐火浇注料的制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110963809B (zh) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101423406A (zh) * | 2008-11-20 | 2009-05-06 | 武汉科技大学 | 一种Al4SiC4-Al2O3复合耐火材料及其制备方法 |
| CN101492300A (zh) * | 2009-01-15 | 2009-07-29 | 范圣良 | 超强耐磨浇注料 |
| CN101885617A (zh) * | 2010-06-28 | 2010-11-17 | 阳泉金隅通达高温材料有限公司 | 一种采用矾土基均质料制备的耐磨抗侵蚀浇注料及其方法 |
| CN108530040A (zh) * | 2017-03-02 | 2018-09-14 | 上海安可科技股份有限公司 | 用于钢包烘烤烧嘴的耐火浇注料及钢包烘烤烧嘴 |
-
2019
- 2019-12-16 CN CN201911295998.1A patent/CN110963809B/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101423406A (zh) * | 2008-11-20 | 2009-05-06 | 武汉科技大学 | 一种Al4SiC4-Al2O3复合耐火材料及其制备方法 |
| CN101492300A (zh) * | 2009-01-15 | 2009-07-29 | 范圣良 | 超强耐磨浇注料 |
| CN101885617A (zh) * | 2010-06-28 | 2010-11-17 | 阳泉金隅通达高温材料有限公司 | 一种采用矾土基均质料制备的耐磨抗侵蚀浇注料及其方法 |
| CN108530040A (zh) * | 2017-03-02 | 2018-09-14 | 上海安可科技股份有限公司 | 用于钢包烘烤烧嘴的耐火浇注料及钢包烘烤烧嘴 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110963809A (zh) | 2020-04-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101885617B (zh) | 一种采用矾土基均质料制备的耐磨抗侵蚀浇注料及其方法 | |
| CN102491770B (zh) | 一种耐磨耐火浇注料 | |
| CN104909771B (zh) | 铝酸钙水泥结合刚玉质浇注料及其制备方法 | |
| CN108083765B (zh) | 低导热抗剥落砖及其制备方法 | |
| CN107573098B (zh) | 一种用于烧结点火炉的轻量化浇注料 | |
| CN101492303B (zh) | 三次风管闸板专用耐火浇注料 | |
| CN104909772B (zh) | 含复合添加剂的铝酸钙水泥结合刚玉质浇注料及其制备方法 | |
| CN109704774B (zh) | 一种代替碳砖的高炉炉底炉缸高导热率浇注料的制备方法 | |
| CN101734936A (zh) | 一种Si3N4-SiC-C耐火原料粉体的制备方法 | |
| CN101613214A (zh) | 一种水泥窑高温带用镁铁铝尖晶石砖及其使用方法 | |
| CN108424016A (zh) | 一种结构工程用高性能轻骨料 | |
| CN104725058A (zh) | 方镁石-镁铁铁铝尖晶石/镁橄榄石复合砖 | |
| CN105272314A (zh) | 一种环保无铬透气砖 | |
| CN110937905B (zh) | 一种高抗热震性复合窑口浇注料 | |
| CN106336227B (zh) | 一种矿产废弃物耐火材料及其制备工艺 | |
| CN104909773B (zh) | 含复合添加剂的铝酸钙水泥结合铝镁质浇注料及其制备方法 | |
| CN103922775A (zh) | 旋流器耐磨陶瓷衬板及其制备方法 | |
| CN113651621A (zh) | 一种水泥回转窑用特种新型硅莫砖及其制备工艺 | |
| CN109320218A (zh) | 一种铝锆尖晶石耐火材料砖及其制备方法 | |
| CN110963809B (zh) | 一种Al4Si4C-Al2O3质耐火浇注料的制备方法 | |
| CN111018506B (zh) | 一种用于水泥窑预热器抗结皮喷涂料 | |
| CN107540351A (zh) | 一种海水镁砂‑镁铝尖晶石‑氧化锆高纯复合材料 | |
| CN112898036A (zh) | 一种高性能莫来石浇注料及其制备方法 | |
| CN104387096A (zh) | 一种冶炼钢包用刚玉尖晶石不烧砖及其制备方法 | |
| CN109354425B (zh) | 一种适用于白色硫铝酸盐水泥熟料煅烧的复合矿化剂及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |