CN110923022A - High-cleanness alcohol-based liquid fuel - Google Patents
High-cleanness alcohol-based liquid fuel Download PDFInfo
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- CN110923022A CN110923022A CN201911294532.XA CN201911294532A CN110923022A CN 110923022 A CN110923022 A CN 110923022A CN 201911294532 A CN201911294532 A CN 201911294532A CN 110923022 A CN110923022 A CN 110923022A
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- parts
- alcohol
- based liquid
- liquid fuel
- additive
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 59
- 239000000446 fuel Substances 0.000 title claims abstract description 54
- 239000007788 liquid Substances 0.000 title claims abstract description 41
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000000654 additive Substances 0.000 claims abstract description 24
- 230000000996 additive effect Effects 0.000 claims abstract description 24
- -1 isooctyl Chemical group 0.000 claims abstract description 14
- OPLCSTZDXXUYDU-UHFFFAOYSA-N 2,4-dimethyl-6-tert-butylphenol Chemical compound CC1=CC(C)=C(O)C(C(C)(C)C)=C1 OPLCSTZDXXUYDU-UHFFFAOYSA-N 0.000 claims abstract description 13
- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920000193 polymethacrylate Polymers 0.000 claims abstract description 13
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims abstract description 12
- FEXQDZTYJVXMOS-UHFFFAOYSA-N Isopropyl benzoate Chemical compound CC(C)OC(=O)C1=CC=CC=C1 FEXQDZTYJVXMOS-UHFFFAOYSA-N 0.000 claims abstract description 12
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims abstract description 12
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 claims abstract description 12
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 claims abstract description 12
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 claims abstract description 11
- IZFGRAGOVZCUFB-HJWRWDBZSA-N methyl palmitoleate Chemical compound CCCCCC\C=C/CCCCCCCC(=O)OC IZFGRAGOVZCUFB-HJWRWDBZSA-N 0.000 claims abstract description 11
- 239000003502 gasoline Substances 0.000 claims abstract description 9
- OWHWHWGFYMLSTN-UHFFFAOYSA-N 2-n-butan-2-yl-1-n-phenylbenzene-1,2-diamine Chemical compound CCC(C)NC1=CC=CC=C1NC1=CC=CC=C1 OWHWHWGFYMLSTN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims description 15
- RURPJGZXBHYNEM-UHFFFAOYSA-N 2-[2-[(2-hydroxyphenyl)methylideneamino]propyliminomethyl]phenol Chemical compound C=1C=CC=C(O)C=1C=NC(C)CN=CC1=CC=CC=C1O RURPJGZXBHYNEM-UHFFFAOYSA-N 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000009210 therapy by ultrasound Methods 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 19
- 239000002184 metal Substances 0.000 abstract description 19
- 238000002485 combustion reaction Methods 0.000 abstract description 11
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000428 dust Substances 0.000 abstract description 4
- 239000000779 smoke Substances 0.000 abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- 230000008021 deposition Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 description 13
- 230000007797 corrosion Effects 0.000 description 13
- 238000012360 testing method Methods 0.000 description 8
- 230000003749 cleanliness Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- FLIACVVOZYBSBS-UHFFFAOYSA-N Methyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC FLIACVVOZYBSBS-UHFFFAOYSA-N 0.000 description 2
- 238000003915 air pollution Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003949 liquefied natural gas Substances 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
- C10L1/1832—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom mono-hydroxy
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
- C10L1/1905—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/196—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
- C10L1/1963—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof mono-carboxylic
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
- C10L1/2425—Thiocarbonic acids and derivatives thereof, e.g. xanthates; Thiocarbamic acids or derivatives thereof, e.g. dithio-carbamates; Thiurams
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
- C10L1/2443—Organic compounds containing sulfur, selenium and/or tellurium heterocyclic compounds
- C10L1/2456—Organic compounds containing sulfur, selenium and/or tellurium heterocyclic compounds sulfur with oxygen and/or nitrogen in the ring, e.g. thiazoles
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention provides a high-cleanness alcohol-based liquid fuel, and belongs to the technical field of alcohol-based liquid fuels. The high-cleanness alcohol-based liquid fuel is prepared from methanol, ethanol gasoline and an additive; the additive is prepared from isooctyl polymethacrylate, 2, 4-dimethyl-6-tert-butylphenol, N '-disalicylidene-1, 2-propane diamine, dodecyl methacrylate, diethylene glycol monomethyl ether, methyl palmitoleate, diethylaminoethyl methacrylate, zinc dibutyl dithiocarbamate, 2-N-octyl-4-isothiazoline-3-ketone, dioctyl phthalate, N-phenyl-N' -sec-butyl phenylenediamine and isopropyl benzoate. The alcohol-based liquid fuel has the advantages of small corrosivity to metal parts, good lubricity, large viscosity, high heat value, reddish brown color, bluish green combustion fire, no residual liquid, no smoke dust, no carbon deposition, no harmful gas such as sulfur dioxide and the like in the combustion process, and meets the requirement of environmental protection.
Description
Technical Field
The invention relates to the technical field of alcohol-based liquid fuels, in particular to a high-cleanness alcohol-based liquid fuel.
Background
Energy utilization is a main cause of air pollution. In the energy utilization structure of China, coal with serious pollution accounts for about 70% of the total energy consumption, and various fuels are combusted in various boilers, catering stoves and other devices to generate a large amount of pollutants such as smoke dust, particulate matters, sulfides and the like. In particular, small-sized hot water and heating boilers around cities are large in quantity, wide in distribution, poor in combustion conditions, and large in influence of various pollutant emissions on air pollution of local areas.
The use of a small coal-fired boiler is reduced, and the novel alcohol-based fuel boiler and the clean fuel are popularized and applied, so that the method is an effective measure for improving the urban atmospheric environment quality.
The alcohol-based fuel is a liquid fuel mainly prepared from alcohols (mainly methanol), and is a cheap and environment-friendly clean energy source. The alcohol-based fuel contains oxygen, so that the oxygen demand is less during combustion, and the fuel is fully combusted. The raw material source of the alcohol-based fuel is wide, the methanol production capacity of 7000 ten thousand tons is realized in China, the market demand can be completely met, and the cost for producing the alcohol-based fuel in a large scale is far lower than that of other fuels such as liquefied petroleum gas, natural gas and artificial gas. Therefore, the large-scale popularization and use of the alcohol-based fuel conforms to the national conditions of 'rich coal, lack of oil and little gas' in China, has very good market prospect and has important strategic significance for guaranteeing the energy safety in China.
Although two standards of GB 16663-. The quality levels of the existing burners used by the alcohol-based fuel are not uniform, and the problem that the normal use cannot be caused due to the serious corrosion of metal parts exists after the burners are used for a long time; in addition, the poor lubricating performance of the alcohol-based fuel easily causes abnormal wear of the fuel delivery pump. Meanwhile, because the alcohol-based fuel is colorless and has the fragrance of wine, the flame is colorless during combustion, so that the risk of mistaken drinking and eating is also caused, and the problem that the flame color is not easy to find during ignition is solved.
Disclosure of Invention
The invention aims to provide a high-cleanness alcohol-based liquid fuel which has the advantages of small corrosivity to metal parts, good lubricity, large viscosity, high heat value, self color, colored combustion flame, no residual liquid, no smoke dust, no carbon deposition, no harmful gas such as sulfur dioxide and the like in the combustion process and meets the requirement of environmental protection.
In order to realize the purpose, the high-cleanness alcohol-based liquid fuel adopts the technical scheme that: the high-cleanness alcohol-based liquid fuel is prepared from the following raw materials in parts by volume: 60-100 parts of methanol, 10-20 parts of ethanol gasoline and 5-12 parts of additive;
the additive is prepared from the following raw materials in parts by volume:
5-15 parts of isooctyl polymethacrylate;
6-20 parts of 2, 4-dimethyl-6-tert-butylphenol;
2-6 parts of N, N' -bis (salicylidene) -1, 2-propane diamine;
8-20 parts of dodecyl methacrylate;
5-15 parts of diethylene glycol monomethyl ether;
15-35 parts of methyl palmitoleate;
5-12 parts of diethylaminoethyl methacrylate;
5-12 parts of zinc dibutyl dithiocarbamate;
5-10 parts of 2-n-octyl-4-isothiazoline-3-ketone;
10-20 parts of dioctyl phthalate;
8-16 parts of N-phenyl-N' -sec-butylbenzene diamine;
2-6 parts of isopropyl benzoate.
Preferably, the high-cleanness alcohol-based liquid fuel is prepared from the following raw materials in parts by volume: 80 parts of methanol, 15 parts of ethanol gasoline and 8 parts of additive;
the additive is prepared from the following raw materials in parts by volume:
10 parts of isooctyl polymethacrylate;
15 parts of 2, 4-dimethyl-6-tert-butylphenol;
4 parts of N, N' -bis (salicylidene) -1, 2-propane diamine;
14 parts of dodecyl methacrylate;
10 parts of diethylene glycol monomethyl ether;
28 parts of methyl palmitoleate;
8 parts of diethylaminoethyl methacrylate;
7 parts of zinc dibutyl dithiocarbamate;
7 parts of 2-n-octyl-4-isothiazoline-3-ketone;
16 parts of dioctyl phthalate;
12 parts of N-phenyl-N' -sec-butylbenzene diamine;
4 parts of isopropyl benzoate.
The preparation method of the additive comprises the following steps: mixing the isooctyl polymethacrylate, the methyl palmitoleate, the dodecyl methacrylate, the dioctyl phthalate and the isopropyl benzoate with the zinc dibutyl dithiocarbamate at normal temperature and normal pressure in parts by volume, heating to 75 ℃ for ultrasonic treatment to form viscous liquid, cooling to room temperature, adding the 2, 4-dimethyl-6-tert-butyl phenol, the N, N '-disalicylidene-1, 2-propylene diamine, diethylene glycol monomethyl ether, diethylaminoethyl methacrylate, 2-N-octyl-4-isothiazoline-3-ketone and the N-phenyl-N' -sec-butyl phenylenediamine in parts by weight, stirring for 30 minutes, and uniformly blending to obtain the finished product.
The isooctyl polymethacrylate, the methyl palmitate, the dodecyl methacrylate, the dioctyl phthalate, the isopropyl benzoate and the zinc dibutyl dithiocarbamate in the additive can form a reticular molecular group which takes the isooctyl polymethacrylate as a main body and is similar to a rubber structure, a large number of polar bonds are arranged on the molecular group, and a larger molecular group can be formed with methanol molecules through intermolecular force, so that the viscosity and the lubricity of the methanol fuel are changed. The diethylaminoethyl methacrylate has good dispersibility, and the addition of a proper amount of diethylaminoethyl methacrylate can prevent excessive polymerization of additive molecular groups to form functional molecular groups with relatively proper molecular mass.
The 2, 4-dimethyl-6-tert-butyl phenol has strong oxidation resistance, and can prevent the metal parts from being corroded by the enhancement of the oxidation of methanol into formic acid. The N-phenyl-N '-sec-butylbenzene diamine and the N, N, N' -bis salicylidene-1, 2-propane diamine can form a metal complexing agent with complementary functions, are adsorbed on the surface of metal to form a protective layer, prevent the corrosion of fuel to the metal, and act with 2, 4-dimethyl-6-tert-butyl phenol synergistically to enhance the corrosion resistance of the alcohol-based liquid fuel.
Meanwhile, the formed metal complexing agent can also enable the original colorless alcohol-based liquid fuel to show reddish brown color, and plays a role in warning color. When the alcohol-based liquid fuel is combusted, the combustion flame presents bright blue-green color due to the zinc contained in the additive component.
The invention has the beneficial effects that: the alcohol-based liquid fuel has the advantages of small corrosivity to metal parts, good lubricity, large viscosity, high heat value, reddish brown color, bluish green combustion fire, no residual liquid, no smoke dust, no carbon deposition, no harmful gas such as sulfur dioxide and the like in the combustion process, and meets the requirement of environmental protection.
Detailed Description
The present invention will be further described with reference to the following specific examples.
Example 1
The high-cleanness vehicle alcohol-based liquid fuel is prepared from the following raw materials in parts by volume: 80 parts of methanol, 15 parts of ethanol gasoline and 8 parts of additive.
The additive is prepared from the following raw materials in parts by volume:
10 parts of isooctyl polymethacrylate;
15 parts of 2, 4-dimethyl-6-tert-butylphenol;
4 parts of N, N' -bis (salicylidene) -1, 2-propane diamine;
14 parts of dodecyl methacrylate;
10 parts of diethylene glycol monomethyl ether;
28 parts of methyl palmitoleate;
8 parts of diethylaminoethyl methacrylate;
7 parts of zinc dibutyl dithiocarbamate;
7 parts of 2-n-octyl-4-isothiazoline-3-ketone;
16 parts of dioctyl phthalate;
12 parts of N-phenyl-N' -sec-butylbenzene diamine;
4 parts of isopropyl benzoate.
The preparation method of the additive comprises the following steps: mixing the isooctyl polymethacrylate, the methyl palmitoleate, the dodecyl methacrylate, the dioctyl phthalate and the isopropyl benzoate with the zinc dibutyl dithiocarbamate at normal temperature and normal pressure in parts by volume, heating to 75 ℃ for ultrasonic treatment to form viscous liquid, cooling to room temperature, adding the 2, 4-dimethyl-6-tert-butyl phenol, the N, N '-disalicylidene-1, 2-propylene diamine, diethylene glycol monomethyl ether, diethylaminoethyl methacrylate, 2-N-octyl-4-isothiazoline-3-ketone and the N-phenyl-N' -sec-butyl phenylenediamine in parts by weight, stirring for 30 minutes, and uniformly blending to obtain the finished product.
The high-cleanness car alcohol-based liquid fuel of the embodiment is tested for corrosivity and other basic performances, and the test results of the high-cleanness car alcohol-based liquid fuel of the embodiment on corrosion of various metal sheets are shown in table 1.
The corrosion test refers to SAEJ 1747 recommended method for testing corrosion of gasoline/methanol mixed fuel, and adopts soaking of various metal sheets as a screening evaluation method to investigate the corrosion performance of the alcohol-based liquid fuel. The selection range of the metal sheet is metal which may exist in a boiler oil supply system and a fuel combustion system, the metal sheet is soaked in the high-cleanness vehicle alcohol-based liquid fuel of the embodiment for 168 hours at the temperature of 50 ℃, the corrosion degree of the metal sheet is observed, and the corrosion weight loss is calculated.
Table 1 corrosion test effect of highly clean car alcohol-based liquid fuel of example 1 on various metal pieces
The basic performance test methods and test results are shown in table 2.
Table 2 comparison of basic properties of high cleanliness car alcohol-based liquid fuel of example 1
From the above test results, it can be seen that the highly clean car alcohol-based liquid fuel of example 1 has no significant corrosion to seven metals. In the aspect of cost saving performance, the viscosity is increased by 8.1 times compared with the common methanol fuel, and the heat value is increased by 42.8 percent.
Example 2
The high-cleanness vehicle alcohol-based liquid fuel is prepared from the following raw materials in parts by volume: 60 parts of methanol, 20 parts of ethanol gasoline and 12 parts of additive.
The additive is prepared from the following raw materials in parts by volume:
5 parts of isooctyl polymethacrylate;
20 parts of 2, 4-dimethyl-6-tert-butylphenol;
2 parts of N, N' -bis (salicylidene) -1, 2-propane diamine;
20 parts of dodecyl methacrylate;
5 parts of diethylene glycol monomethyl ether;
35 parts of methyl palmitoleate;
5 parts of diethylaminoethyl methacrylate;
12 parts of zinc dibutyl dithiocarbamate;
5 parts of 2-n-octyl-4-isothiazoline-3-ketone;
20 parts of dioctyl phthalate;
8 parts of N-phenyl-N' -sec-butylbenzene diamine;
6 parts of isopropyl benzoate.
The preparation of the additive was the same as in example 1.
The high cleanliness automotive alcohol-based liquid fuel of example 2 was tested for corrosivity and other basic properties according to the method of example 1, and the results are shown in tables 2 and 4.
TABLE 3 Corrosion test Effect of the highly clean car alcohol-based liquid fuel of example 2 on various metal pieces
Table 4 comparison of basic properties of high cleanliness car alcohol-based liquid fuel of example 2
Example 3
The high-cleanness vehicle alcohol-based liquid fuel is prepared from the following raw materials in parts by volume: 100 parts of methanol, 10 parts of ethanol gasoline and 5 parts of additive.
The additive is prepared from the following raw materials in parts by volume:
15 parts of isooctyl polymethacrylate;
6 parts of 2, 4-dimethyl-6-tert-butylphenol;
6 parts of N, N' -bis (salicylidene) -1, 2-propane diamine;
8 parts of dodecyl methacrylate;
15 parts of diethylene glycol monomethyl ether;
15 parts of methyl palmitoleate;
12 parts of diethylaminoethyl methacrylate;
5 parts of zinc dibutyl dithiocarbamate;
10 parts of 2-n-octyl-4-isothiazoline-3-ketone;
10 parts of dioctyl phthalate;
16 parts of N-phenyl-N' -sec-butylbenzene diamine;
2 parts of isopropyl benzoate.
The preparation of the additive was the same as in example 1.
TABLE 5 Corrosion test Effect of the highly clean car alcohol-based liquid fuel of example 3 on various metal pieces
Table 6 comparison of basic properties of high cleanliness car alcohol-based liquid fuel of example 3
The above description of the embodiments is only intended to facilitate the understanding of the method of the invention and its core idea. It should be noted that, for those skilled in the art, it is possible to make various improvements and modifications to the present invention without departing from the principle of the present invention, and those improvements and modifications also fall within the scope of the claims of the present invention.
Claims (3)
1. The high-cleanness alcohol-based liquid fuel is characterized by being prepared from the following raw materials in parts by volume: 60-100 parts of methanol, 10-20 parts of ethanol gasoline and 5-12 parts of additive;
the additive is prepared from the following raw materials in parts by volume:
5-15 parts of isooctyl polymethacrylate;
6-20 parts of 2, 4-dimethyl-6-tert-butylphenol;
2-6 parts of N, N' -bis (salicylidene) -1, 2-propane diamine;
8-20 parts of dodecyl methacrylate;
5-15 parts of diethylene glycol monomethyl ether;
15-35 parts of methyl palmitoleate;
5-12 parts of diethylaminoethyl methacrylate;
5-12 parts of zinc dibutyl dithiocarbamate;
5-10 parts of 2-n-octyl-4-isothiazoline-3-ketone;
10-20 parts of dioctyl phthalate;
8-16 parts of N-phenyl-N' -sec-butylbenzene diamine;
2-6 parts of isopropyl benzoate.
2. The high-cleanness alcohol-based liquid fuel as claimed in claim 1, which is prepared from the following raw materials in parts by volume: 80 parts of methanol, 15 parts of ethanol gasoline and 8 parts of additive;
the additive is prepared from the following raw materials in parts by volume:
10 parts of isooctyl polymethacrylate;
15 parts of 2, 4-dimethyl-6-tert-butylphenol;
4 parts of N, N' -bis (salicylidene) -1, 2-propane diamine;
14 parts of dodecyl methacrylate;
10 parts of diethylene glycol monomethyl ether;
28 parts of methyl palmitoleate;
8 parts of diethylaminoethyl methacrylate;
7 parts of zinc dibutyl dithiocarbamate;
7 parts of 2-n-octyl-4-isothiazoline-3-ketone;
16 parts of dioctyl phthalate;
12 parts of N-phenyl-N' -sec-butylbenzene diamine;
4 parts of isopropyl benzoate.
3. The high-cleanness alcohol-based liquid fuel as claimed in claim 1 or 2, wherein the additive is prepared by a method comprising: mixing the isooctyl polymethacrylate, the methyl palmitoleate, the dodecyl methacrylate, the dioctyl phthalate and the isopropyl benzoate with the zinc dibutyl dithiocarbamate at normal temperature and normal pressure in parts by volume, heating to 75 ℃ for ultrasonic treatment to form viscous liquid, cooling to room temperature, adding the 2, 4-dimethyl-6-tert-butyl phenol, the N, N '-disalicylidene-1, 2-propylene diamine, diethylene glycol monomethyl ether, diethylaminoethyl methacrylate, 2-N-octyl-4-isothiazoline-3-ketone and the N-phenyl-N' -sec-butyl phenylenediamine in parts by weight, stirring for 30 minutes, and uniformly blending to obtain the finished product.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112159689A (en) * | 2020-09-09 | 2021-01-01 | 重庆耐燃新能源科技有限公司 | Synthetic environment-friendly clean liquid fuel and preparation method thereof |
| CN112175681A (en) * | 2020-09-15 | 2021-01-05 | 深圳市诚进能源有限公司 | Novel energy-saving liquid fuel |
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| CN1824738A (en) * | 2006-04-05 | 2006-08-30 | 黑龙江建业燃料有限责任公司 | Preparation method of high efficiency alcohol base gasoline fuel additive |
| CN106957701A (en) * | 2017-04-05 | 2017-07-18 | 太原师范学院 | Alcohol radical liquid fuel additive |
| CN110003959A (en) * | 2019-04-18 | 2019-07-12 | 刘安平 | A kind of typed high-energy liquid fuel in alcohol group and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1824738A (en) * | 2006-04-05 | 2006-08-30 | 黑龙江建业燃料有限责任公司 | Preparation method of high efficiency alcohol base gasoline fuel additive |
| CN106957701A (en) * | 2017-04-05 | 2017-07-18 | 太原师范学院 | Alcohol radical liquid fuel additive |
| CN110003959A (en) * | 2019-04-18 | 2019-07-12 | 刘安平 | A kind of typed high-energy liquid fuel in alcohol group and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112159689A (en) * | 2020-09-09 | 2021-01-01 | 重庆耐燃新能源科技有限公司 | Synthetic environment-friendly clean liquid fuel and preparation method thereof |
| CN112175681A (en) * | 2020-09-15 | 2021-01-05 | 深圳市诚进能源有限公司 | Novel energy-saving liquid fuel |
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Application publication date: 20200327 |