CN102161922B - Methanol diesel oil additive and methanol diesel oil - Google Patents
Methanol diesel oil additive and methanol diesel oil Download PDFInfo
- Publication number
- CN102161922B CN102161922B CN 201110063418 CN201110063418A CN102161922B CN 102161922 B CN102161922 B CN 102161922B CN 201110063418 CN201110063418 CN 201110063418 CN 201110063418 A CN201110063418 A CN 201110063418A CN 102161922 B CN102161922 B CN 102161922B
- Authority
- CN
- China
- Prior art keywords
- parts
- diesel oil
- methanol diesel
- oil
- methanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention discloses a methanol diesel oil additive and simultaneously discloses methanol diesel oil with the methanol diesel oil additive. The methanol diesel oil prepared by the invention is prepared by mixing 0.04-0.07 part of ferrocene, 2-5 parts of acetone, 4 parts of diemethyl carbonate, 2-3 parts of isobutanol, 2-3 parts of toluene, 70 parts of diesel oil and 20-25 parts of methanol. The methanol diesel oil has the advantages of low corrosion, good intersolubility and swelling property, uniform texture, high flash point, low condensation point and high cetane number, is safe to use and meets all indexes of automobile diesel oil GB19147-2009. The methanol diesel oil can be applied to internal-combustion engines, general engines, power plant fuels, burner substances and the like, thus the applicable range of the methanol diesel oil is wide.
Description
Technical field
The present invention relates to the vehicle fuel technical field, be specifically related to a kind of methanol diesel fuel additive, also relate to the methanol diesel-oil that is added with this methanol diesel fuel additive simultaneously.
Background technology
Vehicle fuel is all taken from oil at present, China is the country of " rich coal, oil-poor, weak breath ", since China in 1993 becomes oil importers for the first time, China's crude oil external interdependency is by then 6% rising all the way, broken through 45% by 2006, every year with about 2 percentage point speed one road direction on soaring by 2009 year reach 52%, break through 50% barrier line thereafter.The energy demand in domestic future is still very big, and the impetus is powerful, the continuous minimizing of petroleum resources and depend on import serious threat unduly to national security and the sustainable development of China.The consumption of diesel oil is three times of gasoline in the consumption of petroleum resources, and particularly nationwide existing " diesel oil famine " frequently in recent years causes diesel oil nervous with oil, had a strong impact on the Economic development of China.
Under present severe situation, methanol diesel-oil because it can effectively reduce the oil usage quantity, reduces environmental pollution, reduce fuel price, therefore has been subjected to common concern as a kind of alternate resources of vehicle fuel.But the research to methanol diesel-oil over surplus in the of ten year does not obtain big breakthrough, there is the corrodibility height in varying degrees in the present methanol diesel-oil that uses, shortcomings such as mutual solubility is poor, flash-point is low, swelling property is not good, dynamic property difference, has seriously limited the use range of methanol diesel-oil.
Summary of the invention
The purpose of this invention is to provide a kind of methanol diesel fuel additive.
The present invention also aims to provide a kind of methanol diesel-oil that adds methanol diesel fuel additive of the present invention.
In order to realize above purpose, the technical solution adopted in the present invention is: a kind of methanol diesel fuel additive, formed by the component of following parts by weight: ferrocene 0.04-0.07 part, acetone 2-5 part, 4 parts of methylcarbonates, isopropylcarbinol 2-3 part, toluene 2-3 part.
Further, a kind of methanol diesel fuel additive is made up of the component of following parts by weight: 0.06 part of ferrocene, 4 parts in acetone, 4 parts of methylcarbonates, 2 parts of isopropylcarbinols, 3 parts of toluene.
A kind of methanol diesel-oil is made up of the component of following parts by weight: ferrocene 0.04-0.07 part, acetone 2-5 part, 4 parts of methylcarbonates, isopropylcarbinol 2-3 part, toluene 2-3 part, 70 parts of diesel oil, methyl alcohol 20-25 part.
Further, a kind of methanol diesel-oil is made up of the component of following parts by weight: 0.06 part of ferrocene, 4 parts in acetone, 4 parts of methylcarbonates, 2 parts of isopropylcarbinols, 3 parts of toluene, 70 parts of diesel oil, 25 parts of methyl alcohol.
In methanol diesel-oil of the present invention, ferrocene can improve the dynamic property of methanol diesel-oil, plays effect combustion-supporting and minimizing nozzle carbon distribution; Acetone, toluene and isopropylcarbinol can improve mutual solubility and the swelling property between methyl alcohol and the diesel oil, and can improve the calorific value of methanol diesel-oil, improve the condensation point of methanol diesel-oil, wherein the adding of isopropylcarbinol can also reduce the content of sulphur in the combustion tail gas, reduces emission of harmful substances; Add that methylcarbonate can greatly reduce or basically eliminate is used the combustion fumes of the diesel engine of methanol diesel-oil of the present invention, can obviously reduce methanol diesel-oil burning pollution on the environment, can also improve simultaneously the efficiency of heat engine of diesel engine, compare with ordinary diesel oil, methanol diesel-oil burning of the present invention reduces about 20% to the pollution of environment, it is about 10% to improve the diesel engine efficiency of heat engine simultaneously, and fuel consumption per hundred kilometers can not raise nontoxic, the environmental protection of the tail gas after the burning.
Methanol diesel-oil of the present invention is compared with diesel oil such as commercially available No. 0 ,-No. 10 and is had the following advantages: the calorific value height; Environmental protection characteristic is good, and sulphur content is low in the combustion tail gas, and sulphur emissions reduces about 30%; Because the oxygen level height, sufficient combustion, so oil consumption significantly reduces, and improved equipment dynamic, and smoke evacuation is few, CO2 emissions reduces greatly; Startability is good, and low-temperature fluidity is good, starts easily under the engine low temperature; Protective value is strong, and the kinematic viscosity height under the situation that does not influence fuel spray, has improved the oilness of moving parts, has reduced the wear rate of oil injection pump, engine cylinder-body and union lever, and then has prolonged parts work-ing life; Ignition characteristic is good, and cetane value is greater than 45; Use properties is wide, need not to transform engine, can directly use separately, also can with the use of infinitely dissolving each other arbitrarily of commercially available diesel oil, need not increase other fuel oil storage facilitiess separately; Safe and reliable, flash-point is suitable with commercially available diesel oil, and no self-firing and self-explosion danger manifests, transportation, storage safe; Mutual solubility is good, and outward appearance is as clear as crystal.
The corrodibility of methanol diesel-oil of the present invention is low, mutual solubility and swelling property are good, the quality homogeneous, flash-point height, use safety, condensation point is low, the cetane value height, the every index that meets derv fuel oil GB19147-2009, oil engine, general engine, power plant's fuel oil, burning implements etc. all can use, and are applied widely.
Embodiment
Embodiment 1
Methanol diesel fuel additive is made up of the component of following parts by weight: 0.04 part of ferrocene, 2 parts in acetone, 4 parts of methylcarbonates, 3 parts of isopropylcarbinols, 2 parts of toluene.
Be added with the methanol diesel-oil of above-mentioned methanol diesel fuel additive, component by following parts by weight is formed: 0.04 part of ferrocene, 2 parts in acetone, 4 parts of methylcarbonates, 3 parts of isopropylcarbinols, 2 parts of toluene, 70 parts of diesel oil, 20 parts of methyl alcohol, its preparation method is: the parts by weight by each component take by weighing each component respectively, mix afterwards to stir namely to make.
Embodiment 2
Methanol diesel fuel additive is made up of the component of following parts by weight: 0.06 part of ferrocene, 4 parts in acetone, 4 parts of methylcarbonates, 2 parts of isopropylcarbinols, 3 parts of toluene.
Be added with the methanol diesel-oil of above-mentioned methanol diesel fuel additive, component by following parts by weight is formed: 0.06 part of ferrocene, 4 parts in acetone, 4 parts of methylcarbonates, 2 parts of isopropylcarbinols, 3 parts of toluene, 70 parts of diesel oil, 25 parts of methyl alcohol, its preparation method is: the parts by weight by each component take by weighing each component respectively, mix afterwards to stir namely to make.
Embodiment 3
Methanol diesel fuel additive is made up of the component of following parts by weight: 0.07 part of ferrocene, 5 parts in acetone, 4 parts of methylcarbonates, 2 parts of isopropylcarbinols, 2 parts of toluene.
Be added with the methanol diesel-oil of above-mentioned methanol diesel fuel additive, component by following parts by weight is formed: 0.07 part of ferrocene, 5 parts in acetone, 4 parts of methylcarbonates, 2 parts of isopropylcarbinols, 2 parts of toluene, 70 parts of diesel oil, 23 parts of methyl alcohol, its preparation method is: the parts by weight by each component take by weighing each component respectively, mix afterwards to stir namely to make.
The test result of the methanol diesel-oil of embodiment 1, embodiment 2, embodiment 3 is shown in Table 1.
The measurement result of each embodiment methanol diesel-oil of table 1
(connecing following table)
(connecting table)
Diesel soot is the big problem of diesel machine, is the major ingredient of grey haze, and is particularly evident to urban air-quality influence, is the important factor in order of Global climate change, accounts for 1/4, is 2000 times of carbonic acid gas to the degree of influence of climate change.Methanol diesel-oil provided by the invention can greatly reduce or basically eliminate diesel combustion flue dust, can reduce diesel combustion to the pollution of environment about 20%, improve diesel engine efficiency of heat engine about 10% simultaneously, fuel consumption per hundred kilometers does not raise, oil depot, fuel tank, engine there is not particular requirement, nontoxic, environmental protection, biodegradable, methanol diesel-oil provided by the invention can partly substitute diesel oil, and its market potential is worth nearly 2,000 hundred million yuan/year.Adopt diesel engine CO quantity discharged under idling operation of methanol diesel-oil provided by the invention can drop to 11%, HC and can descend 10.6%, at the uniform velocity under the operating mode, the CO quantity discharged can drop to 13%, HC can descend 36.8%.
Adopt the methanol diesel-oil of the embodiment of the invention 1 to carry out real train test, all start well at 0 ℃ ,-10 ℃ following vehicles.Diesel oil such as alternative commercially available No. 0 ,-No. 10 of methanol diesel-oil of the present invention use.
Claims (4)
1. methanol diesel fuel additive, it is characterized in that: the component by following parts by weight is formed: ferrocene 0.04-0.07 part, acetone 2-5 part, 4 parts of methylcarbonates, isopropylcarbinol 2-3 part, toluene 2-3 part.
2. methanol diesel fuel additive according to claim 1, it is characterized in that: the component by following parts by weight is formed: 0.06 part of ferrocene, 4 parts in acetone, 4 parts of methylcarbonates, 2 parts of isopropylcarbinols, 3 parts of toluene.
3. methanol diesel-oil that is added with the described methanol diesel fuel additive of claim 1, it is characterized in that: the component by following parts by weight is formed: ferrocene 0.04-0.07 part, acetone 2-5 part, 4 parts of methylcarbonates, isopropylcarbinol 2-3 part, toluene 2-3 part, 70 parts of diesel oil, methyl alcohol 20-25 part.
4. methanol diesel-oil according to claim 3, it is characterized in that: the component by following parts by weight is formed: 0.06 part of ferrocene, 4 parts in acetone, 4 parts of methylcarbonates, 2 parts of isopropylcarbinols, 3 parts of toluene, 70 parts of diesel oil, 25 parts of methyl alcohol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110063418 CN102161922B (en) | 2011-03-16 | 2011-03-16 | Methanol diesel oil additive and methanol diesel oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110063418 CN102161922B (en) | 2011-03-16 | 2011-03-16 | Methanol diesel oil additive and methanol diesel oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102161922A CN102161922A (en) | 2011-08-24 |
| CN102161922B true CN102161922B (en) | 2013-09-11 |
Family
ID=44463377
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110063418 Expired - Fee Related CN102161922B (en) | 2011-03-16 | 2011-03-16 | Methanol diesel oil additive and methanol diesel oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102161922B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103805297B (en) * | 2012-11-15 | 2017-12-15 | 亚申科技研发中心（上海）有限公司 | Smokeless diesel oil and preparation method thereof |
| CN103205287B (en) * | 2013-03-25 | 2014-11-26 | 刘寿全 | Environment-friendly methanol diesel mixed fuel and preparation method thereof |
| CN103642542A (en) * | 2013-12-25 | 2014-03-19 | 济南开发区星火科学技术研究院 | Methanol diesel oil |
| CN104498110B (en) * | 2014-12-23 | 2017-04-12 | 崔天豪 | Methanol diesel |
| CN107653009A (en) * | 2017-11-21 | 2018-02-02 | 湖北恒泰新能源开发有限公司 | A kind of high-efficiency cleaning alcohol fuel oil and preparation method thereof and device |
| CN114891543B (en) * | 2022-05-17 | 2024-03-22 | 兰州国信环境能源科技有限责任公司 | Method for synthesizing methanol diesel oil |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280231A (en) * | 2008-06-03 | 2008-10-08 | 柏绿山 | Biofuel oil and preparation thereof |
-
2011
- 2011-03-16 CN CN 201110063418 patent/CN102161922B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280231A (en) * | 2008-06-03 | 2008-10-08 | 柏绿山 | Biofuel oil and preparation thereof |
Non-Patent Citations (4)
| Title |
|---|
| "甲醇与柴油互溶性研究";杨蔚权等;《重庆科技学院学报( 自然科学版)》;20060930;第8卷(第3期);第18-20页 * |
| "碳酸二甲酯生产与应用中的清洁性";向兴源等;《天然气化工》;19991231;第24卷(第3期);第35-39页 * |
| 向兴源等."碳酸二甲酯生产与应用中的清洁性".《天然气化工》.1999,第24卷(第3期),第35-39页. |
| 杨蔚权等."甲醇与柴油互溶性研究".《重庆科技学院学报( 自然科学版)》.2006,第8卷(第3期),第18-20页. |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102161922A (en) | 2011-08-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Elvers et al. | Handbook of fuels | |
| Tuner | Review and benchmarking of alternative fuels in conventional and advanced engine concepts with emphasis on efficiency, co 2, and regulated emissions | |
| CN102161922B (en) | Methanol diesel oil additive and methanol diesel oil | |
| Abdel‐Rahman | On the emissions from internal‐combustion engines: a review | |
| CN103275769B (en) | High-cleanness environment-friendly alcohol ether fuel for car | |
| Kitano et al. | Effects of GTL fuel properties on DI diesel combustion | |
| CN103642547B (en) | A kind of compound diesel additive and preparation method thereof | |
| Nagdeote et al. | Experimental study of diethyl ether and ethanol additives with biodiesel-diesel blended fuel engine | |
| Sathiyagnanam et al. | Hexanol-ethanol diesel blends on DI-diesel engine to study the combustion and emission | |
| Zhou et al. | The application prospect and challenge of the alternative methanol fuel in the internal combustion engine | |
| CN101531933A (en) | Fuel for homogeneous charge compression ignition engine | |
| Tunér | Combustion of alternative vehicle fuels in internal combustion engines | |
| Najafi et al. | Experimental investigation of using methanol-diesel blended fuels in diesel engine | |
| CN101338228A (en) | Vehicle-mounted hydrogen, alcohol, ether and diesel composite fuel made for methanol and engine thereof | |
| Caban et al. | Alternative fuels for diesel engines | |
| Mehra et al. | Prospects and challenges of DME fueled low-temperature combustion engine technology | |
| CN101245266A (en) | Environment protection cleaning type gasoline and manufacture method thereof | |
| Labeckas et al. | Performance and emission characteristics of diesel engine fuelled with ethanol-diesel-biodiesel blend | |
| CN101709234A (en) | Methanol diesel fuel complex additive and preparation method thereof | |
| Kannan | Effect of injection pressures and timings on the performance emission and combustion characteristics of a direct injection diesel engine using biodiesel-diesel-ethanol blend | |
| Banapurmath et al. | Performance, Emission Characteristics of Dual Fuel (DF) & Homogeneous Charge Compression Ignition (HCCI) Engines Operated on Compressed Natural Gas (CNG)–Uppage Oil Methylester (UOME) | |
| Bhardwaj et al. | A comparative study of Performance and Emission Characteristics of a CRDe SUV fueled with Biodiesel blends & Diesel fuel | |
| Shi et al. | A renewable clean energy application: Oxyhydrogen negative pressure inhalation for enhancing the combustion and emission characteristics of isopropanol/gasoline dual-fuel combined injection engine | |
| Roy | Improving cold flow properties of biodiesel, and hydrogen-biodiesel dual-fuel engine aiming near-zero emissions | |
| CN106190373A (en) | Diesel fuel additive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 463100 north section of Qianjin Road, Henan, Zhumadian Applicant after: Lantian Chemical Co., Ltd. of China Pingmei Shenma Group Address before: 463100 north section of Qianjin Road, Henan, Zhumadian Applicant before: Pingmei & Lantian Chemicals Co., Ltd. |
|
| CB03 | Change of inventor or designer information |
Inventor after: Zhou Wensheng Inventor after: Wang Shaofeng Inventor after: Wang Jiande Inventor after: Zhi Hualin Inventor after: Li Pangen Inventor after: Li Guangqi Inventor after: Zhang Bo Inventor before: Qiao Sihuai Inventor before: Zhou Wensheng Inventor before: Wang Jiande Inventor before: Li Pangen Inventor before: Liu Gencheng Inventor before: Deng Cunyu Inventor before: Zhu Hongyin |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: PINGMEI + LANTIAN CHEMICALS CO., LTD. TO: LANTIAN CHEMICAL CO., LTD. OF CHINA PINGMEI SHENMA GROUP Free format text: CORRECT: INVENTOR; FROM: QIAO SIHUAI ZHOU WENSHENG WANG JIANDE LI PANGEN LIU GENCHENG DENG CUNYU ZHU HONGYIN TO: ZHOU WENSHENG WANG SHAOFENG WANG JIANDE ZHI HUALIN LI PANGEN LI GUANGQI ZHANG BO |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130911 Termination date: 20160316 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |