CN108219869B - Low-carbon high-cleanness diesel vehicle fuel and preparation method thereof - Google Patents
Low-carbon high-cleanness diesel vehicle fuel and preparation method thereof Download PDFInfo
- Publication number
- CN108219869B CN108219869B CN201611195236.0A CN201611195236A CN108219869B CN 108219869 B CN108219869 B CN 108219869B CN 201611195236 A CN201611195236 A CN 201611195236A CN 108219869 B CN108219869 B CN 108219869B
- Authority
- CN
- China
- Prior art keywords
- parts
- oil
- fuel
- diesel oil
- low
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1857—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The invention discloses a low-carbon high-cleanness diesel vehicle fuel and a preparation method thereof, wherein the fuel is composed of the following raw materials in parts by weight: 10-20 parts of methanol, 33-41 parts of diesel oil, 5-12 parts of sodium formaldehyde sulfoxylate, 11-19 parts of itaconic acid, 3-7 parts of cerium acetylacetonate and 1-3 parts of nano zinc oxide. The fuel prepared by pretreating diesel oil by using itaconic acid and nano zinc oxide and mixing the pretreated diesel oil with other raw materials has excellent anticoagulation property, has a copper sheet corrosion index of 1, and does not generate corrosion phenomena higher than that of diesel oil for vehicles on an oil tank, an oil delivery pipe, an oil pump, an oil nozzle and an engine combustion chamber in use. The oil product contains sufficient oxygen, so that the fuel can be sufficiently combusted, the generation of carbon deposition can be effectively reduced, the smoke value is 0.3, the purification rate is 75%, and the environment-friendly performance is better. The basic raw materials of the invention have diversified sources, simple production process, simple and convenient operation, low production cost and obvious economic and social benefits.
Description
Technical Field
The invention relates to the technical field of fuels, in particular to a low-carbon high-cleanness diesel vehicle fuel and a preparation method thereof.
Background
With the rapid development of national economy, the fuel consumption rises sharply, and the global oil resource storage is very limited. Diesel oil is used as a main fuel of a high-power internal combustion engine, and the development of industry, agriculture and fishery is greatly influenced. Compared with gasoline, the diesel engine has the advantages of high thermal efficiency, good fuel economy, higher explosion pressure, larger output torque, low CO and HC emission and the like. However, the content of particulate matters, nitrogen oxides and hydrocarbons in the exhaust gas discharged by the diesel engine is very high, and the particle size of the particles is small and the mass concentration of the particles is about 30-80 times that of the gasoline engine. The environment is polluted, and the human health is seriously damaged. Alcohol fuels are recognized by the world as clean, renewable alternative fuels, where methanol is in close proximity to gasoline and diesel. However, some technical problems need to be overcome, such as low methanol heat value, certain corrosivity, low flash point of the diesel oil for the vehicle, abrasion to an engine cylinder body and carbon deposition, difficult low-temperature starting of the diesel oil for the vehicle, poor stability and the like.
Disclosure of Invention
The invention aims to provide a low-carbon high-cleanness diesel vehicle fuel and a preparation method thereof, so as to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme:
the low-carbon high-cleanness diesel vehicle fuel consists of the following raw materials in parts by weight: 10-20 parts of methanol, 33-41 parts of diesel oil, 5-12 parts of sodium formaldehyde sulfoxylate, 11-19 parts of itaconic acid, 3-7 parts of cerium acetylacetonate and 1-3 parts of nano zinc oxide.
As a further scheme of the invention: the low-carbon high-cleanness diesel vehicle fuel is composed of the following raw materials in parts by weight: 12-18 parts of methanol, 35-39 parts of diesel oil, 7-10 parts of sodium formaldehyde sulfoxylate, 13-17 parts of itaconic acid, 4-6 parts of cerium acetylacetonate and 1.5-2.5 parts of nano zinc oxide.
As a further scheme of the invention: the low-carbon high-cleanness diesel vehicle fuel is composed of the following raw materials in parts by weight: 15 parts of methanol, 37 parts of diesel oil, 8 parts of sodium formaldehyde sulfoxylate, 15 parts of itaconic acid, 5 parts of cerium acetylacetonate and 2 parts of nano zinc oxide.
A preparation method of low-carbon high-cleanness diesel vehicle fuel comprises the following steps:
1) mixing diesel oil, itaconic acid and nano zinc oxide, and hermetically stirring at 73 ℃ for 35-40min to obtain a mixture A;
2) mixing methanol, sodium formaldehyde sulfoxylate and cerium acetylacetonate, and stirring at the temperature of 62 ℃ for 1.2 hours to prepare a mixture B;
3) mixing the mixture A and the mixture B, heating to 65 ℃, stirring for 10min, and then carrying out ultrasonic treatment at the temperature for 42min with the ultrasonic power of 1000W to obtain the fuel.
Compared with the prior art, the invention has the beneficial effects that:
the fuel prepared by pretreating the diesel oil by using the itaconic acid and the nano zinc oxide and mixing the pretreated diesel oil with other raw materials has excellent anticoagulation property, and the oil product has the anticoagulation effect of No. 20 and can achieve the anticoagulation effect of No. 45 aiming at the oil product used in winter. The corrosion index of the copper sheet is 1, which is quasi-identical to GB 19147-2009. Years of use and experiments prove that the fuel does not corrode an oil tank, an oil delivery pipe, an oil pump, an oil nozzle and an engine combustion chamber higher than that of diesel oil for vehicles in use. The oil product contains sufficient oxygen (the oxygen content is 12.1 percent (m/m)), so that the fuel is sufficiently combusted, the generation of carbon deposition can also be effectively reduced, and the smoke value of the detection result of the free acceleration smoke emission is as follows: 0.3, the purification rate is 75 percent, and the environment-friendly performance is better. The basic raw materials of the invention have diversified sources, simple production process, simple and convenient operation, low production cost and obvious economic and social benefits.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
In the embodiment of the invention, the low-carbon high-cleanness diesel vehicle fuel is composed of the following raw materials in parts by weight: 10 parts of methanol, 33 parts of diesel oil, 5 parts of sodium formaldehyde sulfoxylate, 11 parts of itaconic acid, 3 parts of cerium acetylacetonate and 1 part of nano zinc oxide.
Mixing diesel oil, itaconic acid and nano zinc oxide, and sealing and stirring at 73 deg.C for 35min to obtain mixture A. Methanol, sodium formaldehyde sulfoxylate and cerium acetylacetonate were mixed and stirred at a temperature of 62 ℃ for 1.2h to obtain a mixture B. Mixing the mixture A and the mixture B, heating to 65 ℃, stirring for 10min, and then carrying out ultrasonic treatment at the temperature for 42min with the ultrasonic power of 1000W to obtain the fuel.
Example 2
In the embodiment of the invention, the low-carbon high-cleanness diesel vehicle fuel is composed of the following raw materials in parts by weight: 20 parts of methanol, 41 parts of diesel oil, 12 parts of sodium formaldehyde sulfoxylate, 19 parts of itaconic acid, 7 parts of cerium acetylacetonate and 3 parts of nano zinc oxide.
Mixing diesel oil, itaconic acid and nano zinc oxide, and sealing and stirring at 73 deg.C for 40min to obtain mixture A. Methanol, sodium formaldehyde sulfoxylate and cerium acetylacetonate were mixed and stirred at a temperature of 62 ℃ for 1.2h to obtain a mixture B. Mixing the mixture A and the mixture B, heating to 65 ℃, stirring for 10min, and then carrying out ultrasonic treatment at the temperature for 42min with the ultrasonic power of 1000W to obtain the fuel.
Example 3
In the embodiment of the invention, the low-carbon high-cleanness diesel vehicle fuel is composed of the following raw materials in parts by weight: 12 parts of methanol, 35 parts of diesel oil, 7 parts of sodium formaldehyde sulfoxylate, 13 parts of itaconic acid, 4 parts of cerium acetylacetonate and 1.5 parts of nano zinc oxide.
Mixing diesel oil, itaconic acid and nano zinc oxide, and sealing and stirring at 73 deg.C for 38min to obtain mixture A. Methanol, sodium formaldehyde sulfoxylate and cerium acetylacetonate were mixed and stirred at a temperature of 62 ℃ for 1.2h to obtain a mixture B. Mixing the mixture A and the mixture B, heating to 65 ℃, stirring for 10min, and then carrying out ultrasonic treatment at the temperature for 42min with the ultrasonic power of 1000W to obtain the fuel.
Example 4
In the embodiment of the invention, the low-carbon high-cleanness diesel vehicle fuel is composed of the following raw materials in parts by weight: 18 parts of methanol, 39 parts of diesel oil, 10 parts of sodium formaldehyde sulfoxylate, 17 parts of itaconic acid, 6 parts of cerium acetylacetonate and 2.5 parts of nano zinc oxide.
Mixing diesel oil, itaconic acid and nano zinc oxide, and sealing and stirring at 73 deg.C for 38min to obtain mixture A. Methanol, sodium formaldehyde sulfoxylate and cerium acetylacetonate were mixed and stirred at a temperature of 62 ℃ for 1.2h to obtain a mixture B. Mixing the mixture A and the mixture B, heating to 65 ℃, stirring for 10min, and then carrying out ultrasonic treatment at the temperature for 42min with the ultrasonic power of 1000W to obtain the fuel.
Example 5
In the embodiment of the invention, the low-carbon high-cleanness diesel vehicle fuel is composed of the following raw materials in parts by weight: 15 parts of methanol, 37 parts of diesel oil, 8 parts of sodium formaldehyde sulfoxylate, 15 parts of itaconic acid, 5 parts of cerium acetylacetonate and 2 parts of nano zinc oxide.
Mixing diesel oil, itaconic acid and nano zinc oxide, and sealing and stirring at 73 deg.C for 38min to obtain mixture A. Methanol, sodium formaldehyde sulfoxylate and cerium acetylacetonate were mixed and stirred at a temperature of 62 ℃ for 1.2h to obtain a mixture B. Mixing the mixture A and the mixture B, heating to 65 ℃, stirring for 10min, and then carrying out ultrasonic treatment at the temperature for 42min with the ultrasonic power of 1000W to obtain the fuel.
Comparative example 1
The raw material content and the preparation process were the same as those of example 5 except that itaconic acid was not contained.
Comparative example 2
Except that cerium acetylacetonate was not contained, the raw material contents and the preparation process were the same as those of example 5.
Comparative example 3
The raw material content and the preparation process were the same as those of example 5, except that itaconic acid and cerium acetylacetonate were not contained.
Example 6
The comparative detection data of the performance index of the product in example 5 with the GB252-2000 national standard vehicle diesel oil by a certain provincial quality supervision and detection research institute are shown in Table 1.
TABLE 1
The fuel of example 5 was subjected to vehicle emissions testing:
the detection basis is as follows: GB 3847-2005 exhaust smoke emission limit value and measurement method for vehicle compression ignition engine and compression ignition engine automobile
The same Jetta FV7190GDF car was first subjected to exhaust gas detection using "0 # diesel oil" and then to comparative exhaust gas detection using the sample of "example 5", and the detection results are shown in Table 2. It can be seen that the smoke purification rate of the filter paper of the sample of the present invention is 75% by the comparison test of the car under the free acceleration condition using 0# diesel oil and example 5.
TABLE 2
| No. 0 diesel oil | Example 5 | Purification Rate (%) | |
| Smoke number value (Rb) | 1.2 | 0.3 | 75 |
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.
Claims (3)
1. The low-carbon high-cleanness diesel vehicle fuel is characterized by comprising the following raw materials in parts by weight: 10-20 parts of methanol, 33-41 parts of diesel oil, 5-12 parts of sodium formaldehyde sulfoxylate, 11-19 parts of itaconic acid, 3-7 parts of cerium acetylacetonate and 1-3 parts of nano zinc oxide;
the preparation method of the low-carbon high-cleanness diesel vehicle fuel comprises the following steps of:
1) mixing diesel oil, itaconic acid and nano zinc oxide, and hermetically stirring at 73 ℃ for 35-40min to obtain a mixture A;
2) mixing methanol, sodium formaldehyde sulfoxylate and cerium acetylacetonate, and stirring at the temperature of 62 ℃ for 1.2 hours to prepare a mixture B;
3) mixing the mixture A and the mixture B, heating to 65 ℃, stirring for 10min, and then carrying out ultrasonic treatment at the temperature for 42min with the ultrasonic power of 1000W to obtain the fuel.
2. The low-carbon high-cleanness diesel vehicle fuel of claim 1, which is prepared from the following raw materials in parts by weight: 12-18 parts of methanol, 35-39 parts of diesel oil, 7-10 parts of sodium formaldehyde sulfoxylate, 13-17 parts of itaconic acid, 4-6 parts of cerium acetylacetonate and 1.5-2.5 parts of nano zinc oxide.
3. The low-carbon high-cleanness diesel vehicle fuel of claim 1, which is prepared from the following raw materials in parts by weight: 15 parts of methanol, 37 parts of diesel oil, 8 parts of sodium formaldehyde sulfoxylate, 15 parts of itaconic acid, 5 parts of cerium acetylacetonate and 2 parts of nano zinc oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611195236.0A CN108219869B (en) | 2016-12-22 | 2016-12-22 | Low-carbon high-cleanness diesel vehicle fuel and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611195236.0A CN108219869B (en) | 2016-12-22 | 2016-12-22 | Low-carbon high-cleanness diesel vehicle fuel and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108219869A CN108219869A (en) | 2018-06-29 |
| CN108219869B true CN108219869B (en) | 2020-04-24 |
Family
ID=62656790
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611195236.0A Active CN108219869B (en) | 2016-12-22 | 2016-12-22 | Low-carbon high-cleanness diesel vehicle fuel and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108219869B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1324921A (en) * | 2000-05-19 | 2001-12-05 | 太凤工业株式会社 | Fuel additive for asphalt heavy-oil/aqueous fuel and combustion method thereof |
| CN101333467A (en) * | 2007-06-28 | 2008-12-31 | 詹姆士·肯尼思·桑德斯 | Nano-sized metal and metal oxide particles for more complete fuel combustion |
-
2016
- 2016-12-22 CN CN201611195236.0A patent/CN108219869B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1324921A (en) * | 2000-05-19 | 2001-12-05 | 太凤工业株式会社 | Fuel additive for asphalt heavy-oil/aqueous fuel and combustion method thereof |
| CN101333467A (en) * | 2007-06-28 | 2008-12-31 | 詹姆士·肯尼思·桑德斯 | Nano-sized metal and metal oxide particles for more complete fuel combustion |
Non-Patent Citations (1)
| Title |
|---|
| 铈基燃油添加剂的制备及其催化性能的研究;廖军海;《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》;20151231;第3.6.1节和第3.6.2节 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108219869A (en) | 2018-06-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109207212A (en) | A kind of diesel fuel additives and preparation method thereof of environment friendly combustion-supporting type | |
| Bhurat et al. | Experimental study on performance and emissions characteristics of single cylinder diesel engine with ethanol and biodiesel blended fuels with diesel | |
| CN108219869B (en) | Low-carbon high-cleanness diesel vehicle fuel and preparation method thereof | |
| CN110923024A (en) | High-cleanness methanol diesel oil for vehicles | |
| CN103923708A (en) | High-cleanness ether-based gasoline | |
| CN102634386B (en) | Compounded diesel oil | |
| CN106520221B (en) | A kind of automobile-used denatured fuel methanol for putting combustion system altogether for methanol/diesel oil | |
| CN102559294A (en) | Alcohol ether diesel oil | |
| CN101016478A (en) | Multiple-effect fuel oil saving agent for assembling high-energy substance by nano water | |
| CN109294640B (en) | Diesel oil additive and preparation method thereof | |
| Kim et al. | The characteristics of biodiesel and oxygenated additives in a compression ignition engine | |
| CN103642536A (en) | Alcohol gasoline additives and preparation method thereof | |
| CN104449882B (en) | A kind of Alcohol-ether-ester methanol fuel | |
| CN106753601B (en) | A kind of low-carbon fuel with high cleanness and preparation method thereof | |
| CN106753602B (en) | A kind of low-carbon clean fuel and preparation method thereof | |
| CN103642543B (en) | The preparation method of biofuel composite additive | |
| CN101314740B (en) | High-efficiency environment friendly energy-conservation gasoline additive | |
| CN106635187A (en) | Preparation method of low-carbon clean fuel | |
| CN106590774B (en) | Diesel oil environment protection energy saving additive and environmental-friendly high-efficiency diesel | |
| CN106753606A (en) | A kind of low-carbon (LC) fuel with high cleanness | |
| CN108148642A (en) | A kind of preparation method of fuel oil additive | |
| CN102002404A (en) | High-cleaning composite gasoline and preparation method thereof | |
| CN102071072B (en) | Methanol-diesel and preparation method thereof | |
| Patil et al. | Literature review on effect of oxygenated additives on SI Engine performance & emissions | |
| KR20210097976A (en) | Fuel additives for the diesel car black smoke elimination using bio-energy liquid and its manufacturing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |