CN106590774B - Diesel oil environment protection energy saving additive and environmental-friendly high-efficiency diesel - Google Patents

Diesel oil environment protection energy saving additive and environmental-friendly high-efficiency diesel Download PDF

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CN106590774B
CN106590774B CN201510666552.0A CN201510666552A CN106590774B CN 106590774 B CN106590774 B CN 106590774B CN 201510666552 A CN201510666552 A CN 201510666552A CN 106590774 B CN106590774 B CN 106590774B
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diesel oil
energy saving
environmental protection
diesel
saving additive
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CN106590774A (en
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曾宪林
李锋
刘智原
曾珞军
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Blue Sky Clean Energy Technology Co Ltd
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Blue Sky Clean Energy Technology Co Ltd
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  • Enzymes And Modification Thereof (AREA)

Abstract

" diesel oil environment protection energy saving additive and environmental-friendly high-efficiency diesel " of the invention, belongs to clean energy technology.It is characterized by comprising following composition by weight: biological enzyme: 0.002-0.004 parts, coenzyme preparation: 0.001-0.003 parts, plant extracts: and 0.3~0.5 part, and as the petroleum distillate of carrier: 30~40 parts;It can reduce diesel oil stickiness and become oxidizing combustible, promote the performance of diesel oil burnout characteristic and low oxygen combustion, reduce the discharge of nitrogen oxides, oxysulfide and hydrocarbon after diesel combustion.

Description

Diesel oil environment protection energy saving additive and environmental-friendly high-efficiency diesel
Technical field
The present invention relates to clean energy technology, especially a kind of environmental protection and energy saving additive and environment-friendly high-efficiency bavin for diesel oil Oil.
Background technique
What diesel oil generated, which discharges pollutants mainly, carbon monoxide, nitrogen oxides, hydrocarbon, sulfide, subtle Grain object (PM substance) etc., they are mainly shown as generation greenhouse effects to the pollution of environment, destroy ozone layer, generate acid rain, black Phenomena such as rain.The harm of human body is mainly shown as and causes various diseases, seriously damages respiratory system, and there is very strong cause It is carcinous.
Reducing the common method to discharge pollutants after diesel combustion has physical method and chemical method.Physical method is primarily directed to interior Combustion engine/engine injection system is transformed, for example, reduce injection advance angle, improve fuel injector quality control burning condition, Adjust the fuel delivery optimization combustion gas ratio etc. of injection pump.And chemical method mainly mixes addition change propellant composition and changes to diesel oil Matter, to reduce the purpose of engine emission pollutant up to cause.
Diesel oil is the most heavy product oil of Consumption of China accounting, and annual consumption is twice of gasoline or more, but in the bavin of restricted driving In oil standard, diesel quality and spatter property are still problem urgently to be resolved, and diesel oil cleaning technology still has very big development space.
Summary of the invention
Demand and blank based on above-mentioned field are supplied to a kind of additive being added in diesel oil, can reduce diesel oil Stickiness becomes oxidizing combustible, promotes the performance of diesel oil burnout characteristic and low oxygen combustion, reduces nitrogen oxidation after diesel combustion The discharge of object, oxysulfide and hydrocarbon.The technical solution that the present invention requests is as follows:
A kind of environmental protection and energy saving additive for diesel oil, it is characterised in that including following composition by weight: biological enzyme: 0.002-0.004 parts, coenzyme preparation: 0.001-0.003 parts, plant extracts: 0.3~0.5 part, and as the stone of carrier Oily distillate: 30~40 parts;
The biological enzyme is selected from alcohol dehydrogenase, cellulase, hemicellulase and/or lignoenzyme;
The coenzyme preparation includes niacinamide, ubiquinone and/or coacetylase;
Plant extracts is selected from coconut extractive, black fruit cranberry extract and microalgae extract;
Petroleum distillate as carrier is selected from naphtha and butanol;
The biological enzyme includes alcohol dehydrogenase, cellulase, hemicellulase and lignoenzyme;Proportion is 2:2:0.5: 1。
The coenzyme preparation includes niacinamide, ubiquinone and coacetylase;It is 1.5:0.5:0.5 that it, which is matched,.Plant extracts packet Include coconut extractive, black fruit cranberry extract and microalgae extract;It is 2:0.5:6 that it, which is matched,.
Petroleum distillate as carrier includes naphtha and butanol;It is 5.5:4.5 that it, which is matched,.
The method for preparing any environmental protection and energy saving additive, includes the following steps:
It is added as after 30~40 parts of petroleum distillate of carrier, after 0.3~0.5 part of plant extracts of addition in a reservoir Start at the uniform velocity to stir 1 hour;
Then be sequentially added 0.001~0.003 part of coenzyme preparation, the followed by addition of agitation 15-20 minute by 0.002~ 0.004 part of biological enzyme starts at the uniform velocity to stir to sufficiently molten under 25 DEG C~35 DEG C environment temperatures with 180 turns of revolving speed per minute It is packed after solution.
A kind of cleaning diesel oil, which is characterized in that comprising diesel oil and be added to any efficient section in the diesel oil It can environmental-protection additive.
The present invention is directed to using oil as deficiency present in internal combustion engine/boiler operatiopn of fuel, and biological enzyme is taken to decompose catalysis Diesel oil molecules structural character is recombinated, oxidizing combustible is become, is a kind of high-efficiency environment friendly energy-conservation additive of diesel oil.It is specific and Speech, pre-processes diesel oil using the characteristic of biological enzyme group, recombinates the molecular structure of diesel oil at normal temperatures and pressures, cuts diesel oil Carbochain, recombination diesel oil molecules group make its small molecule, decompose fiber carbon, oily wax, colloid, nitrogen compound, vulcanization in diesel oil Object and other impurity are closed, because diesel oil molecules group becomes smaller, kinematic viscosity reduces, mobility is promoted, atomizing effect can be obviously improved, bavin Oilconsumption is reduced, synchronousing combustion and after-flame performance improve, hydrocarbon, carbon monoxide, nitrogen oxides, oxysulfide and The discharge of PM substance is reduced naturally.And give diesel oil oxygen containing molecular structure using biological enzyme group, keep diesel oil molecules group inside and outside same Quick and complete burning is walked, by the promotion of diesel combustion efficiency, in the case of improving power, still saving oil consumption.Utilize life Object enzyme group gives diesel oil oxygen containing molecular structure, and anaerobic sulfate radical reducing bacteria < SRB > is inhibited to breed, for ocean shipping also Diesel oil can be prevented rancid, rotten.
The present invention is also claimed the preparation method of above-mentioned additive, it is any for the purpose of sale to additive of the invention Preparation/production process belong to interest field of the invention.
Experimental data shows that flue gas after diesel combustion can be greatly reduced using after energy conservation and environmental protection additive of the invention The discharge of middle carbon monoxide, hydrocarbon, nitrogen oxides, be used for a long time it is average can also fuel-efficient 10% or more, more than 2,000 The highlands use of rice can fuel-efficient 20% or more.
Additive of the invention can be added in diesel oil to diesel oil carry out pretreatment obtain environmental-friendly high-efficiency diesel it is direct Sale uses.Therefore, such environmental-friendly high-efficiency diesel also belongs to the claimed range of the present invention.
Specific embodiment
Experimental material of the invention is the known reagent being commercially available.
Alcohol dehydrogenase, cellulase, hemicellulase, lignoenzyme, niacinamide, ubiquinone, coacetylase, using sigma Product product.
Coconut extractive: Changsha Nong Jian Science and Technology Ltd., dry powder, specification are as follows: (original powder removes slag 10:1 through ethyl alcohol extraction Afterwards, it is concentrated, dries and obtain, cocnentration factor 10:1)
Black fruit cranberry extract: Xi'an Yi Yuan biology, specification: anthocyanidin 25%UV.
Microalgae extract (chlorella): chlorella dry powder, Xi'an Rayleigh Biotechnology Co., Ltd, content 100%.
Naphtha, Shanghai and ease Chemical Co., Ltd.;
Butanol, Shanghai Guang Jia Chemical Company.
The preparation of the diesel oil environment protection energy saving additive of the invention of embodiment 1
(1) it is added in a reservoir as after 30~40 parts of petroleum distillate of carrier, plant extracts 0.3~0.5 is added Start at the uniform velocity to stir 1 hour after part;
(2) be then sequentially added 0.001~0.003 part of coenzyme, the followed by addition of agitation 15-20 minute by 0.002~ 0.004 part of biological enzyme starts at the uniform velocity to stir to sufficiently molten under 25 DEG C~35 DEG C environment temperatures with 180 turns of revolving speed per minute It is packed after solution
Application method: additive of the invention is added in diesel oil by 0.1-5:10000 volume ratio, maintains diesel oil Mobility mixes it uniformly.
Illustrate the present invention by taking the addition of 1:10000 volume ratio as an example below.
Representative additive formulations of the invention 18 formulas as listed by following table 1- table 3.
1. additive 1-6 of table formula
2. additive 7-12 of table formula
3. additive 13-18 of table formula
1. additive of the present invention physicochemical property survey report of experimental example
● test basis
GB/T14951-2007 " vehicle fuel saving technique assessment method "
GB/T25348-2010 " Energy saving Auto Products use technical conditions "
● inspection result: the examined Project Technical index of check sample meets GB/T25348-2010, and " automobile fuel saving produces Product use technical conditions " as defined in require.Details as Follows for inspection:
After No. 0 diesel oil is added in 2. No. 1 additive of the present invention of experimental example, the report of oil product detergency physico-chemical analysis
● test foundation:
GB19147-2013 " derv fuel "
SH/H0689 " the total sulfur content measuring method of light hydrocarbon and engine fuel and other oil products "
SH/T0806 " measurement of midbarrel arene content "
● detection unit: State Environmental Protection Administration's motor vehicle blowdown monitoring center
● testing result:
3. No. 1 additive of the present invention of experimental example reduces the oil consumption of diesel oil car and soot emission test result
Remaining 17 kinds of additive of table 1-3 are tested, effect is essentially identical.
Remaining 17 kinds of additive of table 1-3 are tested, effect is essentially identical.
Remaining 17 kinds of additive of table 1-3 are tested, effect is essentially identical.
4. additive of the present invention of experimental example reduces diesel-powered truck oil consumption test result 2,500 meters of highlands
Vehicle: dragon (SX3314BM286) difficult to understand
Power: 206KW
Remaining 17 kinds of additive of table 1-3 are tested, effect is essentially identical.
Experimental example 1-4's statistics indicate that, the of the invention diesel oil stickiness that can reduce becomes oxidizing combustible, promotes bavin The performance of oily burnout characteristic and low oxygen combustion reduces the discharge of nitrogen oxides, oxysulfide and hydrocarbon after diesel combustion.

Claims (7)

1. a kind of environmental protection and energy saving additive for diesel oil, it is characterised in that including following composition by weight: biological enzyme: 0.002~ 0.004 part, coenzyme preparation: 0.001~0.003 part, plant extracts: 0.3~0.5 part, and petroleum as carrier distillates Object: 30~40 parts;
The biological enzyme is selected from short-chain dehydrogenase, cellulase, hemicellulase and/or lignoenzyme;
The coenzyme preparation includes niacinamide, ubiquinone and/or coacetylase;
Plant extracts is selected from coconut extractive, black fruit cranberry extract and microalgae extract;
Petroleum distillate as carrier is selected from naphtha and butanol.
2. environmental protection and energy saving additive according to claim 1, it is characterised in that:
The biological enzyme includes alcohol dehydrogenase, cellulase, hemicellulase and lignoenzyme;Proportion is 2:2:0.5:1.
3. environmental protection and energy saving additive according to claim 1, it is characterised in that:
The coenzyme preparation includes niacinamide, ubiquinone and coacetylase;It is 1.5:0.5:0.5 that it, which is matched,.
4. environmental protection and energy saving additive according to claim 1, it is characterised in that: plant extracts includes coconut extractive, black Fruit cranberry extract and microalgae extract;It is 2:0.5:6 that it, which is matched,.
5. environmental protection and energy saving additive according to claim 1, it is characterised in that: the petroleum distillate as carrier includes stone brain Oil and butanol;It is 5.5:4.5 that it, which is matched,.
6. the method for preparing any environmental protection and energy saving additive of claim 1-5, includes the following steps:
It is added in a reservoir as after 30~40 parts of petroleum distillate of carrier, is started after being added 0.3~0.5 part of plant extracts At the uniform velocity stir 1 hour;
Then it is sequentially added 0.001~0.003 part of coenzyme preparation, agitation 15~be subsequently added into 0.002~0.004 part after twenty minutes Biological enzyme, at the uniform velocity agitation is started to wrapping after completely dissolution with 180 turns of revolving speed per minute under 25 DEG C~35 DEG C environment temperatures Dress.
7. a kind of cleaning diesel oil, which is characterized in that include diesel oil and any institute of the claim 1-5 being added in the diesel oil The environmental protection and energy saving additive stated.
CN201510666552.0A 2015-10-15 2015-10-15 Diesel oil environment protection energy saving additive and environmental-friendly high-efficiency diesel Active CN106590774B (en)

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109777526A (en) * 2018-09-18 2019-05-21 湘潭正宇节能科技有限公司 A kind of energy conservation and environmental protection BF diesel oil

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101405373A (en) * 2006-01-27 2009-04-08 Oryxe能源国际公司 Biodiesel fuel additive
CN102304395A (en) * 2011-08-04 2012-01-04 山东京博控股股份有限公司 Diesel biological modifier

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101405373A (en) * 2006-01-27 2009-04-08 Oryxe能源国际公司 Biodiesel fuel additive
CN102304395A (en) * 2011-08-04 2012-01-04 山东京博控股股份有限公司 Diesel biological modifier

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