CN106590774A - Environmental friendly and energy saving additive for diesel oil as well as environmental friendly and high efficient diesel oil - Google Patents

Environmental friendly and energy saving additive for diesel oil as well as environmental friendly and high efficient diesel oil Download PDF

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Publication number
CN106590774A
CN106590774A CN201510666552.0A CN201510666552A CN106590774A CN 106590774 A CN106590774 A CN 106590774A CN 201510666552 A CN201510666552 A CN 201510666552A CN 106590774 A CN106590774 A CN 106590774A
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China
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diesel oil
energy saving
additive
parts
coenzyme
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CN201510666552.0A
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CN106590774B (en
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曾宪林
李锋
刘智原
曾珞军
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Blue Sky Clean Energy Technology Co Ltd
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Blue Sky Clean Energy Technology Co Ltd
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  • Enzymes And Modification Thereof (AREA)

Abstract

The invention provides an environmental friendly and energy saving additive for diesel oil as well as environmental friendly and high efficient diesel oil, and belongs to the energy cleaning technology. The additive is characterized in that the additive comprises the following components in parts by weight: 0.002-0.004 parts of a biological enzyme, 0.001-0.003 parts of a coenzyme preparation, 0.3-0.5 parts of a plant extract product, and 30-40 parts of a petroleum distillate which is used as a carrier. The additive can reduce viscosity of diesel oil, so that the diesel oil can become oxygen-rich fuel, burning-out characteristics and low oxygen combustion performance of the diesel oil are improved, and discharge of nitrogen oxide, oxysulfide and hydrocarbon of the diesel oil after combustion is reduced.

Description

Diesel oil environment protection energy saving additive and environmental-friendly high-efficiency diesel
Technical field
The present invention relates to clean energy technology, particularly a kind of environmental protection and energy saving additive and environmental-friendly high-efficiency diesel for diesel oil.
Background technology
Carbon monoxide, nitrogen oxides, Hydrocarbon, sulfide, the fine particulates of mainly have that discharging pollutants that diesel oil is produced (PM materials) etc., their pollutions to environment are mainly shown as generation greenhouse effect, damage the ozone layer, and produce acid rain, black rain Etc. phenomenon.The harm of human body is mainly shown as and causes various diseases, seriously damage respiratory system, and with very strong carcinogenic Property.
The common method discharged pollutants after reducing diesel combustion has Physical and chemical method.Physical be primarily directed to internal combustion engine/send out Motivation injection system is transformed, for example, reduce injection advance angle, the quality control burning condition for improving fuel injector, adjustment oil spout Fuel delivery optimization combustion gas ratio of pump etc..And chemical method mainly mixes addition change propellant composition and diesel oil is modified, caused with reaching Reduce the purpose of engine emission pollutant.
Diesel oil is the most heavy product oil of Consumption of China accounting, and annual consumption is more than the twice of gasoline, but in the diesel oil standard restricted driving In, diesel quality and spatter property are still a difficult problem urgently to be resolved hurrily, and diesel oil cleaning technology still has very big development space.
The content of the invention
Demand and blank based on above-mentioned field, there is provided to a kind of additive being added in diesel oil, diesel oil stickiness can be reduced Oxidizing combustible is become, the performance of diesel oil burnout characteristic and low oxygen combustion is lifted, nitrogen oxides, sulfur oxygen after diesel combustion is reduced The discharge of compound and Hydrocarbon.The technical scheme of present invention request is as follows:
A kind of environmental protection and energy saving additive for diesel oil, it is characterised in that including following composition by weight:Enzyme:0.002-0.004 Part, coenzyme preparation:0.001-0.003 parts, plant extract:0.3~0.5 part, and as the petroleum distillate of carrier:30~ 40 parts;
The enzyme is selected from ethanol dehydrogenase, cellulase, hemicellulase and/or lignoenzyme;
The coenzyme preparation includes nicotiamide, ubiquinone and/or coenzyme A;
Plant extract is selected from coconut extractive, Vaccinium myrtillus Linn. extract and microalgae extract;
Petroleum and butanol are selected from as the petroleum distillate of carrier;
The enzyme includes ethanol dehydrogenase, cellulase, hemicellulase and lignoenzyme;Proportioning is 2:2:0.5:1.
The coenzyme preparation includes nicotiamide, ubiquinone and coenzyme A;Its proportioning is 1.5:0.5:0.5.Plant extract includes Coconut extractive, Vaccinium myrtillus Linn. extract and microalgae extract;Its proportioning is 2:0.5:6.
Include Petroleum and butanol as the petroleum distillate of carrier;Its proportioning is 5.5:4.5.
The method for preparing arbitrary described environmental protection and energy saving additive, comprises the steps:
After adding 30~40 parts of the petroleum distillate as carrier in a reservoir, start after adding 0.3~0.5 part of plant extract even Speed agitation 1 hour;
Then 0.001~0.003 part of coenzyme preparation, agitation 15-20 minutes is sequentially added followed by add 0.002~0.004 part Enzyme, start at the uniform velocity to stir under 25 DEG C~35 DEG C ambient temperatures with 180 turns per minute of rotating speed to after fully dissolving and pack.
A kind of cleaning diesel oil, it is characterised in that comprising diesel oil and be added to arbitrary described high-efficient energy-saving environment friendly in the diesel oil Additive.
The present invention takes enzyme to decompose catalysis restructuring diesel oil for not enough present in the internal combustion engine/boiler operatiopn with oil as fuel Molecular structure character so as to become oxidizing combustible, is a kind of high-efficiency environment friendly energy-conservation additive of diesel oil.Specifically, utilize The characteristic of enzyme group carries out pretreatment to diesel oil, the molecular structure of diesel oil of recombinating at normal temperatures and pressures, cuts off diesel oil carbochain, weight Group diesel oil molecules group makes its small molecule, decompose fiber carbon in diesel oil, oily wax, colloid, nitrogen compound, sulphur compound and Other impurity, diminish because of diesel oil molecules group, kinematic viscosity is reduced, mobility is lifted, and atomizing effect can be obviously improved, and diesel oil disappears Consumption is reduced, synchronousing combustion and after-flame performance are improved, Hydrocarbon, carbon monoxide, nitrogen oxides, oxysulfide and PM The discharge of material is reduced naturally.And give diesel oil oxygen containing molecular structure using enzyme group, make diesel oil molecules group inside and outside synchronous fast Speed is burnt completely, by the lifting of diesel combustion efficiency, in the case of power is improved, still saves oil consumption.Using enzyme Group gives diesel oil oxygen containing molecular structure, suppresses anaerobic sulfate radical reducing bacteria < SRB > to grow, may be used also for ocean shipping Prevent diesel oil from becoming sour, go bad.
The present invention is also claimed the preparation method of above-mentioned additive, any preparation for the purpose of sale to additive of the invention / production process belongs to the interest field of the present invention.
Experimental data shows, after the energy-conserving and environment-protective additive using the present invention, an oxygen in flue gas can be greatly reduced after diesel combustion Change carbon, Hydrocarbon, the discharge of nitrogen oxides, life-time service averagely can also fuel-efficient more than 10%, more than 2,000 meters Highlandss are using can fuel-efficient more than 20%.
The additive of the present invention can be added in diesel oil and diesel oil is carried out pretreatment acquisition environmental-friendly high-efficiency diesel direct marketing or make With.Therefore, such environmental-friendly high-efficiency diesel falls within the scope that the present invention is claimed.
Specific embodiment
The experiment material of the present invention is the known reagent being commercially available.
Ethanol dehydrogenase, cellulase, hemicellulase, lignoenzyme, nicotiamide, ubiquinone, coenzyme A, using sigma Product product.
Coconut extractive:Changsha Nong Jian Science and Technology Ltd.s, dry powder, specification is:10:1 (former powder Jing ethanol extract remove slag after, Concentrate, be dried and obtain, cocnentration factor is 10:1)
Vaccinium myrtillus Linn. extract:Xi'an Yi Yuan is biological, specification:Anthocyanidin 25%UV.
Microalgae extract (chlorella):Chlorella dry powder, Xi'an Rayleigh bio tech ltd, content 100%.
Petroleum, Shanghai and ease Chemical Co., Ltd.;
Butanol, Shanghai Guang Jia Chemical Companies.
The preparation of the diesel oil environment protection energy saving additive of 1 present invention of embodiment
(1) after adding 30~40 parts of the petroleum distillate as carrier in a reservoir, after adding 0.3~0.5 part of plant extract Start at the uniform velocity to stir 1 hour;
(2) 0.001~0.003 part of coenzyme, agitation 15-20 minutes and then is sequentially added followed by add 0.002~0.004 The enzyme of part, is started at the uniform velocity to stir to after fully dissolving under 25 DEG C~35 DEG C ambient temperatures with 180 turns per minute of rotating speed and is wrapped Dress
Using method:The additive of the present invention is pressed into 0.1-5:10000 volume ratios are added in diesel oil, maintain the mobility of diesel oil Make its uniform mixing.
Below with 1:As a example by 10000 volume ratios are added, explanation is of the invention.
18 formula of the representative additive formulations of the present invention as listed by following table 1- table 3.
1. additive 1-6 formula of table
2. additive 7-12 formula of table
3. additive 13-18 formula of table
1. additive physicochemical property survey report of the present invention of experimental example
● test basis
GB/T14951-2007《Vehicle fuel saving technique assessment method》
GB/T25348-2010《Energy saving Auto Products use technical conditions》
● assay:The examined Project Technical index of check sample meets GB/T25348-2010《Energy saving Auto Products use skill Art condition》The requirement of regulation.Details as Follows for inspection:
After 2. No. 1 additive of the present invention of experimental example adds No. 0 diesel oil, the report of oil product detergency physico-chemical analysis
● test foundation:
GB19147-2013《Derv fuel》
SH/H0689《The total sulfur content algoscopy of light hydrocarbon and engine fuel and other oil products》
SH/T0806《The measure of midbarrel arene content》
● detection unit:Motor vehicles blowdown Surveillance center of State Environmental Protection Administration
● testing result:
3. No. 1 additive of the present invention of experimental example reduces the oil consumption of diesel oil car and soot emission test result
Remaining 17 kinds of additive of table 1-3 are tested, effect is essentially identical.
Remaining 17 kinds of additive of table 1-3 are tested, effect is essentially identical.
Remaining 17 kinds of additive of table 1-3 are tested, effect is essentially identical.
4. additive of the present invention of experimental example reduces diesel-powered truck oil consumption test result 2,500 meters of highlandss
Vehicle:Dragon (SX3314BM286) difficult to understand
Power:206KW
Remaining 17 kinds of additive of table 1-3 are tested, effect is essentially identical.
The as shown by data of experimental example 1-4, the diesel oil stickiness that can reduce of the present invention become oxidizing combustible, lift diesel oil combustion The performance of characteristic and low oxygen combustion, reduces the discharge of nitrogen oxides, oxysulfide and Hydrocarbon after diesel combustion to the greatest extent.

Claims (7)

1. a kind of environmental protection and energy saving additive for diesel oil, it is characterised in that including following composition by weight:Enzyme:0.002-0.004 parts, coenzyme preparation:0.001-0.003 parts, plant extract:0.3~0.5 part, and as the petroleum distillate of carrier:30~40 parts;
The enzyme is selected from short-chain dehydrogenase, cellulase, hemicellulase and/or lignoenzyme;
The coenzyme preparation includes nicotiamide, ubiquinone and/or coenzyme A;
Plant extract is selected from coconut extractive, Vaccinium myrtillus Linn. extract and microalgae extract;
Petroleum and butanol are selected from as the petroleum distillate of carrier.
2. environmental protection and energy saving additive according to claim 1, it is characterised in that:
The enzyme includes ethanol dehydrogenase, cellulase, hemicellulase and lignoenzyme;Proportioning is 2:2:0.5:1.
3. environmental protection and energy saving additive according to claim 1, it is characterised in that:
The coenzyme preparation includes nicotiamide, ubiquinone and coenzyme A;Its proportioning is 1.5:0.5:0.5.
4. environmental protection and energy saving additive according to claim 1, it is characterised in that:Plant extract includes coconut extractive, Vaccinium myrtillus Linn. extract and microalgae extract;Its proportioning is 2:0.5:6.
5. environmental protection and energy saving additive according to claim 1, it is characterised in that:Include Petroleum and butanol as the petroleum distillate of carrier;Its proportioning is 5.5:4.5.
6. the method for preparing the arbitrary described environmental protection and energy saving additive of claim 1-6, comprises the steps:
After adding 30~40 parts of the petroleum distillate as carrier in a reservoir, start at the uniform velocity to stir 1 hour after adding 0.3~0.5 part of plant extract;
Then sequentially add 0.001~0.003 part of coenzyme preparation, agitation 15-20 minutes followed by add 0.002~0.004 part of enzyme, start at the uniform velocity to stir to after fully dissolving under 25 DEG C~35 DEG C ambient temperatures with 180 turns per minute of rotating speed and pack.
7. it is a kind of to clean diesel oil, it is characterised in that comprising the arbitrary described highly-efficient, energy-saving and environmentally-friendly additive of diesel oil and claim 1-5 being added in the diesel oil.
CN201510666552.0A 2015-10-15 2015-10-15 Diesel oil environment protection energy saving additive and environmental-friendly high-efficiency diesel Active CN106590774B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109777526A (en) * 2018-09-18 2019-05-21 湘潭正宇节能科技有限公司 A kind of energy conservation and environmental protection BF diesel oil

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101405373A (en) * 2006-01-27 2009-04-08 Oryxe能源国际公司 Biodiesel fuel additive
CN102304395A (en) * 2011-08-04 2012-01-04 山东京博控股股份有限公司 Diesel biological modifier

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101405373A (en) * 2006-01-27 2009-04-08 Oryxe能源国际公司 Biodiesel fuel additive
CN102304395A (en) * 2011-08-04 2012-01-04 山东京博控股股份有限公司 Diesel biological modifier

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109777526A (en) * 2018-09-18 2019-05-21 湘潭正宇节能科技有限公司 A kind of energy conservation and environmental protection BF diesel oil

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