CN114656996A - Environment-friendly fuel oil agent and preparation method and application thereof - Google Patents
Environment-friendly fuel oil agent and preparation method and application thereof Download PDFInfo
- Publication number
- CN114656996A CN114656996A CN202210371124.5A CN202210371124A CN114656996A CN 114656996 A CN114656996 A CN 114656996A CN 202210371124 A CN202210371124 A CN 202210371124A CN 114656996 A CN114656996 A CN 114656996A
- Authority
- CN
- China
- Prior art keywords
- environment
- diethoxytetrahydrofuran
- octanol
- mass
- composition comprises
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000295 fuel oil Substances 0.000 title claims abstract description 56
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- -1 polyoxypropylene Polymers 0.000 claims abstract description 68
- 239000000463 material Substances 0.000 claims abstract description 53
- ZLKHNURELCONBB-UHFFFAOYSA-N 2,5-diethoxyoxolane Chemical compound CCOC1CCC(OCC)O1 ZLKHNURELCONBB-UHFFFAOYSA-N 0.000 claims abstract description 30
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims abstract description 30
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 30
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 30
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000000446 fuel Substances 0.000 claims abstract description 28
- 150000001540 azides Chemical class 0.000 claims abstract description 24
- SJWFXCIHNDVPSH-UHFFFAOYSA-N octan-2-ol Chemical compound CCCCCCC(C)O SJWFXCIHNDVPSH-UHFFFAOYSA-N 0.000 claims abstract description 24
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 22
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 18
- 229940031957 lauric acid diethanolamide Drugs 0.000 claims abstract description 16
- NNKQLUVBPJEUOR-UHFFFAOYSA-N 3-ethynylaniline Chemical compound NC1=CC=CC(C#C)=C1 NNKQLUVBPJEUOR-UHFFFAOYSA-N 0.000 claims abstract description 14
- 235000013162 Cocos nucifera Nutrition 0.000 claims abstract description 14
- 244000060011 Cocos nucifera Species 0.000 claims abstract description 14
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims description 38
- 239000003921 oil Substances 0.000 claims description 29
- 235000019198 oils Nutrition 0.000 claims description 29
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical group CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 12
- 239000000047 product Substances 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 235000019864 coconut oil Nutrition 0.000 claims description 8
- 239000003240 coconut oil Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000004327 boric acid Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical compound [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 claims description 4
- 125000005233 alkylalcohol group Chemical group 0.000 claims description 4
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 4
- 239000006227 byproduct Substances 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 229920001184 polypeptide Polymers 0.000 claims description 3
- 102000004196 processed proteins & peptides Human genes 0.000 claims description 3
- 108090000765 processed proteins & peptides Proteins 0.000 claims description 3
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- 238000011049 filling Methods 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 abstract description 29
- 230000009467 reduction Effects 0.000 abstract description 17
- 230000009286 beneficial effect Effects 0.000 abstract description 5
- 238000005516 engineering process Methods 0.000 abstract description 5
- 230000007246 mechanism Effects 0.000 abstract description 3
- 238000007084 catalytic combustion reaction Methods 0.000 abstract description 2
- 239000003502 gasoline Substances 0.000 description 35
- 239000003981 vehicle Substances 0.000 description 29
- 230000002195 synergetic effect Effects 0.000 description 24
- 238000012423 maintenance Methods 0.000 description 16
- 239000002283 diesel fuel Substances 0.000 description 15
- 238000012360 testing method Methods 0.000 description 15
- 230000007613 environmental effect Effects 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 238000001514 detection method Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 238000003860 storage Methods 0.000 description 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000010687 lubricating oil Substances 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- URSLCTBXQMKCFE-UHFFFAOYSA-N dihydrogenborate Chemical compound OB(O)[O-] URSLCTBXQMKCFE-UHFFFAOYSA-N 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 239000002816 fuel additive Substances 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- KFVINGKPXQSPNP-UHFFFAOYSA-N 4-amino-2-[2-(diethylamino)ethyl]-n-propanoylbenzamide Chemical compound CCN(CC)CCC1=CC(N)=CC=C1C(=O)NC(=O)CC KFVINGKPXQSPNP-UHFFFAOYSA-N 0.000 description 1
- 101000780028 Homo sapiens Natriuretic peptides A Proteins 0.000 description 1
- 102100034296 Natriuretic peptides A Human genes 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000000852 azido group Chemical group *N=[N+]=[N-] 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/224—Amides; Imides carboxylic acid amides, imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/226—Organic compounds containing nitrogen containing at least one nitrogen-to-nitrogen bond, e.g. azo compounds, azides, hydrazines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
- C10L1/231—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/232—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
- C10L1/233—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring containing nitrogen and oxygen in the ring, e.g. oxazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
- C10L1/2387—Polyoxyalkyleneamines (poly)oxyalkylene amines and derivatives thereof (substituted by a macromolecular group containing 30C)
Abstract
The invention relates to an environment-friendly fuel oil agent and a preparation method and application thereof, and the environment-friendly fuel oil agent provided by the invention comprises the following materials in percentage by mass: 1-9% of sec-octanol, 1-5% of methylbenzotriazole, 8-60% of 2, 5-diethoxytetrahydrofuran, 10-60% of azide, 1-28% of nonylphenol polyoxypropylene ether amine, 0-20% of lauric acid diethanolamide borate, 0-10% of coconut acid methyl monoethanolamide and 0-30% of isooctyl nitrate. The invention adopts the organic combination mechanism of technologies such as clean combustion, combustion control, catalytic combustion, wear resistance and friction reduction, and the like, and obtains beneficial effects by combining various functional raw materials into a fuel agent and adding the fuel agent into the fuel, thereby finally realizing the upgrading of the quality and the efficacy of the fuel.
Description
The application is a divisional application with application date of 2017, 3, 14 and application number of 201710151695.7, and the invention name of 'an environment-friendly fuel oil agent and environment-friendly fuel oil for upgrading the quality and the effect of fuel oil'.
Technical Field
The invention relates to an environment-friendly fuel oil agent and a preparation method and application thereof, belonging to the technical field of fuel oil.
Background
Petroleum energy, particularly internal combustion engine fuel, is an important material basis for survival and development of human society, the demand of the petroleum energy is continuously increased, and various new energy sources cannot effectively replace fuel within 30 years in the future, so that the work of energy conservation, emission reduction and the like is more and more emphasized.
In the past, 5 upgrades of fuel additive technology, 5 upgrades of gasoline and diesel oil manufacturing technology and 5 upgrades of automobile manufacturing technology still do not solve the following 5 big problems: (1) the automobile engine is easy to generate carbon deposit, and the problems of on-line quick prevention and removal of the carbon deposit exist in a combustion chamber and an exhaust system. (2) The emission reduction of the automobile can not be finished in the combustion chamber, the emission reduction is compensated by the three-way catalyst after the fact, and the three-way catalyst is easy to lose effectiveness by sulfur poisoning in fuel oil. (3) The sulfur reduction content in the fuel is beneficial to emission reduction, but the abrasion of the combustion chamber of the engine is increased, and the service life is shortened. (4) The existing automobile engine has the potential of over 60 percent thermal efficiency to be urgently excavated (for example, in 100 parts of energy of a gasoline automobile combustion chamber, the heat loss brought by exhaust gas accounts for about 34 percent, the heat loss brought by cooling water accounts for about 30 percent, and the friction energy loss accounts for about 5 percent). (5) The existing engine still needs further power increasing, noise reducing, temperature reducing and the like.
At present, the searched patents related to fuel additives and similar products in the market solve the problems of incomplete efficacy, insignificant effect, low efficiency, poor comprehensive benefit and the like.
Disclosure of Invention
In order to solve the technical problems, the invention aims to provide an environment-friendly fuel agent and a preparation method and application thereof.
In order to achieve the purpose, the technical scheme of the invention is as follows:
an environment-friendly fuel oil agent for upgrading the quality and the efficacy of fuel oil is composed of the following materials in percentage by mass: 1-9% of sec-octanol, 1-5% of methylbenzotriazole, 8-60% of 2, 5-diethoxytetrahydrofuran, 10-60% of azide, 1-28% of nonylphenol polyoxypropylene ether amine, 0-20% of lauric acid diethanolamide borate, 0-10% of coconut acid methyl monoethanolamide and 0-30% of isooctyl nitrate; the azide is a mixture containing a main product poly-azide-glycidyl ether obtained by taking saturated alkyl alcohol or phenol, epoxy chloropropane and sodium azide as raw materials, a small amount of chlorine-containing isomers of a byproduct poly-azide-glycidyl ether and a self-made azide catalyst; wherein: the number of polymerization n is 1-8, n may not be an integer; the saturated alkyl alcohol or phenol has a saturated alkyl group with a carbon atom number R of 2-18.
Preferably, the material composition comprises the following materials in percentage by mass: 1-8% of sec-octanol, 1-5% of tolyltriazole, 10-30% of 2, 5-diethoxytetrahydrofuran, 10-45% of azide, 5-28% of nonylphenol polyoxypropylene ether amine and 5-20% of lauric acid diethanolamide borate;
or the material composition comprises the following materials in percentage by mass: 1-8% of sec-octanol, 1-5% of methylbenzotriazole, 10-60% of 2, 5-diethoxytetrahydrofuran, 15-55% of azide, 1-10% of nonylphenol polyoxypropylene ether amine and 1-10% of coconut acid methyl monoethanolamide;
or the material composition comprises the following materials in percentage by mass: 1-8% of sec-octanol, 1-5% of methylbenzotriazole, 8-30% of 2, 5-diethoxytetrahydrofuran, 20-60% of azide, 1-10% of nonylphenol polyoxypropylene ether amine, 1-10% of coconut oil acid methyl monoethanolamide and 5-30% of isooctyl nitrate.
Preferably, the material composition comprises the following materials in percentage by mass: 1-7% of sec-octanol, 1-4% of tolyltriazole, 12-25% of 2, 5-diethoxytetrahydrofuran, 15-44% of azide, 8-25% of nonylphenol polyoxypropylene ether amine and 8-18% of lauric acid diethanolamide borate;
or the material composition comprises the following materials in percentage by mass: 1-7% of sec-octanol, 1-4% of tolyltriazole, 18-50% of 2, 5-diethoxytetrahydrofuran, 20-50% of azide, 3-9% of nonylphenol polyoxypropylene ether amine and 1-8% of coconut acid methyl monoethanolamide;
or the material composition comprises the following materials in percentage by mass: 1-7% of sec-octanol, 1-4% of tolyltriazole, 10-25% of 2, 5-diethoxytetrahydrofuran, 25-55% of azide, 3-9% of nonylphenol polyoxypropylene ether amine, 1-8% of coconut acid methyl monoethanolamide and 7-22% of isooctyl nitrate.
Preferably, the material composition comprises the following materials in percentage by mass: the secondary octanol is 2 percent, the benzotriazole is 3 percent, the 2, 5-diethoxytetrahydrofuran is 25 percent, the polymer is 40 percent, the nonyl phenol polyoxypropylene ether amine is 20 percent, and the lauric acid diethanolamide borate is 10 percent;
or the material composition comprises the following materials in percentage by mass: 3% of sec-octanol, 2% of tolytriazole, 20% of 2, 5-diethoxytetrahydrofuran, 40% of polypeptide, 18% of nonylphenol polyoxypropylene ether amine and 17% of lauric acid diethanolamide borate;
or the material composition comprises the following materials in percentage by mass: 1% of secondary octanol, 2% of tolytriazole, 47% of 2, 5-diethoxytetrahydrofuran, 40% of polycide, 7% of nonylphenol polyoxypropylene ether amine and 3% of coconut methyl monoethanolamide;
or the material composition comprises the following materials in percentage by mass: 2% of sec-octanol, 1% of tolytriazole, 37% of 2, 5-diethoxytetrahydrofuran, 50% of polypeptide, 8% of nonylphenol polyoxypropylene ether amine and 2% of coconut oil acid methyl monoethanolamide;
or the material composition comprises the following materials in percentage by mass: the composition comprises 2% of sec-octanol, 1% of tolytriazole, 17% of 2, 5-diethoxytetrahydrofuran, 55% of polycide, 10% of nonylphenol polyoxypropylene ether amine, 3% of coconut oil acid methyl monoethanolamide and 12% of isooctyl nitrate.
Or the material composition comprises the following materials in percentage by mass: the composition comprises 2% of sec-octanol, 1% of tolytriazole, 18% of 2, 5-diethoxytetrahydrofuran, 50% of polycide, 6% of nonylphenol polyoxypropylene ether amine, 5% of coconut oil acid methyl monoethanolamide and 18% of isooctyl nitrate.
The invention also provides a preparation method of the environment-friendly fuel oil agent, which comprises the following steps:
(1) taking a 1.5-liter three-mouth glass bottle, installing a 100 ℃ thermometer, fixing the glass bottle on a magnetic temperature-control stirrer, starting heating, controlling the temperature to be 40-80 ℃, and adding the raw materials while stirring at normal pressure;
(2) weighing the raw materials according to the mass fraction, wherein the total weight of the raw materials is 1 kg;
(3) sequentially and respectively adding secondary octanol, methylbenzotriazole, 2, 5-diethoxytetrahydrofuran, azide, nonylphenol polyoxypropylene ether amine, lauric acid diethanol amide boric acid ester, coconut oil acid methyl monoethanolamide and isooctyl nitrate into a bottle;
(4) after all the raw materials are added, hermetically stirring the mixture for 1 hour at the temperature of between 30 and 80 ℃ under normal pressure;
(5) stopping stirring and heating, and respectively filling into plastic bottles for later use.
The invention also provides the application of the environment-friendly fuel agent in the technical scheme or the preparation method of the technical scheme in the fuel oil, and the environment-friendly fuel agent is respectively added into fuel oil tanks or oil tanks of various fuel oils according to the volume ratio of 20-1000ppm under normal temperature and normal pressure and is uniformly mixed.
Preferably, the volume ratio of the environment-friendly fuel agent in the fuel is preferably 400 ppm.
The mechanism and the beneficial effects of the invention are as follows: the beneficial effects are obtained by adopting the organic combination mechanism of technologies such as clean combustion, combustion control, catalytic combustion, wear resistance and friction reduction and combining various functional raw materials into a fuel agent and adding the fuel oil, and finally the upgrading of the quality and the efficacy of the fuel oil is realized.
In the azide of the present invention, a small amount of the chlorine-containing isomer of the byproduct polyaziridinyl glycidyl ether, in the prior art, the chlorine-containing component is separated and removed due to its flame retardant properties. The invention utilizes the characteristic that the bond energy (334kJ/mol) of carbon-chlorine (C-Cl) bond is lower than the bond energy (422kJ/mol) of carbon-hydrogen (C-H) bond, and the chlorine isomer of the poly-azido glycidyl ether generates alkyl free radical and chlorine free radical at the first time when the temperature of a combustion chamber is raised, thereby improving the azido group (-N) in the main product poly-azido glycidyl ether3) The decomposition and heat release effects of (1) accelerate the formation of nitrene (-N:) and ammonia (N)2) So that the oil drops have instantaneous local high temperature, accelerate the reaction of nitrene (-N:) and carbon deposit on the surface of hot metal and make the carbon deposit burn instantaneouslyBurning into ash, thereby solving the problem of the existing primary amine (-NH)2) The scale removing and preventing group can not clean the combustion chamber on line in a combustion state; meanwhile, the explosion and ignition intensity of the poly-nitrogen glycidyl ether is increased, the heat and the temperature in the combustion chamber are balanced, and the generation of NO due to the local high temperature in the combustion chamber is avoidedxAnd CO and HC phenomena are generated at local low temperature, so that fuel oil is quickly and fully combusted in the combustion chamber to reduce emission, and the problem of sulfur poisoning caused by emission reduction by using a three-way catalyst is solved.
In the prior art, lauric acid diethanolamide borate (LDBE) is used as an additive of lubricating oil for lubricating an air cylinder in a crankcase, and the LDBE and the lubricating oil are adhered to the wall of the air cylinder, so that incomplete combustion can be caused to generate carbon deposit, harmful tail gas emission is increased, the lubricating oil in the crankcase is polluted, and solid borate particles with the melting point of about 450 ℃ can be generated with metal grinding dust of the crankcase or the air cylinder to scratch a metal surface. The LDBE is added into the fuel oil, the fuel oil enters a combustion chamber to be combusted, an alkyl part is combusted to generate carbon dioxide and water to be discharged, a boroxy part generates liquid boric acid under the condition of high temperature and water (the freezing point of the boric acid is 171 ℃, the temperature of the combustion chamber after ignition is 500-1700 ℃), the liquid boric acid can generate borate when meeting clean metal surfaces of the combustion chamber, an air cylinder, a piston ring and the like at high temperature, the positive ion end of the borate is hidden in the metal surface, the flexible borate negative ion end is exposed out of the metal surface, when the surface of the piston ring and the surface of the air cylinder after salification rub with each other, the mutually exclusive borate negative ion ends on the two surfaces can generate the same polarity effect, and the smaller the gap distance is, the larger the repulsive force is, and the effects of wear resistance, friction reduction, noise reduction and the like are realized. Because the mutual repulsion action of the borate anion end is always filled in the gap of the friction surface, the power reduction caused by air leakage of the cylinder can be prevented, and simultaneously, the borate anion end is fully distributed on the metal surface so as not to be directly exposed, thereby avoiding carbon deposition or corrosion.
Detailed Description
The following description of specific embodiments of the present invention is provided in connection with examples to facilitate a better understanding of the present invention.
Examples
An environment-friendly fuel oil agent formula comprises the following components in percentage by weight, wherein the specific components are shown in Table 1:
TABLE 1 formulation table of environment-friendly fuel oil agent
| Serial number | Name of raw materials | For short | Environmental protection fuel oil agent% | Remarks for note |
| A | Sec-octanol | 1-9 | Commercially available | |
| B | Methyl benzotriazole | TTA | 1-5 | Commercially available |
| C | 2, 5-diethoxytetrahydrofuran | 8-60 | Self-made | |
| D | Azide compound | RGAP | 10-60 | Self-made |
| E | Nonyl phenol polyoxypropylene ether amine | NPPA | 1-28 | Commercially available |
| F | Lauric acid diethanolamide borate | LDBE | 0-20 | Commercially available |
| G | Coconut methyl monoethanolamide | CMMEA | 0-10 | Commercially available |
| H | Isooctyl nitrate | 0-30 | Commercially available | |
| Total up to | 100 |
The formula of the environment-friendly fuel agent comprises the following optimized refined classification mass percentages, and the specific formula is shown in Table 2:
TABLE 2 optimized refined formulation table for environment-friendly fuel oil agent
An environment-friendly fuel oil agent formula comprises the following more preferable refined and classified mass percentages, and the specific formula is shown in a table 3:
TABLE 3 refining formulation table for environment-friendly fuel oil agent
A preparation method of an environment-friendly fuel oil agent comprises the following steps:
(1) taking a 1.5L three-mouth glass bottle, installing a 100 ℃ thermometer, fixing the bottle on a magnetic temperature-control stirrer, starting heating, controlling the temperature to be 40-80 ℃, and adding the raw materials while stirring under normal pressure.
(2) The raw materials are weighed according to the more preferable weight parts in the table, and the total weight of the raw materials is 1 kg.
(3) The more preferred parts by weight of the ingredients weighed in the above table are added to the bottles in the sequence No. A → H, respectively.
(4) After the addition of each raw material was completed, the mixture was hermetically stirred at 40 to 80 ℃ under normal pressure for 1 hour.
(5) The stirring and heating were stopped, and three plastic bottles were filled, respectively.
The preparation method comprises the following steps: 1kg of environment-friendly maintenance fuel oil agent, 1kg of environment-friendly synergistic gasoline agent and 1kg of environment-friendly synergistic diesel oil agent.
A preparation method and dosage of environment-friendly fuel oil are as follows: under normal temperature and normal pressure, respectively adding 1kg of environment-friendly maintenance fuel oil agent, 1kg of environment-friendly synergistic gasoline agent and 1kg of environment-friendly synergistic fuel oil agent into various fuel oils according to the dosage of 0.04 percent, and uniformly mixing to obtain the environment-friendly fuel oil, wherein the specific formula is shown in Table 4:
TABLE 4 environmental protection maintenance oil and environmental protection synergistic oil proportioning table
| Oil name and score | Gasoline/diesel oil based on environmental protection maintenance | Environment-friendly synergistic gasoline | Environment-friendly synergistic diesel oil/kerosene/fuel oil |
| Class I | Kerosene/fuel oil | ||
| Name of the preparation | Environment-friendly maintenance fuel agent | Environment-friendly synergistic gasoline agent | Environment-friendly synergistic diesel oil agent |
| By dosage | Each 1kg | 1kg | Each 1kg |
| Oil obtaining quantity | Each 2500kg | 2500kg | Each 2500kg |
The specific efficacy and performance data of the environment-friendly fuel in the internal combustion engine are shown in the following table 5:
TABLE 5 efficacy and Performance of various environmental protection fuels in the Combustion improver
| Performance of efficacy | Environment-friendly maintenance fuel | Environment-friendly synergistic gasoline | Environment-friendly synergistic diesel oil |
| 1 fuel consumption saving | The oil saving rate is about 8 percent | The oil saving rate is more than 20 percent | The oil saving rate is more than 12 percent |
| 2 emission reduction | The super-emission vehicle reaches the standard within 0.5h | After 5 hours, the super-emission vehicle reaches the standard | After 5 hours, the super-discharge vehicle reaches the standard |
| 3 liter power | The power is improved by more than 20 percent | The power is improved by about 16 percent | The power is improved by about 20 percent |
| 4 removing accumulated carbon | 1h can clean oil circuit/exhaust system | Can clear oil circuit system after 10h | Can clear oil circuit system after 10h |
| 5 reduction of wear | Wear halving repair scratches | Reducing wear | Reducing wear |
| 6 noise reduction | Soft sound with half noise | Noise reduction and sound softness | Noise reduction and sound softness |
| 7 degree of temperature reduction | The temperature of the combustion chamber is reduced by more than 150 DEG C | The temperature of the combustion chamber is reduced by more than 100 DEG C | The temperature of the combustion chamber is reduced by more than 100 DEG C |
| 8 increase the life of the car | Increase of car life | Long service life of vehicle | Long service life of vehicle |
The use and usage of an environment-friendly fuel oil in an internal combustion engine are shown in a table 6:
TABLE 6 usage and usage in various environmental protection fuel internal combustion engines
The environment-friendly maintenance fuel oil is obtained by adding a small-package environment-friendly maintenance fuel oil agent into an oil tank at present, is short-term oil, can be stopped when a vehicle runs for 2-3 kilometers and is maintained to reach an optimal state, and can be recycled when the vehicle runs for 3-5 kilometers; the environment-friendly synergistic gasoline and the environment-friendly synergistic diesel oil are long-term oil, can achieve the best efficiency after running for 2 kilometers generally, and gradually lose the beneficial effects after being stopped.
Detailed Description
The invention is further illustrated with reference to the following specific examples, which are not intended to be limiting of the invention.
The formula and the mass percentage of the environment-friendly fuel agent in the embodiment are as shown in the following table 7:
TABLE 7 environmental protection fuel oil agent formulation table for different embodiments
The preparation method and the steps of the formula of the environment-friendly fuel agent of the embodiment are as follows:
according to the preparation method and the steps of the formula 1-5, respectively obtaining 1kg of the environment-friendly fuel oil agent in each of the examples 1-6 according to the formula and the weight parts of the formula 1-6 in the above table; 2500kg of the environment-friendly synergistic fuel oil of each of the examples 1 to 6 is respectively obtained.
Detection of efficacy and application of environment-friendly fuel
Detecting the efficacy and the application of the environment-friendly maintenance gasoline:
example 1 the test vehicle type is Beijing modern BH7162MX gasoline car, driving 60 kilometres to give up the car, manual gear, closed loop electrojet, the testing result is shown in Table 8:
TABLE 8 comparison table of efficacy test results of common gasoline for vehicle and environment-friendly maintenance gasoline for vehicle in example 1
Example 2 the test vehicle type is Beijing modern BH7200MX gasoline vehicle, 2.6 kilometres new vehicle, manual gear, closed loop electric spray, the detection result is shown in Table 9:
TABLE 9 comparison table of efficacy test results of common gasoline for vehicle and environment-friendly maintenance gasoline for vehicle in example 2
According to the environment-friendly fuel oil agent, any harmful elements and substances such as oil, vehicles and the environment are not added, after lauric acid diethanol amide boric acid ester in the environment-friendly maintenance fuel oil agent is combusted, redundant boric acid which does not participate in salt forming reaction is a liquid lubricant in a combustion chamber, does not deposit in a solid state, is discharged along with water vapor, does not pollute the environment after being discharged, but easily increases the detected PM (g/km), misjudges the exhaust gas standard exceeding, and can be detected according to GB3847-2005 'emission limit value and measurement mode of automobile exhaust smoke intensity of compression ignition engines and compression ignition engines for vehicles'.
And (3) detecting the effects and the purposes of the environment-friendly synergistic gasoline:
example 3 the test vehicle type is audi A6L1.8B gasoline vehicle, driving 22.3 kilometres, manual gear, closed loop electronic injection, the test result is shown in table 10:
TABLE 10 comparison table of efficacy test results of common gasoline for vehicle and environmental protection maintenance gasoline for vehicle in example 3
Example 4 the test vehicle type is audi A6L1.8B gasoline vehicle, running 32.4 kilometres, manual gear, closed loop electrojet, the test results are shown in table 11:
TABLE 11 comparison table of efficacy test results of common gasoline for vehicles and environment-friendly maintenance gasoline for vehicles in EXAMPLE 4
And (3) detecting the effects and the purposes of the environment-friendly synergistic diesel oil:
example 5 the test vehicle type is a Jianghuai wind commercial diesel vehicle, the displacement is 2.0cc, the vehicle runs for 30.2 kilometers, and the detection results are shown in table 12:
TABLE 12 comparison table of efficacy test results of common diesel oil for vehicles and environmental protection maintenance gasoline for vehicles in example 5
Example 6 the test vehicle type is a Jianghuai wind commercial diesel vehicle, the displacement is 2.0cc, the driving is 15.6 kilometers, and the detection results are shown in table 13:
TABLE 13 comparison table of efficacy test results of common diesel oil for vehicles and environment-friendly maintenance gasoline for vehicles in EXAMPLE 6
The invention is not limited to the above detection embodiments, and more embodiments can be formed according to different proportions, different oil products and grades. For example: adding environment-friendly synergistic diesel oil to be used in an environment-friendly synergistic fuel oil embodiment on a marine internal combustion engine; another example is: the Audi A6L1.8B gasoline vehicle requires to use 95 # gasoline, while the gasoline obtained by adding 92 # gasoline and environment-friendly synergistic gasoline agent can be used as the environment-friendly synergistic gasoline, so that the functions of increasing and improving the efficiency of the internal combustion engine are not influenced, and the economic benefit is more remarkable.
The invention is not limited to the detection embodiment, and can also be used for detecting various physicochemical indexes and different storage period physicochemical indexes of the environment-friendly fuel oil according to the embodiment that different oil products are added with corresponding environment-friendly fuel oil agents to form more oil product quality. The oil quality detection for two years finds that: compared with the unadditized fuel oil, the environment-friendly fuel oil has the advantages that the quality is remarkably improved, particularly the storage period is greatly prolonged, more buffer time is provided for preventing international oil price impact, sufficient and flexible storage is provided for guaranteeing high-quality and high-efficiency combat readiness oil supply, and the raw material and storage cost of military oil is greatly reduced.
Example 7 the results of the change of the physical and chemical properties of the oil product after storing for 6 months by adding 0.04% of the environment-friendly synergistic gasoline agent into the national standard common gasoline are shown in Table 14:
TABLE 14 comparison table of physicochemical index changes of oil products after 6 months storage of common gasoline and environment-friendly synergistic gasoline
Example 8 the results of the change of the physical and chemical properties of the oil product stored for 6 months when 0.04% of the environment-friendly synergistic diesel oil agent is added to the national standard common diesel oil are shown in table 15:
TABLE 15 comparison table of physicochemical index changes of oils after 6 months storage of ordinary diesel oil and environmental-friendly synergistic diesel oil
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.
Claims (7)
1. An environment-friendly fuel oil agent for upgrading the quality and the efficacy of fuel oil is characterized in that: the material composition comprises the following materials in percentage by mass: 1-9% of sec-octanol, 1-5% of methylbenzotriazole, 8-60% of 2, 5-diethoxytetrahydrofuran, 10-60% of azide, 1-28% of nonylphenol polyoxypropylene ether amine, 0-20% of lauric acid diethanolamide borate, 0-10% of coconut acid methyl monoethanolamide and 0-30% of isooctyl nitrate; the azide is a main product poly-azide glycidyl ether obtained by taking saturated alkyl alcohol or phenol, epoxy chloropropane and sodium azide as raw materials, a small amount of chlorine-containing isomers of the side product poly-azide glycidyl ether, and a mixture containing an azide catalyst; wherein: the polymerization number n is 1-8, n is not an integer, and the saturated alkyl alcohol or phenol has a saturated alkyl carbon atom number R of 2-18.
2. The environment-friendly fuel agent according to claim 1, characterized in that:
the material composition comprises the following materials in percentage by mass: 1-8% of sec-octanol, 1-5% of tolyltriazole, 10-30% of 2, 5-diethoxytetrahydrofuran, 10-45% of azide, 5-28% of nonylphenol polyoxypropylene ether amine and 5-20% of lauric acid diethanolamide borate;
or the material composition comprises the following materials in percentage by mass: 1-8% of sec-octanol, 1-5% of methylbenzotriazole, 10-60% of 2, 5-diethoxytetrahydrofuran, 15-55% of azide, 1-10% of nonylphenol polyoxypropylene ether amine and 1-10% of coconut acid methyl monoethanolamide;
or the material composition comprises the following materials in percentage by mass: 1-8% of sec-octanol, 1-5% of methylbenzotriazole, 8-30% of 2, 5-diethoxytetrahydrofuran, 20-60% of azide, 1-10% of nonylphenol polyoxypropylene ether amine, 1-10% of coconut acid methyl monoethanolamide and 5-30% of isooctyl nitrate.
3. The environment-friendly fuel agent according to claim 1, characterized in that:
the material composition comprises the following materials in percentage by mass: 1-7% of sec-octanol, 1-4% of tolyltriazole, 12-25% of 2, 5-diethoxytetrahydrofuran, 15-44% of azide, 8-25% of nonylphenol polyoxypropylene ether amine and 8-18% of lauric acid diethanolamide borate;
or the material composition comprises the following materials in percentage by mass: 1-7% of sec-octanol, 1-4% of tolyltriazole, 18-50% of 2, 5-diethoxytetrahydrofuran, 20-50% of azide, 3-9% of nonylphenol polyoxypropylene ether amine and 1-8% of coconut acid methyl monoethanolamide;
or the material composition comprises the following materials in percentage by mass: 1-7% of sec-octanol, 1-4% of tolyltriazole, 10-25% of 2, 5-diethoxytetrahydrofuran, 25-55% of azide, 3-9% of nonylphenol polyoxypropylene ether amine, 1-8% of coconut acid methyl monoethanolamide and 7-22% of isooctyl nitrate.
4. The environment-friendly fuel agent according to claim 1, characterized in that:
the material composition comprises the following materials in percentage by mass: the secondary octanol is 2 percent, the benzotriazole is 3 percent, the 2, 5-diethoxytetrahydrofuran is 25 percent, the polymer is 40 percent, the nonyl phenol polyoxypropylene ether amine is 20 percent, and the lauric acid diethanolamide borate is 10 percent;
or the material composition comprises the following materials in percentage by mass: 3% of sec-octanol, 2% of tolytriazole, 20% of 2, 5-diethoxytetrahydrofuran, 40% of polypeptide, 18% of nonylphenol polyoxypropylene ether amine and 17% of lauric acid diethanolamide borate;
or the material composition comprises the following materials in percentage by mass: 1% of secondary octanol, 2% of tolytriazole, 47% of 2, 5-diethoxytetrahydrofuran, 40% of polycide, 7% of nonylphenol polyoxypropylene ether amine and 3% of coconut methyl monoethanolamide;
or the material composition comprises the following materials in percentage by mass: 2% of sec-octanol, 1% of tolyltriazole, 37% of 2, 5-diethoxytetrahydrofuran, 50% of polyatomic compound, 8% of nonylphenol polyoxypropylene ether amine and 2% of coconut methyl monoethanolamide;
or the material composition comprises the following materials in percentage by mass: the composition comprises 2% of sec-octanol, 1% of tolytriazole, 17% of 2, 5-diethoxytetrahydrofuran, 55% of polycide, 10% of nonylphenol polyoxypropylene ether amine, 3% of coconut oil acid methyl monoethanolamide and 12% of isooctyl nitrate.
Or the material composition comprises the following materials in percentage by mass: the composition comprises 2% of sec-octanol, 1% of tolytriazole, 18% of 2, 5-diethoxytetrahydrofuran, 50% of polycide, 6% of nonylphenol polyoxypropylene ether amine, 5% of coconut oil acid methyl monoethanolamide and 18% of isooctyl nitrate.
5. The method for preparing the environment-friendly fuel oil agent as claimed in any one of claims 1 to 4, is characterized in that: the method comprises the following steps:
(1) taking a 1.5-liter three-mouth glass bottle, installing a 100 ℃ thermometer, fixing the glass bottle on a magnetic temperature-control stirrer, starting heating, controlling the temperature to be 40-80 ℃, and adding the raw materials while stirring at normal pressure;
(2) weighing the raw materials according to the mass fraction, wherein the total weight of the raw materials is 1 kg;
(3) sequentially and respectively adding secondary octanol, methylbenzotriazole, 2, 5-diethoxytetrahydrofuran, azide, nonylphenol polyoxypropylene ether amine, lauric acid diethanol amide boric acid ester, coconut oil acid methyl monoethanolamide and isooctyl nitrate into a bottle;
(4) after all the raw materials are added, hermetically stirring the mixture for 1 hour at the temperature of between 30 and 80 ℃ under normal pressure;
(5) stopping stirring and heating, and respectively filling into plastic bottles for later use.
6. The application of the environment-friendly fuel oil agent as defined in claim 1-4 or the environment-friendly fuel oil agent prepared by the preparation method as defined in claim 5 in fuel oil is characterized in that: at normal temperature and normal pressure, the components are respectively added into oil tanks or oil cans of various fuel oils according to the volume ratio of 20-1000ppm and are uniformly mixed.
7. Use according to claim 6, characterized in that: the volume ratio of the environment-friendly fuel agent in the fuel is preferably 400 ppm.
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| CN1745163A (en) * | 2002-12-13 | 2006-03-08 | 卢布里佐尔公司 | Water blended fuel composition |
| CN101565377A (en) * | 2008-04-24 | 2009-10-28 | 天津市澳林特石油科技有限公司 | Nonyl phenol poly-oxypropylene ether amine |
| CN105884648A (en) * | 2016-04-04 | 2016-08-24 | 黎明化工研究设计院有限责任公司 | GAP (glycidyl azide polymer) as well as preparation method and application thereof |
| CN106010694A (en) * | 2016-06-01 | 2016-10-12 | 倪江波 | Oil-saving environment-friendly additive for fuel oil |
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| US4303414A (en) * | 1980-12-15 | 1981-12-01 | Rockwell International Corporation | Azido additives for liquid hydrocarbon motor fuels |
| CN1320682A (en) * | 2001-04-16 | 2001-11-07 | 徐清华 | Oil additive |
| CN104178232B (en) * | 2014-07-18 | 2016-06-29 | 周亦鹏 | The compound additive of a kind of M5～M25 carbinol gasoline fuel and methanol gasoline thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1745163A (en) * | 2002-12-13 | 2006-03-08 | 卢布里佐尔公司 | Water blended fuel composition |
| CN101565377A (en) * | 2008-04-24 | 2009-10-28 | 天津市澳林特石油科技有限公司 | Nonyl phenol poly-oxypropylene ether amine |
| CN105884648A (en) * | 2016-04-04 | 2016-08-24 | 黎明化工研究设计院有限责任公司 | GAP (glycidyl azide polymer) as well as preparation method and application thereof |
| CN106010694A (en) * | 2016-06-01 | 2016-10-12 | 倪江波 | Oil-saving environment-friendly additive for fuel oil |
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Effective date of registration: 20240401 Address after: No. 9 Fenghuang Avenue, Xinzhou District, Shangrao City, Jiangxi Province, 334001 Patentee after: Shangrao Manni Technology Co.,Ltd. Country or region after: China Address before: 334000 Room 301, building 10, No. 9, Fenghuang Avenue, Xinzhou District, Shangrao City, Jiangxi Province Patentee before: Nie Zhishou Country or region before: China |