CN114656996B - Environment-friendly fuel agent capable of remarkably saving fuel and preparation method and application thereof - Google Patents
Environment-friendly fuel agent capable of remarkably saving fuel and preparation method and application thereof Download PDFInfo
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- CN114656996B CN114656996B CN202210371124.5A CN202210371124A CN114656996B CN 114656996 B CN114656996 B CN 114656996B CN 202210371124 A CN202210371124 A CN 202210371124A CN 114656996 B CN114656996 B CN 114656996B
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- 239000000446 fuel Substances 0.000 title claims abstract description 62
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- -1 polyoxypropylene Polymers 0.000 claims abstract description 30
- 239000002994 raw material Substances 0.000 claims abstract description 20
- 150000001540 azides Chemical class 0.000 claims abstract description 19
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 16
- ZLKHNURELCONBB-UHFFFAOYSA-N 2,5-diethoxyoxolane Chemical compound CCOC1CCC(OCC)O1 ZLKHNURELCONBB-UHFFFAOYSA-N 0.000 claims abstract description 14
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims abstract description 14
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims abstract description 14
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 14
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 14
- 239000002253 acid Substances 0.000 claims abstract description 13
- SJWFXCIHNDVPSH-UHFFFAOYSA-N octan-2-ol Chemical compound CCCCCCC(C)O SJWFXCIHNDVPSH-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003921 oil Substances 0.000 claims description 28
- 239000000295 fuel oil Substances 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 16
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical compound [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 claims description 4
- 125000005233 alkylalcohol group Chemical group 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 2
- 238000011049 filling Methods 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical group CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims 2
- 238000002485 combustion reaction Methods 0.000 abstract description 23
- 230000009286 beneficial effect Effects 0.000 abstract description 5
- 239000002816 fuel additive Substances 0.000 abstract description 5
- NNKQLUVBPJEUOR-UHFFFAOYSA-N 3-ethynylaniline Chemical compound NC1=CC=CC(C#C)=C1 NNKQLUVBPJEUOR-UHFFFAOYSA-N 0.000 abstract description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 abstract description 2
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 abstract description 2
- 238000007084 catalytic combustion reaction Methods 0.000 abstract description 2
- 229940031957 lauric acid diethanolamide Drugs 0.000 abstract description 2
- 239000003502 gasoline Substances 0.000 description 17
- 238000003860 storage Methods 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 238000001514 detection method Methods 0.000 description 6
- 239000002283 diesel fuel Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 6
- 238000009472 formulation Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- KFVINGKPXQSPNP-UHFFFAOYSA-N 4-amino-2-[2-(diethylamino)ethyl]-n-propanoylbenzamide Chemical compound CCN(CC)CCC1=CC(N)=CC=C1C(=O)NC(=O)CC KFVINGKPXQSPNP-UHFFFAOYSA-N 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- 101000780028 Homo sapiens Natriuretic peptides A Proteins 0.000 description 3
- 102100034296 Natriuretic peptides A Human genes 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000002035 prolonged effect Effects 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- FXBXOZPXPAXZKM-UHFFFAOYSA-N 2-(azidooxymethyl)oxirane Chemical compound C(C1CO1)ON=[N+]=[N-] FXBXOZPXPAXZKM-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000000852 azido group Chemical group *N=[N+]=[N-] 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000002828 fuel tank Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/224—Amides; Imides carboxylic acid amides, imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/226—Organic compounds containing nitrogen containing at least one nitrogen-to-nitrogen bond, e.g. azo compounds, azides, hydrazines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
- C10L1/231—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/232—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
- C10L1/233—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring containing nitrogen and oxygen in the ring, e.g. oxazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
- C10L1/2387—Polyoxyalkyleneamines (poly)oxyalkylene amines and derivatives thereof (substituted by a macromolecular group containing 30C)
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Lubricants (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The invention relates to an environment-friendly fuel agent, a preparation method and application thereof, and the environment-friendly fuel agent provided by the invention comprises the following materials in percentage by mass: 1-9% of sec-octanol, 1-5% of methyl benzotriazole, 8-60% of 2, 5-diethoxy tetrahydrofuran, 10-60% of azide, 1-28% of nonylphenol polyoxypropylene ether amine, 0-20% of lauric acid diethanolamide borate, 0-10% of coco acid methyl monoethanolamide and 0-30% of isooctyl nitrate. The invention adopts the technical organic combination mechanism of clean combustion, control combustion, catalytic combustion, wear resistance, antifriction and the like, and combines various functional raw materials into the fuel additive which is added into the fuel to obtain the beneficial effect, and finally, the quality and the efficacy of the fuel are upgraded.
Description
The application is a divisional application of an environment-friendly fuel agent for upgrading fuel quality and efficacy, wherein the application date is 2017, 3-14, the application number is 201710151695.7 and the invention name is environment-friendly fuel.
Technical Field
The invention relates to an environment-friendly fuel agent capable of remarkably saving fuel, and a preparation method and application thereof, and belongs to the technical field of fuel.
Background
Fuel is an important material basis for human society to survive and develop. Although many techniques have been invented for centuries to improve the heat engine efficiency of an internal combustion engine, the technical problems of knocking or rough handling of the internal combustion engine cannot be solved effectively, which is why the heat engine efficiency of the internal combustion engine is improved only a limited period of time.
In the past, the fuel additive manufacturing technology is upgraded for 5 times, the gasoline and diesel manufacturing technology is upgraded for 5 times, and the automobile manufacturing technology is upgraded for 5 times, so that the following 5 problems are not solved yet: (1) The automobile engine is easy to generate carbon deposit, and the problems of on-line rapid carbon deposit prevention and carbon deposit removal exist in a combustion chamber and an exhaust system. (2) The automobile cannot finish emission reduction in a combustion chamber, the emission reduction is compensated for afterwards by the three-way catalyst, and the three-way catalyst is easy to be poisoned and lose efficacy by sulfur in fuel oil. (3) The sulfur content in the fuel is reduced, which is beneficial to emission reduction, but the abrasion of the combustion chamber of the engine is increased, and the service life is shortened. (4) The existing automobile engine has the potential of heat efficiency of more than 60 percent to be rapidly excavated (for example, in 100 parts of energy of a gasoline automobile combustion chamber, exhaust heat loss is about 34 percent, cooling water heat loss is about 29 percent, and friction energy loss is about 5 percent). (5) The existing engine still needs further power rise, noise reduction, temperature reduction and the like.
At present, the problems of incomplete efficacy, insignificant effect, low efficiency, poor comprehensive benefit and the like of the problems are solved when the related fuel additive patent and the related products in the same market are searched.
Disclosure of Invention
In order to solve the technical problems, the invention aims to provide the environment-friendly fuel agent which can save oil remarkably, and the preparation method and the application thereof.
In order to achieve the above object, the technical scheme of the present invention is as follows:
an environment-friendly fuel agent capable of remarkably saving fuel is composed of the following materials in parts by mass: 1-9% of sec-octanol, 1-5% of methylbenzotriazole, 8-60% of 2, 5-diethoxy tetrahydrofuran, 10-60% of azide mixed products, 1-28% of nonylphenol polyoxypropylene ether amine and 1-10% of coco acid methyl monoethanolamide; the azide mixed product is a mixture of a target product obtained by taking saturated alkyl alcohol or phenol, epichlorohydrin and sodium azide as raw materials, namely, a azide glycidyl ether, a chlorine-containing azide glycidyl ether and a self-made azide catalyst; wherein: the polymerization number n=1 to 8, n may not be an integer; the saturated alkyl alcohol or phenol has a saturated alkyl carbon number of r=2-18.
Preferably, the material comprises the following materials in percentage by mass: 1-8% of sec-octanol, 1-5% of methylbenzotriazole, 10-60% of 2, 5-diethoxy tetrahydrofuran, 15-55% of azide mixed products, 1-10% of nonylphenol polyoxypropylene ether amine and 1-10% of coco acid methyl monoethanolamide;
or comprises the following materials in percentage by mass: 1-7% of sec-octanol, 1-4% of methylbenzotriazole, 18-50% of 2, 5-diethoxy tetrahydrofuran, 20-50% of azide mixed products, 3-9% of nonylphenol polyoxypropylene ether amine and 1-8% of coco acid methyl monoethanolamide;
preferably, the material comprises the following materials in percentage by mass: 1% of sec-octanol, 2% of methylbenzotriazole, 47% of 2, 5-diethoxy tetrahydrofuran, 40% of a polymer, 7% of nonylphenol polyoxypropylene ether amine and 3% of coco acid methyl monoethanolamide;
or comprises the following materials in percentage by mass: 2% of sec-octanol, 1% of methylbenzotriazole, 37% of 2, 5-diethoxy tetrahydrofuran, 50% of a polymer, 8% of nonylphenol polyoxypropylene ether amine and 2% of coco acid methyl monoethanolamide;
the invention also provides a preparation method of the remarkable oil-saving environment-friendly fuel agent, which comprises the following steps:
(1) Taking a 1.5 liter three-port glass bottle, installing a 100 ℃ thermometer, fixing on a magnetic temperature-control stirrer, starting heating, controlling the temperature to be 40-80 ℃, and adding raw materials while stirring under normal pressure;
(2) Weighing the raw materials according to the mass fraction, wherein the total weight of the added raw materials is 1kg;
(3) Sequentially adding the sec-octanol, the methylbenzotriazole, the 2, 5-diethoxy tetrahydrofuran, the azide mixed product, the nonylphenol polyoxypropylene ether amine, the lauric acid diethanolamide borate, the cocoacid methyl monoethanolamide and the isooctyl nitrate into a bottle respectively;
(4) After the raw materials are added, sealing and stirring for 1 hour at the normal pressure and the temperature of 30-80 ℃;
(5) Stopping stirring and heating, and respectively filling into plastic bottles for standby.
The invention also provides the application of the remarkable oil-saving environment-friendly fuel agent in fuel oil, which is prepared by the technical scheme or the preparation method of the technical scheme, and the remarkable oil-saving environment-friendly fuel agent is respectively added into fuel tanks or oil tanks of various fuel oils according to the volume ratio of 20-1000ppm at normal temperature and normal pressure, and the mixture is uniformly mixed.
Preferably, the volume ratio of the remarkable oil-saving environment-friendly fuel agent in fuel oil is preferably 400ppm.
The mechanism and the beneficial effects of the invention are as follows: the fuel additive is prepared by adopting the organic combination mechanism of technologies such as clean combustion, combustion control, catalytic combustion and the like, and combining various functional raw materials into the fuel additive which is added into fuel, so that the remarkable beneficial effects of energy conservation and emission reduction are obtained, and the quality and efficacy of the fuel are finally upgraded.
In the azide mixture product of the present invention, the chlorine-containing polyglycidyl ether is separated and removed in the prior art because of its flame retardant property. The invention utilizes the characteristic that the bond energy (334 kJ/mol) of the carbon-chlorine (C-Cl) bond is lower than the bond energy (422 kJ/mol) of the hydrocarbon (C-H) bond, and improves the azido (-N) in the azido glycidyl ether by leading chlorine-containing isomer of the azido glycidyl ether to generate alkyl free radicals and chloride free radicals when the combustion chamber is heated up 3 ) The decomposition and heat release effects of the catalyst accelerate the generation of nitrene (-N) and ammonia (N) 2 ) The instant local high temperature in the oil drop can accelerate the carbon deposition reaction between nitrene (-N) and the hot metal surface, and the carbon deposition can be instantly burnt into ash, thereby solving the problem of primary amino (-NH) in the prior art 2 ) The difficult problem that the scale removal and prevention group cannot clean the combustion chamber on line in the combustion state is solved; meanwhile, the explosion and ignition intensity of the poly azide glycidyl ether are increased, the heat and the temperature in the combustion chamber are balanced, and the generation of NO at local high temperature in the combustion chamber is avoided x And CO and HC are generated at local low temperature, so that fuel is quickly and fully combusted in a combustion chamber to reduce emission, and the problem of sulfur poisoning caused by emission reduction by using a three-way catalyst is solved.
Detailed Description
The following description of the invention is provided in connection with examples to provide a better understanding of the invention.
Examples
The formula of the environment-friendly fuel oil agent with remarkable oil saving comprises the following components in percentage by weight, wherein the specific formula is shown in table 1:
table 1 environmental protection fuel formulation table with remarkable oil saving
| Sequence number | Raw material name | Short for short | Oil-saving environment-friendly fuel agent% | Remarks |
| A | Sec-octanol | 1-9 | Commercially available | |
| B | Methyl benzotriazoles | TTA | 1-5 | Commercially available |
| C | 2, 5-Diethoxytetrahydrofuran | 8-60 | Homemade | |
| D | Azidation mixture product | 10-60 | Homemade | |
| E | Nonylphenol polyoxypropylene ether amine | NPPA | 1-28 | Commercially available |
| F | Coconut acid methyl monoethanolamide | CMMEA | 1-10 | Commercially available |
| Totalizing | 100 |
The formula of the fuel-saving environment-friendly fuel oil agent comprises the following optimized mass percentages, and the proportions are shown in table 2:
table 2A significantly oil-saving environmental protection fuel agent optimization formulation table
| Sequence number | Raw material name | Short for short | Oil-saving environment-friendly fuel agent% |
| A | Sec-octanol | 1-8 | |
| B | Methyl benzotriazoles | TTA | 1-5 |
| C | 2, 5-Diethoxytetrahydrofuran | 10-60 | |
| D | Azidation mixture product | 15-55 | |
| E | Nonylphenol polyoxypropylene ether amine | NPPA | 1-10 |
| F | Coconut acid methyl monoethanolamide | CMMEA | 1-10 |
| Totalizing | 100 |
The formula of the fuel-saving environment-friendly fuel oil agent comprises the following more optimized mass percentages, and the proportions are shown in table 3:
TABLE 3 more optimal formulation of environmental friendly fuel with remarkable fuel saving
| Sequence number | Raw material name | Short for short | Oil-saving environment-friendly fuel agent% |
| A | Sec-octanol | 1-7 | |
| B | Methyl benzotriazoles | TTA | 1-4 |
| C | 2, 5-Diethoxytetrahydrofuran | 18-50 | |
| D | Azidation mixture product | 20-50 | |
| E | Nonylphenol polyoxypropylene ether amine | NPPA | 3-9 |
| F | Coconut acid methyl monoethanolamide | CMMEA | 1-8 |
| Totalizing | 100 |
A preparation method of a remarkable oil-saving environment-friendly fuel agent comprises the following steps:
(1) Taking a 1.5 liter three-port glass bottle, installing a 100 ℃ thermometer, fixing on a magnetic temperature-control stirrer, starting heating, controlling the temperature to be 40-80 ℃, and adding raw materials while stirring under normal pressure.
(2) The weight of the raw materials is preferably measured in parts by weight in the above table, and the total weight of the raw materials should be 1kg.
(3) More preferably, the materials in parts by weight as indicated in the above table are added to the bottles in the order of the numbers A to F.
(4) After the raw materials are added, the mixture is stirred for 1 hour under the normal pressure at the temperature of 40-80 ℃.
(5) Stirring and heating were stopped and filled into three plastic bottles, respectively.
The environment-friendly fuel oil agent which can save oil remarkably is obtained by the preparation method of the step 5.
A preparation method and the dosage of the environment-friendly fuel oil which obviously saves oil: 1kg of the remarkable oil-saving environment-friendly fuel agent is added into the fuel oil according to the dosage of 0.04% at normal temperature and normal pressure, and the remarkable oil-saving environment-friendly fuel oil can be obtained, and the specific formulation ratio is shown in the table 4:
table 4. Proportion table of remarkable oil-saving environmental protection fuel oil
| Oil name | Environment-friendly fuel oil with remarkable fuel saving effect |
| Name of the agent | Environment-friendly fuel agent capable of remarkably saving fuel |
| Dosage of | 1kg |
| Total amount of oil | 2500kg |
The efficacy and performance of the environment-friendly fuel oil with obvious oil saving in the internal combustion engine are shown in the table 5:
TABLE 5 efficacy and Performance of remarkable fuel saving environmental protection Fuel in internal Combustion Engine
| Efficacy performance | Environment-friendly fuel oil with remarkable fuel saving effect |
| 1 oil saving and consumption | The oil saving rate is over 20 percent |
| 2 emission reduction | After 5 hours, the super-discharge vehicle reaches the standard |
| 3 liter power | Power is improved by about 16 percent |
| 4 removing carbon deposit | Clean oil circuit system after 10h |
| 5 antifriction loss | Wear reduction |
| 6 noise reduction | Noise reducing sound softness |
| 7 degree of temperature decrease | The temperature of the combustion chamber is reduced by more than 100 DEG C |
| 8 increase the service life of the vehicle | Long-term service life of vehicle |
The application and usage of the environment-friendly fuel oil with obvious oil saving in the internal combustion engine are shown in the table 6:
table 6 shows the use and usage of the engine with obvious oil saving and environment protection
The environment-friendly fuel oil which is obviously saved in oil is used for a long time, the best efficiency can be achieved after the operation is usually carried out for 2 kilokilometers, and the beneficial effects are gradually lost after the operation is stopped.
Detailed Description
The invention will be further illustrated with reference to specific examples, which are not intended to limit the invention.
The formula and the mass percentage components of the environment-friendly fuel oil agent with remarkable fuel saving effect are shown in the following table 7:
table 7 formulation table of different ratio examples fuel saving environment protection fuel agent
The preparation method and the steps of the formula of the environment-friendly fuel oil agent with remarkable oil saving effect are as follows:
according to the preparation method and the steps of the 1-5 formulas, 1kg of the oil-saving environment-friendly fuel agent in each of the examples 1-2 is obtained according to the formulas and the parts by weight of the examples 1-2 in the table; 2500kg of oil-saving environment-friendly synergistic fuel oil of examples 1 to 2 are obtained respectively.
Obvious fuel-saving environment-friendly fuel efficiency and application detection:
example 1, the test vehicle model is an Audi A6L1.8B gasoline vehicle, the running speed is 22.3 km, the manual gear is operated, the closed loop electric spray is carried out, and the detection result is shown in table 8:
table 8 comparison table of test results of general gasoline for vehicle and fuel-saving environment-friendly maintenance gasoline for vehicle of example 1
Example 2, the test vehicle model is Audi A6L1.8B gasoline vehicle, the running speed is 32.4 km, the manual gear is operated, the closed loop electronic fuel injection is carried out, and the detection result is shown in table 11:
table 9 comparison of results of testing the efficacy of conventional gasoline for vehicles and the environmentally friendly maintenance gasoline for vehicles of example 2
The invention is not limited to the above detection embodiments, and can be more embodiments according to different proportions and different oil products and brands. For example: the fuel-saving environment-friendly fuel agent is added for the fuel-saving environment-friendly diesel embodiment on the marine internal combustion engine; also for example: the Audi A6L1.8B gasoline vehicle requires to use No. 95 gasoline, and the No. 92 gasoline can be used as the gasoline with the fuel-saving and environment-friendly fuel agent, so that the purposes of increasing and improving the efficacy of the internal combustion engine are not affected, and the economic benefit is more remarkable.
The invention is not limited to the detection embodiment, and can also detect various physicochemical indexes and different physical and chemical indexes of the oil-saving environment-friendly fuel according to the embodiment that different oil products are added with corresponding oil-saving environment-friendly fuel agents to form more oil products. Oil quality detection for two years shows that: the fuel-saving environment-friendly fuel oil has obviously improved quality compared with fuel oil without additive, particularly greatly prolonged storage period, provides more buffer time for preventing international fuel price impact, provides sufficient and flexible reserve for guaranteeing higher quality and higher efficiency of combat readiness oil supply, and greatly reduces raw materials and reserve cost of military oil.
Example 3 the physicochemical index of the oil product stored for 6 months after 0.04% of the oil-saving environment-friendly fuel agent is added into national standard common gasoline, and the result is shown in table 10: the storage period of the common gasoline after the additive is added is prolonged to 6 months to reach the storage period of the military gasoline.
TABLE 10 comparison of physicochemical index changes of oil products after storage of ordinary gasoline and oil-saving environmental protection gasoline for 6 months
Example 4, the physicochemical index of the oil product stored for 6 months after 0.04% of the oil-saving environment-friendly fuel agent is added into national standard common diesel oil, and the result is shown in table 11: after the additive is added, the storage period of the common diesel oil is prolonged to 6 months, and the storage period of the military diesel oil is reached.
Table 11 comparison table of physicochemical index changes of oil products after storage of ordinary diesel oil and fuel-saving environment-friendly diesel oil for 6 months
The foregoing is merely a preferred embodiment of the present invention and it should be noted that modifications and adaptations to those skilled in the art may be made without departing from the principles of the present invention, which are intended to be comprehended within the scope of the present invention.
Claims (5)
1. An environment-friendly fuel agent capable of remarkably saving fuel is characterized in that: the material comprises the following materials in percentage by mass: 1-7% of sec-octanol, 1-4% of methylbenzotriazole, 18-50% of 2, 5-diethoxy tetrahydrofuran, 20-50% of azide mixed products, 3-9% of nonylphenol polyoxypropylene ether amine and 1-8% of coco acid methyl monoethanolamide; the sum of the contents of all materials is 100 percent;
the azide mixed product is main product azide glycidyl ether obtained by taking saturated alkyl alcohol or phenol, epichlorohydrin and sodium azide as raw materials, preset product chlorine-containing azide glycidyl ether and a mixture containing an azide catalyst; wherein: the polymerization number n=1 to 8, n may not be an integer, and the saturated alkyl alcohol or phenol may have a saturated alkyl carbon number r=2 to 18.
2. The environmentally friendly fuel agent with significant fuel saving according to claim 1, wherein:
the material comprises the following materials in percentage by mass: 1% of secondary octanol, 2% of methylbenzotriazole, 47% of 2, 5-diethoxy tetrahydrofuran, 40% of an azide mixture product, 7% of nonylphenol polyoxypropylene ether amine and 3% of coco acid methyl monoethanolamide;
or comprises the following materials in percentage by mass: 2% of sec-octanol, 1% of methylbenzotriazole, 37% of 2, 5-diethoxy tetrahydrofuran, 50% of an azide mixed product, 8% of nonylphenol polyoxypropylene ether amine and 2% of coco acid methyl monoethanolamide.
3. The method for preparing the environment-friendly fuel agent capable of remarkably saving oil according to claim 1 or 2, which is characterized by comprising the following steps: the method comprises the following steps:
(1) Taking a 1.5 liter three-port glass bottle, installing a 100 ℃ thermometer, fixing on a magnetic temperature-control stirrer, starting heating, controlling the temperature to be 40-80 ℃, and adding raw materials while stirring under normal pressure;
(2) Weighing the raw materials according to the mass fraction, wherein the total weight of the added raw materials is 1kg;
(3) Sequentially adding the sec-octanol, the methylbenzotriazole, the 2, 5-diethoxy tetrahydrofuran, the azide mixed product, the nonylphenol polyoxypropylene ether amine and the coco acid methyl monoethanolamide into a bottle respectively;
(4) After the raw materials are added, sealing and stirring for 1 hour at the normal pressure and the temperature of 30-80 ℃;
(5) Stopping stirring and heating, and respectively filling into plastic bottles for standby.
4. The application of the environment-friendly fuel agent with remarkable fuel saving in the fuel oil prepared by the preparation method in the claim 1 or 2 or the preparation method in the claim 3 is characterized in that: at normal temperature and pressure, the mixture is added into various fuel oil tanks or oil tanks according to the volume ratio of 20-1000ppm, and the mixture is uniformly mixed.
5. The use according to claim 4, characterized in that: the volume ratio of the environment-friendly fuel agent which is remarkably saved in fuel oil is preferably 400ppm.
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| CN1745163A (en) * | 2002-12-13 | 2006-03-08 | 卢布里佐尔公司 | Water blended fuel composition |
| CN101565377A (en) * | 2008-04-24 | 2009-10-28 | 天津市澳林特石油科技有限公司 | Nonyl phenol poly-oxypropylene ether amine |
| CN105884648A (en) * | 2016-04-04 | 2016-08-24 | 黎明化工研究设计院有限责任公司 | GAP (glycidyl azide polymer) as well as preparation method and application thereof |
| CN106010694A (en) * | 2016-06-01 | 2016-10-12 | 倪江波 | Oil-saving environment-friendly additive for fuel oil |
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| US4303414A (en) * | 1980-12-15 | 1981-12-01 | Rockwell International Corporation | Azido additives for liquid hydrocarbon motor fuels |
| CN1320682A (en) * | 2001-04-16 | 2001-11-07 | 徐清华 | Oil additive |
| CN104178232B (en) * | 2014-07-18 | 2016-06-29 | 周亦鹏 | The compound additive of a kind of M5～M25 carbinol gasoline fuel and methanol gasoline thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1745163A (en) * | 2002-12-13 | 2006-03-08 | 卢布里佐尔公司 | Water blended fuel composition |
| CN101565377A (en) * | 2008-04-24 | 2009-10-28 | 天津市澳林特石油科技有限公司 | Nonyl phenol poly-oxypropylene ether amine |
| CN105884648A (en) * | 2016-04-04 | 2016-08-24 | 黎明化工研究设计院有限责任公司 | GAP (glycidyl azide polymer) as well as preparation method and application thereof |
| CN106010694A (en) * | 2016-06-01 | 2016-10-12 | 倪江波 | Oil-saving environment-friendly additive for fuel oil |
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Effective date of registration: 20240401 Address after: No. 9 Fenghuang Avenue, Xinzhou District, Shangrao City, Jiangxi Province, 334001 Patentee after: Shangrao Manni Technology Co.,Ltd. Country or region after: China Address before: 334000 Room 301, building 10, No. 9, Fenghuang Avenue, Xinzhou District, Shangrao City, Jiangxi Province Patentee before: Nie Zhishou Country or region before: China |