CN110903596A - Waterproof sound absorption type foam filling agent suitable for wall - Google Patents

Waterproof sound absorption type foam filling agent suitable for wall Download PDF

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Publication number
CN110903596A
CN110903596A CN201911170460.8A CN201911170460A CN110903596A CN 110903596 A CN110903596 A CN 110903596A CN 201911170460 A CN201911170460 A CN 201911170460A CN 110903596 A CN110903596 A CN 110903596A
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CN
China
Prior art keywords
parts
powder
waterproof sound
expanded perlite
foam filler
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911170460.8A
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Chinese (zh)
Inventor
郭朝辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUNUO (TIANJIN) INDUSTRIAL Co Ltd
Original Assignee
GUNUO (TIANJIN) INDUSTRIAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUNUO (TIANJIN) INDUSTRIAL Co Ltd filed Critical GUNUO (TIANJIN) INDUSTRIAL Co Ltd
Priority to CN201911170460.8A priority Critical patent/CN110903596A/en
Publication of CN110903596A publication Critical patent/CN110903596A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/006Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a waterproof sound-absorbing foam filling agent suitable for a wall. The high-performance polyurethane foam material comprises, by weight, 15-20 parts of polyurethane, 30-35 parts of phenolic resin, 15-20 parts of isopropyl acrylate, 7-11 parts of expanded perlite, 2-4 parts of polyvinyl acetate, 5-8 parts of sodium dodecyl sulfate, 10-15 parts of wood powder, 0.3-0.6 part of carbon black powder, 2-4 parts of fluororubber powder, 4-6 parts of ethylene propylene diene monomer rubber powder, 1-2 parts of silicon carbide, 4-8 parts of dibutyl phthalate and 4-6 parts of mica powder. The invention provides a waterproof sound-absorbing foam filler suitable for a wall body, and the formula effectively utilizes the porous structure of expanded perlite, and improves and compensates the mechanical property of the expanded perlite by being assisted with materials such as ethylene propylene diene monomer, phenolic resin, polyurethane and the like, and simultaneously enhances the cohesiveness and the waterproof performance of the foam filler and improves the waterproof sound-absorbing effect of the wall body.

Description

Waterproof sound absorption type foam filling agent suitable for wall
Technical Field
The invention relates to the field of building decoration materials, in particular to a waterproof sound-absorbing foam filling agent suitable for walls.
Background
The foam filling agent is a building decoration product which is filled in a pressure-resistant aerosol can by components such as polyurethane prepolymer, a foaming agent, a catalyst and the like. It is often used for sealing, plugging and waterproofing between plastic steel or aluminum alloy doors and windows and walls. The foam polyurethane material can be mixed with the water in the wall and the gap thereof to expand and solidify to form foam when being sprayed out. The porous structure of the foam can effectively fill the gap between the wall plates and simultaneously realize the bonding effect between the two wall plates. The cellular structure of the foam also enhances the acoustical effectiveness of the wallboard.
At present, most polyurethane materials still have certain problems in waterproof and fireproof performances, the waterproof and fireproof performances of the foam filler can be effectively enhanced by adopting the expanded perlite, but because the mechanical properties of the expanded perlite are poor, the addition of the expanded perlite leads to the reduction of the viscosity of the polyurethane prepolymer and the reduction of the mechanical strength and toughness of the foamed polyurethane prepolymer, and the use effect of the foam filler is reduced.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides a waterproof sound-absorbing foam filler suitable for a wall, and solves the problems of poor water resistance and poor sound insulation effect of the foam filler.
(II) technical scheme
In order to achieve the purpose, the invention provides the following technical scheme: the utility model provides a waterproof sound absorption type foam filling agent suitable for wall body which characterized in that: comprises the following raw materials in parts by weight:
polyurethane: 15-20 parts of a solvent;
30-35 parts of phenolic resin;
isopropyl acrylate: 15-20 parts of a solvent;
expanded perlite: 7-11 parts;
polyvinyl acetate: 2-4 parts;
sodium lauryl sulfate: 5-8 parts;
wood powder: 10-15 parts;
0.3-0.6 part of carbon black powder;
fluorine rubber powder: 2-4 parts;
ethylene propylene diene monomer rubber powder: 4-6 parts;
silicon carbide: 1-2 parts;
dibutyl phthalate: 4-8 parts;
mica powder: 4-6 parts.
Preferably, the polyurethane material is one of PPG-3000-8000.
Preferably, the isopropyl acrylate is prepared by catalytic phenolization of acrylic acid and isopropanol.
Preferably, the diameter of the expanded perlite is less than or equal to 0.15mm, and the perlite is in a hollow hole shape.
Preferably, the wood flour is at least one of pinus sylvestris, elm and poplar wood flour.
Preferably, the fluororubber is fluororubber 23, and the fluororubber is prepared by dipping and expanding in 98% HNO3 at room temperature.
(III) advantageous effects
The invention provides a waterproof sound-absorbing foam filler suitable for a wall, which has the following beneficial effects:
(1) the effects of the components are as follows:
polyurethane: high stability, chemical resistance, heat insulation, sound insulation, low water absorption and aging resistance;
phenolic resin which is weak acid and weak base resistant, insoluble in water, fireproof, heat resistant and adhesive;
isopropyl acrylate: an organic solvent;
expanded perlite: the high-efficiency heat-preservation, cold-preservation and fire-resistance nonmetal mineral product can be expanded to form a porous structure, and the volume of the nonmetal mineral product is 10-30 times that of the nonmetal mineral product, so that the porous noise reduction effect is realized;
polyvinyl acetate: toughness and shaping are provided, and the adhesive force is strong;
sodium lauryl sulfate: decontamination, emulsification and excellent foaming ability;
wood powder: filling materials, and enhancing the material construction toughness;
carbon black powder to improve heat insulation and fire resistance;
fluorine rubber powder: heat resistance, toughness, oxidation resistance, oil resistance, corrosion resistance and ageing resistance are enhanced;
ethylene propylene diene monomer rubber powder: the heat resistance and the aging resistance are excellent, and the waterproof, the non-polar, the water absorption rate is low, and the insulation is realized;
silicon carbide: the wear resistance is improved, and the mechanical strength of the colloid is improved;
dibutyl phthalate: high stability, high cohesiveness, high water-proof performance and plasticization;
mica powder: high elasticity, toughness, high temp resistance and adhesion.
(2) The foam filler realizes a porous noise reduction structure of the foam filler through a porous structure of expanded perlite, and is supplemented with materials such as ethylene propylene diene monomer, phenolic resin, polyurethane and the like, so that the defects of the material in mechanical properties are effectively made up, and the fireproof and sound insulation properties of the material are improved.
Detailed Description
All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
the waterproof sound absorption type foam filler suitable for the wall in the embodiment 1 comprises the following components in parts by weight:
polyurethane: 15 parts of a polyurethane material, wherein the polyurethane material is PPG-3000;
30 parts of phenolic resin, wherein the isopropyl acrylate is prepared by catalytic phenolization reaction of acrylic acid and isopropanol;
isopropyl acrylate: 15 parts of (1);
expanded perlite: 7 parts of expanded perlite, wherein the diameter of the expanded perlite is less than or equal to 0.15mm, and the perlite is in a hollow hole shape;
polyvinyl acetate: 2 parts of (1);
sodium lauryl sulfate: 5 parts of a mixture;
wood powder: 10 parts of camphor pine wood powder, wherein the diameter of the wood powder is 60 meshes;
0.3 part of carbon black powder, wherein the carbon black powder is a pill-shaped particle, and the diameter of the carbon powder is 70 nm;
fluorine rubber powder: 2 parts of fluororubber, namely fluororubber 23, which is prepared by dipping and expanding in 98% HNO3 at room temperature;
ethylene propylene diene monomer rubber powder: 4 parts of a mixture;
silicon carbide: 1 part;
dibutyl phthalate: 4 parts of a mixture;
mica powder: 4 parts.
Example 2:
the waterproof sound absorption type foam filler suitable for the wall in embodiment 2 comprises the following components in parts by weight:
polyurethane: 18 parts of polyurethane material, PPG-4000;
32 parts of phenolic resin, wherein the isopropyl acrylate is prepared by catalytic phenolization reaction of acrylic acid and isopropanol;
isopropyl acrylate: 17 parts of (1);
expanded perlite: 9 parts of expanded perlite, wherein the diameter of the expanded perlite is less than or equal to 0.15mm, and the perlite is in a hollow hole shape;
polyvinyl acetate: 3 parts of a mixture;
sodium lauryl sulfate: 7 parts;
wood powder: 0.4 part of elm powder, wherein the diameter of the wood powder is 75 meshes;
0.4 part of carbon black powder, wherein the carbon black powder is a pill-shaped particle, and the diameter of the carbon powder is 70 nm;
fluorine rubber powder: 3 parts of fluororubber, namely fluororubber 23, which is prepared by dipping and expanding in 98% HNO3 at room temperature;
ethylene propylene diene monomer rubber powder: 5 parts of a mixture;
silicon carbide: 2 parts of (1);
dibutyl phthalate: 5 parts of a mixture;
mica powder: 5 parts of the raw materials.
Example 3:
the waterproof sound-absorbing foam filler suitable for the wall in embodiment 3 comprises the following components in parts by weight:
polyurethane: 20 parts of a polyurethane material, wherein the polyurethane material is PPG-5000;
35 parts of phenolic resin, wherein the isopropyl acrylate is prepared by catalytic phenolization reaction of acrylic acid and isopropanol;
isopropyl acrylate: 20 parts of (1);
expanded perlite: 11 parts of expanded perlite, wherein the diameter of the expanded perlite is less than or equal to 0.15mm, and the perlite is in a hollow hole shape;
polyvinyl acetate: 4 parts of a mixture;
sodium lauryl sulfate: 8 parts of a mixture;
wood powder: 0.6 part of elm powder, wherein the diameter of the wood powder is 80 meshes;
0.3 part of carbon black powder, wherein the carbon black powder is a pill-shaped particle, and the diameter of the carbon powder is 75 nm;
fluorine rubber powder: 4, the fluororubber is fluororubber 23, and the fluororubber is prepared by dipping and expanding in 96% HNO3 at room temperature;
ethylene propylene diene monomer rubber powder: 6 parts of (1);
silicon carbide: 2 parts of (1);
dibutyl phthalate: 6 parts of (1);
mica powder: 6 parts.
In summary, the waterproof sound absorption type foam filler suitable for the wall effectively realizes the sound insulation effect of the foam filler through the porous structure of the expanded perlite, and simultaneously enhances the viscosity of the foam filler by being supplemented with materials such as ethylene propylene diene monomer, phenolic resin, polyurethane and the like, enhances the mechanical property of the foam filler, effectively makes up the defects of the expanded perlite in the mechanical property, and improves the fireproof and sound insulation properties of the material.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (6)

1. The utility model provides a waterproof sound absorption type foam filling agent suitable for wall body which characterized in that: comprises the following raw materials in parts by weight:
polyurethane: 15-20 parts of a solvent;
30-35 parts of phenolic resin;
isopropyl acrylate: 15-20 parts of a solvent;
expanded perlite: 7-11 parts;
polyvinyl acetate: 2-4 parts;
sodium lauryl sulfate: 5-8 parts;
wood powder: 10-15 parts;
0.3-0.6 part of carbon black powder;
fluorine rubber powder: 2-4 parts;
ethylene propylene diene monomer rubber powder: 4-6 parts;
silicon carbide: 1-2 parts;
dibutyl phthalate: 4-8 parts;
mica powder: 4-6 parts.
2. The waterproof sound-absorbing foam filler suitable for walls according to claim 1, wherein: the polyurethane material is one of PPG-3000-8000.
3. The waterproof sound-absorbing foam filler suitable for walls according to claim 1, wherein: the isopropyl acrylate is prepared by catalytic phenolization reaction of acrylic acid and isopropanol.
4. The waterproof sound-absorbing foam filler suitable for walls according to claim 1, wherein: the diameter of the expanded perlite is less than or equal to 0.15mm, and the perlite is in a hollow hole shape.
5. The waterproof sound-absorbing foam filler suitable for walls according to claim 1, wherein: the wood powder is at least one of pinus sylvestris, elm and poplar wood powder.
6. The waterproof sound-absorbing foam filler suitable for walls according to claim 1, wherein: the fluororubber is fluororubber 23, and is prepared by dipping and expanding fluororubber in 98% of HNO3 at room temperature.
CN201911170460.8A 2019-11-26 2019-11-26 Waterproof sound absorption type foam filling agent suitable for wall Pending CN110903596A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911170460.8A CN110903596A (en) 2019-11-26 2019-11-26 Waterproof sound absorption type foam filling agent suitable for wall

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Application Number Priority Date Filing Date Title
CN201911170460.8A CN110903596A (en) 2019-11-26 2019-11-26 Waterproof sound absorption type foam filling agent suitable for wall

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CN110903596A true CN110903596A (en) 2020-03-24

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113372039A (en) * 2021-07-01 2021-09-10 山东尚治新材料科技有限公司 Wall secondary structure filler

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106633813A (en) * 2016-12-25 2017-05-10 苏州健能新材料科技有限公司 Polyurethane foam caulking agent
CN107312158A (en) * 2017-07-18 2017-11-03 合肥广能新材料科技有限公司 Polyurethane foam external-wall heat-insulation material and preparation method thereof
CN107603253A (en) * 2016-07-11 2018-01-19 江阴汉姆应用界面有限公司 A kind of phenolic foam board mixed filler
CN107603125A (en) * 2016-07-11 2018-01-19 江阴汉姆应用界面有限公司 A kind of phenolic resin foam composite board

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107603253A (en) * 2016-07-11 2018-01-19 江阴汉姆应用界面有限公司 A kind of phenolic foam board mixed filler
CN107603125A (en) * 2016-07-11 2018-01-19 江阴汉姆应用界面有限公司 A kind of phenolic resin foam composite board
CN106633813A (en) * 2016-12-25 2017-05-10 苏州健能新材料科技有限公司 Polyurethane foam caulking agent
CN107312158A (en) * 2017-07-18 2017-11-03 合肥广能新材料科技有限公司 Polyurethane foam external-wall heat-insulation material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113372039A (en) * 2021-07-01 2021-09-10 山东尚治新材料科技有限公司 Wall secondary structure filler

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