CN110903101A - Wear-resisting type antiskid ceramic tile - Google Patents
Wear-resisting type antiskid ceramic tile Download PDFInfo
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- CN110903101A CN110903101A CN201911297855.4A CN201911297855A CN110903101A CN 110903101 A CN110903101 A CN 110903101A CN 201911297855 A CN201911297855 A CN 201911297855A CN 110903101 A CN110903101 A CN 110903101A
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- floor tile
- reducing agent
- polyoxyethylene
- water reducing
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- 239000000919 ceramic Substances 0.000 title claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000004568 cement Substances 0.000 claims abstract description 26
- -1 polyoxyethylene Polymers 0.000 claims abstract description 25
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 21
- ALRHLSYJTWAHJZ-UHFFFAOYSA-N 3-hydroxypropionic acid Chemical compound OCCC(O)=O ALRHLSYJTWAHJZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 241000251468 Actinopterygii Species 0.000 claims abstract description 18
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 18
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 18
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims abstract description 18
- 239000003365 glass fiber Substances 0.000 claims abstract description 18
- 235000021388 linseed oil Nutrition 0.000 claims abstract description 18
- 239000000944 linseed oil Substances 0.000 claims abstract description 18
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 18
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 18
- 229960001922 sodium perborate Drugs 0.000 claims abstract description 18
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims abstract description 18
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 18
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 17
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 17
- 239000004575 stone Substances 0.000 claims abstract description 16
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 229910052573 porcelain Inorganic materials 0.000 claims abstract description 11
- 238000005299 abrasion Methods 0.000 claims abstract 4
- 229910052593 corundum Inorganic materials 0.000 claims description 18
- 239000010431 corundum Substances 0.000 claims description 18
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 5
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 230000006835 compression Effects 0.000 abstract description 4
- 238000007906 compression Methods 0.000 abstract description 4
- 238000005245 sintering Methods 0.000 description 21
- 239000011268 mixed slurry Substances 0.000 description 16
- 238000001035 drying Methods 0.000 description 14
- 238000003756 stirring Methods 0.000 description 14
- 238000003892 spreading Methods 0.000 description 10
- 239000000843 powder Substances 0.000 description 8
- 239000002002 slurry Substances 0.000 description 8
- 238000001816 cooling Methods 0.000 description 6
- 238000007873 sieving Methods 0.000 description 6
- 238000005034 decoration Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 3
- 229940094522 laponite Drugs 0.000 description 3
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 230000003796 beauty Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/71—Ceramic products containing macroscopic reinforcing agents
- C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
- C04B35/80—Fibres, filaments, whiskers, platelets, or the like
- C04B35/82—Asbestos; Glass; Fused silica
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3409—Boron oxide, borates, boric acids, or oxide forming salts thereof, e.g. borax
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/442—Carbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/444—Halide containing anions, e.g. bromide, iodate, chlorite
- C04B2235/445—Fluoride containing anions, e.g. fluosilicate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/447—Phosphates or phosphites, e.g. orthophosphate, hypophosphite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/448—Sulphates or sulphites
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
Abstract
The invention discloses an abrasion-resistant anti-slip floor tile which is prepared from the following raw materials, by weight, 40-50 parts of cement, 10-15 parts of calcite, 12-14 parts of polyoxyethylene, 11-13 parts of glass fiber, 8-10 parts of lithium porcelain stone, 6-8 parts of sodium hexametaphosphate, OP-104-6 parts of octadecanol polyoxyethylene ether, 9-11 parts of hydroxypropionic acid, 7-9 parts of fish shells, 9-10 parts of linseed oil, 5-7 parts of ammonium fluorosilicate, 5-7 parts of polycarboxylic high-performance water reducing agent, 3-5 parts of brown, 1-3 parts of sodium perborate, 1-3 parts of aluminum sulfate and 70-90 parts of water; the floor tile is high in strength, high in compression resistance and breaking resistance, good in anti-skid performance, difficult to scratch on the surface, resistant to scratch and durable, capable of meeting market demands and suitable for large-scale popularization.
Description
Technical Field
The invention relates to a wear-resistant anti-skid floor tile, and belongs to the field of decorative materials.
Background
With the development of economy and the improvement of the living standard of people, the building ground decoration industry is more and more emphasized, and occupies a main part in home decoration. The floor decoration materials in the market are more, three types of floor materials widely applied at present are wood floors, stone materials and floor tiles, from the aspects of economy, practicability, decoration and the like, the floor tiles are popular with consumers due to the characteristics of beauty, simplicity, easy cleaning and the like, and are increasingly used in large buildings such as exhibition halls, hotels, supermarkets, shopping centers, restaurants, gymnasiums, swimming pools, bathrooms and civil houses. At present, the variety of floor tiles in the market is very various, but the problem that the common floor tiles are not good in anti-skid effect, when pedestrians step on the common floor tiles, the common floor tiles can easily fall down due to skidding, and particularly, the ground is more dangerous when being wetted carelessly. In order to increase the surface anti-skid property, the surface roughness of the floor tile is usually increased by means of deep embossing and the like to improve the anti-skid property, but the anti-skid property of the floor tile surface is greatly reduced under a wet condition (liquid such as water). Therefore, the anti-slip property of the tile is one of important indexes for evaluating the safety performance of the tile. Meanwhile, after the smooth floor tiles are laid and used for a period of time, the surfaces of the smooth floor tiles are often seriously scratched, so that the attractiveness is affected.
In view of the above, it is significant to find a durable floor tile with good anti-slip effect and surface scratch resistance.
Disclosure of Invention
In view of the above, the invention aims to provide a floor tile which has good anti-skid performance, is not easy to scratch on the surface, is scratch-resistant and durable, and can meet the market demand.
In order to solve the technical problems, the technical scheme of the invention is as follows:
the wear-resistant anti-slip floor tile is prepared from, by weight, 40-50 parts of cement, 10-15 parts of calcite, 12-14 parts of polyoxyethylene, 11-13 parts of glass fiber, 8-10 parts of lithium porcelain stone, 6-8 parts of sodium hexametaphosphate, OP-104-6 parts of octadecanol polyoxyethylene ether, 9-11 parts of hydroxypropionic acid, 7-9 parts of fish shell, 9-10 parts of linseed oil, 5-7 parts of ammonium fluorosilicate, 5-7 parts of polycarboxylic high-performance water reducing agent, 3-5 parts of brown corundum, 1-3 parts of sodium perborate, 1-3 parts of aluminum sulfate and 70-90 parts of water.
Further, the wear-resistant anti-slip floor tile is prepared from the following raw materials, by weight, 50 parts of cement, 10 parts of calcite, 12 parts of polyoxyethylene, 11 parts of glass fiber, 8 parts of lithium porcelain stone, 6 parts of sodium hexametaphosphate, OP-104 parts of octadecyl alcohol polyoxyethylene ether, 9 parts of hydroxypropionic acid, 7 parts of fish shell, 9 parts of linseed oil, 5 parts of ammonium fluosilicate, 5 parts of polycarboxylic acid high-performance water reducing agent, 3 parts of brown corundum, 1 part of sodium perborate, 1 part of aluminum sulfate and 70 parts of water.
Further, the wear-resistant anti-slip floor tile is prepared from the following raw materials, by weight, 40 parts of cement, 15 parts of calcite, 14 parts of polyoxyethylene, 13 parts of glass fiber, 10 parts of lithium china stone, 8 parts of sodium hexametaphosphate, OP-106 parts of polyoxyethylene octadecanol, 11 parts of hydroxypropionic acid, 9 parts of fish shell, 10 parts of linseed oil, 7 parts of ammonium fluosilicate, 7 parts of polycarboxylic acid high-performance water reducing agent, 5 parts of brown corundum, 3 parts of sodium perborate, 3 parts of aluminum sulfate and 90 parts of water.
Further, the wear-resistant anti-slip floor tile is prepared from the following raw materials, by weight, 45 parts of cement, 12 parts of calcite, 13 parts of polyoxyethylene, 12 parts of glass fiber, 9 parts of laponite, 7 parts of sodium hexametaphosphate, OP-105 parts of octadecyl alcohol polyoxyethylene ether, 10 parts of hydroxypropionic acid, 8 parts of fish shell, 9.5 parts of linseed oil, 6 parts of ammonium fluorosilicate, 6 parts of polycarboxylic acid high-performance water reducing agent, 4 parts of brown corundum, 2 parts of sodium perborate, 2 parts of aluminum sulfate and 80 parts of water.
Another technical problem to be solved by the present invention is to provide a method for preparing a wear-resistant anti-slip floor tile, comprising the following steps:
1) putting 10-15 parts of calcite, 8-10 parts of lithium porcelain stone, 7-9 parts of fish shell and 3-5 parts of brown corundum into an airflow crusher, crushing at the speed of 1000-1200r/min for 20-30 minutes, and sieving with a sieve of 200-250 meshes to obtain wear-resistant powder for later use;
2) putting 40-50 parts of cement, 12-14 parts of polyoxyethylene, 11-13 parts of glass fiber and 70-90 parts of water into a stirrer, starting the stirrer, rotating at the rotating speed of 60-80r/pm, stirring for 10-20 minutes, then adding 5-7 parts of polycarboxylic acid high-performance water reducing agent, rotating at the rotating speed of 40-60r/pm, stirring for 20-30 minutes to obtain mixed cement slurry for later use;
3) putting 6-8 parts of sodium hexametaphosphate, 6-104 parts of octadecyl polyoxyethylene ether OP-104, 9-11 parts of hydroxypropionic acid, 9-10 parts of linseed oil, 5-7 parts of ammonium fluosilicate, 1-3 parts of sodium perborate and 1-3 parts of aluminum sulfate into the mixed cement slurry obtained in the step 2), and continuously stirring for 10-15 minutes at the rotating speed of 40-60r/pm to obtain mixed slurry for later use;
4) uniformly extruding the mixed slurry prepared in the step 3) by a double-rod screw extruder, injecting the mixed slurry into a floor tile mold, standing for 2-3 hours at normal temperature to reduce the moisture content of the mixed slurry, and preparing a floor tile blank for later use;
5) uniformly spreading the wear-resistant powder prepared in the step 1) on the surface of the ground tile blank prepared in the step 4), wherein the spreading thickness is 2-4mm, and obtaining a ground tile blank for later use;
6) tamping the floor tile blank obtained in the step 5) by a tamping machine, wherein the pressure is 1-3MPa, pressing and forming the floor tile blank, and then putting the floor tile blank into a drying chamber for drying for 1-2 days, wherein the drying temperature is 90-100 ℃; then the dried floor tile blank is sent into a sintering kiln for sintering, the sintering temperature is 1200-1300 ℃, the sintering time is 2-3 hours, and the floor tile is obtained after the sintering and natural cooling;
7) and (3) placing the floor tiles prepared in the step 6) in a dry and ventilated warehouse.
The technical effects of the invention are mainly reflected in the following aspects: according to the method, cement is used as a main raw material, calcite, glass fiber, lithium porcelain stone, fish shells and brown which are high in mechanical strength and good in wear resistance are used as fillers, dispersing agent polyoxyethylene is added, accelerator sodium hexametaphosphate, emulsifier octadecanol polyoxyethylene ether OP-10, leveling agent linseed oil, polycarboxylic high-performance water reducing agent, disinfectant ammonium fluorosilicate, oxidant sodium perborate, filler aluminum sulfate and hydroxypropionic acid which is high in hygroscopicity are added, and through the specific smashing, sieving, stirring, mixing, mold entering, standing, spreading, tamping, drying, sintering and cooling manufacturing processes, the manufactured floor tile is high in strength, high in compression resistance and fracture resistance, good in anti-slip performance, not prone to scratches on the surface, resistant to scratch, durable and capable of meeting market demands, and suitable for large-scale popularization.
Detailed Description
Example 1
The wear-resistant anti-slip floor tile is prepared from the following raw materials, by weight, 50 parts of cement, 10 parts of calcite, 12 parts of polyoxyethylene, 11 parts of glass fiber, 8 parts of laponite, 6 parts of sodium hexametaphosphate, OP-104 parts of octadecanol polyoxyethylene ether, 9 parts of hydroxypropionic acid, 7 parts of fish shell, 9 parts of linseed oil, 5 parts of ammonium fluosilicate, 5 parts of polycarboxylic acid high-performance water reducing agent, 3 parts of brown corundum, 1 part of sodium perborate, and 1 part of aluminum sulfate
And 70 parts of water.
A preparation method of the wear-resistant anti-skid floor tile comprises the following steps:
1) putting 10 parts of calcite, 8 parts of lithium porcelain stone, 7 parts of fish shell and 3 parts of brown corundum into a jet mill, crushing for 20 minutes at the speed of 1000r/min, and sieving by a 200-mesh sieve to obtain wear-resistant powder for later use;
2) putting 50 parts of cement, 12 parts of polyoxyethylene, 11 parts of glass fiber and 70 parts of water into a stirrer, starting the stirrer, rotating at the rotating speed of 60r/pm, stirring for 10 minutes, then adding 5 parts of polycarboxylic acid high-performance water reducing agent, rotating at the rotating speed of 40r/pm, stirring for 20 minutes to obtain mixed cement slurry for later use;
3) putting 6 parts of sodium hexametaphosphate, 9 parts of octadecanol polyoxyethylene ether OP-104, 9 parts of hydroxypropionic acid, 9 parts of linseed oil, 5 parts of ammonium fluosilicate, 1 part of sodium perborate and 1 part of aluminum sulfate into the mixed cement slurry obtained in the step 2), and rotating at the rotating speed of 40r/pm to continue stirring for 10 minutes to obtain mixed slurry for later use;
4) uniformly extruding the mixed slurry prepared in the step 3) by a double-rod screw extruder, injecting the mixed slurry into a floor tile mold, standing for 2 hours at normal temperature to reduce the moisture content of the mixed slurry, and preparing a floor tile blank for later use;
5) uniformly spreading the wear-resistant powder prepared in the step 1) on the surface of the floor tile blank prepared in the step 4), wherein the spreading thickness is 2mm, and obtaining a floor tile blank for later use;
6) tamping the floor tile blank obtained in the step 5) by a tamping machine, pressing and forming under the pressure of 1MPa, and then drying in a drying chamber for 1 day at the drying temperature of 90 ℃; then the dried floor tile blank is sent into a sintering kiln for sintering, the sintering temperature is 1200 ℃, the sintering time is 2 hours, and the floor tile is obtained after the sintering and natural cooling;
7) and (3) placing the floor tiles prepared in the step 6) in a dry and ventilated warehouse.
Example 2
The wear-resistant anti-slip floor tile is prepared from the following raw materials, by weight, 40 parts of cement, 15 parts of calcite, 14 parts of polyoxyethylene, 13 parts of glass fiber, 10 parts of lithium china stone, 8 parts of sodium hexametaphosphate, OP-106 parts of octadecanol polyoxyethylene ether, 11 parts of hydroxypropionic acid, 9 parts of fish shell, 10 parts of linseed oil, 7 parts of ammonium fluosilicate, 7 parts of a polycarboxylic acid high-performance water reducing agent, 5 parts of brown corundum, 3 parts of sodium perborate, 3 parts of aluminum sulfate and 90 parts of water.
A preparation method of the wear-resistant anti-skid floor tile comprises the following steps:
1) putting 15 parts of calcite, 10 parts of lithium porcelain stone, 9 parts of fish shell and 5 parts of brown corundum into a jet mill, crushing for 30 minutes at the speed of 1200r/min, and sieving by a 250-mesh sieve to obtain wear-resistant powder for later use;
2) putting 40 parts of cement, 14 parts of polyoxyethylene, 13 parts of glass fiber and 90 parts of water into a stirrer, starting the stirrer, rotating at the rotating speed of 80r/pm, stirring for 20 minutes, then adding 7 parts of polycarboxylic acid high-performance water reducing agent, rotating at the rotating speed of 60r/pm, and stirring for 30 minutes to obtain mixed cement slurry for later use;
3) putting 8 parts of sodium hexametaphosphate, 11 parts of octadecanol polyoxyethylene ether OP-106, 11 parts of hydroxypropionic acid, 10 parts of linseed oil, 7 parts of ammonium fluosilicate, 3 parts of sodium perborate and 3 parts of aluminum sulfate into the mixed cement slurry obtained in the step 2), and rotating at the rotating speed of 60r/pm to continue stirring for 15 minutes to obtain mixed slurry for later use;
4) uniformly extruding the mixed slurry prepared in the step 3) by a double-rod screw extruder, injecting the mixed slurry into a floor tile mold, standing for 3 hours at normal temperature to reduce the moisture content of the mixed slurry, and preparing a floor tile blank for later use;
5) uniformly spreading the wear-resistant powder prepared in the step 1) on the surface of the floor tile blank prepared in the step 4), wherein the spreading thickness is 4mm, and obtaining a floor tile blank for later use;
6) tamping the floor tile blank obtained in the step 5) by a tamping machine, wherein the pressure is 3MPa, pressing and forming the floor tile blank, and then putting the floor tile blank into a drying chamber for drying for 2 days, wherein the drying temperature is 100 ℃; then the dried floor tile blank is sent into a sintering kiln for sintering, the sintering temperature is 1300 ℃, the sintering time is 3 hours, and the floor tile is obtained after being taken out for natural cooling after sintering;
7) and (3) placing the floor tiles prepared in the step 6) in a dry and ventilated warehouse.
Example 3
The wear-resistant anti-slip floor tile is prepared from, by weight, 45 parts of cement, 12 parts of calcite, 13 parts of polyoxyethylene, 12 parts of glass fiber, 9 parts of laponite, 7 parts of sodium hexametaphosphate, OP-105 parts of octadecanol polyoxyethylene ether, 10 parts of hydroxypropionic acid, 8 parts of fish shell, 9.5 parts of linseed oil, 6 parts of ammonium fluosilicate, 6 parts of a polycarboxylic acid high-performance water reducing agent, 4 parts of brown corundum, 2 parts of sodium perborate, 2 parts of aluminum sulfate and 80 parts of water.
A preparation method of the wear-resistant anti-skid floor tile comprises the following steps:
1) putting 12 parts of calcite, 9 parts of lithium porcelain stone, 8 parts of fish shell and 4 parts of brown corundum into a jet mill, crushing for 25 minutes at the speed of 1100r/min, and sieving by a 230-mesh sieve to obtain wear-resistant powder for later use;
2) putting 45 parts of cement, 13 parts of polyoxyethylene, 12 parts of glass fiber and 80 parts of water into a stirrer, starting the stirrer, rotating at the rotating speed of 70r/pm, stirring for 15 minutes, then adding 6 parts of polycarboxylic acid high-performance water reducing agent, rotating at the rotating speed of 50r/pm, stirring for 25 minutes to obtain mixed cement slurry for later use;
3) putting 7 parts of sodium hexametaphosphate, 105 parts of octadecyl polyoxyethylene ether OP-105, 10 parts of hydroxypropionic acid, 9.5 parts of linseed oil, 6 parts of ammonium fluosilicate, 2 parts of sodium perborate and 2 parts of aluminum sulfate into the mixed cement slurry obtained in the step 2), and rotating at the rotating speed of 50r/pm to continue stirring for 13 minutes to obtain mixed slurry for later use;
4) uniformly extruding the mixed slurry prepared in the step 3) by a double-rod screw extruder, injecting the mixed slurry into a floor tile mold, standing for 2.5 hours at normal temperature to reduce the moisture content of the mixed slurry, and preparing a floor tile blank for later use;
5) uniformly spreading the wear-resistant powder prepared in the step 1) on the surface of the floor tile blank prepared in the step 4), wherein the spreading thickness is 3mm, and obtaining a floor tile blank for later use;
6) tamping the floor tile blank obtained in the step 5) by a tamping machine, wherein the pressure is 2MPa, pressing and forming the floor tile blank, and then putting the floor tile blank into a drying chamber for drying for 1.5 days, wherein the drying temperature is 95 ℃; then the dried floor tile blank is sent into a sintering kiln for sintering, the sintering temperature is 1200 ℃, the sintering time is 2.5 hours, and the floor tile is obtained after being taken out for natural cooling;
7) and (3) placing the floor tiles prepared in the step 6) in a dry and ventilated warehouse.
Examples of the experiments
Subject: the tile is used as a comparison group I of common tiles in the market, the high-quality anti-skid tiles in the market are used as a comparison group II, and the tile manufactured in the third embodiment of the invention is used as an experimental group.
The experimental requirements are as follows: and (3) respectively carrying out experiments on the three groups of floor tiles on skid resistance, wear resistance, breaking strength, thermal shock resistance and compressive strength, and respectively recording the experimental conditions of the three groups of floor tiles.
The specific results are shown in the following table:
according to the combination of the above table and the comparison of the first and second control groups, the floor tile has the advantages of strong compression resistance and breaking resistance, good anti-skid property, difficult scratch on the surface, scratch resistance, high anti-skid coefficient and excellent thermal shock resistance under the same experimental method.
The technical effects of the invention are mainly reflected in the following aspects: according to the method, cement is used as a main raw material, calcite, glass fiber, lithium porcelain stone, fish shells and brown which are high in mechanical strength and good in wear resistance are used as fillers, dispersing agent polyoxyethylene is added, accelerator sodium hexametaphosphate, emulsifier octadecanol polyoxyethylene ether OP-10, leveling agent linseed oil, polycarboxylic high-performance water reducing agent, disinfectant ammonium fluorosilicate, oxidant sodium perborate, filler aluminum sulfate and hydroxypropionic acid which is high in hygroscopicity are added, and through the specific smashing, sieving, stirring, mixing, mold entering, standing, spreading, tamping, drying, sintering and cooling manufacturing processes, the manufactured floor tile is high in strength, high in compression resistance and fracture resistance, good in anti-slip performance, not prone to scratches on the surface, resistant to scratch, durable and capable of meeting market demands, and suitable for large-scale popularization.
The above are only typical examples of the present invention, and besides, the present invention may have other embodiments, and all the technical solutions formed by equivalent substitutions or equivalent changes are within the scope of the present invention as claimed.
Claims (4)
1. The utility model provides a wear-resisting type antiskid ceramic tile which characterized in that: the material is prepared from the following raw materials, by weight, 40-50 parts of cement, 10-15 parts of calcite, 12-14 parts of polyoxyethylene, 11-13 parts of glass fiber, 8-10 parts of lithium porcelain stone, 6-8 parts of sodium hexametaphosphate, 6-104 parts of octadecyl polyoxyethylene ether OP-104, 9-11 parts of hydroxypropionic acid, 7-9 parts of fish shell, 9-10 parts of linseed oil, 5-7 parts of ammonium fluosilicate, 5-7 parts of polycarboxylic acid high-performance water reducing agent, 3-5 parts of brown corundum, 1-3 parts of sodium perborate, 1-3 parts of aluminum sulfate and 70-90 parts of water.
2. The abrasion-resistant non-slip floor tile of claim 1, wherein: the high-performance brown corundum water reducing agent is prepared from the following raw materials, by weight, 50 parts of cement, 10 parts of calcite, 12 parts of polyoxyethylene, 11 parts of glass fiber, 8 parts of lithium china stone, 6 parts of sodium hexametaphosphate, OP-104 parts of octadecanol polyoxyethylene ether, 9 parts of hydroxypropionic acid, 7 parts of fish shell, 9 parts of linseed oil, 5 parts of ammonium fluosilicate, 5 parts of a polycarboxylic high-performance water reducing agent, 3 parts of brown corundum, 1 part of sodium perborate, 1 part of aluminum sulfate and 70 parts of water.
3. The abrasion-resistant non-slip floor tile of claim 1, wherein: the high-performance brown corundum water reducing agent is prepared from the following raw materials, by weight, 40 parts of cement, 15 parts of calcite, 14 parts of polyoxyethylene, 13 parts of glass fiber, 10 parts of lithium porcelain stone, 8 parts of sodium hexametaphosphate, OP-106 parts of octadecanol polyoxyethylene ether, 11 parts of hydroxypropionic acid, 9 parts of fish shell, 10 parts of linseed oil, 7 parts of ammonium fluorosilicate, 7 parts of a polycarboxylic high-performance water reducing agent, 5 parts of brown corundum, 3 parts of sodium perborate, 3 parts of aluminum sulfate and 90 parts of water.
4. The abrasion-resistant non-slip floor tile of claim 1, wherein: the high-performance brown corundum water reducing agent is prepared from the following raw materials, by weight, 45 parts of cement, 12 parts of calcite, 13 parts of polyoxyethylene, 12 parts of glass fiber, 9 parts of lithium china stone, 7 parts of sodium hexametaphosphate, OP-105 parts of octadecanol polyoxyethylene ether, 10 parts of hydroxypropionic acid, 8 parts of fish shell, 9.5 parts of linseed oil, 6 parts of ammonium fluosilicate, 6 parts of a polycarboxylic high-performance water reducing agent, 4 parts of brown corundum, 2 parts of sodium perborate, 2 parts of aluminum sulfate and 80 parts of water.
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