CN1108749C - Method of controlling pests - Google Patents

Method of controlling pests Download PDF

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Publication number
CN1108749C
CN1108749C CN95107356A CN95107356A CN1108749C CN 1108749 C CN1108749 C CN 1108749C CN 95107356 A CN95107356 A CN 95107356A CN 95107356 A CN95107356 A CN 95107356A CN 1108749 C CN1108749 C CN 1108749C
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Prior art keywords
frankliniella
active component
insect
species
compound
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Expired - Fee Related
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CN95107356A
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CN1120886A (en
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C·福吕凯格
R·森
S·W·思基尔曼
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Syngenta Participations AG
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Syngenta Participations AG
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Spark Plugs (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

To control pests belonging to the family Thripidae or the genus Aculus by adopting a specific compound or its salt selected from pest control agents as an active component and applying a composition to which the active component is added with at least one kind of auxiliary. Pests belonging to the family Thripidae or the genus Aculus are controlled by applying a pest controlling agent comprising a compound of the formula or its salt as an active component and at least one kind of auxiliary. As the pests, especially the genus Frankliniella, particularly species Frankliniella occidentalis, species Frankliniella fusca, species Frankliniella tritici, species Frankliniella vaccinii, species Frankliniella bispinosa, species Frankliniella gossypiana, species Frankliniella parvula, species Frankliniella robusta, species Franklinella schltzei, species Frankliniella tenuicornis and species Frankliniella williamsi are exemplified. The pest controlling agent exhibits the effect at a low concentration and low toxicity in a warm-blooded animal.

Description

The method of Pest Control
The present invention relates to the method for Pest Control, this method comprises insect or habitat applying pesticide composition, and said composition contains free formula I compound Acarus tritici and belongs to (lufenuron) or its salt as active component With at least a assistant agent, described insect is
(1) typical Thripidae; Perhaps
(2) typical perverse rust mite belongs to.
The invention still further relates to the purposes of described compound, the insecticides that contains described compound and described preparation of compositions method and uses thereof.
European patent EP-B-179022 has instructed the compound of formula I type to be applicable to a lot of different insects of control.How the example controls particularly coleoptera, diptera and lepidopterous insect if disclosing.
Unexpected, and in view of above-mentioned open, the most unexpectedly find: in the chemical compound lot of quoting from EP-B-179022 and the many insect orders that can control with described desinsection compounds effective, formula I compound is particularly suitable for Pest Control, particularly Thripidae and perverse rust mite genus insect.
The control of above-mentioned insect is important for the user in insect control field, because if these insects can not be controlled comprehensively, and so for example will be owing to described insect for example causes very big financial loss to the damages of crops.
Within the scope of the present invention, preferable methods is the method for control the above-mentioned type insect, and this method comprises uses free formula I compound.
Equally preferably control the method for following insect:
(1) typical flower thrips belongs to,
Frankliniella occidentalis (Frankliniella occidentalis) particularly, the brown flower thrips of cigarette (Frankliniella fusca), wheat flower thrips (Frankliniella tritici), blueberry flower thrips (Frankliniella vaccinii), Franlkliniella bispinosa, frankliniella gossypiana, Frankliniella parvula, frankliniella robusta, Frankliniella schultzei, standing grain thrips (Frankliniella tenuicornis) and Frankliniella williamsi, more preferably Frankliniella occidentalis; Or
(2) typical thorn apple rust mite (Aculus schlechtendali), Lee sting rust mite (Aculus fockeui), tomato thorn rust mite (Aculus lycopersici), Aculusmasseii and aculus pelekassi, and
Thorn apple rust mite most preferably.
The formula I compound that the present invention uses is known, particularly is disclosed in EP-B-179022.
The formula I compound that the present invention uses is an agent for controlling noxious insect pests, and it has suitable prevention and cures characteristic under low concentration, and it is fully by warm blooded animal, fish and plant tolerance.The agent for controlling noxious insect pests that the present invention uses is effective to the above-mentioned insect of all or independent differentiation phase that is in common sensitivity or resistance phase.The agent for controlling noxious insect pests of the actual use of the present invention can directly produce biocidal activity, promptly after certain hour or only, after certain hour, kill off the insect pests immediately, for example when casting off a skin, perhaps can produce biocidal activity indirectly, for example reduction is laid eggs and/or is hatched ratio, corresponding to the good activity of at least 50% to 60% lethality rate.
Outstanding especially is the above-mentioned insect that this new method can be controlled the resistance door, the especially Frankliniella occidentalis of resistance door or thorn apple rust mite.
With being applicable to that agent for controlling noxious insect pests of the present invention especially can control (promptly suppress or destroy) in plant (particularly carry and cultivate thing or ornamental plants), agricultural, gardening and forestry or the above-mentioned insect that some parts (for example fruit, flower, leaf, stem, stem tuber or root) of some plants occurs, can also avoid the new first portion of plant to be subjected to the infringement of these insects simultaneously.
Particularly suitable purpose crop is cereal such as wheat, barley, rye, oat, paddy rice, corn or jowar; Beet such as sugar beet and fodder beet; Fruit such as the operatic circle, drupe and berry such as apple, pears, plum, peach, almond, cherry, strawberry, rasp berry, blueberry, redcurrants or blackberry, blueberry; Leguminous plant such as broad bean, lentil, pea and soybean; Oils plant such as rape, mustard seed, opium poppy, olive, sunflower, coconut, castor-oil plant, cocoa bean and peanut; Cucurbitaceous plant such as cucurbitaceae vegetable, cucumber, muskmelon; Fibre plant such as cotton, flax, hemp or jute; Citrus fruit such as oranges and tangerines, lemon, grape and mandarine; Vegetables such as spinach, lettuce, asparagus, wild cabbage, carrot, onion, tomato, potato and red pepper; Lauraceae such as avocado, cinnamon and camphor; Perhaps tobacco, nut, coffee, eggplant, sugarcane, tealeaves, pepper, vine, hop, banana, natural rubber plant and ornamental plants; More preferably the operatic circle, drupe and berry, cereal, cucurbit, cotton, citrus plant, vegetables, tomato, tobacco, banana or ornamental plants; Most preferably cucurbit, vegetables or ornamental plants.
An aspect of this new method particular importance is control
(1) vegetables are carried the Frankliniella occidentalis in cultivation and the ornamental plants; Perhaps
(2) thorn apple rust mite in the operatic circle, the particularly apple.
The further utilization that is applicable to agent for controlling noxious insect pests of the present invention is protection storage article or material, and at hygiene department (hygiene sector), particularly protects domestic animal or livestock to avoid the infringement of described insect.
Therefore, the invention still further relates to the insecticides that is used to prevent above-mentioned insect.According to above-mentioned purpose and main environment; said composition is emulsible concentrate, suspendible concentrate, emulsion that can directly spray or dilutable solution, the pastel that can be coated with, dilution, wettable powder, soluble powder, dispersible powder, powder, particle or or the capsule in polymeric material, said composition comprises at least a agent for controlling noxious insect pests of the present invention that is applicable to.
In these compositions, use active component with pure form, this solid chemical compound uses with specific granularity, and perhaps preferred assistant agent conventional at least a preparation technique is bulking agent such as solvent or solid carrier or surface active cpd (surfactant) use for example.
The solvent that is fit to is normally: aromatic hydrocarbon or partially hydrogenated aromatic hydrocarbon, preferably contain the alkylbenzene of 8-12 carbon atom, normally xylene mixture, alkylating naphthalene or tetrahydronaphthalene; Aliphatic hydrocarbon and cycloaliphatic hydrocarbon such as cyclohexane or paraffin; Alcohol is as ethanol, propyl alcohol or butanols; Glycols and ether thereof and ester such as propane diols, dipropylene glycol ether, diethylene glycol (DEG) or 2 one methyl cellosolves or cellosolvo; Ketone such as cyclohexanone, isophorone or diacetone alcohol; Intensity level solvent such as N-N-methyl-2-2-pyrrolidone N-, dimethyl sulfoxide (DMSO) or N, dinethylformamide; Water; Vegetable oil or epoxidized vegetable oil such as epoxidized oil rapeseed oil, castor oil, cocoa butter or soya-bean oil; Perhaps silicone oil.
Be generally used for powder and solid carrier that can the branch divided powder and be generally natural minerals filler such as calcite, talcum, kaolin, montmorillonite or U.S.'s atlapulgite (attapulgite).In order to improve physical property, can also add the silicic acid of high dispersive or the adsorpting polymerization thing of high dispersive.Suitable particle absorption carrier is a porous, comprises zeolite, brickbat, sepiolite or bentonite; The non-absorption carrier that is fit to is for example calcite or the such material of sand.In addition, can use a lot of other inorganic or organic granular material, particularly dolomite or comminuted plants residues.
According to the type of carrying out the preparation compound, suitable surface active cpd is nonionic, cationic and/or anionic surfactant or the surfactant mixtures with good emulsibility, dispersiveness and wetability.Should think that following listed surfactant only is for example; In pertinent literature, described in formulation art conventional that use and be applicable to more multilist surface-active agent of the present invention.
Non-ionic surface active agent is preferably aliphatic series or cycloaliphatic alcohol or polyglycol ether derivative saturated or unsaturated fatty acid and alkyl phenol, described derivative contains 3-30 glycol ether group and 8-20 carbon atom at (aliphatic series) hydrocarbyl portion, contains 6-18 carbon atom at the moieties of alkyl phenol.Contain the polyadduct of the alkyl polypropylene glycol of 1-10 carbon atom in polyadduct (polyadducts), ethylenediamine base polypropylene glycol and the alkyl chain that other anion surfactant that is fit to is water capacity PEO and polypropylene glycol, described polyadduct contains 20-250 ethylene glycol ether group and 10-100 propylene glycol group.These compounds contain 1-5 ethylene glycol unit/propane diols unit usually.The illustrative example of non-ionic surface active agent is polyadduct, polyethoxy tributyl phenol, polyethylene glycol and the polyethoxy octyl phenol of polyethoxy nonyl phenol (nonylphenolpolyethoxylates), polyethoxy castor oil, polypropylene and PEO.The fatty acid ester of polyethenoxy sorbitan also is suitable non-ionic surface active agent, particularly the polyethenoxy sorbitan trioleate.
The preferred quaternary ammonium salt of cationic surfactant, it has at least one C 8-C 22Alkyl is as substituting group, and substituting group also has other substituting group, and these substituting groups are unsubstituted or haloalkyl, benzyl or hydroxyl low-grade alkyl.This salt is preferably the form of halide, Methylsulfate or sulfovinate, for example chlorination stearyl trimethyl ammonium or bromination benzyl two (2-chloroethyl) ethyl ammonium.
Suitable anion surfactant can be water-soluble soap and water-soluble synthetic surface reactive compound.Suitable soap is higher fatty acid (C 10-C 22) or the ammonium salt of alkali metal salt, alkali salt, ammonium salt or the replacement of the natural acid mixture that particularly can obtain by cocoa butter or oil slick, as oleic acid or stearic acid sodium salt or sylvite.Other suitable soap is the fatty acid methyl taurate.But often use the benzimidizole derivatives or the alkylaryl sulfonate of so-called synthetic surfactant, particularly aliphatic sulfonate, aliphatic sulphate, sulfonation.Fatty alcohol sulphonic acid ester or glim use with the form of alkali metal salt, alkali salt, ammonium salt or substituted ammonium salt usually, and they contain a C usually 8-C 22Alkyl, this alkyl also comprises the moieties of aryl, for example the sodium salt or the calcium salt of lignosulphonic acid sodium salt or lignosulphonic acid calcium salt, lauryl sodium sulfate or dodecyl sulphate calcium or the glim mixture that obtains from natural acid.These compounds also comprise the salt of sulphation or sulfonated aliphatic alcohol/ethylene oxide adduct.Sulphonated benzimidazole derivative preferably contains 2 sulfonic groups and 1 and contains the fatty acid-based of 8-22 carbon atom.The illustrative example of alkylaryl sulfonate is sodium salt, calcium salt or the triethanolamine salt of DBSA, dibutyl naphthalene sulfonic acids or naphthalene sulfonic acids and formaldehyde condensation products.Corresponding phosphate normally also is suitable for the salt of the phosphate of nonyl phenol and 4-14mol ethylene oxide adduct or the salt of phosphatide.
Said composition contains the active component of 0.1-99% (weight), particularly 0.1-95% (weight) usually, and 1-99.9% (weight), the particularly solid of 5-99.9% (weight) or liquid assistant agent at least; Usually said composition contains 0-25%, particularly 0.1-20% surfactant.And the commercially available prod preferably is mixed with concentrate, and final user can use the dilution preparation that has the low concentration active component basically usually.Particularly preferred preparation is prepared as follows (%=percetage by weight): The concentrate of emulsification:Active component: 1-90%, preferred 5-20% surfactant 1-30%, preferred 10-20% solvent: 5-98%, preferred 70-85% Powder:Active component: 0.1-10%, preferred 0.1-1% solid carrier: 99.9-90%, preferred 99.9-99% The suspendible concentrate:Active component: 5-75%, preferred 10-50% water: 94-24%, preferred 88-30% surfactant: 1-40%, preferred 2-30% Wettable powder:Active component: 0.5-90%, preferred 1-80% surfactant: 0.5-20%, preferred 1-15% solid carrier: 5-99%, preferred 15-98% Particle:Active component: 0.5-30%, preferred 3-15% solid carrier: 99.5-70%, preferred 97-85%
The activity profile of new compositions is wide spectrum basically, and is suitable for most of environment by adding other agent for controlling noxious insect pests.The particularly following classes of compounds of suitable additive: organic phosphorus compound, nitrophenols and derivative thereof, carbonamidine, urea, carbamate, pyrethroid, chlorinated hydrocabon and Bacillus thuringiensis composition.This new compositions can also contain solid or liquid assistant agent, normally stabilizing agent such as vegetable oil or epoxidized vegetable oil (for example epoxidation cocoa butter, rapeseed oil or soya-bean oil), defoamer such as silicone oil, preservative, viscosity modifier, adhesive and/or tackifier and fertilizer or other compound (to obtain special effect), normally bactericide, fungicide, nematocide, mollusk lethal agent or selective herbicide.
This new compositions is by the preparation of known method, when not containing assistant agent, for example is prepared by grinding, sieve and/or solid active agent or its mixture being pressed into for example specific granularity; When containing at least a assistant agent,, active component or mixture and assistant agent be prepared by fully being mixed and/or grind.The invention still further relates to the above-mentioned method of new compositions and the purposes that formula I compound is used to prepare described composition of preparing.
Purpose of the present invention also comprises the method for using said composition, promptly control the method for above-mentioned insect, be generally spraying, atomizing, dusting, coating, cover, broadcast sowing or pour into, select application process according to application purpose and main environment, purpose of the present invention comprises that also said composition controls the purposes of above-mentioned insect.General applicating ratio is 0.1-1000ppm, preferred 0.1-500ppm active component.The preferred use contains 30,50,80,100,150 or the Spray Mixing thing of 200ppm concentration active component.Every mu amount of application is generally 1-2000 gram active component/mu, preferred 10-1000g/ mu, more preferably 20-600g/ mu.Use 300,400 and 450 gram active components for preferred every mu.Preferred every tree uses 0.25,0.75,1.0 or 2.0g.
Preferred application process is a foliage applying in the plant protection field.Frequency of using and applicating ratio depend on by the danger of concrete infest.But, can also by with the drenched plant of fluid composition vegetatively or with the active component of solid be applied to plant (for example in the soil) vegetatively, particularly be applied in the soil with particle form, make plant pass through root absorbing activity composition (system activity).
Following non-limiting examples is used to illustrate the present invention.Example of formulations (all percentage number averages by weight) Embodiment F 1: emulsible concentrateA) active component 25% 40% 50% dodecyl benzene sulfonic acid calcium 5% 8% 6% polyethoxy castor oil c b)), (36mol EO) 5%--the polyethoxy tributyl phenol, (30mol EO)-12% 4%, (tribulylphenol polyelhoxylate) cyclohexanone-15% 20% xylene mixture 65% 25% 20%
The emulsion that can prepare any desired concn by this concentrate of dilute with water. Embodiment F 2: solutionA) b) c) d) active component 80% 10% 5% 95%2-methyl cellosolve 20%---polyethylene glycol MG400-70%--N-N-methyl-2-2-pyrrolidone N--20%--epoxidation castor oil--1% 5% petroleum solvent (boiling point 160-190 ℃)--94%-
This solution is suitable for use as the droplet agent. Embodiment F 3; ParticleA) active component 5% 10% 8% 21% kaolin 94%-79% 54% high dispersive silica 1 %-13% 7% U.S.'s atlapulgite-90%-18% d c b)))
Active component is dissolved in the carrene, with this solution spray on carrier, solvent removed in vacuo then. Embodiment F 4: powderA) active component 2% 5% high dispersive silica 1 % 5% talcum 97%-kaolin-90% b)
Active component is acutely mixed the standby powder that obtains with carrier. Embodiment F 5: wettable powderA) c b)) active component 25% 50% 75% sodium lignosulfonate 5% 5%-bay sodium alkyl sulfate 3%-5% diisobutyl sodium naphthalene sulfonates-6% 10% polyethoxy octyl phenol (7-8mol EO)-2%-high dispersive silica 5% 10% 10% kaolin 62% 27%-
Active component is mixed with assistant agent, and will be from then on mixture on suitable grinding machine, fully grind, obtain wettable powder, can water its dilution be obtained the suspension of any desired concn. Embodiment F 6: emulsible concentrateActive component 10% polyethoxy octyl phenol (4-5mol EO) 3% dodecyl benzene sulfonic acid calcium, 3% polyethoxy castor oil (36mol EO) 4% cyclohexanone 30% xylene mixture 50%
The emulsion that can prepare any desired concn by this concentrate of dilute with water. Embodiment F 7: powderA) active component 5% 8% talcum 95%-kaolin-92% b)
Active component acutely mixed with carrier obtain standby powder. Embodiment F 8: the particle of extrudingActive component 10% sodium lignosulfonate 2% carboxymethyl cellulose 1% kaolin 87%
Active component is mixed with assistant agent, grind this mixture then, and use water-wet.With this mixture extruding, granulation, pneumatic conveying drying then. Embodiment F 9: coated particleActive component 3% polyethylene glycol (MG200) 3% kaolin 94%
In blender, levigate active component is applied to equably with on the wetting kaolin of polyethylene glycol.Obtain the particle that non-powdery applies thus. Embodiment F 10: suspension concentratesActive component 40% ethylene glycol, 10% polyethoxy nonyl phenol (15mol EO) 6% sodium lignosulfonate 10% carboxymethyl cellulose, 1%37% formalin, 0.2% silicone oil (75% aqueous emulsion) 0.8% water 32%
Levigate compound mixture acutely mixed obtaining suspension concentrates with assistant agent, its dilution can be prepared the suspension of any desired concn by water.Biology embodiment Embodiment B 1; The effect of anti-Frankliniella occidentalis
Red pepper in the greenhouse is grown in the Frankliniella occidentalis larva nymph (nymphs) and adult population of natural mixing, with 10 days interval it is sprayed 3 times until following with the Spray Mixing thing that contains 10g/hl formula I compound.Before treatment for the second time and after the treatment for the third time one day immediately nymph on the treatment plant and the nymph do not treated on the check plant are counted, and the minimizing of mensuration nymph number.10 days teleonymph numbers reduce by 92%, 21 day teleonymph number and reduce 97%.

Claims (10)

1. the method for Pest Control, this method comprise insect or habitat applying pesticide composition, and said composition contains free formula I compound Acarus tritici urea or the acceptable salt of its agrochemistry as active component With at least a assistant agent, described insect is (1) Thripidae insect; Perhaps (2) thorn rust mite belongs to insect.
2. according to the process of claim 1 wherein that formula I compound uses with free form.
3. according to the method for claim 1 or 2, be used to control flower thrips and belong to insect.
4. according to the method for claim 3, be used for Pest Control Frankliniella occidentalis (Frankliniella occidentalis), the brown flower thrips of cigarette (Frankliniella fusca), wheat flower thrips (Frankliniella tritici), blueberry flower thrips (Frankliniellavaccinii), Frankliniella bilpinosa, frankliniella gossypiana, Frankliniella parvula, Frankliniella robusta, Frankliniellaschultzei, standing grain thrips (Frankliniella tenuicornis) or Frankliniellawilliamsi.
5. according to the method for claim 1 or 2, be used for control thorn rust mite and belong to insect.
6. the insecticides that is used for claim 1 method, said composition contain free formula I compound Acarus tritici urea or the acceptable salt of its agrochemistry as active component With at least a assistant agent.
7. the composition of claim 6 contains free formula I compound.
8. claim 6 requires the preparation of compositions method, and this method comprises acutely mixes active component with assistant agent and/or grind.
9. the formula I compound Acarus tritici urea of free form or the acceptable salt form of agrochemistry is used to prepare the purposes of composition that claim 6 requires
10. the purposes of the desired composition of claim 6 in the method for claim 1.
CN95107356A 1994-06-09 1995-06-08 Method of controlling pests Expired - Fee Related CN1108749C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH01824/94A CH687732A5 (en) 1994-06-09 1994-06-09 A method for combating insects.
CH1824/94 1994-06-09
CH1824/1994 1994-06-09

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CN1120886A CN1120886A (en) 1996-04-24
CN1108749C true CN1108749C (en) 2003-05-21

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CH (1) CH687732A5 (en)
ES (1) ES2114791B1 (en)
FR (1) FR2720898B1 (en)
GR (1) GR950100226A (en)
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IT (1) IT1279007B1 (en)
NL (1) NL1000523C2 (en)
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NO312056B1 (en) * 1998-06-09 2002-03-11 Alpharma As Aquatic Animal Hea Use of preparations for the prevention and treatment of parasites in fish
AU3148599A (en) * 1999-04-15 2000-11-02 Consejo Superior De Investigaciones Cientificas Method for controlling a mediterranean fruit fly pest
GB201416633D0 (en) * 2014-09-19 2014-11-05 Pharmaq As Formulation
CN105116093B (en) * 2015-09-08 2017-03-22 山东省农业科学院农业质量标准与检测技术研究所 Fast analysis method for detecting lufenuron residues in apples and soil
KR20240027210A (en) 2022-08-22 2024-03-04 원태희 Bed type massage device
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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0179022A2 (en) * 1984-10-18 1986-04-23 Ciba-Geigy Ag Benzoylphenyl ureas

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0179022A2 (en) * 1984-10-18 1986-04-23 Ciba-Geigy Ag Benzoylphenyl ureas

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PT101719B (en) 1998-04-30
KR100402907B1 (en) 2003-12-31
PT101719A (en) 1995-12-29
PL308951A1 (en) 1995-12-11
GR950100226A (en) 1996-02-29
IT1279007B1 (en) 1997-12-02
KR960000024A (en) 1996-01-25
JPH07330524A (en) 1995-12-19
BE1008752A3 (en) 1996-07-02
BR9502723A (en) 1996-04-09
HUT71254A (en) 1995-11-28
ES2114791A1 (en) 1998-06-01
NL1000523C2 (en) 1995-12-11
ZA954733B (en) 1995-12-11
ITMI951213A1 (en) 1996-12-08
NZ272296A (en) 1997-11-24
ES2114791B1 (en) 1999-07-01
HU9501665D0 (en) 1995-07-28
ITMI951213A0 (en) 1995-06-08
HU217531B (en) 2000-02-28
FR2720898B1 (en) 1996-10-31
CN1120886A (en) 1996-04-24
FR2720898A1 (en) 1995-12-15
CH687732A5 (en) 1997-02-14

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