CN110862645A - Formula and preparation of spraying-free ABS alloy material with baking varnish imitated high-gloss black flashing effect - Google Patents
Formula and preparation of spraying-free ABS alloy material with baking varnish imitated high-gloss black flashing effect Download PDFInfo
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- CN110862645A CN110862645A CN201810985202.4A CN201810985202A CN110862645A CN 110862645 A CN110862645 A CN 110862645A CN 201810985202 A CN201810985202 A CN 201810985202A CN 110862645 A CN110862645 A CN 110862645A
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
- C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2425/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2425/02—Homopolymers or copolymers of hydrocarbons
- C08J2425/04—Homopolymers or copolymers of styrene
- C08J2425/08—Copolymers of styrene
- C08J2425/12—Copolymers of styrene with unsaturated nitriles
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- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2433/10—Homopolymers or copolymers of methacrylic acid esters
- C08J2433/12—Homopolymers or copolymers of methyl methacrylate
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2455/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2423/00 - C08J2453/00
- C08J2455/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2469/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C08K3/00—Use of inorganic substances as compounding ingredients
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- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
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Abstract
The invention discloses a formula and a preparation method of a spraying-free ABS alloy material with a baking varnish imitated high-gloss black flashing effect, wherein the formula of the ABS alloy material consists of color master batches and the ABS alloy material; the color master batch consists of carbon black (cabot and the like), oil black, dye red, dye yellow, dye blue, a dispersing agent and an AS or ABS carrier, and the color master batch comprises the following components in parts by weight: 10-30 parts of carbon black (cabot and the like); 10-20 parts of oil black; dye red, dye yellow, dye blue: 10-30 parts; 5-20 parts of a dispersing agent. The formula of the ABS alloy material disclosed by the invention consists of the color master batch and the ABS alloy material, so that the ABS alloy material does not need to be sprayed in the later use process, can be subjected to one-step injection molding, achieves the effect of no flow pattern and gorgeous scintillation, has the advantages of high product qualification rate, low cost, greenness, environmental friendliness, no emission of toxic and harmful gases caused by a spraying process, no pollution, energy conservation and high efficiency, improves the social value and economic value of the product, and accords with the benefits of enterprises.
Description
Technical Field
The invention relates to the technical field of high polymer materials, in particular to a formula and a preparation method of a spray-free ABS alloy material with a baking varnish imitated high-gloss black flashing effect.
Background
In order to improve the appearance effect and texture of a plastic product and prolong the service life of the product, the plastic product is generally required to be sprayed, however, the spraying process of the plastic product has many defects of high cost, low efficiency, low yield, great harm to human bodies and environment, easy shedding of a paint surface, influence on the product grade, difficult recovery of products and defective products and the like, the existing black colored plastic has the defect of insufficient material blackness, and the mirror surface effect of high light cannot be achieved even when the surface of the formed product is very flat, so that a formula of a spraying-free ABS alloy material with the effect of simulating high-gloss and black flashing of baking paint is provided.
Disclosure of Invention
The invention aims to provide a formula and a preparation method of a spraying-free ABS alloy material with a high-gloss black flashing effect of imitation baking varnish, so as to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: the formula of the spraying-free ABS alloy material with the baking varnish imitated high-gloss black flashing effect comprises color master batches and an ABS alloy material;
the color master batch consists of carbon black (cabot and the like), oil black, dye red, dye yellow, dye blue, a dispersing agent and an AS or ABS carrier, and the color master batch comprises the following components in parts by weight: 10-30 parts of carbon black (cabot and the like); 10-20 parts of oil black; dye red, dye yellow, dye blue: 10-30 parts; 5-20 parts of a dispersing agent; 50-70 parts of AS or ABS carrier;
the ABS alloy material consists of black color master batch, three-dimensional granular non-flaky metal powder, a compatilizer, an antioxidant, an ABS material, a PMMA material and a PC material, and comprises the following components in parts by weight: 4-8 parts of black color master batch; 2-8 parts of three-dimensional granular non-flaky metal powder; 0.1-0.3 part of a compatilizer; 0.1-0.8 part of antioxidant; 90-95 parts of ABS material, PMMA material and PC material.
Preferably, the preparation method comprises the following steps:
A. selecting high-concentration carbon black (Kabot, etc.), oil black, dye red, dye yellow, dye blue and ABS alloy materials;
B. preparing color master batches with special color effects by using a high-shear double screw rod so as to pre-disperse color materials;
C. selecting wear-resistant three-dimensional granular non-flaky metal powder, and using a double-screw side feeding system to reduce grinding of the three-dimensional granular non-flaky metal powder during melt blending, so as to ensure the texture of metal flicker;
D. the spraying-free ABS alloy material with the baking varnish-imitating high-brightness glittering effect is obtained through the steps of mixing, water bracing, drying, grain cutting and the like.
Preferably, the temperature of the double-screw extruder is controlled to be 240-280 ℃, and the particle size of the color master batch is 1.8-2.4 mm.
Preferably, the ABS alloy material comprises ABS/PMMA, ABS/PC and the like, and the plastic substrate also comprises pure ABS, PMMA, PC and the like.
Compared with the prior art, the invention has the following beneficial effects:
the formula of the ABS alloy material disclosed by the invention consists of the color master batch and the ABS alloy material, so that the ABS alloy material does not need to be sprayed in the later use process, can be subjected to one-step injection molding, achieves the effect of no flow pattern and gorgeous scintillation, has the advantages of high product qualification rate, low cost, greenness, environmental friendliness, no emission of toxic and harmful gases caused by a spraying process, no pollution, energy conservation and high efficiency, improves the social value and economic value of the product, and accords with the benefits of enterprises.
Drawings
FIG. 1 is a schematic diagram of a color masterbatch formulation form of the present invention;
FIG. 2 is a table of ABS alloy material compounding of the present invention;
FIG. 3 is a schematic flow chart of the method of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1-3, a formula of a spray-free ABS alloy material with high gloss and black flashing effect of imitation baking varnish, the formula of the ABS alloy material is composed of color master batch and ABS alloy material, so that the material does not need to be sprayed in the later use process, and can be injection molded once, so as to achieve the effect of no flow pattern and gorgeous flashing, and at the same time, the product has high qualification rate, lower cost, environmental protection, no emission of toxic and harmful gas caused by spraying process, no pollution, energy saving and high efficiency, thereby improving the social value and economic value of the product, and meeting the benefits of enterprises;
the color master batch consists of carbon black (cabot and the like), oil black, dye red, dye yellow, dye blue, a dispersing agent and an AS or ABS carrier, and the color master batch comprises the following components in parts by weight: 10-30 parts of carbon black (cabot and the like); 10-20 parts of oil black; dye red, dye yellow, dye blue: 10-30 parts; 5-20 parts of a dispersing agent; 50-70 parts of AS or ABS carrier;
the ABS alloy material consists of black color master batch, three-dimensional granular non-flaky metal powder, a compatilizer, an antioxidant, an ABS material, a PMMA material and a PC material, and comprises the following components in parts by weight: 4-8 parts of black color master batch; 2-8 parts of three-dimensional granular non-flaky metal powder; 0.1-0.3 part of a compatilizer; 0.1-0.8 part of antioxidant; 90-95 parts of ABS material, PMMA material and PC material.
The preparation method comprises the following steps:
A. selecting high-concentration carbon black (Kabot, etc.), oil black, dye red, dye yellow, dye blue and ABS alloy materials;
B. preparing color master batches with special color effects by using a high-shear double screw rod so as to pre-disperse color materials;
C. selecting wear-resistant three-dimensional granular non-flaky metal powder, and using a double-screw side feeding system to reduce grinding of the three-dimensional granular non-flaky metal powder during melt blending, so as to ensure the texture of metal flicker;
D. the spraying-free ABS alloy material with the baking varnish-imitating high-brightness glittering effect is obtained through the steps of mixing, water bracing, drying, grain cutting and the like.
The temperature of the double-screw extruder is controlled to be 240-280 ℃, and the particle size of the color master batch is 1.8-2.4 mm.
The ABS alloy material comprises ABS/PMMA, ABS/PC and the like, and the plastic base material also comprises pure ABS, PMMA, PC and the like.
When the ABS alloy material is used, the formula of the ABS alloy material consists of the color master batch and the ABS alloy material, so that the ABS alloy material does not need to be sprayed in the later use process, can be subjected to one-step injection molding, achieves the effect of no flow pattern and gorgeous scintillation, has the advantages of high product percent of pass, low cost, environmental friendliness, no emission of toxic and harmful gases caused by a spraying process, no pollution, energy conservation and high efficiency, improves the social value and the economic value of the product, and accords with the benefits of enterprises.
The related modules involved in the invention are all hardware invention modules or functional modules combining computer software programs or protocols with hardware in the prior art, and the computer software programs or the protocols involved in the functional modules are all known to those skilled in the art, and are not improvements of the invention; the improvement of the invention is the interaction relation or the connection relation among all the modules, namely the improvement of the integral structure of the invention, so as to solve the corresponding technical problems to be solved by the invention.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (4)
1. The formula of the spraying-free ABS alloy material with the baking varnish imitated high-gloss black flashing effect is characterized in that: the formula of the ABS alloy material consists of color master batches and the ABS alloy material;
the color master batch consists of carbon black (cabot and the like), oil black, dye red, dye yellow, dye blue, a dispersing agent and an AS or ABS carrier, and the color master batch comprises the following components in parts by weight: 10-30 parts of carbon black (cabot and the like); 10-20 parts of oil black; dye red, dye yellow, dye blue: 10-30 parts; 5-20 parts of a dispersing agent; 50-70 parts of AS or ABS carrier;
the ABS alloy material consists of black color master batch, three-dimensional granular non-flaky metal powder, a compatilizer, an antioxidant, an ABS material, a PMMA material and a PC material, and comprises the following components in parts by weight: 4-8 parts of black color master batch; 2-8 parts of three-dimensional granular non-flaky metal powder; 0.1-0.3 part of a compatilizer; 0.1-0.8 part of antioxidant; 90-95 parts of ABS material, PMMA material and PC material.
2. The preparation method of the spraying-free ABS alloy material with the simulated varnish high-gloss black flashing effect according to claim 1 is characterized in that: the preparation method comprises the following steps:
A. selecting high-concentration carbon black (Kabot, etc.), oil black, dye red, dye yellow, dye blue and ABS alloy materials;
B. preparing color master batches with special color effects by using a high-shear double screw rod so as to pre-disperse color materials;
C. selecting wear-resistant three-dimensional granular non-flaky metal powder, and using a double-screw side feeding system to reduce grinding of the three-dimensional granular non-flaky metal powder during melt blending, so as to ensure the texture of metal flicker;
D. the spraying-free ABS alloy material with the baking varnish-imitating high-brightness glittering effect is obtained through the steps of mixing, water bracing, drying, grain cutting and the like.
3. The preparation method of the spraying-free ABS alloy material with the simulated varnish high-gloss black flashing effect according to claim 2, is characterized in that: the temperature of the double-screw extruder is controlled to be 240-280 ℃, and the particle size of the color master batch is 1.8-2.4 mm.
4. The preparation method of the spraying-free ABS alloy material with the simulated varnish high-gloss black flashing effect according to claim 2, is characterized in that: the ABS alloy material comprises ABS/PMMA, ABS/PC and the like, and the plastic base material also comprises pure ABS, PMMA, PC and the like.
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| CN201810985202.4A CN110862645A (en) | 2018-08-28 | 2018-08-28 | Formula and preparation of spraying-free ABS alloy material with baking varnish imitated high-gloss black flashing effect |
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| CN201810985202.4A CN110862645A (en) | 2018-08-28 | 2018-08-28 | Formula and preparation of spraying-free ABS alloy material with baking varnish imitated high-gloss black flashing effect |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111995863A (en) * | 2020-07-09 | 2020-11-27 | 柏力开米复合塑料(昆山)有限公司 | PA/ABS alloy material based on pyrene ketone dye coloring |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106832838A (en) * | 2017-03-17 | 2017-06-13 | 金旸（厦门）新材料科技有限公司 | It is a kind of to polish in the 3D printing material and methods for making and using same of metal appearance |
| CN107474395A (en) * | 2017-09-21 | 2017-12-15 | 浙江百力塑业有限公司 | One kind exempts from painted plastic shell formula |
| CN107619544A (en) * | 2017-09-04 | 2018-01-23 | 珠海市南蓝塑胶科技有限公司 | Blue phase black agglomerate for AS or ABS and preparation method thereof |
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- 2018-08-28 CN CN201810985202.4A patent/CN110862645A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106832838A (en) * | 2017-03-17 | 2017-06-13 | 金旸（厦门）新材料科技有限公司 | It is a kind of to polish in the 3D printing material and methods for making and using same of metal appearance |
| CN107619544A (en) * | 2017-09-04 | 2018-01-23 | 珠海市南蓝塑胶科技有限公司 | Blue phase black agglomerate for AS or ABS and preparation method thereof |
| CN107474395A (en) * | 2017-09-21 | 2017-12-15 | 浙江百力塑业有限公司 | One kind exempts from painted plastic shell formula |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111995863A (en) * | 2020-07-09 | 2020-11-27 | 柏力开米复合塑料(昆山)有限公司 | PA/ABS alloy material based on pyrene ketone dye coloring |
| CN111995863B (en) * | 2020-07-09 | 2022-12-02 | 柏力开米复合塑料(昆山)有限公司 | PA/ABS alloy material based on pyrene ketone dye coloring |
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Application publication date: 20200306 |