CN110844993A - Composite oxygen increasing agent and preparation method thereof - Google Patents

Composite oxygen increasing agent and preparation method thereof Download PDF

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Publication number
CN110844993A
CN110844993A CN201911206622.9A CN201911206622A CN110844993A CN 110844993 A CN110844993 A CN 110844993A CN 201911206622 A CN201911206622 A CN 201911206622A CN 110844993 A CN110844993 A CN 110844993A
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China
Prior art keywords
parts
oxygen increasing
increasing agent
sodium
composite oxygen
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CN201911206622.9A
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Chinese (zh)
Inventor
汤广斌
刘旭
王恩伟
郑强
李保华
赵梦溪
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HENAN JUNHUA DEVELOPMENT Co Ltd
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HENAN JUNHUA DEVELOPMENT Co Ltd
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Priority to CN201911206622.9A priority Critical patent/CN110844993A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K63/00Receptacles for live fish, e.g. aquaria; Terraria
    • A01K63/04Arrangements for treating water specially adapted to receptacles for live fish
    • A01K63/042Introducing gases into the water, e.g. aerators, air pumps
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007Contaminated open waterways, rivers, lakes or ponds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/20Nature of the water, waste water, sewage or sludge to be treated from animal husbandry

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Animal Husbandry (AREA)
  • Health & Medical Sciences (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Medicinal Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention belongs to the technical field of aquaculture, and particularly relates to a composite oxygen increasing agent and a preparation method thereof. The composite oxygen increasing agent comprises 40-60 parts of sodium percarbonate, 10-15 parts of a microbial preparation, 5-10 parts of an adhesive, 3-8 parts of a stabilizer, 2-5 parts of a slow-release cosolvent and 1.5-5 parts of a synergist. The composite oxygen increasing agent has the special effect of three-dimensional oxygen increasing, effectively increases dissolved oxygen in water, has better oxygen increasing stability and durability, improves the oxygen increasing efficiency, fundamentally solves the problem of oxygen deficiency of the bottom layer of a pond, can inhibit the growth of anaerobic bacteria on the bottom layer, adsorbs and degrades nitrite, ammonia nitrogen, hydrogen sulfide and other harmful substances, simultaneously hinders the increase of pathogenic bacteria, improves the immunity of aquatic animals, effectively improves the problem of water quality deterioration, and creates a good environment of the bottom layer of the pond.

Description

Composite oxygen increasing agent and preparation method thereof
Technical Field
The invention belongs to the technical field of aquaculture, and particularly relates to a composite oxygen increasing agent and a preparation method thereof.
Background
The aquaculture industry is an important component in economic activities in China, the improvement of the aquatic supply can meet the living needs of people, the living standard of people is improved, when aquaculture is carried out in a pond, the problem of poor water quality due to the fact that the flow of a water body is not smooth easily caused by the sealing property of the pond, the oxygen content of the water body can be increased by adopting a mechanical oxygen increasing mode for improving the problem of poor water quality, but the method can only increase the dissolved oxygen on the surface of the water body, the contents of residual baits, excrement and silt at the bottom of the aquaculture pond are more, meanwhile, the contents of toxic substances such as ammonia nitrogen, nitrite, hydrogen sulfide and the like are higher, and the water quality of the water body can be continuously deteriorated. In order to improve water quality, an oxygen increasing agent is added into water, wherein the oxygen increasing agent mainly comprises a disinfection component and a microbial preparation, but the microbial preparation can only play a role under aerobic conditions, and the dissolved oxygen at the bottom of a pool is low, so that the microbial preparation cannot play a role, and fish and shrimp are anoxic and even die, and therefore the existing oxygen increasing agent needs to be further improved.
Disclosure of Invention
The invention aims to provide a composite oxygen increasing agent which has good oxygen increasing effect, improves water quality deterioration and is convenient to produce and a preparation method thereof.
Based on the purpose, the invention adopts the following technical scheme:
the composite oxygen increasing agent comprises the following raw materials in parts by weight: 40-60 parts of sodium percarbonate, 10-15 parts of microbial preparation, 5-10 parts of adhesive, 3-8 parts of stabilizer, 2-5 parts of slow-release cosolvent and 1.5-5 parts of synergist.
Further, the microbial preparation is at least one of ferment bacteria, bacillus, lactobacillus and photosynthetic bacteria.
Further, the adhesive is prepared by mixing dextrin, starch and water, wherein the mass volume ratio of the dextrin to the starch to the water is 0.1-0.5 g: 0.1-0.8 g: 3-5 mL.
Further, the stabilizer is at least one of sodium silicate, magnesium chloride, magnesium stearate, polyacrylamide, sodium polyphosphate, sodium citrate, sodium tartrate, sodium gluconate and sodium stannate.
Further, the slow-release cosolvent is carboxymethyl cellulose and/or hydroxypropyl methyl cellulose.
Further, the synergist is at least one of sodium dodecyl benzene sulfonate, sodium dodecyl sulfate, alkylphenol ethoxylates, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid-polyoxyethylene ether, fatty acid methyl ester polyoxyethylene ether and polysorbate.
Further, the composite oxygen increasing agent is prepared by the following steps: uniformly mixing sodium percarbonate, a microbial preparation, an adhesive, a stabilizer, a slow-release cosolvent and a synergist, and extruding the mixture into a sheet or a column at the temperature of 10-70 ℃ to obtain a finished product.
The composite oxygen increasing agent and the preparation method thereof provided by the invention have the following beneficial effects:
(1) the composite oxygen increasing agent is sunk into the bottom of the pond and reacts with water to generate oxygen, a large amount of micro oxygen bubbles can be effectively dissolved in a water body in the rising process to increase oxygen for the bottom layer and middle and lower layers of the water body of the pond, the special effect of three-dimensional oxygen increasing is really achieved, the composite oxygen increasing agent has good oxygen increasing stability and durability, the oxygen increasing efficiency is improved, and the problem of oxygen deficiency of the bottom layer of the pond is fundamentally solved.
(2) The composite oxygen increasing agent can also inhibit the growth of bottom layer anaerobic bacteria, adsorb and degrade nitrite, ammonia nitrogen, hydrogen sulfide and other harmful substances, simultaneously obstruct the increase of pathogenic bacteria, improve the immunity of aquatic animals, effectively improve the problem of water quality deterioration, and create a good pool bottom environment.
(3) The preparation method can well compound various components with different effects, and can prevent sodium percarbonate from decomposing due to overhigh temperature by extruding at 10-70 ℃.
Detailed Description
Example 1:
a composite oxygen increasing agent comprises 40 parts of sodium percarbonate, 10 parts of a microbial preparation, 5 parts of an adhesive, 3 parts of a stabilizer, 2 parts of a slow-release cosolvent and 1.5 parts of a synergist.
The microbial preparation is photosynthetic bacteria, the adhesive is prepared by mixing dextrin, starch and water, and the mass volume ratio of the dextrin to the starch to the water is 0.1 g: 0.1 g: 3mL, the stabilizer is sodium polyphosphate, the slow-release cosolvent is carboxymethyl cellulose, and the synergist is sodium dodecyl benzene sulfonate and sodium dodecyl sulfate.
A preparation method of a composite oxygen increasing agent comprises the following steps: the sodium percarbonate, the microbial preparation, the adhesive, the stabilizer, the slow-release cosolvent and the synergist are put into a stirring kettle together for stirring and mixing, the stirring kettle is connected with a refrigerating device, the stirring speed is 60r/min, the uniform mixed material is obtained after stirring for 30min and then enters an extruder for extrusion, the extruder is connected with the refrigerating device, the extrusion temperature of the extruder is 10 ℃, and the mixed material is extruded into sheets.
Example 2:
a composite oxygen increasing agent comprises 50 parts of sodium percarbonate, 12.5 parts of microbial preparation, 7.5 parts of adhesive, 5.5 parts of stabilizer, 3.5 parts of slow-release cosolvent and 3.25 parts of synergist.
The microbial preparation is prepared from ferment bacteria and bacillus according to the mass ratio of 1g to 1g, the adhesive is prepared by mixing dextrin, starch and water, and the mass volume ratio of the dextrin to the starch to the water is 0.3 g: 0.45 g: 4mL, the stabilizing agent is sodium silicate, magnesium silicate and magnesium chloride, the slow-release cosolvent is hydroxypropyl methyl cellulose, and the synergist is alkylphenol polyoxyethylene ether.
A preparation method of a composite oxygen increasing agent comprises the following steps: the sodium carbonate, the microbial preparation, the adhesive, the stabilizer, the slow-release cosolvent and the synergist are put into a stirring kettle together to be stirred and mixed, the stirring speed is 60r/min, the uniform mixed material is obtained after stirring for 30min, the uniform mixed material enters an extruder to be extruded, the extrusion temperature of the extruder is 40 ℃, and the mixed material is extruded into a column shape.
Example 3:
a composite oxygen increasing agent comprises 60 parts of sodium percarbonate, 15 parts of microbial preparation, 10 parts of adhesive, 8 parts of stabilizer, 5 parts of slow-release cosolvent and 5 parts of synergist.
The microbial preparation is lactobacillus, the adhesive is prepared by mixing dextrin, starch and water, and the mass volume ratio of the dextrin to the starch to the water is 0.5 g: 0.8 g: 5mL, the stabilizing agent is sodium citrate, sodium tartrate and sodium gluconate, the slow-release cosolvent is carboxymethyl cellulose and hydroxypropyl methyl cellulose, and the synergist is fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid-polyoxyethylene ether and polysorbate.
A preparation method of a composite oxygen increasing agent comprises the following steps: putting sodium carbonate, a microbial preparation, an adhesive, a stabilizer, a slow-release cosolvent and a synergist into a stirring kettle, stirring and mixing at a stirring speed of 60r/min for 30min to obtain a uniform mixed material, and finally extruding the uniform mixed material into an extruder at an extrusion temperature of 70 ℃, wherein the mixed material is extruded into a column shape.
Test example 1:
shrimp pond experiment: 3 thousands of shrimps are released per mu, the shrimp larvae are about 1.2 cm in size, the composite oxygen increasing agent prepared in the embodiment 1 is applied every 20 days after one month of releasing, the dosage is 220g each time, the water quality of the pond is obviously improved, and after 3 months, the dissolved oxygen content of the water body at the bottom of the pond is detected to be 6.20mg/L, the ammonia nitrogen content is 0.17mg/L, the hydrogen sulfide content is 0.08mg/L, and no diseases are caused.
Test example 2:
fish pond experiments: 1500 carp fries per mu are thrown and matched with 20 percent of chub fries, the composite oxygenation agent prepared in the embodiment 2 is applied every 15 days after stocking for one month, the dosage is 250g each time, after 5 months, the dissolved oxygen content is detected to be 5.75mg/L, the ammonia nitrogen content is detected to be 0.08mg/L, the nitrosonitrogen content is detected to be 1.24mg/L, the hydrogen sulfide content is detected to be 0.10mg/L, and no diseases occur.
The composite oxygen increasing agent provided by the invention can effectively increase the dissolved oxygen content of a water body, has better oxygen increasing stability and durability, and can reduce the content of harmful substances such as nitrite, ammonia nitrogen, hydrogen sulfide and the like, thereby improving the problem of water quality deterioration and creating a good pool bottom environment.

Claims (7)

1. The composite oxygen increasing agent is characterized by comprising the following raw materials in parts by weight: 40-60 parts of sodium percarbonate, 10-15 parts of microbial preparation, 5-10 parts of adhesive, 3-8 parts of stabilizer, 2-5 parts of slow-release cosolvent and 1.5-5 parts of synergist.
2. The composite oxygen increasing agent as claimed in claim 1, wherein the microbial preparation is at least one of ferment bacteria, bacillus, lactobacillus and photosynthetic bacteria.
3. The composite oxygen increasing agent as claimed in claim 1, wherein the binder is prepared by mixing dextrin, starch and water, and the mass volume ratio of the dextrin to the starch to the water is 0.1-0.5 g: 0.1-0.8 g: 3-5 mL.
4. The compound oxygen increasing agent as claimed in claim 1, wherein the stabilizer is at least one of sodium silicate, magnesium chloride, magnesium stearate, polyacrylamide, sodium polyphosphate, sodium citrate, sodium tartrate, sodium gluconate, and sodium stannate.
5. The composite oxygen increasing agent as claimed in claim 1, wherein the slow-release cosolvent is carboxymethyl cellulose and/or hydroxypropyl methyl cellulose.
6. The composite oxygen increasing agent as claimed in claim 1, wherein the synergist is at least one of sodium dodecyl benzene sulfonate, sodium dodecyl sulfate, alkylphenol ethoxylates, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid-polyoxyethylene ether, fatty acid methyl ester polyoxyethylene ether and polysorbate.
7. The method for preparing the composite oxygen increasing agent according to claim 1, wherein the composite oxygen increasing agent is prepared by the following steps: uniformly mixing sodium percarbonate, a microbial preparation, an adhesive, a stabilizer, a slow-release cosolvent and a synergist, and extruding the mixture into a sheet or a column at the temperature of 10-70 ℃ to obtain a finished product.
CN201911206622.9A 2019-11-29 2019-11-29 Composite oxygen increasing agent and preparation method thereof Pending CN110844993A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111807327A (en) * 2020-07-22 2020-10-23 濮阳宏业环保技术研究院有限公司 Aquaculture oxygenation agent

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU4096400A (en) * 1999-04-26 2000-11-10 Ivan Macdonald Water oxygenation and system of aquaculture
CN1493188A (en) * 2003-08-26 2004-05-05 无锡中顺生物技术有限公司 Non powdered preparation water body aeration agent and its production method
CN101525164A (en) * 2009-04-20 2009-09-09 河北科技大学 Sodium percarbonate preparation used for water fast oxygenation and disinfection and preparation method thereof
CN104671433A (en) * 2015-02-09 2015-06-03 华南理工大学 Compound microbiological oxygenate for removing ammonia nitrogen in aquatic water and preparation method of compound microbiological oxygenate
CN104828955A (en) * 2015-05-05 2015-08-12 山东宝来利来生物工程股份有限公司 Biological composite oxygen producer and preparation method thereof
CN109626554A (en) * 2019-01-16 2019-04-16 合肥工业大学 A kind of preparation method of the solid oxygen particle with slow-release oxygen function

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU4096400A (en) * 1999-04-26 2000-11-10 Ivan Macdonald Water oxygenation and system of aquaculture
CN1493188A (en) * 2003-08-26 2004-05-05 无锡中顺生物技术有限公司 Non powdered preparation water body aeration agent and its production method
CN101525164A (en) * 2009-04-20 2009-09-09 河北科技大学 Sodium percarbonate preparation used for water fast oxygenation and disinfection and preparation method thereof
CN104671433A (en) * 2015-02-09 2015-06-03 华南理工大学 Compound microbiological oxygenate for removing ammonia nitrogen in aquatic water and preparation method of compound microbiological oxygenate
CN104828955A (en) * 2015-05-05 2015-08-12 山东宝来利来生物工程股份有限公司 Biological composite oxygen producer and preparation method thereof
CN109626554A (en) * 2019-01-16 2019-04-16 合肥工业大学 A kind of preparation method of the solid oxygen particle with slow-release oxygen function

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* Cited by examiner, † Cited by third party
Title
汪多仁编著: "《现代日用化工产品》", 冶金工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111807327A (en) * 2020-07-22 2020-10-23 濮阳宏业环保技术研究院有限公司 Aquaculture oxygenation agent

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