CN110820319A - 一种基于纳米石墨烯的精蜡带及其制备方法 - Google Patents
一种基于纳米石墨烯的精蜡带及其制备方法 Download PDFInfo
- Publication number
- CN110820319A CN110820319A CN201910953969.3A CN201910953969A CN110820319A CN 110820319 A CN110820319 A CN 110820319A CN 201910953969 A CN201910953969 A CN 201910953969A CN 110820319 A CN110820319 A CN 110820319A
- Authority
- CN
- China
- Prior art keywords
- parts
- wax
- graphene
- powder
- composite material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 93
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000001993 wax Substances 0.000 claims abstract description 124
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 100
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000002131 composite material Substances 0.000 claims abstract description 47
- 239000007788 liquid Substances 0.000 claims abstract description 46
- -1 polyethylene Polymers 0.000 claims abstract description 34
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 32
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 32
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims abstract description 32
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 30
- 239000004698 Polyethylene Substances 0.000 claims abstract description 24
- 229920000573 polyethylene Polymers 0.000 claims abstract description 24
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 22
- 239000010439 graphite Substances 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 22
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 16
- 239000005639 Lauric acid Substances 0.000 claims abstract description 16
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 16
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 16
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 16
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000010445 mica Substances 0.000 claims abstract description 16
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 16
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 16
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000012188 paraffin wax Substances 0.000 claims abstract description 16
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 16
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 16
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 16
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 16
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 16
- 239000011863 silicon-based powder Substances 0.000 claims abstract description 16
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 16
- 239000003549 soybean oil Substances 0.000 claims abstract description 16
- 239000003381 stabilizer Substances 0.000 claims abstract description 16
- 239000008117 stearic acid Substances 0.000 claims abstract description 16
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 16
- 229940045860 white wax Drugs 0.000 claims abstract description 16
- 239000011787 zinc oxide Substances 0.000 claims abstract description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 15
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 15
- 239000003921 oil Substances 0.000 claims abstract description 15
- 235000019198 oils Nutrition 0.000 claims abstract description 15
- 239000004014 plasticizer Substances 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 239000002250 absorbent Substances 0.000 claims abstract description 12
- 230000002745 absorbent Effects 0.000 claims abstract description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000001035 drying Methods 0.000 claims abstract description 8
- 239000000835 fiber Substances 0.000 claims description 29
- 239000011259 mixed solution Substances 0.000 claims description 10
- 238000007670 refining Methods 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 239000004743 Polypropylene Substances 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 229920001155 polypropylene Polymers 0.000 claims description 9
- 239000004745 nonwoven fabric Substances 0.000 claims description 8
- 238000005096 rolling process Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 238000002791 soaking Methods 0.000 claims description 7
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000003825 pressing Methods 0.000 claims description 5
- LGERWORIZMAZTA-UHFFFAOYSA-N silicon zinc Chemical compound [Si].[Zn] LGERWORIZMAZTA-UHFFFAOYSA-N 0.000 claims description 5
- 235000010215 titanium dioxide Nutrition 0.000 claims description 5
- 235000014692 zinc oxide Nutrition 0.000 claims description 5
- 239000006096 absorbing agent Substances 0.000 claims description 4
- 235000010216 calcium carbonate Nutrition 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 13
- 239000003063 flame retardant Substances 0.000 abstract description 12
- 239000002861 polymer material Substances 0.000 abstract description 3
- 238000007598 dipping method Methods 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 description 11
- 239000004927 clay Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000007797 corrosion Effects 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 230000001788 irregular Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 230000004224 protection Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000005536 corrosion prevention Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/47—Oxides or hydroxides of elements of Groups 5 or 15 of the Periodic Table; Vanadates; Niobates; Tantalates; Arsenates; Antimonates; Bismuthates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明提供一种基于纳米石墨烯的精蜡带及其制备方法,涉及高分子材料领域。此精蜡带由柔性载体浸渍在复合材料液中一定时间后,干燥、卷曲后形成的卷材;其中,按照重量份数计,复合材料液的原料包括:聚乙烯蜡5~30份、石蜡50~90份、月桂酸0.2~1份、氧化锌、10~30份、甘油0.5~5份、环氧大豆油0.2~1份、稳定剂0.2~3份、增塑剂10~40份、石墨1~10份、石墨烯1~10份、聚乙烯吡咯烷酮5~15份、微精蜡40~85份、硬脂酸0.2~0.5份、钛白粉10~25份、碳酸钙10~20份、高岭土5~15份、滑石粉3~13份、白蜡油1~15份、铝粉3~15份、锌粉2~10份、云母云5~25份、二氧化硅5~25份、三氧化锑2~15、磷铁锌硅粉2~15份、磷铁粉2~15份、UV吸收剂0.1~0.5份、消泡剂0.1~0.5份。本发明提供的精蜡带具有良好的防水、防腐和阻燃性能。
Description
技术领域
本发明涉及高分子新材料领域,且特别涉及一种基于纳米石墨烯的精蜡带及其制备方法。
背景技术
随着时间的流逝,很多建筑物和机械设备均会因为水、酸(雨水)、火等因素而减少了使用年限。随着人们对建筑物和机械设备使用年限的要求越来越高,人们对防水、防腐、阻燃材料质量的要求也越来越重视。
当前,随着高分子防水材料研发技术及配套设施的研究和完善,高分子材料应用于建筑物和机械设备领域的防水、防腐、阻燃功能方面越来越备受青睐。其中,高分子卷材是公认的性能优异,且可常温施工、不需要热熔施工的的防水材料,被广泛应用于工业和民用建筑领域中。但一般的高分子卷材均含有黏土填料,用于提高卷材的可塑性,更适于建筑的防水、防腐要求。但正是添加了黏土材料,使卷材易硬化,耐环境开裂性较差,特别是热氧化作用会使其性能下降。
因此,需要一种可综合耐温性、防水性、防腐性、耐候性、施工性能的卷材,用以满足建筑领域的防水、防腐需求。
发明内容
本发明的目的在于提供一种基于纳米石墨烯的精蜡带,此精蜡带具有优良的防水性、防腐性和阻燃性能,且该精蜡带具有的高含量与黏土触感相同的精蜡,使其可更适于不规则的建筑物及机械设备,且不会和黏土一样发生干枯断裂现象。
本发明的另一目的在于提供一种基于纳米石墨烯的精蜡带的制备方法,该制备方法简单。
本发明解决其技术问题是采用以下技术方案来实现的。
本发明提出一种基于纳米石墨烯的精蜡带,所述精蜡带由柔性载体浸渍在复合材料液中一定时间后,干燥、卷曲后形成的卷材;
其中,按照重量份数计,所述复合材料液的原料包括:聚乙烯蜡5~30份、石蜡50~90份、月桂酸0.2~1份、氧化锌10~30份、甘油0.5~5份、环氧大豆油0.2~1份、稳定剂0.2~3份、增塑剂10~40份、石墨1~10份、石墨烯1~10份、聚乙烯吡咯烷酮5~15份、微精蜡40~85份、硬脂酸0.2~0.5份、钛白粉10~25份、碳酸钙10~20份、高岭土5~15份、滑石粉3~13份、白蜡油1~15份、铝粉3~15份、锌粉2~10份、云母云5~25份、二氧化硅5~25份、三氧化锑2~15、磷铁锌硅粉2~15份、磷铁粉2~15份、UV吸收剂0.1~0.5份、消泡剂0.1~0.5份。
进一步地,按照重量份数计,所述复合材料液的原料包括:
所述聚乙烯蜡7~25份、所述石蜡55~85份、所述月桂酸0.5~0.8份、所述氧化锌12~28份、所述甘油1~4.5份、所述环氧大豆油0.5~0.8份、所述稳定剂0.5~2.5份、所述增塑剂13~30份、所述石墨1.5~8.5份、所述石墨烯1.5~8.5份、所述聚乙烯吡咯烷酮8~13份、所述微精蜡55~80份、所述硬脂酸0.25~0.45份、所述钛白粉12~20份、所述碳酸钙11~18份、所述高岭土8~10份、所述滑石粉5~10份、所述白蜡油3~12份、所述铝粉5~10份、所述锌粉5~8份、所述云母云8~22份、二氧化硅8~22份、所述三氧化锑5~10、所述磷铁锌硅粉5~10份、所述磷铁粉5~10份、所述UV吸收剂0.15~0.45份以及所述消泡剂0.15~0.45份。
进一步地,所述柔性载体为聚丙烯纤维、聚丙烯腈纤维、聚乙烯纤维或者聚酯化学纤维制成的无纺布。
进一步地,所述聚丙烯纤维、聚丙烯腈纤维、聚乙烯纤维或者聚酯化学纤维的单丝为2D~6D,所述柔性载体的拉力强度为50~100kN/m,拉伸率小于30%。
进一步地,所述柔性载体的厚度为0.1~0.4mm、宽度为1~30英寸、強度为100~400g/㎡
进一步地,所述石墨烯为氧化型石墨烯和天然型石墨烯的一种或多种。
进一步地,所述精蜡带的耐高温范围为50~250℃。
本发明还提供了一种上述的基于纳米石墨烯的精蜡带的制备方法,包括以下步骤:
S1,制备复合材料液;
S2,将柔性载体裁剪成合适尺寸后,在90~150℃条件下,将所述柔性载体浸渍在所述复合材料液中0.5~2min,获得预制体;
S3,将所述预制体通过压严、干燥步骤后,卷成圆形获得所述精蜡带。
进一步地,所述复合材料液的制备过程包括以下步骤:
S11,按照原料之间的配比,将聚乙烯蜡、石蜡、月桂酸、甘油、环氧大豆油、稳定剂、增塑剂、聚乙烯吡咯烷酮、微精蜡、硬脂酸、白蜡油于于150~200℃的温度下进行混合加热45~75min直至完全熔融,获得初制混合液;
S12,在所述初制混合液中加入石墨及石墨烯直至完全熔融;
S13,再加入氧化锌、钛白粉、碳酸钙、高岭土、滑石粉、铝粉、锌粉、云母云、二氧化硅、三氧化锑、磷铁锌硅粉、磷铁粉继续混练30~60min分钟;
S14,最后加入UV吸收剂以及消泡剂再熔融10~30min分钟后,静置2h,获得所述复合材料液。
本发明实施例的一种基于纳米石墨烯的精蜡带及其制备方法的有益效果是:首先本发明提供的精蜡带含有高含量与黏土触感相同的精蜡,使其可更适于不规则的建筑物及机械设备,且不会和黏土一样发生干枯断裂现象。除此之外,本发明的精蜡带采用非针织无纺布作为柔性载体材料,充分浸润在复合材料液中,一方面加强了精蜡带的拉伸与断裂性能;另一方面则为复合材料液提供了载体,使其不仅可更好地包覆在不规则的曲面异型物上,且包覆的厚度可控。除此之外,本发明的复合材料中还加入天然型石墨烯和氧化型石墨烯,石墨烯的二维片层结构使其能够在熔融共混中形成致密物理隔绝层,达到明显的物理性隔绝作用,提高材料的隔热,亦达到阻燃性能。而且本发明提供的精蜡带可进行裁剪,施工条件简单。
附图说明
为了更清楚地说明本发明实施例的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,应当理解,以下附图仅示出了本发明的某些实施例,因此不应被看作是对范围的限定,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他相关的附图。
图1为本发明提供的基于纳米石墨烯的精蜡带的制备方法的流程图;
图2为本发明提供的基于纳米石墨烯的精蜡带的制备方法的结构流程示意图;
图3为本发明提供的基于纳米石墨烯的精蜡带的实物图。
附图标记:1-柔性载体;2-复合材料液。
具体实施方式
为使本发明实施例的目的、技术方案和优点更加清楚,下面将对本发明实施例中的技术方案进行清楚、完整地描述。实施例中未注明具体条件者,按照常规条件或制造商建议的条件进行。所用试剂或仪器未注明生产厂商者,均为可以通过市售购买获得的常规产品。
下面对本发明实施例提供的一种基于纳米石墨烯的精蜡带及其制备方法进行具体说明。
以下结合实施例对本发明的特征和性能作进一步的详细描述。
本发明提供了一种基于纳米石墨烯的精蜡带,精蜡带由柔性载体1浸渍在复合材料液2中一定时间后,干燥、卷曲后形成的卷材;
其中,按照重量份数计,复合材料液2的原料包括:聚乙烯蜡5~30份、石蜡50~90份、月桂酸0.2~1份、氧化锌、10~30份、甘油0.5~5份、环氧大豆油0.2~1份、稳定剂0.2~3份、增塑剂10~40份、石墨1~10份、石墨烯1~10份、聚乙烯吡咯烷酮5~15份、微精蜡40~85份、硬脂酸0.2~0.5份、钛白粉10~25份、碳酸钙10~20份、高岭土5~15份、滑石粉3~13份、白蜡油1~15份、铝粉3~15份、锌粉2~10份、云母云5~25份、二氧化硅5~25份、三氧化锑2~15、磷铁锌硅粉2~15份、磷铁粉2~15份、UV吸收剂0.1~0.5份、消泡剂0.1~0.5份。
本发明提供的基于纳米石墨烯的精蜡带,通过添加聚乙烯蜡、石蜡、微精蜡以及白蜡油等蜡质材料以及月桂酸、甘油、环氧大豆油和硬脂酸等脂质材料,制备形成与黏土触感性质相似的精蜡,且该精蜡带具有高含量的上述精蜡,因为这种精蜡本身的触感与黏土的极为相似,施工时不需特殊的器械进行加热即可使用。且因其具备与黏土相似的特性,使精蜡带可以包覆在不规则的曲面异形物表面,更适于不同建筑物与机械设备的包裹。此外,精蜡具备的高燃点,使精蜡带具备了高阻燃性能。而石墨烯是一种由碳原子构成的单层片状结构的二维材料,其片层结构可层层叠加,交错排列,在复合材料液2中可以形成“迷宫式”的屏蔽结构,从而能够有效地抑制腐蚀介质(水、酸)的浸润、渗透以及扩散,因此其可提高精蜡带的防水、防腐性能。此外,本发明采用的是纳米石墨烯,其具备小尺寸效应,可以填充到复合材料液2的缺陷中,减少精蜡带的孔隙率,增强致密性,进一步延缓和阻止腐蚀因子的侵蚀。且石墨烯的片层结构可以将复合材料液2分割成许多小区间,能够有效降低精蜡带内部的应力,进而提升精蜡带的柔韧性、抗冲击性以及耐磨性。聚乙烯吡咯烷酮和稳定剂则可以防止石墨烯团聚,加强石墨烯分散效果,提高石墨烯性能。而氧化锌、钛白粉、高岭土、滑石粉、锌粉、云母云、二氧化硅、三氧化锑、磷铁锌硅粉、磷铁粉这些材料在作为精蜡带填充材料,使精蜡带在增强韧性,提高阻燃性能的同时,锌元素可提高精蜡带的成膜性能。锌元素在空气的氧化下,形成一层氧化薄膜,该薄膜可隔绝水分与空气并填补缝隙与毛孔以确保精蜡带紧密贴覆,而不接触空气的精蜡带内部则不会干枯硬化,从而进一步避免了崩裂现象的发生。UV吸收剂则可以吸收紫外线,防止精蜡带干固,进一步提升精蜡带的粘弹性与耐候性能,使其可在户外耐候20年以上。而消泡剂则可以出去复合材料液2中的气泡,增加材料与材料之间的紧密性,减少精蜡带的空隙。
进一步地,按照重量份数计,复合材料液2的原料包括:
聚乙烯蜡7~25份、石蜡55~85份、月桂酸0.5~0.8份、氧化锌12~28份、甘油1~4.5份、环氧大豆油0.5~0.8份、稳定剂0.5~2.5份、增塑剂13~30份、石墨1.5~8.5份、石墨烯1.5~8.5份、聚乙烯吡咯烷酮8~13份、微精蜡55~80份、硬脂酸0.25~0.45份、钛白粉12~20份、碳酸钙11~18份、高岭土8~10份、滑石粉5~10份、白蜡油3~12份、铝粉5~10份、锌粉5~8份、云母云8~22份、二氧化硅8~22份、三氧化锑5~10、磷铁锌硅粉5~10份、磷铁粉5~10份、UV吸收剂0.15~0.45份以及消泡剂0.15~0.45份。在上述比例下制备形成的复合材料液2,其防水、防腐以及阻燃性能更佳。
更为优选地,在本发明的较佳实施例中,按照重量份数计,复合材料液2的原料包括:聚乙烯蜡18份、石蜡75份、月桂酸0.6份、氧化锌20份、甘油3.5份、环氧大豆油0.6份、稳定剂1.6份、增塑剂27份、石墨6份、石墨烯6.5份、聚乙烯吡咯烷酮10份、微精蜡75份、硬脂酸0.35份、钛白粉18份、碳酸钙16份、高岭土8份、滑石粉8份、白蜡油7份、铝粉7份、锌粉7份、云母云12份、二氧化硅12份、三氧化锑6份、磷铁锌硅粉6份、磷铁粉6份、UV吸收剂0.25份以及消泡剂0.25份。在上述比例下,所制备形成的复合材料液2其防水、防腐以及阻燃性能最佳。在上述比例下的石墨烯,其不易团聚,且其丰富的含氧基团能够调节复合材料中的分散性能,从而提高精蜡带的拉伸强度、断裂伸长率以及抗渗性等。
进一步地,柔性载体1为聚丙烯纤维、聚丙烯腈纤维、聚乙烯纤维或者聚酯化学纤维制成的无纺布。无纺布作为精蜡带的骨架,为精蜡带形成良好的支撑,保证制备得到的精蜡带具有一定的厚度,该厚度不仅可以保证防水、防腐性能,也可避免精蜡带像防腐涂料一样不易固定包裹在建筑物或者机械设备上。
更为优选地,柔性载体1为聚丙烯纤维制成的无纺布。聚丙烯纤维质轻,且具备强度高、弹性好、耐磨、耐腐蚀特性,进一步提高了精蜡带的可拉伸性能以及抗断裂性。
进一步地,聚丙烯纤维、聚丙烯腈纤维、聚乙烯纤维或者聚酯化学纤维的单丝为2D~6D,柔性载体1的拉力强度为50~100kN/m,拉伸率小于30%。以上述条件制备成的无纺布,强度高,弹性好,进一步提高了精蜡带的可拉伸性能以及抗断裂性。
进一步地,柔性载体1的厚度为0.1~0.4mm、宽度为1~30英寸、強度为100~400g/㎡。确保柔性载体1具备一定厚度包裹在建筑物或者机械设备上,更好地起到防水防腐、阻燃效果。而具备一定的宽度则可以对建筑物或者机械设备进行包覆,避免需要包裹位置的缺失,也可对精蜡带进行裁剪,更适配于包裹物。柔性载体1的强度则进一步确保了精蜡带不易断裂。
进一步地,石墨烯为氧化型石墨烯和天然型石墨烯的一种或多种。
更为优选地,石墨烯中氧化型石墨烯与天然型石墨烯的质量比为1:1~2。更为优选地,石墨烯中氧化型石墨烯与天然型石墨烯的质量比为1:1.3。氧化型石墨烯的防水、防腐和阻燃性能优于天然型石墨烯。但氧化型石墨烯的表面有大量的官能团,如羧基、羟基、环氧基,这使其与其他的有机物易于反应和易于发生团聚,而天然型石墨烯则没有这么多官能团,不易发生团聚,将天然型石墨烯掺杂在氧化石墨中,可以阻止氧化型石墨烯的团聚,让氧化型石墨烯所具备的良好的防水、防腐和阻燃性能能够更好的发挥。
进一步地,精蜡带的耐高温范围为50~250℃。可通过改变精蜡的含量来改变精蜡带的耐温范围。可将精蜡带分为一般型,其耐高温范围为50~65℃;中温型,其耐高温范围为80~125℃;高温型,其耐高温范围为125~250℃。
本发明还提供了一种上述的基于纳米石墨烯的精蜡带的制备方法,包括以下步骤:
S1,制备复合材料液2。
进一步地,复合材料液2的制备过程包括以下步骤:
S11,按照原料之间的配比,将聚乙烯蜡、石蜡、月桂酸、甘油、环氧大豆油、稳定剂、增塑剂、聚乙烯吡咯烷酮、微精蜡、硬脂酸、白蜡油于于150~200℃的温度下进行混合加热45~75min直至完全熔融,获得初制混合液。先将精蜡进行溶解,形成液体,便于后续石墨烯进行分散。
S12,在初制混合液中加入石墨及石墨烯直至完全熔融。确保石墨及石墨烯在混合液中分散均匀,在初制混合液中形成石墨烯的片层结构,从而确保石墨烯的防水、防腐和阻燃性能。
S13,再加入氧化锌、钛白粉、碳酸钙、高岭土、滑石粉、铝粉、锌粉、云母云、二氧化硅、三氧化锑、磷铁锌硅粉、磷铁粉继续混练30~60min分钟。确保填料加进去后可以混合在石墨性形成的片层结构中,不仅可以填补石墨烯之间的空隙,还可以改善精蜡带的性能。
S14,最后加入UV吸收剂以及消泡剂再熔融10~30min分钟后,静置2h,获得复合材料液2。UV吸收剂会降低复合材料液2的交联密度,因此不宜过早放入。而消泡剂作为表面活性剂,同样会改变成分间的交联程度。
S2,将柔性载体1裁剪成合适尺寸后,在90~150℃条件下,将柔性载体1浸渍在复合材料液2中0.5~2min,获得预制体。
S3,将预制体通过压严、干燥步骤后,卷成圆形获得精蜡带。
具体地,如图2所示,将柔性载体1裁剪成合适尺寸后,放在三滚轮机上,通过滚轮的作用将柔性载体1送入具有复合材料液2的原料槽内,在复合材料液2中浸渍0.5~2min后,再次通过另一台三滚轮机将预制体从原料槽内带出,并通过滚轮的作用对预制体进行压严,进一步减少制备成的精蜡带的缝隙,提高防水防腐性能。可通过多次浸渍、压严步骤调整精蜡带的厚度,其厚度范围为0.1mm~1mm,而后干燥后进行卷曲从而制成精蜡带。
本发明提供的一种基于纳米石墨烯的精蜡带及其制备方法,将石墨烯运用在防腐蚀领域,其优越的阻隔性,优良的化学稳定性能,超大笔表面积对建筑物以及金属部件的防腐蚀有非常大的改善。而本发明还将天然型及氧化型石墨烯与无纺布进行复合材料的制备,大大提升石墨烯应用领域,本发明提供的精蜡带产品如图3所示,其可运用于风电、火电、热电、核电、石化储罐、燃气、管线阀门等领域,解决了目前传统的石墨烯涂料所无法达到对金属部件附着力、耐磨性、防腐蚀性、防水性、环保、安全、无二次污染等问题。
实施例1
本发明提供了一种基于纳米石墨烯的精蜡带,其包括由聚丙烯纤维制备形成的柔性载体以及复合材料液,其中,按照重量份数计,复合材料液包括:聚乙烯蜡18份、石蜡75份、月桂酸0.6份、氧化锌20份、甘油3.5份、环氧大豆油0.6份、稳定剂1.6份、增塑剂27份、石墨6份、石墨烯6.5份、聚乙烯吡咯烷酮10份、微精蜡75份、硬脂酸0.35份、钛白粉18份、碳酸钙16份、高岭土8份、滑石粉8份、白蜡油7份、铝粉7份、锌粉7份、云母云12份、二氧化硅12份、三氧化锑6份、磷铁锌硅粉6份、磷铁粉6份、UV吸收剂0.25份以及消泡剂0.25份。
基于纳米石墨烯的精蜡带其按照以下步骤制备:
(1)制备复合材料液:将聚乙烯蜡、石蜡、月桂酸、甘油、环氧大豆油、稳定剂、增塑剂、聚乙烯吡咯烷酮、微精蜡、硬脂酸、白蜡油于于175℃的温度下进行混合加热60min直至完全熔融,获得初制混合液;在初制混合液中加入石墨及石墨烯直至完全熔融;再加入氧化锌、钛白粉、碳酸钙、高岭土、滑石粉、铝粉、锌粉、云母云、二氧化硅、三氧化锑、磷铁锌硅粉、磷铁粉继续混练40min分钟;
(2)将柔性载体裁剪成厚度为0.2mm,宽度为25英寸的尺寸后,在100℃条件下,将柔性载体浸渍在复合材料液中1min,获得预制体;
(3)将预制体通过压严、干燥步骤后,卷成圆形获得精蜡带,其中,精蜡带的厚度为0.4mm,宽度为25英寸。
经测量,本实施例提的基于纳米石墨烯的精蜡带具有以下特性:
1.物理特性:施作温度:-20℃~65℃;使用温度-45℃~65℃。
2.化学特性:耐盐雾、抗紫外钱、抗化学性、潮湿等侵蚀。
盐雾测试:ASTM B117 1000Hr以上;
抗紫外线:ASTM B154 1000Hr以上;
抗化学性:ASTM G20 1,000Hr以上
3.其他性能:
介电强度:≥170Volt/mil(ASTM D149);
断裂强度:≥3,940N/m(ASTM D1000);
破坏延伸率:≥6%(ASTM D1000);
闪火点:≥150℃(ASTM D92);
水气渗透率:≤0.25Perms(ASTM E96);
水气渗透率:≤7.5g/㎡/day(ASTM D1653);
吸水率:小于5%(ASTM D570);
耐水性:38℃,24h,目视外观无变色起泡及光泽改变(ASTM D870);
安全环保:符合REACH法规(2015.12.17正式公告168项)
燃烧试验:燃烧速率为0(mm/min)(ASTM D635~10)
实施例2
本发明提供了一种基于纳米石墨烯的精蜡带,其包括由聚乙稀纤维制备形成的柔性载体以及复合材料液,其中,按照重量份数计,复合材料液包括:聚乙烯蜡7份、石蜡85份、月桂酸0.5份、氧化锌12份、甘油4.5份、环氧大豆油0.5份、稳定剂0.5份、增塑剂30份、石墨5.5份、石墨烯5.5份、聚乙烯吡咯烷酮8份、微精蜡55份、硬脂酸0.25份、钛白粉12份、碳酸钙11份、高岭土8份、滑石粉5份、白蜡油3份、铝粉5份、锌粉5份、云母云8份、二氧化硅8份、三氧化锑5份、磷铁锌硅粉5份、磷铁粉5份、UV吸收剂0.15份以及消泡剂0.15份。
按照实施例1中的制备步骤将上述原料制成基于纳米石墨烯的精蜡带。
实施例3
本发明提供了一种基于纳米石墨烯的精蜡带,其包括由聚乙稀纤维制备形成的柔性载体以及复合材料液,其中,按照重量份数计,复合材料液包括:聚乙烯蜡25份、石蜡55份、月桂酸0.8份、氧化锌28份、甘油1份、环氧大豆油0.8份、稳定剂2.5份、增塑剂13份、石墨8.5份、石墨烯8.5份、聚乙烯吡咯烷酮13份、微精蜡80份、硬脂酸0.45份、钛白粉20份、碳酸钙18份、高岭土10份、滑石粉10份、白蜡油12份、铝粉10份、锌粉8份、云母云22份、二氧化硅22份、三氧化锑10份、磷铁锌硅粉10份、磷铁粉10份、UV吸收剂0.45份以及消泡剂0.45份。
按照实施例1中的制备步骤将上述原料制成基于纳米石墨烯的精蜡带。
以上所描述的实施例是本发明一部分实施例,而不是全部的实施例。本发明的实施例的详细描述并非旨在限制要求保护的本发明的范围,而是仅仅表示本发明的选定实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
Claims (9)
1.一种基于纳米石墨烯的精蜡带,其特征在于,所述精蜡带由柔性载体浸渍在复合材料液中一定时间后,干燥、卷曲后形成的卷材;
其中,按照重量份数计,所述复合材料液的原料包括:聚乙烯蜡5~30份、石蜡50~90份、月桂酸0.2~1份、氧化锌10~30份、甘油0.5~5份、环氧大豆油0.2~1份、稳定剂0.2~3份、增塑剂10~40份、石墨1~10份、石墨烯1~10份、聚乙烯吡咯烷酮5~15份、微精蜡40~85份、硬脂酸0.2~0.5份、钛白粉10~25份、碳酸钙10~20份、高岭土5~15份、滑石粉3~13份、白蜡油1~15份、铝粉3~15份、锌粉2~10份、云母云5~25份、二氧化硅5~25份、三氧化锑2~15、磷铁锌硅粉2~15份、磷铁粉2~15份、UV吸收剂0.1~0.5份、消泡剂0.1~0.5份。
2.根据权利要求1所述的基于纳米石墨烯的精蜡带,其特征在于,按照重量份数计,所述复合材料液的原料包括:
所述聚乙烯蜡7~25份、所述石蜡55~85份、所述月桂酸0.5~0.8份、所述氧化锌12~28份、所述甘油1~4.5份、所述环氧大豆油0.5~0.8份、所述稳定剂0.5~2.5份、所述增塑剂13~30份、所述石墨1.5~8.5份、所述石墨烯1.5~8.5份、所述聚乙烯吡咯烷酮8~13份、所述微精蜡55~80份、所述硬脂酸0.25~0.45份、所述钛白粉12~20份、所述碳酸钙11~18份、所述高岭土8~10份、所述滑石粉5~10份、所述白蜡油3~12份、所述铝粉5~10份、所述锌粉5~8份、所述云母云8~22份、二氧化硅8~22份、所述三氧化锑5~10、所述磷铁锌硅粉5~10份、所述磷铁粉5~10份、所述UV吸收剂0.15~0.45份以及所述消泡剂0.15~0.45份。
3.根据权利要求1所述的基于纳米石墨烯的精蜡带,其特征在于,所述柔性载体为聚丙烯纤维、聚丙烯腈纤维、聚乙烯纤维或者聚酯化学纤维制成的无纺布。
4.根据权利要求3所述的基于纳米石墨烯的精蜡带,其特征在于,所述聚丙烯纤维、聚丙烯腈纤维、聚乙烯纤维或者聚酯化学纤维的单丝为2D~6D,所述柔性载体的拉力强度为50~100kN/m,拉伸率小于30%。
5.根据权利要求1所述的基于纳米石墨烯的精蜡带,其特征在于,所述柔性载体的厚度为0.1~0.4mm、宽度为1~30英寸、強度为100~400g/㎡。
6.根据权利要求1所述的基于纳米石墨烯的精蜡带,其特征在于,所述石墨烯为氧化型石墨烯和天然型石墨烯的一种或多种。
7.根据权利要求1所述的基于纳米石墨烯的精蜡带,其特征在于,所述精蜡带的耐高温范围为50~250℃。
8.一种如1~7任意一项所述的基于纳米石墨烯的精蜡带的制备方法,其特征在于,包括以下步骤:
S1,制备复合材料液;
S2,将柔性载体裁剪成合适尺寸后,在90~150℃条件下,将所述柔性载体浸渍在所述复合材料液中0.5~2min,获得预制体;
S3,将所述预制体通过压严、干燥步骤后,卷成圆形获得所述精蜡带。
9.根据权利要求8所述的基于纳米石墨烯的精蜡带的制备方法,其特征在于,所述复合材料液的制备过程包括以下步骤:
S11,按照原料之间的配比,将聚乙烯蜡、石蜡、月桂酸、甘油、环氧大豆油、稳定剂、增塑剂、聚乙烯吡咯烷酮、微精蜡、硬脂酸、白蜡油于于150~200℃的温度下进行混合加热45~75min直至完全熔融,获得初制混合液;
S12,在所述初制混合液中加入石墨及石墨烯直至完全熔融;
S13,再加入氧化锌、钛白粉、碳酸钙、高岭土、滑石粉、铝粉、锌粉、云母云、二氧化硅、三氧化锑、磷铁锌硅粉、磷铁粉继续混练30~60min分钟;
S14,最后加入UV吸收剂以及消泡剂再熔融10~30min分钟后,静置2h,获得所述复合材料液。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910953969.3A CN110820319A (zh) | 2019-10-09 | 2019-10-09 | 一种基于纳米石墨烯的精蜡带及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910953969.3A CN110820319A (zh) | 2019-10-09 | 2019-10-09 | 一种基于纳米石墨烯的精蜡带及其制备方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN110820319A true CN110820319A (zh) | 2020-02-21 |
Family
ID=69548795
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201910953969.3A Pending CN110820319A (zh) | 2019-10-09 | 2019-10-09 | 一种基于纳米石墨烯的精蜡带及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN110820319A (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113292864A (zh) * | 2021-06-16 | 2021-08-24 | 辽宁东科新材料有限公司 | 一种石墨烯橡胶防护蜡 |
TWI805270B (zh) * | 2022-03-11 | 2023-06-11 | 大陸商辰港(泉州)科技有限公司 | 基於奈米石墨烯之精蠟帶及其製備方法 |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030220205A1 (en) * | 2002-05-23 | 2003-11-27 | Manka John S. | Emulsified based lubricants |
US20110095244A1 (en) * | 2008-06-30 | 2011-04-28 | Dow Global Technologies, Inc. | Polymer composite with intumescent graphene |
CN102604511A (zh) * | 2012-03-05 | 2012-07-25 | 大连理工大学 | 一种高固体份省工型涂料 |
CN105086682A (zh) * | 2014-10-30 | 2015-11-25 | 合肥蓝天家具制造有限责任公司 | 一种石墨烯防腐涂料 |
CN105131679A (zh) * | 2015-10-26 | 2015-12-09 | 王秋芹 | 一种石墨烯防腐涂料及其制备方法 |
CN106633268A (zh) * | 2015-07-23 | 2017-05-10 | 斯耐克(天津)防腐科技有限公司 | 一种耐高温精蜡防腐材料 |
CN108395785A (zh) * | 2018-03-29 | 2018-08-14 | 合肥励仙电力工程有限公司 | 一种电力设备表层用防腐涂料及其制备方法 |
CN109337517A (zh) * | 2018-10-09 | 2019-02-15 | 福建师范大学福清分校 | 一种石墨烯基防腐涂料 |
CN109554163A (zh) * | 2018-12-30 | 2019-04-02 | 柳州豪祥特科技有限公司 | 一种车用石墨烯材料 |
CN109608966A (zh) * | 2018-12-11 | 2019-04-12 | 四川省安德盖姆石墨烯科技有限公司 | 一种石墨烯防腐涂料 |
-
2019
- 2019-10-09 CN CN201910953969.3A patent/CN110820319A/zh active Pending
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030220205A1 (en) * | 2002-05-23 | 2003-11-27 | Manka John S. | Emulsified based lubricants |
US20110095244A1 (en) * | 2008-06-30 | 2011-04-28 | Dow Global Technologies, Inc. | Polymer composite with intumescent graphene |
CN102604511A (zh) * | 2012-03-05 | 2012-07-25 | 大连理工大学 | 一种高固体份省工型涂料 |
CN105086682A (zh) * | 2014-10-30 | 2015-11-25 | 合肥蓝天家具制造有限责任公司 | 一种石墨烯防腐涂料 |
CN106633268A (zh) * | 2015-07-23 | 2017-05-10 | 斯耐克(天津)防腐科技有限公司 | 一种耐高温精蜡防腐材料 |
CN105131679A (zh) * | 2015-10-26 | 2015-12-09 | 王秋芹 | 一种石墨烯防腐涂料及其制备方法 |
CN108395785A (zh) * | 2018-03-29 | 2018-08-14 | 合肥励仙电力工程有限公司 | 一种电力设备表层用防腐涂料及其制备方法 |
CN109337517A (zh) * | 2018-10-09 | 2019-02-15 | 福建师范大学福清分校 | 一种石墨烯基防腐涂料 |
CN109608966A (zh) * | 2018-12-11 | 2019-04-12 | 四川省安德盖姆石墨烯科技有限公司 | 一种石墨烯防腐涂料 |
CN109554163A (zh) * | 2018-12-30 | 2019-04-02 | 柳州豪祥特科技有限公司 | 一种车用石墨烯材料 |
Non-Patent Citations (2)
Title |
---|
李沙等: "海上油田飞溅区海管立管防腐工艺", 《化工设计通讯》 * |
魏远娟等: "精蜡防腐技术及应用", 《化工管理》 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113292864A (zh) * | 2021-06-16 | 2021-08-24 | 辽宁东科新材料有限公司 | 一种石墨烯橡胶防护蜡 |
CN113292864B (zh) * | 2021-06-16 | 2022-03-29 | 辽宁东科新材料有限公司 | 一种石墨烯橡胶防护蜡 |
TWI805270B (zh) * | 2022-03-11 | 2023-06-11 | 大陸商辰港(泉州)科技有限公司 | 基於奈米石墨烯之精蠟帶及其製備方法 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN110820319A (zh) | 一种基于纳米石墨烯的精蜡带及其制备方法 | |
JP3232713U (ja) | 橋梁ケーブル保護用複合シース | |
CN110294901A (zh) | 一种耐腐蚀零收缩阻燃电缆材料 | |
CN105086723A (zh) | 一种建筑物防火涂料 | |
CN202205484U (zh) | 环保安全型阻水防火电缆 | |
CN103045030A (zh) | 一种防水涂料 | |
CN103756089A (zh) | 一种光伏电缆用无卤阻燃绝缘料 | |
CN103641502A (zh) | 一种纳米型耐火材料 | |
CN105199181A (zh) | 一种轻质阻燃热塑性聚烯烃防水卷材及其制备方法 | |
CN110156926A (zh) | 低密度发泡水凝胶垫及其制备方法、灭火装置 | |
CN104139564A (zh) | 一种高分子聚乙烯丙纶复合防水卷材 | |
CN116714327A (zh) | 一种屋面用节碳阻燃防水卷材及其制备方法 | |
TWI805270B (zh) | 基於奈米石墨烯之精蠟帶及其製備方法 | |
CN106674708A (zh) | 低烟无卤陶瓷化聚烯烃耐火绝缘料及其制备方法 | |
CN107471764A (zh) | 自清洁阻燃自粘改性沥青防水卷材 | |
CN215096169U (zh) | 一种镀铝pe膜自粘聚合物改性沥青防水卷材 | |
CN112109397A (zh) | 一种阻燃型sbs改性沥青防水卷材及其制备方法 | |
CN212925780U (zh) | 一种桥梁缆索用防护织物 | |
CN108691224A (zh) | 一种阻燃缆绳 | |
CN103204657B (zh) | 一种复合软材及其制作方法 | |
CN113152280A (zh) | 一种具有防水、阻燃、耐候性能的桥梁缆索 | |
CN202917232U (zh) | 电线 | |
CN213012664U (zh) | 一种阻燃型改性沥青防水卷材 | |
CN202805785U (zh) | 一种阻燃自粘型防水卷材 | |
CN107901538A (zh) | 高分子自粘防水卷材及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20211102 Address after: 362200 room 1025, complex building, No. 29, Yuandong Road, Jinjiang Economic Development Zone (An Dong Yuan), Quanzhou City, Fujian Province Applicant after: Chengang (Quanzhou) Technology Co.,Ltd. Address before: 361000 unit 1001-11, No. 808, Lianting Road, Xiang'an District, Xiamen City, Fujian Province Applicant before: Fangang (Xiamen) Technology Co.,Ltd. |
|
TA01 | Transfer of patent application right |